Characteristics and discovery significance of the Upper Triassic–Lower Jurassic marine shale oil in Qiangtang Basin,China

Mesozoic marine shale oil was found in the Qiangtang Basin by a large number of hydrocarbon geological surveys and shallow drilling sampling.Based on systematic observation and experimental analysis of outcrop and core samples,the deposition and development conditions and characteristics of marine shale are revealed,the geochemical and reservoir characteristics of marine shale are evaluated,and the layers of marine shale oil in the Mesozoic are determined.The following geological understandings are obtained.First,there are two sets of marine organic-rich shales,the Lower Jurassic Quse Formation and the Upper Triassic Bagong Formation,in the Qiangtang Basin.They are mainly composed of laminated shale with massive mudstone.The laminated organic-rich shale of the Quse Formation is located in the lower part of the stratum,with a thickness of 50–75 m,and mainly distributed in southern Qiangtang Basin and the central-west of northern Qiangtang Basin.The laminated organic-rich shale of the Bagong Formation is located in the middle of the stratum,with a thickness of 250–350 m,and distributed in both northern and southern Qiangtang Basin.Second,the two sets of laminated organic-rich shales develop foliation,and various types of micropores and microfractures.The average content of brittle minerals is 70%,implying a high fracturability.The average porosity is 5.89%,indicating good reservoir physical properties to the level of moderate–good shale oil reservoirs.Third,the organic-rich shale of the Quse Formation contains organic matters of types II1 and II2,with the average TOC of 8.34%,the average content of chloroform bitumen'A'of 0.66%,the average residual hydrocarbon generation potential(S1+S2)of 29.93 mg/g,and the Ro value of 0.9%–1.3%,meeting the standard of high-quality source rock.The organic-rich shale of the Bagong Formation contains mixed organic matters,with the TOC of 0.65%–3.10%and the Ro value of 1.17%–1.59%,meeting the standard of moderate source rock.Fourth,four shallow wells(depth of 50–250 m)with oil shows have been found in the organic shales at 50–90 m in the lower part of the Bagong Formation and 30–75 m in the middle part of the Quse Formation.The crude oil contains a high content of saturated hydrocarbon.Analysis and testing of outcrop and shallow well samples confirm the presence of marine shale oil in the Bagong Formation and the Quse Formation.Good shale oil intervals in the Bagong Formation are observed in layers 18–20 in the lower part of the section,where the shales with(S0+S1)higher than 1 mg/g are 206.7 m thick,with the maximum and average(S0+S1)of 1.92 mg/g and 1.81 mg/g,respectively.Good shale oil intervals in the Quse Formation are found in layers 4–8 in the lower part of the section,where the shales with(S0+S1)higher than 1 mg/g are 58.8 m thick,with the maximum and average(S0+S1)of 6.46 mg/g and 2.23 mg/g,respectively.

Some Characterizations of Upper and Lower M-Asymmetric Preirresolute Multifunctions

In this present paper, we introduce and investigate a new form of mappings namely;upper and lower M-asymmetric preirresolute multifunctions defined between M-structural asymmetric topological spaces. The relationships between the multifunctions in our sense and other types of precountinuous and preirresolute multifunctions defined on both symmetric and asymmetric topological structures are discussed.

About Upper and Lower Strong Fractional Weighted Mean Convergence by Moduli for Triple Sequences

In article, I present a study on upper and lower statistical convergence, and upper and lower strong fractional weighted mean convergence by moduli for triple sequences. One of the generalizations of the discrete operator Cesàro, was weighted mean operators, which are linear operators, too. Given a modulus function f, I established that a triple sequence that is f-upper or lower strong fractional weighted mean convergent, in some supplementary conditions, is also f-lower or upper statistically convergent. The results of this paper adapt the results obtained in [1] and [2] to upper and lower strong fractional weighted mean convergence and to triple sequence concept. Furthermore, new concepts can be applied to the approximation theory, topology, Fourier analysis, analysis interdisciplinary with applications electrical engineering, robotics and other domains.

