Re-recognition of “unconventional” in unconventional oil and gas

Taking the Wufeng–Longmaxi shale gas in the Sichuan Basin as a typical example,based on the new progress in exploration and development,this study re-examines the"unconventional"of unconventional oil and gas from two aspects:oil and gas formation and accumulation mechanisms,and main features of oil and gas layers.The oil and gas of continuous accumulation and distribution from integrated source and reservoir is unconventional oil and gas,and the study focusing on shale oil and gas in comparison with conventional oil and gas has made progress in five aspects:(1)Unconventional oil and gas have source-reservoir-in-one and in-situ accumulation;according to the theory of continuous oil and gas accumulation,the accumulation power of oil and gas is overpressure and diffusion;for conventional oil and gas,the source and reservoir are different formations,the trapping accumulation is its theoretical foundation,and the accumulation power is characterized by buoyancy and capillary force.(2)The unconventional oil and gas reservoirs are mainly formed in the low-energy oxygen-anaerobic environment,dominantly semi-deep to deep shelf facies and the semi-deep to deep lake facies,simple in lithology,rich in organic matter and clay minerals;conventional oil and gas mainly occur in coarse-grained sedimentary rocks formed in high-energy waters with complex lithology.(3)The unconventional oil and gas reservoirs have mainly nano-scale pores,of which organic matter pores take a considerable proportion;conventional oil and gas reservoirs mainly have micron-millimeter pores and no organic matter pores.(4)Unconventional shale oil and gas reservoirs have oil and gas in uniform distribution,high oil and gas saturation,low or no water content,and no obvious oil and gas water boundary;conventional oil and gas reservoirs have oil and gas of complex properties,moderate oil and gas saturation,slightly higher water content,and obvious oil,gas and water boundaries.(5)Organic-rich shale is the main target of unconventional oil and gas exploration;the sedimentary environment controls high organic matter abundance zone and organic matter content controls oil and gas abundance;positive structure and high porosity control the yields of shale wells;bedding and fracture development are important factors deciding high yield.

Unconventional Geochemical Exploration for Gold Deposits

Conventional geochemical exploration for gold deposits has not always been very satisfactory, especially for buried and blind ones. New considerations and methodology in sampling, analysis and interpretation have been developed in China during the past decade. Important considerations for unconventional gold exploration in this paper are that (1) gold is active in surface environments; (2) gold occurs not only as discrete grains, but also as ultrafine particles (submicron?to nanometer-sized particles of gold) and other complex forms; (3) regional low anomalies and superimposed anomalies over buried gold deposits are produced by ultrafine gold grains and other complex forms of gold. The methodology based on these considerations has been developed both in regional and in local geochemical exploration for gold. Examples of the preliminary application of these methods in two areas covered by transported overburden are given.

An aqueous BiI_(3)-Zn battery with dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox

The development of aqueous battery with dual mechanisms is now arousing more and more interest.The dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox bring unexpected effects.Herein,differing from previous studies using Zn I_(2)additive,this work designs an aqueous Bi I_(3)-Zn battery with selfsupplied I^(-).Ex situ tests reveal the conversion of Bi I_(3)into Bi(discharge)and Bi OI(charge)at the 1st cycle and the dissolved I^(-)in electrolyte.The active I^(-)species enhances the specific capacity and discharge medium voltage of electrode as well as improves the generation of Zn dendrite and by-product.Furthermore,the porous hard carbon is introduced to enhance the electronic/ionic conductivity and adsorb iodine species,proven by experimental and theoretical studies.Accordingly,the well-designed Bi I_(3)-Zn battery delivers a high reversible capacity of 182 m A h g^(-1)at 0.2 A g^(-1),an excellent rate capability with 88 m A h g^(-1)at 10 A g^(-1),and an impressive cyclability with 63%capacity retention over 20 K cycles at 10 A g^(-1).An excellent electrochemical performance is obtained even at a high mass loading of 6 mg cm^(-2).Moreover,a flexible quasi-solid-state Bi I_(3)-Zn battery exhibits satisfactory battery performances.This work provides a new idea for designing high-performance aqueous battery with dual mechanisms.

