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Efficient and rapid capture of uranium(Ⅵ) in wastewater via multiamine modified β-cyclodextrin porous polymer
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作者 Xing Zhong Yubin Tan +6 位作者 Siyuan Wu Caixia Hu Kai Guo Yongchuan Wu Neng Yu Mingyang Ma Ying Dai 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第4期144-155,共12页
It is quite important to ensure the safety and sustainable development of nuclear energy for the treatment of radioactive wastewater. To treat radioactive wastewater efficiently and rapidly, two multi-amine β-cyclode... It is quite important to ensure the safety and sustainable development of nuclear energy for the treatment of radioactive wastewater. To treat radioactive wastewater efficiently and rapidly, two multi-amine β-cyclodextrin polymers(diethylenetriamine β-cyclodextrin polymer(DETA-TFCDP) and triethylenetetramine β-cyclodextrin polymer(TETA-TFCDP)) were prepared and applied to capture uranium. Results exhibited that DETA-TFCDP and TETA-TFCDP displayed the advantages of high adsorption amounts(612.2and 628.2 mg·g-1, respectively) and rapid adsorption rates, which can reach(88 ± 1)% of their equilibrium adsorption amounts in 10 min. Moreover, the adsorbent processes of DETA-TFCDP and TETATFCDP on uranium(Ⅵ) followed the Langmuir model and pseudo-second-order model, stating they were mainly chemisorption and self-endothermic. Besides, TETA-TFCDP also showed excellent selectivity in the presence of seven competing cations and could be effectively reused five times via Na2CO3as the desorption reagent. Meanwhile, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy illustrated that the enriched multi-amine groups and oxygen-containing functional groups on the surface of TETA-TFCDP were the main active sites for capturing uranium(Ⅵ). Hence, multi-amine β-cyclodextrin polymers are a highly efficient, rapid, and promising adsorbent for capturing uranium(Ⅵ)from radioactive wastewater. 展开更多
关键词 Adsorption Waste water Pollution uranium(VI) b-Cyclodextrin
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Three-dimensional Modeling of Ore-forming Elements and Mineralization Prognosis for the Yechangping Mo Deposit,Henan Province,China
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作者 DING Gaoming JI Genyuan +5 位作者 YAN Guolong XU Yongzhong WANG Kunming XIAO Chun WANG Quanle GUO Dongbao 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第3期736-752,共17页
Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-di... Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-dimensional fine interpolation,analysis of spatial distribution patterns,and extraction of quantitative mineral-seeking markers.The Yechangping molybdenum(Mo)deposit is a significant and extensive porphyry-skarn deposit in the East Qinling-Dabie Mo polymetallic metallogenic belt at the southern margin of the North China Block.Abundant borehole data on oreforming elements underpin deep geochemical predictions.The methodology includes the following steps:(1)Threedimensional geological modeling of the deposit was established.(2)Correlation,cluster,and factor analyses post delineation of mineralization stages and determination of mineral generation sequence to identify(Cu,Pb,Zn,Ag)and(Mo,W,mfe)assemblages.(3)A three-dimensional geochemical block model was constructed for Mo,W,mfe,Cu,Zn,Pb,and Ag using the ordinary kriging method,and the variational function was developed.(4)Spatial distribution and enrichment characteristics analysis of ore-forming elements are performed to extract geological information,employing the variogram and w(Cu+Pb+Zn+Ag)/w(Mo+W)as predictive indicators.(5)Identifying the western,northwestern,and southwestern areas of the mine with limited mineralization potential,contrasted by the northeastern and southeastern areas favorable for mineral exploration. 展开更多
关键词 3D geochemical model ore-forming elements GEOSTATISTICS deep mineralization prediction Yechangping Mo deposit
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Apatite Fission Track Thermochronology of Granite from the Xiazhuang Uranium Ore Field,South China:Implications for Exhumation History and Ore Preservation
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作者 SUN Yue CHEN Zhengle +4 位作者 PAN Jiayong HUO Hailong LI Haidong SUN Junjie XU Guangchun 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第2期430-440,共11页
