Faced with the proliferation of quarries extracting silty sand and river sand used in the building and public works sector in Togo, recognition of the granular properties of these materials remains a major challenge f...Faced with the proliferation of quarries extracting silty sand and river sand used in the building and public works sector in Togo, recognition of the granular properties of these materials remains a major challenge for builders. This study aims to take stock of the use of sand in construction in Togo. One hundred and eighteen (118) sand quarries in operation, including thirty-eight (38) silty sand quarries and eighty (80) river sand quarries, were identified following surveys carried out among stakeholders involved in the chain of construction on 40% of the national territory. It appears from these surveys that river sands (59.43% to 84.68%) are prioritized over silty sands (15.32% to 40.57%). Three (3) main reasons are behind the choice of sand type;namely, proximity (28%), cleanliness (25%), good appearance (25%). These three (03) reasons partly explain the strong dependence of users on the sands located in their vicinity as well as the related expenses. Thus, making data available on the characteristics of sand, the materials most used in construction in Togo, would contribute to improving the housing conditions of the Togolese population. .展开更多
This study analyzed the pyrolysis mechanism,developed a pyrolysis kinetic model,and determined the corresponding thermodynamic parameters for the removal of calcium from used lubricating oil using sulfurized calcium a...This study analyzed the pyrolysis mechanism,developed a pyrolysis kinetic model,and determined the corresponding thermodynamic parameters for the removal of calcium from used lubricating oil using sulfurized calcium alkyl phenolate(T-115B)as a model compound.The pyrolysis process and products were evaluated by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy.Visual inspection indicated that the removal of calcium from T-115B depended primarily on the destruction of micelles caused by the pyrolysis of compounds at high temperatures.The pyrolysis characteristics of T-115B at different heating rates were investigated by thermogravimetry and differential thermal analysis,which revealed two distinct pyrolysis phases.Thus,the pyrolysis mechanism can be described by a twostep model.The activation energy and thermodynamic parameters(ΔH,ΔG,andΔS)were determined by applying the Kissinger-Akahira-Sunose,Flynn-Wall-Ozawa,Friedman,and Starink methods;the average activation energies for T-115B pyrolysis obtained using these methods were 115.80,119.84,124.96,and 116.14 kJ/mol,respectively.Further,both stages of the pyrolysis reaction followed Fn mechanisms with n=1.39 in the first stage and n=0.86 in the second stage.This study provides reliable and effective pyrolysis models along with kinetic and thermodynamic parameters to facilitate the largescale industrial application of used lubricating oil.展开更多
This paper outlines a mechanical transformation process for rubber recycling, demonstrating the development of a new material from used tires. With the crumbs obtained using a crusher-compactor, a novel material for t...This paper outlines a mechanical transformation process for rubber recycling, demonstrating the development of a new material from used tires. With the crumbs obtained using a crusher-compactor, a novel material for the manufacture of O-rings has been developed, with properties close to those found on the market. The process includes an experimental methodology of a sulfur vulcanization system choice and the quantification of ingredients, as well as the experimental determination of cure parameters. Mechanical tests on the samples completed the work by providing the mechanical characteristics of both unaged and aged (thermo-oxidative ageing) novel material. This process has a high potential for sustainable development and industrialization, making it a valuable contribution to the recycling of rubber in African developing countries.展开更多
