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A robust method for performance evaluation of the vapor cell for magnetometry
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作者 柳治 邹升 +3 位作者 尹凯峰 石韬 唐钧剑 袁珩 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第4期283-289,共7页
A robust performance evaluation method for vapor cells used in magnetometers is proposed in this work.The performance of the vapor cell determines the sensitivity of the magnetic measurement,which is the core paramete... A robust performance evaluation method for vapor cells used in magnetometers is proposed in this work.The performance of the vapor cell determines the sensitivity of the magnetic measurement,which is the core parameter of a magnetometer.After establishing the relationship between intrinsic sensitivity and the total relaxation rate,the total relaxation rate of the vapor cell can be obtained to represent the intrinsic sensitivity of the magnetometer by fitting the parameters of the magnetic resonance experiments.The method for measurement of the total relaxation rate based on the magnetic resonance experiment proposed in this work is robust and insensitive to ambient noise.Experiments show that,compared with conventional sensitivity measurement,the total relaxation rate affected by magnetic noise below 0.9 n T,pump light frequency noise below 1.5 GHz,pump light power noise below 9%,probe light power noise below 3%and temperature fluctuation of 150±3℃deviates by less than 2%from the noise-free situation.This robust performance evaluation method for vapor cells is conducive to the construction of a multi-channel high-spatial-resolution cardio-encephalography system. 展开更多
关键词 evaluation method MAGNETOMETER ROBUST vapor cell
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Characterizing passive coherent population trapping resonance in a cesium vapor cell filled with neon buffer gas 被引量:1
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作者 刘智 王杰英 +2 位作者 刁文婷 何军 王军民 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第4期232-236,共5页
We present a pair of phase-locked lasers with a 9.2-GHz frequency difference through the injection locking of a master laser to the RF-modulation sideband of a slave diode laser. Using this laser system, a coherent po... We present a pair of phase-locked lasers with a 9.2-GHz frequency difference through the injection locking of a master laser to the RF-modulation sideband of a slave diode laser. Using this laser system, a coherent population trapping (CPT) signal with a typical linewidth of ~ 182 Hz is obtained in a cesium vapor cell filled with 30 Torr (4kPa) of neon as the buffer gas. We investigate the influence of the partial pressure of the neon buffer gas on the CPT linewidth, amplitude, and frequency shift. The results may offer some references for CPT atomic clocks and CPT atomic magnetometers. 展开更多
关键词 coherent population trapping (CPT) phase locking of two-color lasers cesium (Cs) vapor cell buffer gas
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Influence of architecture and temperature of alkali atom vapor cells on absorption spectra 被引量:1
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作者 Yali Liu Wei Li +3 位作者 Yudong Li Xiaokuan Li Liangsen Feng Xinliang Li 《Journal of Semiconductors》 EI CAS CSCD 2022年第12期88-94,共7页
Chip-sized alkali atom vapor cells with high hermeticity are successfully fabricated through deep silicon etching and two anodic bonding processes.A self-built absorption spectrum testing system is used to test the ab... Chip-sized alkali atom vapor cells with high hermeticity are successfully fabricated through deep silicon etching and two anodic bonding processes.A self-built absorption spectrum testing system is used to test the absorption spectra of the ru-bidium atoms in alkali atom vapor cells.The influence of silicon cavity size,filling amount of rubidium atoms and temperature on the absorption spectra of rubidium atom vapor in the atom vapor cells are studied in depth through a theoretical analysis.This study provides a reference for the design and preparation of high quality chip-sized atom vapor cells. 展开更多