Xiazhuang uranium ore field,located in the southern part of the Nanling Metallogenic Belt,is considered one of the largest granite-related U regions in South China.In this paper,we contribute new apatite fission track... Xiazhuang uranium ore field,located in the southern part of the Nanling Metallogenic Belt,is considered one of the largest granite-related U regions in South China.In this paper,we contribute new apatite fission track data and thermal history modeling to constrain the exhumation history and evaluate preservation potential of the Xiazhuang Uranium ore field.Nine Triassic outcrop granite samples collected from different locations of Xiazhuang Uranium ore field yield AFT ages ranging from 43 to 24 Ma with similar mean confined fission track lengths ranging from 11.8±2.0 to 12.9±1.9μm and Dpar values between 1.01 and 1.51μm.The robustness time-temperature reconstructions of samples from the hanging wall of Huangpi fault show that the Xiazhuang Uranium ore field experienced a time of monotonous and slow cooling starting from middle Paleocene to middle Miocene(~60-10 Ma),followed by relatively rapid exhumation in the late Miocene(~10-5 Ma)and nearly thermal stability in the Pliocene-Quaternary(~5-0 Ma).The amount of exhumation after U mineralization since the Middle Paleogene was estimated as~4.3±1.8 km according to the integrated thermal history model.Previous studies indicate that the ore-forming ages of U deposits in the Xiazhuang ore field are mainly before Middle Paleocene and the mineralization depths are more than 4.4±1.2 km.Therefore,the exhumation history since middle Paleocene plays important roles in the preservation of the Xiazhuang Uranium ore field. 展开更多
关键词 apatite fission track exhumation history ore preservation Xiazhuang uranium ore field South China
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Efficient and selective extraction of uranium from seawater based on a novel pulsed liquid chromatography radionuclide separation method 被引量:2
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作者 Jian‑Hua Ye Tao Yu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第2期13-27,共15页
The novel pulsed liquid chromatography radionuclide separation method presented here provides a new and promising strategy for the extraction of uranium from seawater.In this study,a new chromatographic separation met... The novel pulsed liquid chromatography radionuclide separation method presented here provides a new and promising strategy for the extraction of uranium from seawater.In this study,a new chromatographic separation method was proposed,and a pulsed nuclide automated separation device was developed,alongside a new chromatographic column.The length of this chromatographic column was 10 m,with an internal warp of 3 mm and a packing size of 1 mm,while the total separation units of the column reached 12,250.The most favorable conditions for the separation of nuclides were then obtained through optimizing the separation conditions of the device:Sample pH in the column=2,sample injection flow rate=5.698 mL/min,chromatographic column heating temperature=60℃.Separation experiments were also carried out for uranium,europium,and sodium ions in mixed solutions;uranium and sodium ions in water samples from the Ganjiang River;and uranium,sodium,and magnesium ions from seawater samples.The separation factors between the different nuclei were then calculated based on the experimental data,and a formula for the separation level was derived.The experimental results showed that the separation factor in the mixed solution of uranium and europium(1:1)was 1.088,while achieving the initial separation of uranium and europium theoretically required a 47-stage separation.Considering the separation factor of 1.50for the uranium and sodium ions in water samples from the Ganjiang River,achieving the initial separation of uranium and sodium ions would have theoretically required at least a 21-stage separation.Furthermore,for the seawater sample separation experiments,the separation factor of uranium and sodium ions was 1.2885;therefore,more than 28 stages of sample separation would be required to achieve uranium extraction from seawater.The novel pulsed liquid chromatography method proposed in this study was innovative in terms of uranium separation and enrichment,while expanding the possibilities of extracting uranium from seawater through chromatography. 展开更多
关键词 Pulsed liquid chromatography Nuclide separation Seawater uranium extraction uranium enrichment
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MODELING OF THE PALEOGEOTHERMAL FIELD AND ANALYSIS OF THE HEAT SOURCE FOR THE XIANGSHAN URANIUM ORE-FORMING HYDROTHERMALSYSTEM, EAST CHINA