Terrestrial ecosystem water use efficiency(WUE)is an important indicator for coupling plant photosynthesis and transpiration,and is also a key factor linking the carbon and water cycles between the land and atmosphere...Terrestrial ecosystem water use efficiency(WUE)is an important indicator for coupling plant photosynthesis and transpiration,and is also a key factor linking the carbon and water cycles between the land and atmosphere.However,under the combination of climate change and human intervention,the change in WUE is still unclear,especially on the Tibetan Plateau(TP).Therefore,satellite remote sensing data and process-based terrestrial biosphere models(TBMs)are used in this study to investigate the spatiotemporal variations of WUE over the TP from 2001 to 2010.Then,the effects of land use and land cover change(LULCC)and CO_(2) fertilization on WUE from 1981-2010 are assessed using TBMs.Results show that climate change is the leading contributor to the change in WUE on the TP,and temperature is the most important factor.LULCC makes a negative contribution to WUE(-20.63%),which is greater than the positive contribution of CO_(2) fertilization(11.65%).In addition,CO_(2) fertilization can effectively improve ecosystem resilience on the TP.On the northwest plateau,the effects of LULCC and CO_(2) fertilization on WUE are more pronounced during the driest years than the annual average.These findings can help researchers understand the response of WUE to climate change and human activity and the coupling of the carbon and water cycles over the TP.展开更多
[问][415]《全国成人高考统考全真模拟试卷英语》(新世界出版社p.56)有一道试题: There used to be a coffer shop next to your house,______? A.wasn’t there B.didn’t there C.wasn’t it D.didn't it 答案为A。请问这个答案对...[问][415]《全国成人高考统考全真模拟试卷英语》(新世界出版社p.56)有一道试题: There used to be a coffer shop next to your house,______? A.wasn’t there B.didn’t there C.wasn’t it D.didn't it 答案为A。请问这个答案对吗? [答]《牛津高阶英汉双解词典》指出。展开更多
The behavior of flow stress of Al sheets used for pressure can prepared by different melt-treatment during plastic deformation at elevated temperature was studied by isothermal compression test using Gleeble1500 dynam...The behavior of flow stress of Al sheets used for pressure can prepared by different melt-treatment during plastic deformation at elevated temperature was studied by isothermal compression test using Gleeble1500 dynamic hot-simulation testing machine. The results show that the AI sheets possess the remarkable characteristic of steady state flow stress when they are deformed in the temperature range of 350-500℃ at strain rates within the range of 0.01-10.0s^-1. A hyperbolic sine relationship is found to correlate well the flow stress with the strain rate, and an Arrhenius relationship with the temperature, which implies that the process of plastic deformation at elevated temperature for this material is thermally activated. Compared with the AI pieces prepared by no or conventional melt-treatment, hot deformation activation energy of AI sheets prepared by high-efficient melt-treatment is the smallest ( Q= 168.0kJ/mol), which reveals that the hot working formability of this material is very better, and has directly to do with the effective improvement of its metallurgical quality.展开更多
The refining effect of Al3Ti1B1RE master alloy on Al sheets used for pressure can manufacture and the behavior of mixed rare earths in master alloy were investigated with XRD, OM, SEM and EDAX. It is found that the r...The refining effect of Al3Ti1B1RE master alloy on Al sheets used for pressure can manufacture and the behavior of mixed rare earths in master alloy were investigated with XRD, OM, SEM and EDAX. It is found that the refining effect of the refiner on the material has superiority over foreign or domestic Al5Ti1B refiner, and the refiner still retains its refining ability for 6 h after adding it to molten Al, thus improving the strength and plasticity of the material remarkably. The excellent refining effect and stability of AlTiBRE refiner result from that RE can lower the surface energy of molten Al and improve the wetting characteristics of molten Al on refinement nuclei such as TiAl 3, TiB 2, etc., thus giving full play to the effect of heterogeneous nucleation and impeding the congregating tendency of TiB 2 phase in molten Al. At the same time, RE gathering in front of solid/liquid interface are also easy to cause composition supercooling in molten Al, thus impeding the growth of α Al grains and promoting α Al nucleation on refinement nuclei. In addition, RE also play certain role in purification and grain refinement, or modification, especially their effect of purification can improve the metallurgical quality of AlTiBRE master alloy.展开更多
Based on the characteristics of used sodium silicate sand and the different use requirements for recycled sand, "dry reusing and wet reclaiming of used sodium silicate sand" is considered as the most suitabl...Based on the characteristics of used sodium silicate sand and the different use requirements for recycled sand, "dry reusing and wet reclaiming of used sodium silicate sand" is considered as the most suitable technique for the used sand. When the recycled sand is used as support sand, the used sand is only reused by dry process including breaking, screening, dust-removal, etc., and it is not necessary that the used sand is reclaimed with strongly rubbing and scraping method, but when the recycled sand is used as facing sand (or single sand), the used sand must be reclaimed by wet method for higher removal rate of the residual binders. The characteristics and the properties of the dry reused sand are compared with the wet reclaimed sand after combining the different use requirements of support sand and facing sand (or single sand), and above the most adaptive scheme has also been validated.展开更多