Characterization of Cd1-xZnxTe（0≤x≤1） Nanolayers Grown by Atomic Layer Deposition on GaSb and GaAs（001） Oriented Substrates

ZnTe, CdTe, and the ternary alloy CdZnTe are important semiconductor materials used widely for the detection of an important range of electromagnetic radiation as gamma ray and X-ray. Although, recently these materials have acquired renewed importance due to the new explored nanolayer properties of modern devices. In addition, as shown in this work they can be grown using uncomplicated synthesis techniques based on the deposition in vapour phase of the elemental precursors. This work presents the results obtained from the deposition of nanolayers of these materials using the precursor vapour on GaAs and GaSb (001) substrates. This growth technique, extensively known as atomic layer deposition (ALD), allows the layers growth with nanometric dimension. The main results presented in this work are the used growth parameters and the results of the structural characterization of the layers by the means of Raman spectroscopy measurements. Raman scattering shows the peak corresponding to longitudinal optical (LO)-ZnTe, which is weak and slightly redshift in comparison with that reported for the ZnTe bulk at 210 cm^-1. For the case of the CdTe nanolayer, Raman spectra presented the LO-CdTe peak, which is indicative of the successful growth of the layer. Its weak and slightly redshift in comparison with that reported for the CdTe bulk can be related with the nanometric characteristic of this layer. The performed high-resolution X-ray diffraction (HR-XRD) measurement allows to study some important characteristics such as the crystallinity of the grown layer. In addition, the HR-XRD measurement suggests that the crystalline quality has dependence on the growth temperature.

The Dust Comportment in the Latitudinal Band 10°North - 20°North in Africa: Emission and Deposition

The three measurement periods: the TOMS Nimbus-7 TOMSN7L3 v008 from 1978 to 1993, the TOMS EP TOMSEPL3 v008 from 1996 to 2005 and the OMI OMTO3d v003 from 2004 to 2008 have allowed the presence of dust to be observed in the 10°North to 20°North latitudinal band (10 - 20 band) of Africa. The 10 - 20 band has a permanent dust presence. The AERONET data show AOD peaks exceeding 2 in Senegal and Niger (on an AOD scale). The statistical study reveals intra-annual relationships in deposition. In Senegal, a significant deposition is observed.

Re–Os dating of molybdenite and in-situ Pb isotopes of sulfides from the Lamo Zn–Cu deposit in the Dachang tin-polymetallic ore field, Guangxi, China

The Dachang tin-polymetallic district, Guangxi,China, is one of the largest tin ore fields in the world. Both cassiterite-sulfide and Zn–Cu skarn mineralization are hosted in the Mid-Upper Devonian carbonate-rich sediments adjacent to the underlying Cretaceous Longxianggai granite(91–97 Ma). The Lamo Zn–Cu deposit is a typical skarn deposit in the district and occurs at the contact zone between the Upper Devonian limestone and the granite.The ore minerals mainly consist of sphalerite, arsenopyrite,pyrrhotite, galena, chalcopyrite, and minor molybdenite.However, the age of mineralization and source of the metals are not well constrained. In this study, we use the molybdenite Re–Os dating method and in-situ Pb isotopes of sulfides from the Lamo deposit for the first time in order to directly determine the age of mineralization and the tracing source of metals. Six molybdenite samples yielded a more accurate Re–Os isochron age of 90.0 ± 1.1 Ma(MSWD = 0.72), which is much younger than the reported garnet Sm–Nd isochron age of 95 ± 11 Ma and quartz fluid inclusions Rb–Sr isochron age of 99 ± 6 Ma. This age is also interpreted as the age of Zn–Cu skarn mineralization in the Dachang district. Further, in this study we found that in-situ Pb isotopes of sulfides from the Lamo deposit and feldspars in the district's biotite granite and granitic porphyry dikes have a narrow range and an overlap of Pb isotopic compositions(^(206) Pb/^(204) Pb =18.417–18.594,^(207) Pb/^(204) Pb = 15.641–15.746, and^(208) Pb/^(204) Pb = 38.791–39.073), suggesting that the metals were mainly sourced from Cretaceous granitic magma.

