Symmetric six oxygen-coordinated Mn structural units(MnO6)in MnO2 with small Mn–O orbital overlap hamper electron transfer rates during energy storage.Herein,we report a novel bond angle modulation strategy to manipu...Symmetric six oxygen-coordinated Mn structural units(MnO6)in MnO2 with small Mn–O orbital overlap hamper electron transfer rates during energy storage.Herein,we report a novel bond angle modulation strategy to manipulate Mn–O orbital overlap in MnO2 through the construction of Mn vacancies(MnO2-VMn),aiming at expediting electron transfer,and thus enhancing energy storage performance.Both experimental and theoretical results disclose that the amplification of Mn–O–Mn bond angles exclusively augments the Mn(dx2-y2)-O(py)orbital overlap and triggers the electron redistribution in MnO2-VMn,inducing an augmented Mn dx2-y2 electron occupation.This heightened presence of active electrons in the Mn dx2-y2 orbital paves the way for accelerating electron transfer and ion transfer in MnO2-VMn.Notably,MnO2-VMn delivers an improved specific capacitance of 425 F g−1 at 1 A g−1 and a superior rate capacity of 265 F g−1 at 20 A g−1.Furthermore,an asymmetric supercapacitor(MnO2-VMn//AC ASC)was fabricated,exhibiting a high energy density of 64.3 Wh kg−1 at a power density of 1000 W kg−1.Furthermore,theoretical insights uncover the profound implications of metal–oxygen–metal bond angle regulation on interatomic orbital overlap modulation.These revelations illuminate pathways for the design of advanced energy storage materials.展开更多
To track human across non-overlapping cameras in depression angles for applications such as multi-airplane visual human tracking and urban multi-camera surveillance,an adaptive human tracking method is proposed,focusi...To track human across non-overlapping cameras in depression angles for applications such as multi-airplane visual human tracking and urban multi-camera surveillance,an adaptive human tracking method is proposed,focusing on both feature representation and human tracking mechanism.Feature representation describes individual by using both improved local appearance descriptors and statistical geometric parameters.The improved feature descriptors can be extracted quickly and make the human feature more discriminative.Adaptive human tracking mechanism is based on feature representation and it arranges the human image blobs in field of view into matrix.Primary appearance models are created to include the maximum inter-camera appearance information captured from different visual angles.The persons appeared in camera are first filtered by statistical geometric parameters.Then the one among the filtered persons who has the maximum matching scale with the primary models is determined to be the target person.Subsequently,the image blobs of the target person are used to update and generate new primary appearance models for the next camera,thus being robust to visual angle changes.Experimental results prove the excellence of the feature representation and show the good generalization capability of tracking mechanism as well as its robustness to condition variables.展开更多
基于重叠网格技术,VOF(volume of fluid)多相流模型以及改进型分离涡模型相结合方法,建立了基于主动通气下双体水下齐射降载增稳数值方法,分析了通气量对空泡形态、载荷特性及运动稳定性的影响规律。结果表明:在一定范围内,随着通气量...基于重叠网格技术,VOF(volume of fluid)多相流模型以及改进型分离涡模型相结合方法,建立了基于主动通气下双体水下齐射降载增稳数值方法,分析了通气量对空泡形态、载荷特性及运动稳定性的影响规律。结果表明:在一定范围内,随着通气量的增加,当通气空泡完全包裹航行体孔口下方区域后,横向载荷幅值和交变峰值均减小,同时,产生的扶偏力矩能够大幅度减小双发航行体之间狭长流域产生的流动干扰现象。另外,为了避免发生共振现象,设计航行体时应尽量使其固有频率在通气效应产生的低频范围之外。综合分析,主动通气方式对多体水下齐射运动姿态的不稳定性具有较好的改善作用。展开更多
The effect of overlapping treatment on microstructure of laser clad WC/Ni60A composite coating was studied with XRD, SEM, TEM and SAED etc. The results show that during the overlapping treatment the existence of the ...The effect of overlapping treatment on microstructure of laser clad WC/Ni60A composite coating was studied with XRD, SEM, TEM and SAED etc. The results show that during the overlapping treatment the existence of the residual heat and edge angle effect on the substrate has changed the composition and microstructure of the coating by raising the fusion temperature and increasing the dilution degree of the coating.展开更多
The performance tests were conducted on oil–water heat transfer in circumferential overlap trisection helical baffle heat exchangers with incline angles of 12°, 16°, 20°, 24° and 28°, and com...The performance tests were conducted on oil–water heat transfer in circumferential overlap trisection helical baffle heat exchangers with incline angles of 12°, 16°, 20°, 24° and 28°, and compared with a segmental baffle heat exchanger. The results show that the shell side heat transfer coefficient h_o and pressure drop Δp_o both increase while the comprehensive index h_o/Δp_o decreases with the increase of the mass flow rate of all schemes. And the shell side heat transfer coefficient, pressure drop and the comprehensive index ho/Δpo decrease with the increase of the baffle incline angle at a certain mass flow rate. The average values of shell side heat transfer coefficient and the comprehensive index h_o/Δp_o of the 12° helical baffled scheme are above 50% higher than those of the segmental one correspondingly, while the pressure drop value is very close and the ratios of the average values are about 1.664 and 1.596, respectively. The shell-side Nusselt number Nu_o and the comprehensive index Nu_o·Eu_(zo)^(-1) increase with the increase of Reynolds number of the shell side axial in all schemes, and the results also demonstrate that the small incline angled helical scheme has better comprehensive performance.展开更多