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作者 SUN Zhanxue (East China Geological Institute, Fuzhou, 344000, Jiangxi, China ) 《Geotectonica et Metallogenia》 1996年第Z2期132-139,共8页
Through the finite-element modeling. a quantitative analysis of paleogeothermal evolution after the main volcanic eruption at Cretaceous period for the Xiangshan uranium ore-field. East China. has been presented. Rese... Through the finite-element modeling. a quantitative analysis of paleogeothermal evolution after the main volcanic eruption at Cretaceous period for the Xiangshan uranium ore-field. East China. has been presented. Researches reveal that the energy from the volcanic lava could affect the geothermal field for only three million years after their eruption. and could not provide heat for the Xiangshan uranium ore-foming hydrothermal system because the time gap between the volcanic activities and the uranium mineralizations is longer than 40 million years. The evidences show that the heat energy for the ore-forming system came from anomalously high paleogeothermal gradient in the study area during the mineralization period. 展开更多
关键词 Paleogeotemperature modeling heat source ANALYSIS HYDROTHERMAL uranium deposit Xiangshan uranium ore-field East China
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Branched fibrous amidoxime adsorbent with ultrafast adsorption rate and high amidoxime utilization for uranium extraction from seawater 被引量:1
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作者 Wan-Ning Ren Xin-Xin Feng +5 位作者 Yu-Long He Ming-Lei Wang Wan-Feng Hong Hong-Wei Han Jiang-Tao Hu Guo-Zhong Wu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第6期79-90,共12页
Direct collection of uranium from low uranium systems via adsorption remains challenging.Fibrous sorbent materials with amidoxime(AO)groups are promising adsorbents for uranium extraction from seawater.However,low AO ... Direct collection of uranium from low uranium systems via adsorption remains challenging.Fibrous sorbent materials with amidoxime(AO)groups are promising adsorbents for uranium extraction from seawater.However,low AO adsorption group utilization remains an issue.We herein fabricated a branched structure containing AO groups on polypropylene/polyethylene spun-laced nonwoven(PP/PE SNW)fibers using grafting polymerization induced by radiation(RIGP)to improve AO utilization.The chemical structures,thermal properties,and surface morphologies of the raw and treated PP/PE SNW fibers were studied.The results show that an adsorptive functional layer with a branching structure was successfully anchored to the fiber surface.The adsorption properties were investigated using batch adsorption experiments in simulated seawater with an initial uranium concentration of 500μg·L^(−1)(pH 4,25℃).The maximum adsorption capacity of the adsorbent material was 137.3 mg·g^(−1)within 24 h;moreover,the uranyl removal reached 96%within 240 min.The adsorbent had an AO utilization rate of 1/3.5 and was stable over a pH range of 4–10,with good selectivity and reusability,demonstrating its potential for seawater uranium extraction. 展开更多
关键词 Radiation graft technology Branching structure High amidoxime utilization Seawater uranium extraction Ultrafast adsorption
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Depleted uranium oxide supported nickel catalyst for autothermal CO_(2)methanation in non-adiabatic reactor under induction heating 被引量:1
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作者 Lai Truong-Phuoc Jean-Mario Nhut +7 位作者 Loïc Vidal Cuong Duong-Viet Sécou Sall Corinne Petit Christophe Sutter Mehdi Arab Alex Jourdan Cuong Pham-Huu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第10期310-323,I0010,共15页
Undoped nickel-based catalysts supported on depleted uranium oxide allow one to carry out CO_(2)methanation process under extremely low reaction temperature under atmospheric pressure and powered by a contactless indu... Undoped nickel-based catalysts supported on depleted uranium oxide allow one to carry out CO_(2)methanation process under extremely low reaction temperature under atmospheric pressure and powered by a contactless induction heating.By adjusting the reaction conditions,the catalyst is able to perform CO_(2)methanation reaction under autothermal process operated inside a non-adiabatic reactor,without any external energy supply.Such autothermal process is possible thanks to the high apparent density of the UO_x which allows one to confine the reaction heat in a small catalyst volume in order to confine the exothermicity of the reaction inside the catalyst and to operate the reaction at equilibrium heat in-heat out.Such autothermal operation mode allows one to significantly reduce the complexity of the process compared to that operated using adiabatic reactor,where complete insulation is required to prevent heat disequilibrium,in order to reduce as much as possible,the heat exchange with the external medium.The catalyst displays an extremely high stability as a function of time on stream as no apparent deactivation.It is expected that such new catalyst with unprecedented catalytic performance could open new era in the field of heterogeneous catalysis where traditional supports show their limitations to operate catalytic processes under severe reaction conditions. 