Coordinated Exploration Model and its Application to Coal and Coal-associated Deposits in Coal Basins of China

China is a top world producer of coal resources with numerous coal-rich basins country-wide that also contain coalbed methane(CBM),an unconventional natural gas resource.Recent exploration of coal and CBM resources has also led to the discovery of rare,precious,and scattered metal minerals,including sandstone-type U and Ga–Ge–Li.High-grade and industrial-value deposits have been discovered in the Ordos,Junggar,and other basins across China during exploration for coal resources.Application of coordinated exploration theories and techniques in multiple energy and coal-associated ore deposits,such as coal and unconventional natural gas in coal,achieves efficient and practical exploration of natural resources.Based on the systematic study of accumulation and occurrence of coal and coal-associated mineral resources in coal basins,the basic idea of coordinated exploration for coal and coal-associated deposits is proposed,and multi-targets and multi-methods based on a coordinated exploration model of coal-associated deposits is developed.Coordinated exploration expands the main exploration objective from coal seams to coal-associated series,extending the exploration target from targeting coal only to coal-associated deposits.Entrance times for exploration are decreased to realize coordinated exploration for coal,unconventional natural gas and syngenetic/associated mineral resources in coal by implementing a’one-time approach’―one time in and out of a coal seam to minimize disturbance and time needed for extraction.According to the differences of geological background in China’s coal basins,four coordinated exploration model types,including co-exploration of coal and coal-associated unconventional natural gas,coal and solid minerals,coal and metal minerals,and coal with water resources are established.Other models discussed include a multi-target coordinated exploration model for the combination of coal,coal-associated gas,solid minerals,and metal minerals accordingly.The exploration techniques of coal and coal-associated resources include regional geological investigation and research and synthetic application of other techniques including seismic surveys,drilling,logging,and geochemical exploration.Particularly,applying the’multi-purpose drill hole’or reworking coalfield drill holes into parameter wells,adding sample testing and logging wells,determining gas-bearing layers by logging and gas content measurement,jointly measuring multiple logging parameters,sampling,and testing of coal-strata help in the exploration and evaluation of coal resources,coal-associated unconventional natural gas resources,and coal-associated element minerals.Accordingly,a system of integrated Space–Air–Ground exploration techniques for coordinated exploration of coal and coal-associated minerals is established.This includes high-resolution,hyperspectral remote-sensing technique,high-precision geophysical exploration and fast,precise drilling,testing of experimental samples,as well as coordinated exploration and determination methods of multi-target factors,multi-exploration means,multi-parameter configuration and optimization,big data fusions and interpretation techniques.In recent years,the application of this integrated system has brought significant breakthroughs in coal exploration in Inner Mongolia,Xinjiang and other provinces,discovering several large,ten-billionton coalfields,such as the Eastern Junggar and Tuha basins,and also in exploration and development of CBM from lowrank coals in Fukang,Xinjiang,discovery the Daying U Deposit in Inner Mongolia,the Junggar Ultralarge Ga Deposit,Lincang,Yunnan,and the Wulantuga,Inner Mongolia,Ge-bearing coal deposits,and the Pingshuo Ultralarge Li–Ge Deposit.