The flow stress feature of aluminum sheet used for pressure can during plastic deformation at elevated temperature was studied by isothermal compression test using Gleeble 1 500 dynamic materials testing machine. The ...The flow stress feature of aluminum sheet used for pressure can during plastic deformation at elevated temperature was studied by isothermal compression test using Gleeble 1 500 dynamic materials testing machine. The experimental results show that the steady state deformation is remarkable when the material is deformed in the temperature range of 350~500 ℃ at strain rates within the range of 10 -2 ~10.0 s -1 . The material is sensitive to positive strain rate. A hyperbolic sine relationship is found to correlate well the flow stress with the strain rate, and an Arrhenius relationship with the temperature. Semi empirical constitutive equations of the flow stress are derived from all experimental data for tested material during plastic deformation at elevated temperature by polyelement linear regression analysis. [展开更多
The massive amount of sodium silicate in the used sand was a pollution source,especially in the waste water from the wet reclamation of used sand.A new process of wet reclamation by biologically treating the waste wat...The massive amount of sodium silicate in the used sand was a pollution source,especially in the waste water from the wet reclamation of used sand.A new process of wet reclamation by biologically treating the waste water produced during the wet reclamation process of used sand was studied in the paper.In the work,the pre-cultivation of N.palea was performed firstly,and three different scrubbing solutions:(1) tap water,(2) modified medium for N.palea,and (3) filtrate of the broth treated by N.palea for 15 days,were used.The results of the primary investigation show that a de-skinning ratio of 90% is obtained when using the scrubbing solution containing modified medium for N.palea at the ratio 1:2 of sand and scrubbing solution,and the maximal concentrations of Na+ and SiO32are 1.49 g·L-1 and 0.51 g·L-1,respectively.The results of the optimal biomass,pH value decrease and Na+ and SiO32consumption indicate the optimal incubation conditions are at the irradiance of 5,000 lux and 25 oC.Using the filtrate of the broth treated by N.palea for 15 days as the scrubbing solution directly,a de-skinning ratio of 93% is the highest compared to the results of the tap water and the modified medium for N.palea.In the biological process using N.palea,less water is used and little wastewater is produced,which is advantageous to the purpose of green manufacturing and environmental protection.展开更多
Cellulose membrane was used as Stahonary phase Of affinity chromeqraphy. A  ̄ for theprepeboon Of microPOre cellulose membone born cellulose balm is describ6d. Terne dyeS,Cibacron BIne F3GA and cave Red KZBP were immo...Cellulose membrane was used as Stahonary phase Of affinity chromeqraphy. A  ̄ for theprepeboon Of microPOre cellulose membone born cellulose balm is describ6d. Terne dyeS,Cibacron BIne F3GA and cave Red KZBP were immobilbe as amnty figeds. UP tO IO0 mgCibacron BIne F3G^ can be coupled ontO 1 g merebrane mainx. A membene cadridge cocainingblue affinty membranes was also Prepared. The flux of the cadridge was much superior to that Ofcolumn PaCked ed agarose as sepadsn odium. On this cable, the Chromatography ofhuman seam albumin was performed.展开更多
This study was to analyze the risk of sulfites in food consumed by the Chinese people and assess the health protection capability of maximum-permitted level (MPL) of sulfites in GB 2760-2011. Sulfites as food additi...This study was to analyze the risk of sulfites in food consumed by the Chinese people and assess the health protection capability of maximum-permitted level (MPL) of sulfites in GB 2760-2011. Sulfites as food additives are overused or abused in many food categories. When the MPL in GB 2760-2011 was used as sulfites content in food, the intake of sulfites in most surveyed populations was lower than the acceptable daily intake (ADI). Excess intake of sulfites was found in all the surveyed groups when a high percentile of sulfites in food was intaken. Moreover, children aged 1-6 years are at a high risk to intake excess sulfites. The primary cause for the excess intake of sulfites in Chinese people is the overuse and abuse of sulfites by the food industry. The current MPL of sulfites in GB 2760-2011 protects the health of most populations.展开更多