展开更多
关键词 CO_(2)methanation Auto-methanation Induction heating Depleted uranium oxide Electrification process Operando DRIFTS
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Unveil the Redox Evolution of Ore-forming Fluids using Sulfur Isotope:A Case Study of the Zhengguang Intermediate Sulfidation Epithermal Au-Zn Deposit,NE China
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作者 WANG Le GAO Shen +6 位作者 QIN Kezhang SONG Guoxue HAN Ri SU Shiqiang GUO Jihai PANG Xuyong LI Guangming 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第5期1462-1474,共13页
Oxygen fugacity(fO_(2))is a key intensity variable during the entire magmatic-hydrothermal mineralization courses.The redox state and its variations between different stages of the ore-forming fluids of intermediate s... Oxygen fugacity(fO_(2))is a key intensity variable during the entire magmatic-hydrothermal mineralization courses.The redox state and its variations between different stages of the ore-forming fluids of intermediate sulfidation epithermal deposits are rarely deciphered due to the lack of appropriate approaches to determine fO_(2)of the fluids.Here,we reported theδ^(34)S of the sulfides from three different stages(stageⅠ,Ⅱ,Ⅲ)of Zhengguang,an Early Ordovician Au-rich intermediate sulfidation(IS)epithermal deposit,to decipher the redox evolution of the ore-forming fluids.The increasingδ^(34)S values from stageⅠpyrite(pyl,average-2.6‰)through py2(average-1.9‰)to py3(average-0.2‰)indicates a decrease of the oxygen fugacity of the ore-forming fluids.A compilation ofδ^(34)S values of sulfides from two subtypes of IS deposits(Au-rich and Ag-rich)from NE China shows that theδ^(34)S values of sulfides from Au-rich IS deposits are systematically lighter than those of Ag-rich IS Ag-Pb-Zn deposit,indicating the ore-forming fluids of the former are more oxidized than the latter.We highlight that sulfur isotopic composition of hypogene sulfides is an efficacious proxy to fingerprint the oxygen fugacity fluctuations of epithermal deposits and could potentially be used to distinguish the subtypes of IS deposits. 展开更多
关键词 intermediate sulfidation EPITHERMAL sulfur isotope ore-forming fluids oxygen fugacity Zhengguang
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Metallogenic Age and Ore-forming Material Sources of the Dahongshan Fe-Cu Deposit,Yunnan Province:Insights from Molybdenite Re-Os Dating and H-O-S-Pb Isotopes
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作者 YE Zifeng YANG Guangshu +2 位作者 YU Wenxiu CHEN Aibing JIA Fuju 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第6期1698-1718,共21页
The Dahongshan Fe-Cu(-Au)deposit is a superlarge deposit in the Kangdian metallogenic belt,southwestern China,comprising approximately 458 Mt of Fe ores(40%Fe)and 1.35 Mt Cu.Two main types of Fe-Cu(-Au)mineralization ... The Dahongshan Fe-Cu(-Au)deposit is a superlarge deposit in the Kangdian metallogenic belt,southwestern China,comprising approximately 458 Mt of Fe ores(40%Fe)and 1.35 Mt Cu.Two main types of Fe-Cu(-Au)mineralization are present in the Dahongshan deposit:(1)early submarine volcanic exhalation and sedimentary mineralization characterized by strata-bound fine-grained magnetite and banded Fe-Cu sulfide(pyrite and chalcopyrite)hosted in the Na-rich metavolcanic rocks;(2)late hydrothermal(-vein)type mineralization characterized by Fe-Cu sulfide veins in the hosted strata or massive coarse-grained magnetite orebodies controlled by faults.While previous studies have focused primarily on the early submarine volcanic and sedimentary mineralization of the deposit,data related to late hydrothermal mineralization is lacking.In order to establish the metallogenic age and ore-forming material source of the late hydrothermal(-vein)type mineralization,this paper reports the Re-Os dating of molybdenite from the late hydrothermal vein Fe-Cu orebody and H,O,S,and Pb isotopic