Corrosion behaviour of PEEK or β-TCP-impregnated Ti6Al4V SLM structures targeting biomedical applications

Ti6Al4V cellular structures were produced by selective laser melting(SLM)and then filled either with beta-tricalcium phosphate(β-TCP)or PEEK(poly-ether-ether-ketone)through powder metallurgy techniques,to improve osteoconductivity and wear resistance.The corrosion behavior of these structures was explored considering its importance for the long-term performance of implants.Results revealed that the incorporation of open cellular pores induced higher electrochemical kinetics when being compared with dense structures.The impregnation ofβ-TCP and PEEK led to the creation of voids or gaps between the metallic matrix and the impregnated material which also influenced the corrosion behavior of the cellular structures.

P-wave velocity structure in the crust and the uppermost mantle of Chao Lake region of the Tan-Lu Fault inferred from teleseismic arrival time tomography

Chao Lake is a Geoheritage site on the active Tan-Lu Fault between the Yangtze craton,the North China craton,and the Dabie orogenic belt in the southeast.This segment of the fault is not well constrained at depth partly due to the overprinting of the fault zone by intrusive materials and its relatively low seismic activity and sparse seismic station coverage.This study took advantage of a dense seismic array deployed around Chao Lake to delineate the P-wave velocity variations in the crust and uppermost mantle using teleseismic earthquake arrival time tomography.The station-pair double-difference with waveform crosscorrelation technique was employed.We used a multiscale resolution 3-D initial model derived from the combination of highresolution 3-D v S models within the region of interest to account for the lateral heterogeneity in the upper crust.The results revealed that the velocity of the upper crust is segmented with structures trending in the direction of the strike of the fault.Sedimentary basins are delineated on both sides of the fault with slow velocities,while the fault zone is characterized by high velocity in the crust and uppermost mantle.The high-velocity structure in the fault zone shows characteristics of magma intrusion that may be connected to the Mesozoic magmatism in and around the Middle and Lower Yangtze River Metallogenic Belt(MLYMB),implying that the Tan-Lu fault might have formed a channel for magma intrusion.Magmatic material in Chao Lake is likely connected to the partial melting,assimilation,storage,and homogenization of the uppermost mantle and the lower crustal rocks.The intrusions,however,seem to have suffered severe regional extension along the Tan-Lu fault driven by the eastward Paleo-Pacific plate subduction,thereby losing its deep trail due to extensional erosion.

A Single-Crystal Neutron Diffraction Study on Magnetic Structure of the Quasi-One-Dimensional Antiferromagnet SrCo_2V_2O_8

The magnetic structure of the spin-chain antiferromagnet SrCo2 V208 is determined by single-crystal neutron diffraction experiment. The system undergoes a long-range magnetic order below the critical temperature TN=4.96 K. The moment of 2.16#B per Co at 1.6K in the screw chain running along the c axis Mternates in the c axis. The moments of neighboring screw chains are arranged antiferromagnetically along one in-plane axis and ferromagnetieally Monk the other in-plane axis. This magnetic configuration breaks the four-fold symmetry of the tetragonM crystal structure and leads to two equally populated magnetic twins with the antiferromagnetic vector in the a or b axis. The very similar magnetic state to the isostructural BaCo2 V~ 08 warrants SrCo2 V2 08 as another interesting half-integer spin-chain antiferromagnet for investigation on quantum antiferromagnetism.

Progress and prospect for NASICON-type Na3V2(PO4)3 forelectrochemical energy storage

Sodium-ion batteries （SIBs） have attracted increasing attention in the past decades, because of high over-all abundance of precursors, their even geographical distribution, and low cost. Na3V2（PO4）3 （NVP）, atypical sodium super ion conductor （NASlCON）-based electrode material, exhibits pronounced structuralstability, exceptionally high ion conductivity, rendering it a most promising electrode for sodium storage.However. the comparatively low electronic conductivity makes the theoretical capacity of NVP cannot befully accessible even at comparatively low rates, presenting a major drawback for further practical ap-plications, especially when high rate capability is especially important. Thus, many endeavors have beenconformed to increase the surface and intrinsic electrical conductivity of NVP by coating the active mate-rials with a conductive carbon layer, downsizing the NVP particles, combining the NVP particle with vari-ous carbon materials and ion doping strategy. In this review, to get a better understanding on the sodiumstorage in NVP, we firstly present 4 distinct crystal structures in the temperature range of-30℃-225℃ namely α-NVP, β-NVP, β′-NVP and γ-NVP. Moreover, we give an overview of recent approaches to en-hance the surface electrical conductivity and intrinsic electrical conductivity of NVP. Finally, some poten-tial applications of NVP such as in all-climate environment and PHEV, EV fields have been prospected.

Hydrothermal Synthesis and Characterization of a Novel Two-dimensional Framework Materials Constructed from Polyoxometalate and Coordination Groups: [H_2Mo_(5.5)V_(10.5)O_(40)(PO_4)][Cu(en)_2]_4·7H_2O

A novel compound [H_2Mo_ 5.5V_ 10.5O_ 40(PO_4)][Cu(en)_2]_4·7H_2O(1) was synthesized from V_2O_5, MoO_3, CuCl_2·2H_2O, en, H_3PO4 and H_2O in an aqueous solution via the hydrothermal method and characterized by means of single-crystal X-ray diffraction, elemental analyses, IR, EPR spectra and thermal analyses. C_ 16H_ 80Cu_4Mo_ 5.5N_ 16O_ 51PV_ 10.5 crystallized in a triclinic system, the space group is P1 with M=2660.63, a= 1.283590(10) nm, b=1.289910(10) nm, c=1.387870(10) nm, V=1.80942(2) nm 3, Z=2, D_x=4.883 g/cm 3, F(000)=2599, μ=6.956 mm -1, (Δ/σ)=0.000, S=1.089. The crystal structure was solved by the direct methods with the final R=0.0752 and wR=0.1988 for 6311 observed reflections with I≥2σ(I). The X-ray crystallography reveals that compound 1 is a novel two-dimensional framework material constructed from the mixed Mo/V polyoxometalate and coordination groups.