Due to thermal stability and excellent resistance to slag erosion,the used refractories can be recycled as the main raw material for some refractories.In this article the latest developments about used refractories in...Due to thermal stability and excellent resistance to slag erosion,the used refractories can be recycled as the main raw material for some refractories.In this article the latest developments about used refractories in metallurgical industry has been reviewed,focusing on the results reported in the past decade.The research and reutilization methods of used refractories were discussed.For the research of used refractories,the results of two aspects,the performance and surface corrosion characteristics,are summarized.Then,the advances in research on recycling technology of several main kinds of used refractories,such as MgO-C,Al2O3-SiC-C,Al2O3-MgO-C,magnesium-chrome,and corundum-spinel refractories were summarized and discussed in detail.Some results of the author’s group were reported等线accompanied by these comments.The microstructure and chemical composition were studied by scanning electron microscopy and energy dispersion spectra,and the properties of the refractories were analyzed.Afterwards,the scope of application of materials was determined according to the classification and analysis of refractories.Finally,the large-scale application of used refractories and an outlook is given to future developments of the entire recycling industry.展开更多
The co-liquefaction of lignite coal and used tire was performed in a 250-ml batch reactor, in supercritical water under a nitrogen atmosphere to investigate the effects of temperature (380-440℃), water/feedstock rati...The co-liquefaction of lignite coal and used tire was performed in a 250-ml batch reactor, in supercritical water under a nitrogen atmosphere to investigate the effects of temperature (380-440℃), water/feedstock ratio (4/1-10/1 (wt./wt.)) and the % used tire content in the feedstock (0-100 wt.%) on the conversion efficiency, liquid yield and oil composition attained. The maximum conversion and oil yield were 67 and 50%, respectively, obtained at 400℃ at 1 min, with water/feedstock ratio of 10/1 and 80% used tire content. The distillation characteristics of the oil products, analyzed by simulated distillation gas chromatography, revealed that the oil composition depended significantly on the reaction temperature. The co-liquefaction of coal and used tire yielded a synergistically increased level of oil production. Moreover, the total conversion level obtained with co-liquefaction alone was almost equal to those obtained in the presence of either Fe2O3 or NiMo as catalysts, under the same conditions. Therefore, supercritical water is a good medium for the dissolution of the volatile matter from a coal and used tire matrix.展开更多
This paper addresses increasing concern about the pollution threat of used oil being illegally dumped and the impact of oil on air pollution and freshwater ecosystems in Asian countries. Used oil is a very serious was...This paper addresses increasing concern about the pollution threat of used oil being illegally dumped and the impact of oil on air pollution and freshwater ecosystems in Asian countries. Used oil is a very serious waste management problem. These results call for management action such as maximising the collection and recovery of used oil. The Thai government recognizes the need to recycle used oil and has been active in encouraging programs to accomplish this goal. Thus unless new approaches and incentives are developed, used oil generation may become an increasing serious problem to our environment. The purpose of this study is to examine the technical and economic feasibility, of recycling used oils. In addition, this paper briefly discusses the problems to be overcome and outlines potential mechanisms for providing the necessary disposal controls in order to maximize the protection to public health and environmental quality from potential hazards posed by used lube oil disposal.展开更多