compositions of the hydrothermal quartz-sulfide veins.The primary aim of this study was to establish the metallogenic age and ore-forming material source of the hydrothermal type orebody.Results show that the molybdenite separated from quartz-sulfide veins has a Re-Os isochron age of 831±11 Ma,indicating that the Dahongshan Fe-Cu deposit experienced hydrothermal superimposed mineralization in Neoproterozoic.The molybdenite has a Re concentration of 99.7-382.4 ppm,indicating that the Re of the hydrothermal vein ores were primarily derived from the mantle.The δ^(34)S values of sulfides from the hydrothermal ores are 2‰-8‰ showing multi-peak tower distribution,suggesting that S in the ore-forming period was primarily derived from magma and partially from calcareous sedimentary rock.Furthermore,the abundance of radioactive Pb increased significantly from ore-bearing strata to layered and hydrothermal vein ores,which may be related to the later hydrothermal transformation.The composition of H and O isotopes within the hydrothermal quartz indicates that the ore-forming fluid is a mixture of magmatic water and a small quantity of water.These results further indicate that the late hydrothermal orebodies were formed by the Neoproterozoic magmatic hydrothermal event,which might be related to the breakup of the Rodinia supercontinent.Mantle derived magmatic hydrothermal fluid extracted ore-forming materials from the metavolcanic rocks of Dahongshan Group and formed the hydrothermal(-vein)type Fe-Cu orebodies by filling and metasomatism. 展开更多
关键词 stable isotopes Re-Os dating ore-forming material Dahongshan Fe-Cu deposit Kangdian region
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An artificial neural network potential for uranium metal at low pressures
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作者 郝茂生 管鹏飞 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第9期514-521,共8页
Based on machine learning,the high-dimensional fitting of potential energy surfaces under the framework of first principles provides density-functional accuracy of atomic interaction potential for high-precision and l... Based on machine learning,the high-dimensional fitting of potential energy surfaces under the framework of first principles provides density-functional accuracy of atomic interaction potential for high-precision and large-scale simulation of alloy materials.In this paper,we obtained the high-dimensional neural network(NN)potential function of uranium metal by training a large amount of first-principles calculated data.The lattice constants of uranium metal with different crystal structures,the elastic constants,and the anisotropy of lattice expansion of alpha-uranium obtained based on this potential function are highly consistent with first-principles calculation or experimental data.In addition,the calculated formation energy of vacancies in alpha-and beta-uranium also matches the first-principles calculation.The calculated site of the most stable self-interstitial and its formation energy is in good agreement with the findings from density functional theory(DFT)calculations.These results show that our potential function can be used for further large-scale molecular dynamics simulation studies of uranium metal at low pressures,and provides the basis for further construction of potential model suitable for a wide range of pressures. 展开更多
关键词 machine learning potential uranium metal first-principles calculation
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Effect of Natural Zeolite on Pore Structure of Cemented Uranium Tailings Backfill
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作者 Fulin Wang Xinyang Geng +1 位作者 Zhengping Yuan Shijiao Yang 《Journal of Renewable Materials》 SCIE EI 2023年第3期1469-1484,共16页
The use of some environmental functional minerals as backfill-modified materials may improve the leaching resistance of cemented uranium tailings backfill created from alkali-activated slag(CUTB),but these materials m... The use of some environmental functional minerals as backfill-modified materials may improve the leaching resistance of cemented uranium tailings backfill created from alkali-activated slag(CUTB),but these materials may participate in the hydration reaction of the cementitious materials,which could have a certain impact on the pore structure of the CUTB,thus affecting its mechanical properties and leaching resistance.In this paper,natural zeolite is selected as the backfill-modified material,and it is added to alkali-activated slag paste(AASP)and CUTB in cementitious material proportions of 4%,8%,12%,and 