Atmospheric Sulfur Deposition for a Red Soil Broadleaf Forest in Southern China

A two-year study in a typical red soil region of Southern China was conductedto determine 1) the dry deposition velocity (V_d) for SO_2 and particulate SO_4^(2-) above abroadleaf forest, and 2) atmospheric sulfur fluxes so as to estimate the contribution of variousfractions in the total. Using a resistance model based on continuous hourly meteorological data,atmospheric dry sulfur deposition in a forest was estimated according to V_d and concentrations ofboth atmospheric SO_2 and particulate SO_4^(2-). Meanwhile, wet S deposition was estimated based onrainfall and sulfate concentrations in the rainwater. Results showed that about 99% of the drysulfur deposition flux in the forest resulted from SO_2 dry deposition. In addition, the observeddry S deposition was greater in 2002 than in 2000 because of a higher average concentration of SO_2in 2002 than in 2000 and not because of the average dry deposition velocity which was lower for SO_2in 2002. Also, dry SO_2 deposition was the dominant fraction of deposited atmospheric sulfur inforests, contributing over 69% of the total annual sulfur deposition. Thus, dry SO_2 depositionshould be considered when estimating sulfur balance in forest ecological systems.

Effect of Multiple Thermal Cycles on Microstructure and Mechanical Properties of Cu Modified Ti64 Thin Wall Fabricated by Wire-Arc Directed Energy Deposition

This study investigated the effect of thermal cycles on Cu-modified Ti64 thin-walled components deposited using the wire-arc directed energy deposition(wire-arc DED)process.For the samples before and after experiencing thermal cycles,it was found that both microstructures consisted of priorβ,grain boundaryα(GBα),and basketweave structures containingα+βlamellae.Thermal cycles realized the refinement ofαlaths,the coarsening of priorβgrains andβlaths,while the size and morphology of continuously distributed GBαremained unchanged.The residualβcontent was increased after thermal cycles.Compared with the heat-treated sample with nanoscale Ti2Cu formed,short residence time in high temperature caused by the rapid cooling rate of thermal cycles restricted Ti2Cu formation.No formation of brittle Ti2Cu means that only grain refinement strengthening and solid-solution strengthening matter.The yield strength increased from 809.9 to 910.85 MPa(12.46%increase).Among them,the main contribution from solid solution strengthening(~51 MPa)was due to the elemental redistribution effect betweenαandβphases caused by thermal cycles through quantitative analysis.The ultimate tensile strength increased from 918.5 to 974.22 MPa(6.1%increase),while fracture elongation increased from 6.78 to 10.66%(57.23%increase).Grain refinement ofαlaths,the promotedα′martensite decomposition,decreased aspect ratio,decreased Schmid factor,and local misorientation change ofαlaths are the main factors in improved ductility.Additionally,although the fracture modes of the samples in the top and middle regions are both brittle-ductile mixed fracture mode,the thermal cycles still contributed to an improvement in tensile ductility.

Zircon U–Pb dating and whole-rock elemental geochemistry of the Shazi anatase deposit in Qinglong,Western Guizhou,SW China

The Shazi deposit is a large-scale anatase deposit in Qinglong, Guizhou Province. Zircon grains from this deposit yielded a zircon U–Pb age of *259 Ma, representing the formation age of the deposit's parent rocks.This age is identical to the eruption age of the Emeishan large igneous province, indicating a synchronous magmatic event. The rare-earth-element patterns of laterite samples were similar to those of the weathered basalt sample, and sub-parallel to those of the Emeishan high-Ti basalts,implying a genetic relationship between the laterite and the basalt. The Chemical Index of Alteration values of laterite ranged from 96 to 98, suggesting a high degree of weathering. SiO_2, MgO, and alkaline metal elements decreased with increasing degree of weathering, while Al_2O_3, Fe_2O_3,and TiO_2 increased. We found the highest TiO_2 in laterite and the lowest in pillow basalts, indicating that Ti migrated from basalt to laterite.Our U–Pb dating and whole-rock elemental geochemistry analyses suggest that the Emeishan basalt is the parent rock of the Shazi anatase ore deposit.Based on our analysis, we propose a metallogenic model to explain the ore-forming process, in which the karst terrain formed by the Emeishan mantle plume and the subsequent basaltic magma eruption were the key factors in the formation the Shazi anatase ore deposit.