关键词 chip-sized alkali atom vapor cell absorption spectrum silicon cavity rubidium azide
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Atomic magnetometer with microfabricated vapor cells based on coherent population trapping
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作者 Xiaojie Li Yue Shi +2 位作者 Hongbo Xue Yong Ruan Yanying Feng 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第3期215-219,共5页
An atomic magnetometer based on coherent population trapping(CPT) resonances in microfabricated vapor cells is demonstrated. Fabricated by the micro-electro-mechanical-system(MEMS) technology, the cells are filled wit... An atomic magnetometer based on coherent population trapping(CPT) resonances in microfabricated vapor cells is demonstrated. Fabricated by the micro-electro-mechanical-system(MEMS) technology, the cells are filled with Rb and Ne at a controlled pressure. An experimental apparatus is built for characterizing properties of microfabricated vapor cells via the CPT effects. The typical CPT linewidth is measured to be about 3 k Hz(1.46 k Hz with approximately zero laser intensity) for the rubidium D1 line at about 90℃. The effects of pressure, temperature and laser intensity on CPT linewidth are studied experimentally. A closed-loop atomic magnetometer is finally finished with a sensitivity of 210.5 p T/Hz1/2 at 1 Hz bandwidth. This work paves the way for developing an integrated chip-scale atomic magnetometer in the future. 展开更多
关键词 atomic magnetometer MEMS vapor cell coherent population trapping
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Experimental evaluation of temperature distribution of a vapor cell using a Hilbert transform procedure
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作者 He Cai You Wang +8 位作者 Ming Gao Wei Zhang Zhigang Jiang Juhong Han Guofei An Shunyan Wang Liangping Xue Hongyuan Wang Jie Zhou 《High Power Laser Science and Engineering》 SCIE CAS CSCD 2016年第4期1-5,共5页
A diode-pumped alkali vapor laser(DPAL) is one of the most promising candidates of the next-generation high-powered laser source. As the saturated number density of alkali vapor is highly dependent on the temperature ... A diode-pumped alkali vapor laser(DPAL) is one of the most promising candidates of the next-generation high-powered laser source. As the saturated number density of alkali vapor is highly dependent on the temperature inside a vapor cell,the temperature distribution in the cross-section of a cell will greatly affect the homogeneity of a laser medium and the output characteristics of a DPAL. In this paper, we developed an algorithm based on the regime concluding quasi-Hilbert transform to evaluate the phase aberration of a wavefront when the probe beam passes through the vapor cell placed in one arm of a Mach–Zehnder interference setup. According to the theoretical algorithm, we deduced the temperature distribution of a cesium vapor cell for different heating conditions. The study is thought to be useful for development of a high-powered laser. 展开更多
关键词 DPAL Hilbert transform temperature distribution vapor cell
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Efforts towards a low-temperature-sensitive physics package for vapor cell atomic clocks
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作者 Qiang Hao Wenxiang Xue +3 位作者 Feng Xu Kemu Wang Peter Yun Shougang Zhang 《Satellite Navigation》 2020年第1期192-197,共6页