16%to prepare AASP mixtures and CUTB mixtures containing environmental functional minerals.After the addition of natural zeolite,the porosity of the CUTB generally increases,but when the content is 4%,the porosity decreases to 22.30%.The uniaxial compressive strength(UCS)of the CUTB generally decreases,but the decrease is the smallest when the content is 4%,and the UCS is 12.37 MPa.The addition of natural zeolite mainly reduces the number of fine pores in the CUTB,but the pores with relaxation times T_(2)of greater than 10 ms account for about 10%of the total pores,and there are a certain number of large pores in the CUTB.The main product of alkali-activated slag is calcium(alumino)silicate hydrate(C-(A)-S-H gel).When natural zeolite is added,the hydration products develop towards denser products with a high degree of polymerization and the formation of low polymerization products is reduced.This affects the internal fracture pores of the hydration products and the interface pores of the CUTB,has an irregular effect on the pore characteristics of the CUTB,and influences the UCS. 展开更多
关键词 Pore structure cemented backfill natural zeolite uranium tailings LF-NMR
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Application of sequential extraction for analyzing source and sink of uranium in Huanghe River sediments,China
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作者 Xihuang ZHONG Xueyan JIANG +3 位作者 Huijun HE Wenwen ZHANG Chunxia MENG Feng SUN 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2023年第3期936-946,共11页
Geochemical behaviors of heavy metals are closely related to their chemical state that can be divided by sequential extraction into exchangeable(F1),bound to carbonates(F2),bound to Fe-Mn oxides(F3),bound to organic m... Geochemical behaviors of heavy metals are closely related to their chemical state that can be divided by sequential extraction into exchangeable(F1),bound to carbonates(F2),bound to Fe-Mn oxides(F3),bound to organic matter or sulfide(F4),and residual(F5).Uranium in sediment of the Huanghe(Yellow)River,China,in different chemical states was extracted using the five-step procedure of Tessier and the source and sink were analyzed.Results show that more than 70%of the total uranium was immobile residual F5 in abundance,followed in order of F4>F3>F2>F1,indicating that the main source of uranium in the sediments was from weathered rock in the drainage basin.In addition,the uranium in the sediments presents potential exogenous input in the Lanzhou,Baotou,and Tongguan reach.Fe-Mn oxides are main carriers of unstable uranium,especially those of F1 and F3.Calcite and illite are secondary adsorption minerals of unstable uranium in sediments under natural conditions.Human activities can also produce an obvious impact on uranium speciation.This study provides a reference for the application of sequential extraction in analyzing the source and sink of uranium in river sediments. 展开更多
关键词 uranium sequential extraction mineral composition SEDIMENT Huanghe(Yellow)River
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Site selective 5f electronic correlations inβ-uranium
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作者 邱睿智 谢刘桦 黄理 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第1期421-426,共6页
We investigate the electronic structure ofβ-uranium,which has five nonequivalent atomic sites in its unit cell,by means of the density functional theory plus Hubbard-U correction with U from linear response calculati... We investigate the electronic structure ofβ-uranium,which has five nonequivalent atomic sites in its unit cell,by means of the density functional theory plus Hubbard-U correction with U from linear response calculation.It is found that the 5f electronic correlations inβ-uranium are moderate.More interestingly,their strengths are site selective,depending on the local atomic environment of the present uranium atom.As a consequence,the occupation matrices and partial 5f density of states ofβ-uranium manifest site dependence.In addition,the complicate experimental structure ofβ-uranium could be well reproduced within this theoretical framework. 展开更多
关键词 uranium low-symmetry crystal structure 5f electronic correlation SITE-SELECTIVITY density-functional theory
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Assessment of Modeling Collimator Designs for Gamma-Ray Transmission of Uranium Oxide Spectrometry Using HPGe Detectors
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作者 Rasha Ali El-Tayebany Hekmat Elbegawy 《World Journal of Engineering and Technology》 2023年第4期663-671,共9页