Enrichment model and major controlling factors of below-source tight oil in Lower Cretaceous Fuyu reservoirs in northern Songliao Basin,NE China

Based on the geochemical,seismic,logging and drilling data,the Fuyu reservoirs of the Lower Cretaceous Quantou Formation in northern Songliao Basin are systematically studied in terms of the geological characteristics,the tight oil enrichment model and its major controlling factors.First,the Quantou Formation is overlaid by high-quality source rocks of the Upper Cretaceous Qingshankou Formation,with the development of nose structure around sag and the broad and continuous distribution of sand bodies.The reservoirs are tight on the whole.Second,the configuration of multiple elements,such as high-quality source rocks,reservoir rocks,fault,overpressure and structure,controls the tight oil enrichment in the Fuyu reservoirs.The source-reservoir combination controls the tight oil distribution pattern.The pressure difference between source and reservoir drives the charging of tight oil.The fault-sandbody transport system determines the migration and accumulation of oil and gas.The positive structure is the favorable place for tight oil enrichment,and the fault-horst zone is the key part of syncline area for tight oil exploration.Third,based on the source-reservoir relationship,transport mode,accumulation dynamics and other elements,three tight oil enrichment models are recognized in the Fuyu reservoirs:(1)vertical or lateral migration of hydrocarbon from source rocks to adjacent reservoir rocks,that is,driven by overpressure,hydrocarbon generated is migrated vertically or laterally to and accumulates in the adjacent reservoir rocks;(2)transport of hydrocarbon through faults between separated source and reservoirs,that is,driven by overpressure,hydrocarbon migrates downward through faults to the sandbodies that are separated from the source rocks;and(3)migration of hydrocarbon through faults and sandbodies between separated source and reservoirs,that is,driven by overpressure,hydrocarbon migrates downwards through faults to the reservoir rocks that are separated from the source rocks,and then migrates laterally through sandbodies.Fourth,the differences in oil source conditions,charging drive,fault distribution,sandbody and reservoir physical properties cause the differential enrichment of tight oil in the Fuyu reservoirs.Comprehensive analysis suggests that the Fuyu reservoir in the Qijia-Gulong Sag has good conditions for tight oil enrichment and has been less explored,and it is an important new zone for tight oil exploration in the future.

A Combination of N2 and CO2 Adsorption to Characterize Nanopore Structure of Organic-Rich Lower Silurian Shale in the Upper Yangtze Platform, South China： Implications for Shale Gas Sorption Capacity

The pores in shales are mainly of nanometer-scale, and their pore size distribution is very important for the preservation and exploitation of shale gas. This study focused on the organic-rich Lower Silurian black shale from four wells in the Upper Yangtze Platform, and their TOC, mineralogical composition and pore characterization were investigated. Low pressure N2 and CO2 adsorption were conducted at 77.35 K and 273.15 K, respectively, and the pore structures were characterized by modified Brunauer-Emmett-Teller （BET）, Dubinin-Radushkevich （DR）, t-plot, Barrett- Joyner-Halenda （BJH） and density functional theory （DFT） methods and then the relationship between pore structure and shale gas sorption capacity was discussed. The results indicate that （1） The Lower Silurian shale has high TOC content of 0.92%~96%, high quartz content of 30.6%-69.5%, and high clays content of 24.1%-51.2%. The total specific surface area varies from 7.56 m^2/g to 25.86 m^2/g. Both the total specific surface area and quartz content are positively associated with the TOC content. （2） Shale samples with higher TOC content have more micropores, which results in more complex nanopore structure. Micropore volumes/surface areas and non-micropore surface areas all increase with the increasing TOC content. （3） A combination of N2 and CO2 adsorption provides the most suitable detection range （~0.3-60 nm） and has high reliability and accuracy for nanopore structure characterization. （4） The TOC content is the key factor to control the gas sorption capacity of the Lower Silurian shale in the Upper Yangtze Platform.