An outdoor experiment was set up to investigate the effects of used lubricating oil (5 L/m^2) on Aegiceras corniculatum Blanco. and Avicennia marina (Forsk) Vierh., two salt-excreting mangroves. A. marina was more...An outdoor experiment was set up to investigate the effects of used lubricating oil (5 L/m^2) on Aegiceras corniculatum Blanco. and Avicennia marina (Forsk) Vierh., two salt-excreting mangroves. A. marina was more sensitive to used lubricating oil than A. corniculatum and canopy-oiling resulted in more direct physical damage and stronger lethal effects than base-oiling. When treated with canopy-oiling, half of A. corniculatum plants survived for the whole treatment time (90 d); but, for A. marina, high mortality (83%) resulted from canopy-oiling within 3 weeks and no plants survived for 80 d. Base-oiling had no lethal effects on A. corniculatum plants even at the termination of this experiment, but 83% of A. marina plants died 80 d after treatment. Forty days after canopyoiling, 93% ofA. corniculatum leaves fell and no live leaves remained on A. marina plants. By the end of the experiment, base-oiling treatment resulted in about 45% ofA. corniculatum leaves falling, while all A. mar/na leaves and buds were burned to die. Lubricating oil resulted in physiological damage to A. corniculatum leaves, including decreases in chlorophyll and carotenoid contents, nitrate reductase, peroxidase and superoxide dismutase activities, and increases in malonaldehyde contents. For both species, oil pollution significantly reduced leaf, root, and total biomass, but did not significantly affect stem biomass. Oil pollution resulted in damage to the xylem vessels of fine roots but not to those of mediate roots.展开更多
文摘Faced with the proliferation of quarries extracting silty sand and river sand used in the building and public works sector in Togo, recognition of the granular properties of these materials remains a major challenge for builders. This study aims to take stock of the use of sand in construction in Togo. One hundred and eighteen (118) sand quarries in operation, including thirty-eight (38) silty sand quarries and eighty (80) river sand quarries, were identified following surveys carried out among stakeholders involved in the chain of construction on 40% of the national territory. It appears from these surveys that river sands (59.43% to 84.68%) are prioritized over silty sands (15.32% to 40.57%). Three (3) main reasons are behind the choice of sand type;namely, proximity (28%), cleanliness (25%), good appearance (25%). These three (03) reasons partly explain the strong dependence of users on the sands located in their vicinity as well as the related expenses. Thus, making data available on the characteristics of sand, the materials most used in construction in Togo, would contribute to improving the housing conditions of the Togolese population. .
基金We are grateful for the support of the Science and Technology Innovation 2025 Major project of Ningbo[2018B10038]the Chair Professorship Program of Shandong University of Technology[117002]the Natural Science Foundation of Shandong Province[ZR2020MB130].
文摘This study analyzed the pyrolysis mechanism,developed a pyrolysis kinetic model,and determined the corresponding thermodynamic parameters for the removal of calcium from used lubricating oil using sulfurized calcium alkyl phenolate(T-115B)as a model compound.The pyrolysis process and products were evaluated by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy.Visual inspection indicated that the removal of calcium from T-115B depended primarily on the destruction of micelles caused by the pyrolysis of compounds at high temperatures.The pyrolysis characteristics of T-115B at different heating rates were investigated by thermogravimetry and differential thermal analysis,which revealed two distinct pyrolysis phases.Thus,the pyrolysis mechanism can be described by a twostep model.The activation energy and thermodynamic parameters(ΔH,ΔG,andΔS)were determined by applying the Kissinger-Akahira-Sunose,Flynn-Wall-Ozawa,Friedman,and Starink methods;the average activation energies for T-115B pyrolysis obtained using these methods were 115.80,119.84,124.96,and 116.14 kJ/mol,respectively.Further,both stages of the pyrolysis reaction followed Fn mechanisms with n=1.39 in the first stage and n=0.86 in the second stage.This study provides reliable and effective pyrolysis models along with kinetic and thermodynamic parameters to facilitate the largescale industrial application of used lubricating oil.
文摘This paper outlines a mechanical transformation process for rubber recycling, demonstrating the development of a new material from used tires. With the crumbs obtained using a crusher-compactor, a novel material for the manufacture of O-rings has been developed, with properties close to those found on the market. The process includes an experimental methodology of a sulfur vulcanization system choice and the quantification of ingredients, as well as the experimental determination of cure parameters. Mechanical tests on the samples completed the work by providing the mechanical characteristics of both unaged and aged (thermo-oxidative ageing) novel material. This process has a high potential for sustainable development and industrialization, making it a valuable contribution to the recycling of rubber in African developing countries.