Many scientific domains use gamma-ray spectrometry, but non-destructive gamma scanning and gamma emission tomography of radioactive fuel in particular. In the experimental setting, a collimator is frequently employed ... Many scientific domains use gamma-ray spectrometry, but non-destructive gamma scanning and gamma emission tomography of radioactive fuel in particular. In the experimental setting, a collimator is frequently employed to focus on a particular location of interest in the fuel. Predictive models for the transmitted gamma-ray intensity through the collimator are required for both the optimization of instrument design and the planning of measurement campaigns. Gamma-ray transport accuracy is frequently predicted using Monte Carlo radiation transport methods, but using these tools in low-efficiency experimental setups is challenging due to the lengthy computation times needed. This study focused on the full-energy peak intensity that was transmitted through several collimator designs, including rectangle and cylinder. The rate of photons arriving at a detector on the other side of the collimator was calculated for anisotropic source of SNM (U<sub>3</sub>O<sub>8</sub>). Some geometrical assumptions that depended on the source-to-collimator distance and collimator dimensions (length, radius or length, height, and width) were applied to achieve precise findings. 展开更多
关键词 Monte Carlo High Purity Germanium (HPGe) COLLIMATOR uranium
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Permeability evolution mechanism and the optimum permeability determination of uranium leaching from low-permeability sandstone treated with low-frequency vibration
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作者 Yong Zhao Xiqi Li +2 位作者 Lin Lei Ling Chen Zhiping Luo 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第10期2597-2610,共14页
Low-frequency vibrations can effectively improve natural sandstone permeability,and higher vibration frequency is associated with larger permeability.However,the optimum permeability and permeability evolution mechani... Low-frequency vibrations can effectively improve natural sandstone permeability,and higher vibration frequency is associated with larger permeability.However,the optimum permeability and permeability evolution mechanism for uranium leaching and the relationship between permeability and the change of chemical reactive rate affecting uranium leaching have not been determined.To solve the above problems,in this study,identical homogeneous sandstone samples were selected to simulate lowpermeability sandstone;a permeability evolution model considering the combined action of vibration stress,pore water pressure,water flow impact force,and chemical erosion was established;and vibration leaching experiments were performed to test the model accuracy.Both the permeability and chemical reactions were found to simultaneously restrict U6þleaching,and the vibration treatment increased the permeability,causing the U6þleaching reaction to no longer be diffusion-constrained but to be primarily controlled by the reaction rate.Changes of the model calculation parameters were further analyzed to determine the permeability evolution mechanism under the influence of vibration and chemical erosion,to prove the correctness of the mechanism according to the experimental results,and to develop a new method for determining the optimum permeability in uranium leaching.The uranium leaching was found to primarily follow a process consisting of(1)a permeability control stage,(2)achieving the optimum permeability,(3)a chemical reactive rate control stage,and(4)a channel flow stage.The resolution of these problems is of great significance for facilitating the application and promotion of lowfrequency vibration in the CO_(2)+O_(2) leaching process. 展开更多
关键词 Low-frequency vibration Low-permeability sandstone uranium migration Permeability evolution mechanism Chemical reactive rate Optimum permeability
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Assessment of the Greenhouse Gas Footprint and Environmental Impact of CO_(2)and O_(2)in situ Uranium Leaching
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作者 YANG Yun ZUO Jinsong +5 位作者 QIU Wenjie WU Jichun QUE Weimin ZHOU Genmao LIU Zhengbang WU Jianfeng 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第3期986-994,共9页