Upper Devonian and Lower Carboniferous Sequence Stratigraphy of South China

In South China four depositional sequences are recognized in the upper part of Upper Devonian and Tournaisian. They are named SQ0 SQ1, SQ2 and SQ3 in ascending order. SQ0 is Strunian (uppermost Devonian), and the other three Tournaisian in age. These four depositional sequences appear to correlate fairly well with the four sequence recognized in Europe, North America and other areas. This may suggest that these sequences are synchronous depos- its resulted from the eustatic changes. The present study on sequence stratigraphy, biostratigraphy and event stratigraphy indicates that in neritic facies areas of South China, the Devonian-Carboniferous boundary, matching the boundary between Siphonodella praesulcata zone and S. sulcata zone in pelagic facies areas, is not only higher than the top of the Cystophrentis zone, but also higher than the top of the Devonian-Carboniferous boundary event bed. In neritic facies areas, the Devonian-Carbonifrerous boundary is marked by the most distinct transgressive surface within the Cystophrentiseudouralina interval zone, i. e. at the base of the TST of the SQ1. This boundary coincides with the top surface of the event bed resulted from the eustatic fall, and approximately corresponds to the basal part of Rseudouralina assemblage zone.

Ramp facies in an intracratonic basin:A case study from the Upper Devonian and Lower Carboniferous in central Hunan,southern China

Detailed studies on Late Devonian to Early Carboniferous carbonate rocks in central Hunan, southern China have led to the recognition of 25 lithofacies which can be grouped into： （I） inner ramp peritidal platform, （2） inner ramp organic hank and mound, （3） mid ramp, （4） outer ramp, and （5） shelf basin facies associations. The peritidal platform facies association dominates the Zimenqiao Formation （Namurian A or late Datangian） and is characterized by gypsum and dolostone-containing sequences, indicating a peritidal platform environment. The other four facies associations dominate the Menggongao Formation （late Famennian）, Liujiatang Formation （Tournaisian or Yangruanian）, Shidengzi Formations （early Visean or early Datangian）. Five upward-shallowing cycles were distinguished in these three Formations. The predominant facies associations developed in each Formation demonstrate an overall transgression-regression cycle in the Late Devonian to Early Carboniferous in central Hunan. The overall transgressive sequence was preserved in the Shaodong, Menggongao, and Liujiatang Formations, and the overall regressive sequence was preserved in the Liujiatang, Shidengzi, Ceshui and Zimenqiao Formations.

Controls on the organic carbon content of the lower Cambrian black shale in the southeastern margin of Upper Yangtze

Control of various factors, including mineral components, primary productivity and redox level, on the total organic carbon(TOC) in the lower Cambrian black shale from southeastern margin of Upper Yangtze(Taozichong, Longbizui and Yanbei areas) is discussed in detail in this article. Mineral components in the study strata are dominated by quartz and clay minerals. Quartz in the Niutitang Formation is mainly of biogenic origin, and the content is in positive correlation with TOC, while the content of clay minerals is negatively correlated with TOC. Primary productivity, represented by the content of Mobio(biogenic molybdenum), Babio(biogenic barium) and phosphorus, is positively correlated with TOC. The main alkanes in studied samples are nCC, and odd–even priority values are closed to 1(0.73–1.13), which suggest the organic matter source was marine plankton. Element content ratios of U/Th and Ni/Co and compound ratio Pr/Ph indicate dysoxic–anoxic bottom water, with weak positive relative with TOC. In total, three main points can be drawn to explain the relationship between data and the factors affecting organic accumulation:(1) quartz-rich and clay-mineral-poor deep shelf–slope–basin environment was favorable for living organisms;(2) high productivity provided the material foundation for organic generation;(3) the redox conditions impact slightly on the content of organic matter under high productivity and dysoxic–anoxic condition.