The concept and the accumulation characteristics of unconventional hydrocarbon resources

Unconventional hydrocarbon resources, which are only marginally economically explored and developed by traditional methods and techniques, are different from conventional hydrocarbon resources in their accumulation mechanisms, occurrence states, distribution models, and exploration and development manners. The types of unconventional hydrocarbon are controlled by the evolu- tion of the source rocks and the combinations of different types of unconventional reservoirs. The fundamental dis- tinction between unconventional hydrocarbon resources and conventional hydrocarbon resources is their non- buoyancy-driven migration. The development of the micro- to nano-scale pores results in rather high capillary resis- tance. The accumulation mechanisms of the unconven- tional and the conventional hydrocarbon resources are also greatly different. In conventional hydrocarbon resources, oil and gas entrapment is controlled by reservoir-forming factors and geological events, which is a dynamic balance process; while for unconventional hydrocarbon resources, the gas content is affected by the temperature and pressure fields, and their preservation is crucial. Unconventional and conventional hydrocarbons are distributed in an orderly manner in subsurface space, having three distribution models of intra-source rock, basin-centered, and source rock interlayer. These results will be of great significance to unconventional hydrocarbon exploration.

The Evolutionary History of Ore-forming Processes of Metallic Ore Deposits in Northern Guangxi

The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian.

The Forming Conditions of and Ore-searching Direction for B, Mg,Pb, Zn and Au Deposits in the Liaoji Proterozoic Rift

The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These deposits were formed as the result of late mobilization, transportation and concentfation of the previously enriched ore-forming mate- rials in several ore-bearing formations formed during the rift stage. So the metallogeny of these deposits in the rift shows both inheritance and new generation of the ore-forming materials. In future ore-searching practice, attentions should be paid on the studies of the ore-bearing formations in the rift, on the multiple stages of metallogeny and and on multiple derivations of the ore-forming materials.

Solvents incubatedπ-πstacking in hole transport layer for perovskite-silicon 2-terminal tandem solar cells with 27.21%efficiency

Room temperature sputtered inorganic nickel oxide(NiO_(x))is one of the most promising hole transport layers(HTL)for perovskite-sillion 2-terminal tandem solar cells with the aid of ultrathin and compact organic layers to passivate the surface defects.In this study,the aromatic solvent with different substituent groups was used to regulate the conformation of poly[bis(4-phenyl)(2,4,6-trimethylphenyl)am ine](PTAA)layer.As a result,the single-junction perovskite solar cell(PSC)gained a power conversion efficiency(PCE)of 20.63%,contributing to a 27.21%efficiency for monolithic perovskite/silicon(double-side polished)2-terminal tandem solar cell,by applying the alkyl aromatic solvent to enhance theπ-πstacking of PTAA molecular chains.The tandem solar cell can maintain 95%initial efficiency after aging over 1000 h.This study provides a universal approach for improving the photovoltaic performance of NiO_(x)/polymer-based perovskite/silicon tandem solar cells and other single junction inverted PSCs.

湖盆细粒沉积岩纹层形成机制及影响因素研究进展

【意义】细粒沉积岩纹层是半深湖—深湖盆内地层中可分辨的、最基本的沉积单元结构,单层厚度一般小于10 mm,其物质组分、连续性和几何形态对于恢复古环境变迁和沉积模式具有重要的作用。伴随着非常规油气革命的发展,众多学者发现湖盆纹层种类丰富、形成机制复杂以及受控因素繁多,且对页岩油气富集、开发生产效果等方面产生重要影响,因此深化细粒沉积岩纹层结构研究可对非常规油气研究和应用提供指导意义。【进展】前人发现、识别、研究纹层成因的过程中分别厘定了黏土矿物纹层、长英质纹层、钙质纹层以及有机质纹层的成因机制,总结了不同环境条件下与优先发育纹层种类的耦合关系,阐述了单因素对纹层的控制作用,并认为细粒凝絮反应是纹层高水动力成因的解释理论,打破了纹层只能成因于静水条件下的连续悬浮沉降的常规认知。【结论与展望】湖盆纹层沉积过程的影响因素可归类为古气候因素、古地理条件、古地质事件和其他因素共四类,且不同影响因素在纹层沉积过程中可能发生相互促进或相互抑制的现象,不同因素组合主控纹层的物质成分、连续性、几何形体等特征。最后提出包含多因素组合作用下的纹层机理模型建立和利用完善模型对纹层状地层精准反演是未来主要的探究方向。