Under the new development philosophy of carbon peaking and carbon neutrality,CO_(2)and O_(2)in situ leaching(ISL)has been identified as a promising technique for uranium mining in China,not only because it solves carb... Under the new development philosophy of carbon peaking and carbon neutrality,CO_(2)and O_(2)in situ leaching(ISL)has been identified as a promising technique for uranium mining in China,not only because it solves carbon dioxide utilization and sequestration,but it also alleviates the environmental burden.However,significant challenges exist in assessment of CO_(2)footprint and water-rock interactions,due to complex geochemical processes.Herein this study conducts a three-dimensional,multicomponent reactive transport model(RTM)of a field-scale CO_(2)and O_(2)ISL process at a typical sandstone-hosted uranium deposit in Songliao Basin,China.Numerical simulations are performed to provide new insight into quantitative interpretation of the greenhouse gas(CO_(2))footprint and environmental impact(SO_(4)^(2–))of the CO_(2)and O_(2)ISL,considering the potential chemical reaction network for uranium recovery at the field scale.RTM results demonstrate that the fate of the CO_(2)could be summarized as injected CO_(2)dissolution,dissolved CO_(2)mineralization and storage of CO_(2)as a gas phase during the CO_(2)and O_(2)ISL process.Furthermore,compared to acid ISL,CO_(2)and O_(2)ISL has a potentially smaller environmental footprint,with 20%of SO_(4)^(2–)concentration in the aquifer.The findings improve our fundamental understanding of carbon utilization in a long-term CO_(2)and O_(2)ISL system and provide important environmental implications when considering complex geochemical processes. 展开更多
关键词 in situ leaching of uranium reactive transport modeling geochemical process CO_(2)utilization
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渗出砂岩型铀矿成矿预测与找矿标志 被引量:4
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作者 李子颖 秦明宽 +29 位作者 郭庆银 贺锋 蔡煜琦 钟军 刘武生 邱林飞 刘持恒 纪宏伟 郭建 林锦荣 李西得 田明明 黄志新 衣龙升 王君贤 刘鑫扬 李伟涛 张云龙 何升 张字龙 郭强 欧光习 贾立城 何中波 吴玉 邢作昌 王文全 刘军港 韩美芝 骆效能 《铀矿地质》 CSCD 2024年第1期1-15,共15页
文章基于渗出砂岩型铀矿成矿机理和模式,认为渗出砂岩型铀成矿作用不同于渗入砂岩型铀矿成矿作用,其成矿预测和找矿标志也不同;提出了渗出砂岩型铀矿成矿作用两大基本关键条件识别标志:红杂色含矿建造原生成因和其中控矿灰色砂体的后生... 文章基于渗出砂岩型铀矿成矿机理和模式,认为渗出砂岩型铀成矿作用不同于渗入砂岩型铀矿成矿作用,其成矿预测和找矿标志也不同;提出了渗出砂岩型铀矿成矿作用两大基本关键条件识别标志:红杂色含矿建造原生成因和其中控矿灰色砂体的后生成因识别;在提出的红杂色沉积建造中渗出砂岩型铀矿“上红下黑、上下连通、红中找灰、灰中找矿”总体找矿新思路基础上,阐明渗出砂岩型铀成矿区域预测评价条件和标志:深部富铀富有机质沉积岩建造、区域构造、区域建造、放射性异常信息和综合预测标志等,提出并阐述“小凹陷成大矿”条件;系统建立渗出砂岩型铀矿床预测定位标志体系,特别是野外可识别的宏观标志,包括控矿构造、沉积建造、蚀变改造、铀矿化砂岩颜色、外来有机质特征等,并对比了渗入和渗出砂岩型铀成矿预测标志。提出的渗出砂岩型铀矿识别标志体系不仅对区分“渗入”和“渗出”两种矿化成因,而且对厘清控矿要素、指导成矿预测和找矿工程部署具有重要意义和价值。 展开更多
关键词 渗出砂岩型铀矿 红杂色含矿建造 成矿预测 找矿标志
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湘西北北部地区黑色岩系铀多金属成矿环境研究 被引量:1
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作者 王健 王文全 +2 位作者 杨帆 王振云 李治兴 《铀矿地质》 CAS CSCD 2024年第2期250-259,共10页
湘西北北部地区主要包括晓坪坳陷、慈利断陷盆地等区域,是湘西北成矿带上有用元素种类和矿物类型最为丰富的地区。文章通过对湘西北北部地区开展系统的地质调查评价和取样分析,研究表明区内铀多金属矿化形成环境主要为深水环境向浅水环... 湘西北北部地区主要包括晓坪坳陷、慈利断陷盆地等区域,是湘西北成矿带上有用元素种类和矿物类型最为丰富的地区。文章通过对湘西北北部地区开展系统的地质调查评价和取样分析,研究表明区内铀多金属矿化形成环境主要为深水环境向浅水环境的过渡区域,海洋中的边缘浅海环境具有更佳的铀成矿条件。微量元素特征参数表明,研究区从震旦纪到寒武纪海洋环境是由相对富氧向缺氧环境的转变,寒武纪在海水缺氧的大背景下,发生过一到两次短时间小规模的充氧事件。对U、Th、稀土等元素的研究表明湘西北北部地区从震旦纪晚期到寒武纪早期U的富集速率明显加快,而后U富集速率逐渐降低,指示研究区在寒武纪早期海洋中的热水作用最为强烈,而后逐步减弱,且成矿作用过程中有深部物质的参与,矿化越好,受深部热水影响越强。对Ce的研究结果表明,研究区震旦纪到寒武纪在大的海退背景下存在3个较为明显的海平面“升-降”转化界面,可以将这段地质历史划分为4个海平面升降变化阶段,在海平面升高阶段,沉积物中Ce异常减小,海洋中还原性增强,有利于有机质和铀多金属元素的富集。研究区矿物学方面的发现与通过地球化学方法得出的结论具有较好的一致性,晶质铀矿、铀石等矿物的晶型、共生关系和所包含的Y、Se等元素指示寒武纪时期研究区黑色岩系成矿处于较高温度、强还原的条件下,且海底热流喷涌过程中携带有深源物质参与成矿。 展开更多
关键词 铀多金属 黑色岩系 成矿环境 湘西北
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氯离子体系铀溶液中铁、钍、稀土的去除研究 被引量:1
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作者 曹令华 张海燕 +5 位作者 曹笑豪 王皓 李大炳 任燕 周志全 舒祖骏 《有色金属(冶炼部分)》 CAS 北大核心 2024年第6期65-70,共6页
采用复盐沉淀法,用硫酸钠同时去除氯离子体系铀溶液中的铁、钍、稀土杂质离子,并研究了硫酸钠用量、反应温度、反应时间、体系pH等对除杂效果的影响。结果表明,反应的最佳条件为:硫酸钠用量为理论量的160%、反应温度95℃、反应时间2 h... 采用复盐沉淀法,用硫酸钠同时去除氯离子体系铀溶液中的铁、钍、稀土杂质离子,并研究了硫酸钠用量、反应温度、反应时间、体系pH等对除杂效果的影响。结果表明,反应的最佳条件为:硫酸钠用量为理论量的160%、反应温度95℃、反应时间2 h、体系pH=0.75~1.25。在此优化条件下,铁、钍和总稀土的平均去除率分别达到99.62%、99.42%和98.27%,铀的平均回收率为99.87%。方法具有除杂效果好、铀损失率低、易分离等优点。 展开更多
关键词 稀土 复盐沉淀 黄钠铁矾
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铀资源勘查技术国际科技前沿动态 被引量:1
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作者 秦明宽 刘祜 +6 位作者 叶发旺 李怀渊 朱鹏飞 李博 程纪星 宋继叶 冯延强 《世界核地质科学》 CAS 2024年第1期1-11,共11页
铀资源勘查技术兼具核科技与地质勘查技术的双重属性,是支撑铀矿勘查不断取得突破的根本动力。全面了解、掌握国外铀资源勘查技术的前沿动态,不仅对发展具中国特色的先进铀资源勘查技术体系具有重要意义,而且对国内铀资源勘查生产亦具... 铀资源勘查技术兼具核科技与地质勘查技术的双重属性,是支撑铀矿勘查不断取得突破的根本动力。全面了解、掌握国外铀资源勘查技术的前沿动态,不仅对发展具中国特色的先进铀资源勘查技术体系具有重要意义,而且对国内铀资源勘查生产亦具有重要借鉴意义。基于大量资料文献的调研、研判及综合分析,概略介绍了铀资源无人机探测、铀资源高精度多维探测、基于大数据的铀资源勘查与预测评价、高效低成本探测等4个技术方向当前国际上的主要研究内容、前沿或热点、重要进展或标志性成果,并结合新时期我国天然铀高质量发展的需求,提出了相关技术国际前沿动态对我国铀资源勘查技术发展的启示。 展开更多
关键词 铀资源 勘查技术 国际前沿动态
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