Differences of Hydrocarbon Enrichment between the Upper and the Lower Structural Layers in the Tazhong Paleouplift

The Tazhong paleouplift is divided into the upper and the lower structural layers, bounded by the unconformity surface at the top of the Ordovician carbonate rock. The reservoirs in the two layers from different parts vary in number, type and reserves, but the mechanism was rarely researched before. Therefore, an explanation of the mechanism will promote petroleum exploration in Tazhong paleouplift. After studying the evolution and reservoir distribution of the Tazhong paleouplift, it is concluded that the evolution in late Caledonian, late Hercynian and Himalayan periods resulted in the upper and the lower structural layers. It is also defined that in the upper structural layer, structural and stratigraphic overlap reservoirs are developed at the top and the upper part of the paleouplift, which are dominated by oil reservoirs, while for the lower structural layer, lithological reservoirs are developed in the lower part of the paleouplift, which are dominated by gas reservoirs, and more reserves are discovered in the lower structural layer than the upper. Through a comparative analysis of accumulation conditions of the upper and the lower structural layers, the mechanism of enrichment differences is clearly explained. The reservoir and seal conditions of the lower structural layer are better than those of the upper layer, which is the reason why more reservoirs have been found in the former. The differences in the carrier system types, trap types and charging periods between the upper and the lower structural layers lead to differences in the reservoir types and distribution. An accumulation model is established for the Tazhong paleouplift. For the upper structural layer, the structural reservoirs and the stratigraphic overlap reservoirs are formed at the upper part of the paleouplift, while for the lower structural layer, the weathering crust reservoirs are formed at the top, the reef-flat reservoirs are formed on the lateral margin, the karst and inside reservoirs are formed in the lower part of the paleouplift.

Sedimentary system characteristics and depositional filling model of Upper Permian——Lower Triassic in South Yellow Sea Basin

In the South Yellow Sea Basin,Mesozoic–Paleozoic marine strata are generally well developed with large thickness,and no substantial breakthroughs have been made in hydrocarbon exploration.Through research,it is believed that the Upper Permian–Lower Triassic can be regarded as a long-term base-level cycle.Based on drilling data,characteristics of the lithology–electric property combination cyclicity,and the special lithology,the long-term base-level cycle was divided into five medium-term base-level cycles(MC1–MC5).On this basis,the Permian–Triassic sedimentary systems and their filling model were analyzed in accordance with the change of base-level cycle and transition of sedimentary environment,as well as characteristics of the drilling sedimentary facies and seismic facies.The results show that there were six sedimentary systems(fluvial,delta,tidal flat,open platform,restricted platform,and continental shelf)developed in the Upper Permian–Lower Triassic,the sedimentary systems were distributed such that the water was deep in the northwest and shallow in the southeast,and there were two base-level cycle filling models(a relatively stable tidal flat facies and a rapidly transgressive continental shelf facies to stable platform facies)developed in the Upper Permian–Lower Triassic.These models can provide a basis for evaluation of the Mesozoic–Paleozoic hydrocarbon geology in the South Yellow Sea Basin.

Does the Luangwa Hippo Population Size and Density Distribution Vary between Upper and Lower Study Blocks? What Are the Management Implications of Such Distribution Pattern?

The pattern of population distribution of the common hippopotamus was examined along the 165 km stretch of the Luangwa River in eastern Zambia. The study area was divided between the upper (A-D) and lower (E-H) study blocks. Population data are collected between 1976-2008 and this study 2009-2012 showed a significant difference in the pattern of density distribution between upper and lower study blocks. Upper blocks had higher density of 41/km than lower blocks 29/km. Length of study blocks was discounted as density was used to determine distribution pattern. Results obtained suggest that primary production in each study block as influenced by river geomorphologic features such as river bends and confluences characterized higher hippopotamus density in the upper blocks. Further research is required to investigate other factors that may have interplayed with food (above ground grass biomass) and river meander features to separate upper and lower blocks.