基金supported by the Second Tibetan Plateau Scientific Expedition and Research Program (STEP) (Grant No. 2019QZKK0206)the Strategic Priority Research Program of Chinese Academy of Sciences (Grant No. XDA20100300)+2 种基金the Youth Innovation Promotion Association CAS (2021073)the National Key Scientific and Technological Infrastructure project “Earth System Science Numerical Simulator Facility ” (EarthLab), the Natural Science Foundation of Hunan Province (Grant No. 2020JJ4074)the Open Fund Project of Key Lab of Virtual Geographic Environment (Nanjing Normal University), Ministry of Education (2021VGE04)
文摘Terrestrial ecosystem water use efficiency(WUE)is an important indicator for coupling plant photosynthesis and transpiration,and is also a key factor linking the carbon and water cycles between the land and atmosphere.However,under the combination of climate change and human intervention,the change in WUE is still unclear,especially on the Tibetan Plateau(TP).Therefore,satellite remote sensing data and process-based terrestrial biosphere models(TBMs)are used in this study to investigate the spatiotemporal variations of WUE over the TP from 2001 to 2010.Then,the effects of land use and land cover change(LULCC)and CO_(2) fertilization on WUE from 1981-2010 are assessed using TBMs.Results show that climate change is the leading contributor to the change in WUE on the TP,and temperature is the most important factor.LULCC makes a negative contribution to WUE(-20.63%),which is greater than the positive contribution of CO_(2) fertilization(11.65%).In addition,CO_(2) fertilization can effectively improve ecosystem resilience on the TP.On the northwest plateau,the effects of LULCC and CO_(2) fertilization on WUE are more pronounced during the driest years than the annual average.These findings can help researchers understand the response of WUE to climate change and human activity and the coupling of the carbon and water cycles over the TP.
文摘[问][415]《全国成人高考统考全真模拟试卷英语》(新世界出版社p.56)有一道试题: There used to be a coffer shop next to your house,______? A.wasn’t there B.didn’t there C.wasn’t it D.didn't it 答案为A。请问这个答案对吗? [答]《牛津高阶英汉双解词典》指出。
基金supported by the Fujian Provincial Natural Science Foundation(No.E0210011)the Educational Commission of Fujian province(No.K20014).
文摘The behavior of flow stress of Al sheets used for pressure can prepared by different melt-treatment during plastic deformation at elevated temperature was studied by isothermal compression test using Gleeble1500 dynamic hot-simulation testing machine. The results show that the AI sheets possess the remarkable characteristic of steady state flow stress when they are deformed in the temperature range of 350-500℃ at strain rates within the range of 0.01-10.0s^-1. A hyperbolic sine relationship is found to correlate well the flow stress with the strain rate, and an Arrhenius relationship with the temperature, which implies that the process of plastic deformation at elevated temperature for this material is thermally activated. Compared with the AI pieces prepared by no or conventional melt-treatment, hot deformation activation energy of AI sheets prepared by high-efficient melt-treatment is the smallest ( Q= 168.0kJ/mol), which reveals that the hot working formability of this material is very better, and has directly to do with the effective improvement of its metallurgical quality.
文摘The refining effect of Al3Ti1B1RE master alloy on Al sheets used for pressure can manufacture and the behavior of mixed rare earths in master alloy were investigated with XRD, OM, SEM and EDAX. It is found that the refining effect of the refiner on the material has superiority over foreign or domestic Al5Ti1B refiner, and the refiner still retains its refining ability for 6 h after adding it to molten Al, thus improving the strength and plasticity of the material remarkably. The excellent refining effect and stability of AlTiBRE refiner result from that RE can lower the surface energy of molten Al and improve the wetting characteristics of molten Al on refinement nuclei such as TiAl 3, TiB 2, etc., thus giving full play to the effect of heterogeneous nucleation and impeding the congregating tendency of TiB 2 phase in molten Al. At the same time, RE gathering in front of solid/liquid interface are also easy to cause composition supercooling in molten Al, thus impeding the growth of α Al grains and promoting α Al nucleation on refinement nuclei. In addition, RE also play certain role in purification and grain refinement, or modification, especially their effect of purification can improve the metallurgical quality of AlTiBRE master alloy.