Strong environmental dependence is an intractable problem for vapor cell clocks,for which the high-temperature sensitivity of the physics package is considered one of the dominant reasons.In this paper,we report the d... Strong environmental dependence is an intractable problem for vapor cell clocks,for which the high-temperature sensitivity of the physics package is considered one of the dominant reasons.In this paper,we report the design and realization of a low-temperature-sensitive physics package for vapor cell clocks.The physics package comprises three layers of magnetic shields,three layers of heating ovens,and the cavity-cell assembly.The cavity-cell assembly employs a compact magnetron-type cavity and a Rb vapor cell sealed with N2-Ar mixed buffer gas.The dependence of the clock frequency on temperature fluctuation is evaluated to be 2×10^(−11)/℃.In pursuit of the stable temperature,a three-stage temperature regulator is implemented on the physics package.It adopts a combination of open andclosed-loop control to address the problem of significant thermal coupling between the heating ovens.Under a laboratory environment,the measured Hadamard deviation of the temperature variation is 4×10^(−5)℃in 1 day of averaging. 展开更多
关键词 vapor cell atomic clock Physics package Temperature sensitivity
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Morphology and efficiency enhancements of PTB7-Th:ITIC nonfullerene organic solar cells processed via solvent vapor annealing 被引量:1
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作者 Robert S. Gurney Wei Li +3 位作者 Yu Yan Dan Liu Andrew J. Pearson Tao Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第10期148-156,共9页
The nanoscale morphology within the photoactive layer of organic solar cells is critical in determining the power conversion efficiency (PCE). Here, we draw attention to the roles of molecular arrangement, and domain ... The nanoscale morphology within the photoactive layer of organic solar cells is critical in determining the power conversion efficiency (PCE). Here, we draw attention to the roles of molecular arrangement, and domain size in improving performance, which can be tuned by subjecting the photovoltaic materials to solvent vapor annealing (SVA). In our PTB7-Th:ITIC devices, the PCE can be improved by exposing the device to solvent vapor for 60 s after solution casting. The solvent vapor prolongs reorganizational time and increases molecular ordering and domain size/phase separation, which are sub-optimal in pristine PTB7-Th:ITIC blend films. This improved morphology results in better charge mobility, reduced recombination, and ultimately an improved PCE from 7.1% to 7.9% when using CS2 as the annealing solvent. This simple SVA technique can be applied to a range of OPV systems where the molecular ordering is inferior within the as-cast photoactive layer. 展开更多
关键词 Polymer SOLAR cellS Non-fullerene SOLVENT vapor ANNEALING
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GaInP/GaInAs/GaInNAs/Ge Four-Junction Solar Cell Grown by Metal Organic Chemical Vapor Deposition with High Efficiency
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作者 张杨 王青 +5 位作者 张小宾 刘振奇 陈丙振 黄珊珊 彭娜 王智勇 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第10期167-171,共5页
We directly grow a lattice matched GalnP/GalnAs/GalnNAs/Ge (1.88 eVil .42 eVil .05 eV/0.67eV) four-junction (4J) solar cell on a Ge substrate by the metal organic chemical vapor deposition technology. To solve the... We directly grow a lattice matched GalnP/GalnAs/GalnNAs/Ge (1.88 eVil .42 eVil .05 eV/0.67eV) four-junction (4J) solar cell on a Ge substrate by the metal organic chemical vapor deposition technology. To solve the current limit of the GalnNAs sub cell, we design three kinds of anti-reflection coatings and adjust the base region thickness of the GalnNAs sub cell. Developed by a series of experiments, the external quantum efficiency of the GalnNAs sub cell exceeds 80%, and its current density reaches 11.24 mA/cm2. Therefore the current limit of the 4J solar cell is significantly improved. Moreover, we discuss the difference of test results between 4J and GalnP/GalnAs/Ge solar cells under the 1 sun AMO spectrum. 展开更多