The Impact of Cut-off Lows on Ozone in the Upper Troposphere and Lower Stratosphere over Changchun from Ozonesonde Observations

In situ measurements of the vertical structure of ozone were made in Changchun （43.53°N, 125.13°E）, China, by the Institute of Atmosphere Physics, in the summers of 2010-13. Analysis of the 89 validated ozone profiles shows the vari- ation of ozone concentration in the upper troposphere and lower stratosphere （UTLS） caused by cut-off lows （COLs） over Changchun. During the COL events, an increase of the ozone concentration and a lower height of the tropopause are observed. Backward simulations with a trajectory model show that the ozone-rich airmass brought by the COL is from Siberia. A case study proves that stratosphere-troposphere exchange （STE） occurs in the COL. The ozone-rich air mass transported from the stratosphere to the troposphere first becomes unstable, then loses its high ozone concentration. This process usually happens during the decay stage of COLs. In order to understand the influence of COLs on the ozone in the UTLS, statistical analysis of the ozone profiles within COLs, and other profiles, are employed. The results indicate that the ozone concentrations of the in-COL profiles are significantly higher than those of the other profiles between ±4 km around the tropopause. The COLs induce an increase in UTLS column ozone by 32% on average. Meanwhile, the COLs depress the lapse-rate tropopause （LRT）/dynamical tropopause height by 1.4/1.7 km and cause the atmosphere above the tropopause to be less stable. The influence of COLs is durable because the increased ozone concentration lasts at least one day after the COL has passed over Changchun. Furthermore, the relative coefficient between LRT height and lower stratosphere （LS） column ozone is -0.62, which implies a positive correlation between COL strength and LS ozone concentration.

Source Rock and Cap Rock Controls on the Upper Ordovician Wufeng Formation–Lower Silurian Longmaxi Formation Shale Gas Accumulation in the Sichuan Basin and its Peripheral Areas

Objective The Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation is one of the priority interval for shale gas exploration in the Sichuan Basin and its peripheral areas, and commercial shale gas has been discovered from this interval in Jiaoshiba, Changning and Weiyuan shale gas fields in Sichuan Province. However, there is no significant discovery in other parts of the basin due to the different quality of black shale and the differences of tectonic evolution. Based on the progress of shale gas geological theory and exploration discoveries, as well as the theory of ＂source rock and cap rock controls on hydrocarbon accumulation＂, of the Upper Ordovician the main controlling factors Wufeng Formation-Lower Silurian Longmaxi Formation shale gas enrichment in the Sichuan Basin and its peripheral areas were analyzed, and the source rock and cap rock controls on the shale gas were also discussed. The results can provide new insights for the next shale gas exploration in this area.

Strong Law of Large Numbers under an Upper Probability

Strong law of large numbers is a fundamental theory in probability and statistics. When the measure tool is nonadditive, this law is very different from additive case. In 2010 Chen investigated the strong law of large numbers under upper probabilityVby assumingVis continuous. This assumption is very strong. Upper probabilities may not be continuous. In this paper we prove the strong law of large numbers for an upper probability without the continuity assumption whereby random variables are quasi-continuous and the upper probability is generated by a weakly compact family of probabilities on a complete and separable metric sample space.

Almost Fixed Points and Fixed Points of Upper [Lower] Semicontinuous Multimap on Locally G-convex Spaces

In this paper, we use the well known KKM type theorem for generalized convex spaces due to Park （Elements of the KKM theory for generalized convex spaces, Korean J. Comp. Appl. Math., 7（2000）, 1-28） to obtain an almost fixed point theorem for upper [resp., lower] semicontinuous multimaps in locally G-convex spaces, and then give a fixed point theorem for upper semicontinuous multimap with closed Γ-convex values.

From Basin Black Shales to Platform Carbonate Rocks:A Study on Sequence Stratigraphy for the Lower Cambrian of the Upper-Yangtze Region in South China