扇三角洲前缘非常规致密油储层裂缝发育模式:以泌阳凹陷东南部古近系核三段为例

泌阳凹陷东南部位于古湖盆短轴陡坡一侧,发育牵引流驱动的扇三角洲前缘复杂沉积体系,不同类型砂体中裂缝的定量刻画对非常规致密油勘探开发具有重要指导作用。该地区古近系核桃园组三段属典型的“凹中隆”背景下的扇三角洲前缘沉积,目前对于该类沉积及构造背景下的天然裂缝发育规律的认识仍存在不足。本文以该地区核三段从Ⅱ到Ⅵ砂组非常规陆相致密油储层为例,利用大量岩心、物性、常规、成像测井资料和数值模拟方法,系统研究了致密砂岩储层裂缝特征及分布规律,提出了该地区扇三角洲前缘非常规致密油储层裂缝发育模式。研究结果表明,岩性、砂体厚度、沉积作用和构造均对致密砂岩储层裂缝分布有显著的控制作用。薄层单砂体或其复合砂体中更容易发育裂缝,当单砂体厚度大于6 m时,砂体中裂缝通常相对欠发育。裂缝主要发育于水下分流河道前缘、侧向加积河道单翼、河口坝和远砂坝中。将河道类型划分为均质河道和非均质河道。侧向快速堆积形成的非对称型非均质河道中砂体叠置厚度较大,可超过18 m,裂缝较为发育;对于均质河道前缘,即靠近扇三角洲前缘河口坝微相区域,其在垂向上通常发育于靠近河口坝顶部的沉积序列中,代表较强的水动力条件,裂缝也较为发育。裂缝与油气聚集有密切的关系,工区核三段裂缝主要形成于新近系坳陷期。通过DFN离散裂缝模拟,恢复了主力小层裂缝三维空间展布。结果显示,核三段主要发育E-W和NE向两组共轭裂缝,且局部以发育其中一组为主,这些裂缝多平行或垂直于隆起构造痕线分布。天然裂缝在背斜低部位和翼部相比顶部更为发育。此外,多条共轭剪切缝相交或同走向一侧单翼裂缝相连接可形成“裂缝嵌合带”,其可能为压驱过程中长距离水窜产生的直接诱因,因而在后期压驱中要规避“裂缝嵌合带”。

鄂尔多斯盆地东缘可容纳空间变化控制的C-P煤系沉积特征

鄂尔多斯盆地东缘是国内煤系非常规天然气勘探开发的重点地区,区域范围广,沉积环境多变。结合野外露头、钻井岩芯、单井和连井剖面刻画了研究区构造隆降、海水进退、多向物源影响下的层序地层格架和沉积环境演变。结果表明:在统一研究区典型标志层的基础上,可将太原组分为4个和山西组3个III级层序;太原组主煤层顶面是区域范围内的构造转换面,南北地势近乎水平,之后中间地势进一步沉降;北部物源在太原期初始即发生影响,但南部物源到山西期才产生明显影响;研究区大致以北纬38°构造带为南北隆降支点,控制地层的厚度和岩性变化,影响厚煤带的迁移;太原期的汇水中心由南部逐渐向中部过渡,即由延川南(Sq1)到大宁—吉县(Sq2)到柳林石楼地区(Sq4),在Sq3沉积时期,海侵范围相对最大。相关成果对认识研究区含煤地层发育规律,开展煤系非常规天然气勘探开发具有支撑作用。

Fate of ^(15)N Labeled Nitrate and Ammonium Salts Added to an Alpine Meadow in the Qinghai-Xizang Plateau, China