关键词 by on it of GaInP/GaInAs/GaInNAs/Ge Four-Junction Solar cell Grown by Metal Organic Chemical vapor Deposition with High Efficiency is THAN Ge GaAs with cell that
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Preparation of CH_3NH_3PbI_3 thin films for solar cells via Vapor Transfer Method 被引量:1
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作者 Kejie Feng Yitong Liu +2 位作者 Yuancheng Zhang Yujie Liu Xiaoliang Mo 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2018年第5期1386-1389,共4页
Organometal halide perovskite based solar cells have emerged as one of the most promising candidates for low-cost and high-efficiency solar cell technologies. Here a Vapor Transfer Method (VTM) is used to fabricate ... Organometal halide perovskite based solar cells have emerged as one of the most promising candidates for low-cost and high-efficiency solar cell technologies. Here a Vapor Transfer Method (VTM) is used to fabricate high quality perovskite thin films in a balanced vacuum capsule. By adjusting the reaction tem- perature, CH_3NHl_3 saturated vapor which then reacts with Pbl_2 films can be controlled and the formation process of CH_3NH_3Pbl_3 perovskite films can be further influenced. Prepared perovskite films which ex- hibit pure phase, smooth surface and high crystallinity are assembled into planar heterojunction inverted solar cells. The whole fabrication process of solar cell devices is organic solution free. Finally, the cham- pion cell achieved power conversion efficiency (PCE) of 13.08% with negligible current-voltage hysteresis under fully open-air conditions. The photovoltaic performance could be further enhanced by optimizing perovskite composition and the device structure. 展开更多
关键词 vapor Transfer Method Organometal halide perovskite Planar heterojunction Inverted architecture Solar cells
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基于创新性内侧壁成型工艺的多光学通道微型碱金属原子气室
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作者 Mingzhi Yu Yao Chen +10 位作者 Yongliang Wang Xiangguang Han Guoxi Luo Libo Zhao Yanbin Wang Yintao Ma Shun Lu Ping Yang Qijing Lin Kaifei Wang Zhuangde Jiang 《Engineering》 SCIE EI CAS CSCD 2024年第4期46-55,共10页
Existing microfabricated atomic vapor cells have only one optical channel,which is insufficient for supporting the multiple orthogonal beams required by atomic devices.In this study,we present a novel wafer-level manu... Existing microfabricated atomic vapor cells have only one optical channel,which is insufficient for supporting the multiple orthogonal beams required by atomic devices.In this study,we present a novel wafer-level manufacturing process for fabricating multi-optical-channel atomic vapor cells and an innovative method for batch processing the inner sidewalls of millimeter glass holes to meet optical channel requirements.Surface characterization and transmittance tests demonstrate that the processed inner sidewalls satisfy the criteria for an optical channel.In addition,the construction of an integrated processing platform enables multilayer non-isothermal anode bonding,the filling of inert gases,and the recovery and recycling of noble gases.Measurements of the absorption spectra and free-induction decay signals of xenon-129(^(129)Xe)and xenon-131(^(131)Xe)under different pump-probe schemes demonstrate the suitability of our vapor cell for use in atomic devices including atomic gyroscopes,dual-beam atomic magnetometers,and other optical/atomic devices.The proposed micromolding technology has broad application prospects in the field of optical-device processing. 展开更多