In the Upper-Yangtze region, especially in Guizhou Province and its adjacent areas, the Lower Cambrian is well developed and is marked by a succession from black shales of the basin facies to carbonate rocks of the platform facies. The drowning event of the platform occurring at the turn from Sinian to Cambrian resulted in a set of black shales, i.e. the Niutitang Formation, which makes up the bottom part of the Lower Cambrian. With the shoaling of the sedimentary environment, a set of carbonate rocks, i.e. the Qingxudong Formation, was formed in the top part of the Lower Cambrian. Thus, the Lower Cambrian in the study area makes up one second-order sequence that can be further subdivided into five third-order sequences, and forms a regularly cyclic succession of transgression-regression. There is a regularly vertical stacking pattern for the third-order sequences in the second-order sequence. From bottom to top, the succession of the ＂CS （condensed section） ＋HST （high-stand system tract）＂ of the third-order sequences is changed into the succession of the ＂TST （transgressive system tract）＋CS＋HST＂. Correspondingly, the drowning-type sequence boundary is changed into the exposure-type one. Therefore, both the second-order and the third-order sequences have similar sedimentary-facies architectures. A concomitant with these temporal changes, the Lower Cambrian with a thickness of 1000 m that contains five third-order sequences is changed into a condensed succession that cannot identify third-order sequences toward the southeast with the deepening of the sedimentary environment. According to the elementary features of the third-order sequences, i.e. the regularity o sedimentary-facies successions in space and the synchronism of sedimentary-environment changes in time, the detailed division of the third-order sequences at main logged sections in different paleogeographical background becomes the basis to establish the sequence-stratigraphic framework that can demonstrate two types of facies-changing surface and two types of diachronism in the stratigraphic records. This sequence-stratigraphic framework shows a growing process of the carbonate platform from the base of the condensed succession formed by black shales of basin facies. Resulting from the rapid transgression at the turn from Sinian to Cambrian the ecological space became open, which formed the antecedent condition of paleogeographical setting for ＂the Cambrian Biological Explosion＂. Ultimately, the genetic relationship between the depositional events and the biological-diversity events is very complex and there remain lots of problems that need further research in the future.

A Generalized Upper and Lower Solution Method for Singular Discrete Boundary Value Problems

This paper presents new existence results for singular discrete boundary value problems. In particular our nonlinearity may be singular in its dependent variable and is allowed to change sign.

A Lower and Upper Bound Method for Complex System Reliability Evaluation

It is hard for the existing methods to obtain the expression of the system reliability for most of the practical complex systems with a large number of components and possible stales. A new regression algorithm based on the lower and upper bounds is presented in this paper, which can obtain the system reliability analytically without concerning the structure of the complex system. The method has been applied to a real system and the reliability results are compared with those acquired by the classical method and the parametric method. The effectiveness and accuracy of the proposed method have been testified.

Variation of Zonal Winds in the Upper Troposphere and Lower Stratosphere in Association with Deficient and Excess Indian Summer Monsoon Scenario

The Indian summer monsoon is one of the most dominant tropical circulation systems in the general circulation of the atmosphere. The country receives more than 80% of the annual rainfall during a short span of four months (June to September) of the southwest monsoon season. Variability in the quantum of rainfall during the monsoon season has profound impacts on water resources, power generation, agriculture, economics and ecosystems in the country. The inter annual variability of Indian Summer Monsoon Rainfall (ISMR) depends on atmospheric and oceanic conditions prevailed during the season. In this study we have made an attempt to understand the variation of the of zonal winds in the tropical Upper Troposphere and Lower Stratosphere (UT/LS) region during deficient and Excess rainfall years of Indian summer monsoon and its relation to Indian Summer Monsoon Rainfall (ISMR). It is found that in the equatorial Upper Troposphere zonal winds have westerly anomalies during deficient rainfall year’s and easterly anomaly during excess rainfall years of Indian summer monsoon and opposite zonal wind anomaly is noted in the equatorial Lower Stratosphere during the deficient and excess rainfall years of Indian summer monsoon. It is also found that the June to September upper troposphere zonal winds averaged between 15°N and 15°S latitudes have a long-term trend during 1960 to 1998. Over this period the tropical easterlies and the tropical jet stream have weakened with time.

Some Results of Upper and Lower <i>M</i>-Asymmetric Irresolute Multifunctions in Bitopological Spaces

In this paper, we aim to introduce and study some basic properties of upper and lower M-asymmetric irresolute multifunctions defined between asymmetric sets in the realm of bitopological spaces with certain minimal structures as a generalization of irresolute functions deal to Crossley and Hildebrand [1] and upper and lower irresolute Multifunctions deal to Popa [2].