文摘Based on the characteristics of used sodium silicate sand and the different use requirements for recycled sand, "dry reusing and wet reclaiming of used sodium silicate sand" is considered as the most suitable technique for the used sand. When the recycled sand is used as support sand, the used sand is only reused by dry process including breaking, screening, dust-removal, etc., and it is not necessary that the used sand is reclaimed with strongly rubbing and scraping method, but when the recycled sand is used as facing sand (or single sand), the used sand must be reclaimed by wet method for higher removal rate of the residual binders. The characteristics and the properties of the dry reused sand are compared with the wet reclaimed sand after combining the different use requirements of support sand and facing sand (or single sand), and above the most adaptive scheme has also been validated.
基金Project (E981 0 0 0 3)supportedbytheNaturalScienceFoundationofFujianProvince P .R .China
文摘The flow stress feature of aluminum sheet used for pressure can during plastic deformation at elevated temperature was studied by isothermal compression test using Gleeble 1 500 dynamic materials testing machine. The experimental results show that the steady state deformation is remarkable when the material is deformed in the temperature range of 350~500 ℃ at strain rates within the range of 10 -2 ~10.0 s -1 . The material is sensitive to positive strain rate. A hyperbolic sine relationship is found to correlate well the flow stress with the strain rate, and an Arrhenius relationship with the temperature. Semi empirical constitutive equations of the flow stress are derived from all experimental data for tested material during plastic deformation at elevated temperature by polyelement linear regression analysis. [
基金financially supported by the National Natural Science Foundation of China (No.51075163)the Research Fund for the Doctoral Program of Higher Education of China (No.20100142110017)
文摘The massive amount of sodium silicate in the used sand was a pollution source,especially in the waste water from the wet reclamation of used sand.A new process of wet reclamation by biologically treating the waste water produced during the wet reclamation process of used sand was studied in the paper.In the work,the pre-cultivation of N.palea was performed firstly,and three different scrubbing solutions:(1) tap water,(2) modified medium for N.palea,and (3) filtrate of the broth treated by N.palea for 15 days,were used.The results of the primary investigation show that a de-skinning ratio of 90% is obtained when using the scrubbing solution containing modified medium for N.palea at the ratio 1:2 of sand and scrubbing solution,and the maximal concentrations of Na+ and SiO32are 1.49 g·L-1 and 0.51 g·L-1,respectively.The results of the optimal biomass,pH value decrease and Na+ and SiO32consumption indicate the optimal incubation conditions are at the irradiance of 5,000 lux and 25 oC.Using the filtrate of the broth treated by N.palea for 15 days as the scrubbing solution directly,a de-skinning ratio of 93% is the highest compared to the results of the tap water and the modified medium for N.palea.In the biological process using N.palea,less water is used and little wastewater is produced,which is advantageous to the purpose of green manufacturing and environmental protection.
文摘Cellulose membrane was used as Stahonary phase Of affinity chromeqraphy. A  ̄ for theprepeboon Of microPOre cellulose membone born cellulose balm is describ6d. Terne dyeS,Cibacron BIne F3GA and cave Red KZBP were immobilbe as amnty figeds. UP tO IO0 mgCibacron BIne F3G^ can be coupled ontO 1 g merebrane mainx. A membene cadridge cocainingblue affinty membranes was also Prepared. The flux of the cadridge was much superior to that Ofcolumn PaCked ed agarose as sepadsn odium. On this cable, the Chromatography ofhuman seam albumin was performed.
文摘This study was to analyze the risk of sulfites in food consumed by the Chinese people and assess the health protection capability of maximum-permitted level (MPL) of sulfites in GB 2760-2011. Sulfites as food additives are overused or abused in many food categories. When the MPL in GB 2760-2011 was used as sulfites content in food, the intake of sulfites in most surveyed populations was lower than the acceptable daily intake (ADI). Excess intake of sulfites was found in all the surveyed groups when a high percentile of sulfites in food was intaken. Moreover, children aged 1-6 years are at a high risk to intake excess sulfites. The primary cause for the excess intake of sulfites in Chinese people is the overuse and abuse of sulfites by the food industry. The current MPL of sulfites in GB 2760-2011 protects the health of most populations.
基金National Key R&D Program of China(Grant No.2018YFC1901504)National Natural Science Foundation of China(Grant No.51872268).