To understand the dynamics of added nitrogen (N) in alpine meadow and the role of alpine plants and soil microorganisms in the retention of deposited N, the fate of 15 N labeled nitrate and ammonium salts was determined in an alpine meadow for two months. Two weeks after 15 N application, total recovery of 15 N from NO - 3_ 15 N was 73.5% while it was 78% from NH + 4_ 15 N. More 15 N was recovered in plants than in soil organic matter or in microbial biomass, irrespective of forms of N added. After one month, 70.6% of added NO - 3_ 15 N and 57.4% of NH + 4_ 15 N were recovered in soils and plants. 15 N recovered in soil organic matter decreased greatly while that recovered in plants varied little, irrespective of the form N. Compared with the results of two weeks after 15 N application, more NO - 3_ 15 N than NH + 4_ 15 N was recovered in microbial biomass. Total recovery was 58.4% (six weeks) and 67% (eight weeks) from NO - 3_ 15 N, and 43.1% and 49% from NH + 4_ 15 N, respectively. Both plants and soil microorganism recovered more NO - 3_ 15 N than NH + 4_ 15 N. But plants recovered more 15 N than soil microorganisms. During the whole experiment plants retained more NO - 3_N and 15 N than soil microorganisms while 15 N recovered in inorganic N pool did not exceed 1% due to lower amount of inorganic N. This indicates that plants play more important roles in the retention of deposited N although microbial biomass can be an important sink for deposited N in early days after N application.

Mg-9Gd-3Y镁合金PEO-EPD复合膜层组织结构与耐蚀性研究

为了提高镁合金的耐蚀性,本文利用扫描电镜分析了Mg-9Gd-3Y(GW93)镁稀土合金表面等离子电解氧化陶瓷层、等离子电解氧化-电泳复合膜层和电泳膜层的表面与纵截面形貌组织,利用傅立叶红外光谱仪(FT-IR)分析了电泳膜层有机官能团类型,用电化学测试手段和盐雾试验方法测试了该合金不同处理膜层的耐蚀性,讨论了电泳电压和固体粉料分数对等离子电解氧化-电泳复合膜层厚度、成膜速率和耐蚀性的影响.研究结果表明,随着电压、固体份的升高,等离子电解氧化-电泳复合涂层厚度和成膜速率呈增大趋势,腐蚀速率随着电压升高呈先减小后增大的趋势,随着固体份的增加呈降低趋势.电泳电压为70V,固体份为19%时,在等离子电解氧化膜层上生成陶瓷层与有机化合物层结合紧密的等离子电解氧化-电泳复合膜层,腐蚀电流密度比等离子电解氧化膜层降低两个数量级,自腐蚀电位正移200mV,耐蚀性提高近13倍.

Nucleation and epitaxy growth of high-entropy REBa_(2)Cu_(3)O_(7-δ)(RE=Y,Dy,Gd,Sm,Eu)thin films by metal organic deposition

High-entropy REBa_(2)Cu_(3)O_(7-δ)(RE=Y_(0.7)+Dy_(0.2)+Gd_(0.2)+Sm_(0.2)+Eu_(0.2))(HE-REBCO) superconducting films doped with multiple rare earth elements were successfully fabricated with thickness up to 800 nm by a trifluoroacetate-metal organic deposition(TFA-MOD).The enhanced entropy change ΔS of the HEREBCO system promotes the c-axis growth of REBCO thin film in the competition with a/b-axis growth.The microstructure and element distribution were investigated by the transmission electron microscopy(TEM) and energy dispersive spectroscopy(EDS).The results show that HE-REBCO films have a great amount of stacking defects,lattice distortions and various rare earth oxides.Furthermore,the microstrain of HE-REBCO films increases significantly compared to the undoped YBCO and(Y,Dy)BCO films.Finally,the superco nducting critical temperature(T_c^(onset)) of HE-REBCO films is about 93 K,and the in-field properties are significantly improved,especially at the temperature of about 77 K.The maximum pinning force density(F_(p,max)) of the HE-REBCO samples at 77 K is 1.7 times higher than that of the undoped YBCO films.