Two kinds of water-soluble and ultraviolet (UV) curable oligomers were synthesized and characterized. The oligomers were evaluated as resins for water-based UV curable coating. The rheology of the two oligomers' a...Two kinds of water-soluble and ultraviolet (UV) curable oligomers were synthesized and characterized. The oligomers were evaluated as resins for water-based UV curable coating. The rheology of the two oligomers' aqueous so-lutions was investigated in terms of solid fraction, pH dependence, and temperature dependence. The solutions were found to be Newtonian fluid showing rather low viscosity even at high solid fraction of 0.55. The drying process of the coatings and the properties of the cured coatings were studied by comparing them with water-dispersed UV-curable polyurethane methyl acrylate. It was evident that the water-soluble coating dried more slowly; and that the overall properties were inferior to those of the water-dispersed coating.展开更多
Among the intrinsically conductive polymers, polyanilines have been of great interest in the past decades due to their wide applications in many fields, thanks to their reasonably good conductivity, easy preparation, ...Among the intrinsically conductive polymers, polyanilines have been of great interest in the past decades due to their wide applications in many fields, thanks to their reasonably good conductivity, easy preparation, and special redox properties. Ever-increasing environmental corsiderations make the processing of polyanilines shift from toxic organic solvent-based system to eco-friendly water-based system. The present paper reviews the synthesis of water-borne conducting polyanilines, and possible applications are discussed including supercapacitor electrode material, metal free corrosion protection coating, lithium oxygen battery cathode material and ultraviolet curable resin.展开更多
文摘Two kinds of water-soluble and ultraviolet (UV) curable oligomers were synthesized and characterized. The oligomers were evaluated as resins for water-based UV curable coating. The rheology of the two oligomers' aqueous so-lutions was investigated in terms of solid fraction, pH dependence, and temperature dependence. The solutions were found to be Newtonian fluid showing rather low viscosity even at high solid fraction of 0.55. The drying process of the coatings and the properties of the cured coatings were studied by comparing them with water-dispersed UV-curable polyurethane methyl acrylate. It was evident that the water-soluble coating dried more slowly; and that the overall properties were inferior to those of the water-dispersed coating.
基金supported by the National Natural Science Foundation of China (Nos. 51073156 and 51021003)Program of Scientific Development of Jilin Province (No. 20116024)
文摘Among the intrinsically conductive polymers, polyanilines have been of great interest in the past decades due to their wide applications in many fields, thanks to their reasonably good conductivity, easy preparation, and special redox properties. Ever-increasing environmental corsiderations make the processing of polyanilines shift from toxic organic solvent-based system to eco-friendly water-based system. The present paper reviews the synthesis of water-borne conducting polyanilines, and possible applications are discussed including supercapacitor electrode material, metal free corrosion protection coating, lithium oxygen battery cathode material and ultraviolet curable resin.