基金Financial support from the National Natural Science Foundation of China(21575016U20A20154+1 种基金22279005)the National Program for Support of Top-notch Young Professionals。
文摘Symmetric six oxygen-coordinated Mn structural units(MnO6)in MnO2 with small Mn–O orbital overlap hamper electron transfer rates during energy storage.Herein,we report a novel bond angle modulation strategy to manipulate Mn–O orbital overlap in MnO2 through the construction of Mn vacancies(MnO2-VMn),aiming at expediting electron transfer,and thus enhancing energy storage performance.Both experimental and theoretical results disclose that the amplification of Mn–O–Mn bond angles exclusively augments the Mn(dx2-y2)-O(py)orbital overlap and triggers the electron redistribution in MnO2-VMn,inducing an augmented Mn dx2-y2 electron occupation.This heightened presence of active electrons in the Mn dx2-y2 orbital paves the way for accelerating electron transfer and ion transfer in MnO2-VMn.Notably,MnO2-VMn delivers an improved specific capacitance of 425 F g−1 at 1 A g−1 and a superior rate capacity of 265 F g−1 at 20 A g−1.Furthermore,an asymmetric supercapacitor(MnO2-VMn//AC ASC)was fabricated,exhibiting a high energy density of 64.3 Wh kg−1 at a power density of 1000 W kg−1.Furthermore,theoretical insights uncover the profound implications of metal–oxygen–metal bond angle regulation on interatomic orbital overlap modulation.These revelations illuminate pathways for the design of advanced energy storage materials.
基金funded by the Natural Science Foundation of Jiangsu Province(No.BK2012389)the National Natural Science Foundation of China(Nos.71303110,91024024)the Foundation of Graduate Innovation Center in NUAA(Nos.kfjj201471,kfjj201473)
文摘To track human across non-overlapping cameras in depression angles for applications such as multi-airplane visual human tracking and urban multi-camera surveillance,an adaptive human tracking method is proposed,focusing on both feature representation and human tracking mechanism.Feature representation describes individual by using both improved local appearance descriptors and statistical geometric parameters.The improved feature descriptors can be extracted quickly and make the human feature more discriminative.Adaptive human tracking mechanism is based on feature representation and it arranges the human image blobs in field of view into matrix.Primary appearance models are created to include the maximum inter-camera appearance information captured from different visual angles.The persons appeared in camera are first filtered by statistical geometric parameters.Then the one among the filtered persons who has the maximum matching scale with the primary models is determined to be the target person.Subsequently,the image blobs of the target person are used to update and generate new primary appearance models for the next camera,thus being robust to visual angle changes.Experimental results prove the excellence of the feature representation and show the good generalization capability of tracking mechanism as well as its robustness to condition variables.
文摘基于重叠网格技术,VOF(volume of fluid)多相流模型以及改进型分离涡模型相结合方法,建立了基于主动通气下双体水下齐射降载增稳数值方法,分析了通气量对空泡形态、载荷特性及运动稳定性的影响规律。结果表明:在一定范围内,随着通气量的增加,当通气空泡完全包裹航行体孔口下方区域后,横向载荷幅值和交变峰值均减小,同时,产生的扶偏力矩能够大幅度减小双发航行体之间狭长流域产生的流动干扰现象。另外,为了避免发生共振现象,设计航行体时应尽量使其固有频率在通气效应产生的低频范围之外。综合分析,主动通气方式对多体水下齐射运动姿态的不稳定性具有较好的改善作用。
文摘The effect of overlapping treatment on microstructure of laser clad WC/Ni60A composite coating was studied with XRD, SEM, TEM and SAED etc. The results show that during the overlapping treatment the existence of the residual heat and edge angle effect on the substrate has changed the composition and microstructure of the coating by raising the fusion temperature and increasing the dilution degree of the coating.
基金Project(50976035)supported by the National Natural Science Foundation of ChinaProject(4521ZK120064004)supported by the Science and Technology Commission Green Energy and Power Engineering of Special Fund Project of Shanghai,China
文摘The performance tests were conducted on oil–water heat transfer in circumferential overlap trisection helical baffle heat exchangers with incline angles of 12°, 16°, 20°, 24° and 28°, and compared with a segmental baffle heat exchanger. The results show that the shell side heat transfer coefficient h_o and pressure drop Δp_o both increase while the comprehensive index h_o/Δp_o decreases with the increase of the mass flow rate of all schemes. And the shell side heat transfer coefficient, pressure drop and the comprehensive index ho/Δpo decrease with the increase of the baffle incline angle at a certain mass flow rate. The average values of shell side heat transfer coefficient and the comprehensive index h_o/Δp_o of the 12° helical baffled scheme are above 50% higher than those of the segmental one correspondingly, while the pressure drop value is very close and the ratios of the average values are about 1.664 and 1.596, respectively. The shell-side Nusselt number Nu_o and the comprehensive index Nu_o·Eu_(zo)^(-1) increase with the increase of Reynolds number of the shell side axial in all schemes, and the results also demonstrate that the small incline angled helical scheme has better comprehensive performance.