文摘Due to thermal stability and excellent resistance to slag erosion,the used refractories can be recycled as the main raw material for some refractories.In this article the latest developments about used refractories in metallurgical industry has been reviewed,focusing on the results reported in the past decade.The research and reutilization methods of used refractories were discussed.For the research of used refractories,the results of two aspects,the performance and surface corrosion characteristics,are summarized.Then,the advances in research on recycling technology of several main kinds of used refractories,such as MgO-C,Al2O3-SiC-C,Al2O3-MgO-C,magnesium-chrome,and corundum-spinel refractories were summarized and discussed in detail.Some results of the author’s group were reported等线accompanied by these comments.The microstructure and chemical composition were studied by scanning electron microscopy and energy dispersion spectra,and the properties of the refractories were analyzed.Afterwards,the scope of application of materials was determined according to the classification and analysis of refractories.Finally,the large-scale application of used refractories and an outlook is given to future developments of the entire recycling industry.
文摘The co-liquefaction of lignite coal and used tire was performed in a 250-ml batch reactor, in supercritical water under a nitrogen atmosphere to investigate the effects of temperature (380-440℃), water/feedstock ratio (4/1-10/1 (wt./wt.)) and the % used tire content in the feedstock (0-100 wt.%) on the conversion efficiency, liquid yield and oil composition attained. The maximum conversion and oil yield were 67 and 50%, respectively, obtained at 400℃ at 1 min, with water/feedstock ratio of 10/1 and 80% used tire content. The distillation characteristics of the oil products, analyzed by simulated distillation gas chromatography, revealed that the oil composition depended significantly on the reaction temperature. The co-liquefaction of coal and used tire yielded a synergistically increased level of oil production. Moreover, the total conversion level obtained with co-liquefaction alone was almost equal to those obtained in the presence of either Fe2O3 or NiMo as catalysts, under the same conditions. Therefore, supercritical water is a good medium for the dissolution of the volatile matter from a coal and used tire matrix.
文摘This paper addresses increasing concern about the pollution threat of used oil being illegally dumped and the impact of oil on air pollution and freshwater ecosystems in Asian countries. Used oil is a very serious waste management problem. These results call for management action such as maximising the collection and recovery of used oil. The Thai government recognizes the need to recycle used oil and has been active in encouraging programs to accomplish this goal. Thus unless new approaches and incentives are developed, used oil generation may become an increasing serious problem to our environment. The purpose of this study is to examine the technical and economic feasibility, of recycling used oils. In addition, this paper briefly discusses the problems to be overcome and outlines potential mechanisms for providing the necessary disposal controls in order to maximize the protection to public health and environmental quality from potential hazards posed by used lube oil disposal.
基金Project supported by the Program for New Century Excellent Talents in University(NCET)Environment and Conservation Fund of the HKSAR(No.9210007)
文摘An outdoor experiment was set up to investigate the effects of used lubricating oil (5 L/m^2) on Aegiceras corniculatum Blanco. and Avicennia marina (Forsk) Vierh., two salt-excreting mangroves. A. marina was more sensitive to used lubricating oil than A. corniculatum and canopy-oiling resulted in more direct physical damage and stronger lethal effects than base-oiling. When treated with canopy-oiling, half of A. corniculatum plants survived for the whole treatment time (90 d); but, for A. marina, high mortality (83%) resulted from canopy-oiling within 3 weeks and no plants survived for 80 d. Base-oiling had no lethal effects on A. corniculatum plants even at the termination of this experiment, but 83% of A. marina plants died 80 d after treatment. Forty days after canopyoiling, 93% ofA. corniculatum leaves fell and no live leaves remained on A. marina plants. By the end of the experiment, base-oiling treatment resulted in about 45% ofA. corniculatum leaves falling, while all A. mar/na leaves and buds were burned to die. Lubricating oil resulted in physiological damage to A. corniculatum leaves, including decreases in chlorophyll and carotenoid contents, nitrate reductase, peroxidase and superoxide dismutase activities, and increases in malonaldehyde contents. For both species, oil pollution significantly reduced leaf, root, and total biomass, but did not significantly affect stem biomass. Oil pollution resulted in damage to the xylem vessels of fine roots but not to those of mediate roots.