关键词 Microfabricated atomic vapor cells Inner-sidewall molding Multiple optical channels Quantum sensing
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氦气渗透导致铷原子钟频率漂移的计算与分析
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作者 李豆 王鹏飞 +2 位作者 钟达 梅刚华 康松柏 《波谱学杂志》 CAS 2024年第3期331-340,共10页
氦气渗透导致的铷原子钟吸收泡内铷原子与氦气碰撞频移发生变化,从而影响铷原子钟频率漂移率.为了量化分析这一影响,选取厚度为1 mm,直径为1.8 cm,长为1.6 cm,工作温度为65℃的圆柱型玻璃气泡为例,通过数值方法模拟了派热克斯玻璃(Pyrex... 氦气渗透导致的铷原子钟吸收泡内铷原子与氦气碰撞频移发生变化,从而影响铷原子钟频率漂移率.为了量化分析这一影响,选取厚度为1 mm,直径为1.8 cm,长为1.6 cm,工作温度为65℃的圆柱型玻璃气泡为例,通过数值方法模拟了派热克斯玻璃(Pyrex,康宁7740)与低氦渗透的铝硅酸盐玻璃(ASG,康宁1720)原子气泡内氦气压随时间的变化规律.计算结果显示,对于Pyrex气泡,铷原子钟工作约12年后,氦渗透致频率漂移率降低至<1.0×10^(-14)/天;而ASG气泡铷原子钟在其寿命期间内的氦渗透致频率漂移率始终<3.0×10^(-17)/天,其对铷原子钟漂移率的贡献可忽略不计.该计算方法同样适用于其它种类气体在不同玻璃材料的渗透过程研究. 展开更多
关键词 氦气渗透 铷原子钟 频率漂移 原子气泡 派热克斯玻璃 铝硅酸盐玻璃
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用于量子微波接收机的原子气室探头RCS分析
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作者 林沂 杨凯 +3 位作者 武博 安强 刘燚 付云起 《现代雷达》 CSCD 北大核心 2024年第7期95-99,共5页
基于里德堡原子的量子微波接收机具有超宽带、高灵敏度等显著优点,在雷达探测、信号侦察等电磁对抗领域具有巨大的应用潜力。经典的微波接收机采用金属天线作为传感器探头,而量子微波接收机的传感器探头是一个全介质的原子气室。文中对... 基于里德堡原子的量子微波接收机具有超宽带、高灵敏度等显著优点,在雷达探测、信号侦察等电磁对抗领域具有巨大的应用潜力。经典的微波接收机采用金属天线作为传感器探头,而量子微波接收机的传感器探头是一个全介质的原子气室。文中对原子气室探头的雷达散射截面积(RCS)进行分析,通过将原子气室与经典的微带贴片天线进行仿真对比,展示了原子气室探头在2 GHz~18 GHz的宽频带内具有更低的RCS。此外,还对影响原子气室RCS的主要因素(结构、尺寸、相对介电常数等)进行仿真分析,给出了低RCS原子气室的参数选取基本原则。 展开更多
关键词 里德堡原子 量子微波接收机 雷达散射截面积 原子气室
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SERF原子自旋陀螺仪中的碱金属气室无磁加热高精度温度控制
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作者 刘进容 李伟 《兵工学报》 EI CAS CSCD 北大核心 2024年第9期3288-3296,共9页
碱金属气室的温度波动与磁噪声是制约无自旋交换弛豫原子自旋陀螺仪灵敏度提升的关键因素。针对这两个问题,采用激光加热方式对气室进行无磁加热,从根本上消除磁噪声,在气室加热面及相邻上下两面装载石墨烯薄膜,进行光热转换、热传导以... 碱金属气室的温度波动与磁噪声是制约无自旋交换弛豫原子自旋陀螺仪灵敏度提升的关键因素。针对这两个问题,采用激光加热方式对气室进行无磁加热,从根本上消除磁噪声,在气室加热面及相邻上下两面装载石墨烯薄膜,进行光热转换、热传导以及避免杂散光干扰;采用线性自抗扰控制(Linear Active Disturbance Rejection Control,LADRC)与热管理技术相结合的方式,提高碱金属气室的控温精度与稳定度。设计基于温控系统的线性自抗扰控制器;从热传导、热对流、热辐射三方面出发设计热结构,优选石墨烯薄膜;搭建碱金属气室温控系统实验平台。研究结果表明,采用LADRC与热管理技术的碱金属气室温控系统的控温精度为±0.003℃,控温稳定度为6 mK。所得研究结果为后续原子自旋陀螺仪灵敏度的提升奠定了基础。 展开更多
关键词 SERF原子自旋陀螺仪 碱金属气室 无磁加热 线性自抗扰控制 热管理技术
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硅基SiC薄膜制备与应用研究进展
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作者 杨晨光 王秀峰 《材料导报》 EI CAS CSCD 北大核心 2024年第7期26-39,共14页
碳化硅(SiC)材料具有极为优良的物理、化学及电学性能,可满足在高温、高腐蚀等极端条件下的应用,碳化硅还是极端工作条件下微机电系统(MEMS)的主要候选材料,成为国际上新材料、微电子和光电子领域研究的热点。同时,碳化硅有与硅同属立... 碳化硅(SiC)材料具有极为优良的物理、化学及电学性能,可满足在高温、高腐蚀等极端条件下的应用,碳化硅还是极端工作条件下微机电系统(MEMS)的主要候选材料,成为国际上新材料、微电子和光电子领域研究的热点。同时,碳化硅有与硅同属立方晶系的同质异形体,可与硅工艺技术相结合制备出适应大规模集成电路需要的硅基器件,因此用硅晶片作为衬底制备碳化硅薄膜的工作受到研究人员的特别重视。本文综述了近年来国内外硅基碳化硅薄膜的研究现状,就其制备方法进行了系统的介绍,主要包括各种化学气相沉积(Chemical vapor deposition,CVD)法和物理气相沉积(Physical vapor deposition,PVD)法,并归纳了对硅基碳化硅薄膜性能的研究,包括杨氏模量、硬度、薄膜反射率、透射率、发光性能、电阻、压阻、电阻率和电导率等,以及其在微机电系统传感器、生物传感器和太阳能电池等领域的应用,最后对硅基碳化硅薄膜未来的发展进行了展望。 展开更多
关键词 硅基碳化硅薄膜 化学气相沉积 物理气相沉积 微机电系统传感器 生物传感器 太阳能电池
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基于主被动冷却耦合的棱柱电池热管理系统研究
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作者 彭泽源 刘泽宇 金积德 《电池工业》 CAS 2024年第1期1-6,24,共7页
随着电动汽车电池包容量的增加和电池单元能量密度的提高,电池的热管理已经成为当前电动汽车设计制造过程中的重点和难点。本文基于单个电池单元和电池模组逐级热分析的方法,在电池模组的热管理系统中,引入液冷板作为主动式制冷,同时采... 随着电动汽车电池包容量的增加和电池单元能量密度的提高,电池的热管理已经成为当前电动汽车设计制造过程中的重点和难点。本文基于单个电池单元和电池模组逐级热分析的方法,在电池模组的热管理系统中,引入液冷板作为主动式制冷,同时采用风冷和均热板作为被动式制冷。首先,通过对单个电池单元进行细致建模,计算得到不同电池单元放电倍率下的产热量。然后,对组装成的电池模组进行主动和被动热管理系统的建模。接着,分别对两种不同的热管理系统—风冷与液冷耦合系统、液冷与均热板耦合系统进行最高温度和温度均匀性的模拟仿真,并选择冷却性能更优的结构。最后,对选定的热管理系统在不同质量流量下对系统冷却效果的影响进行优化设计。研究结果表明,随着冷却液流量的增加,最高温度呈现下降趋势,且在2.125 L/min之后冷却效果趋于平缓。综合考虑冷却效果和系统能耗,2.125 L/min的进口流量是在液冷与均热板耦合系统下的最佳选择。 展开更多
关键词 电池热管理 电池单元 均热板 质量流量
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医用钛表面石墨烯薄膜的PECVD法制备及其性能
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作者 张宪明 蔡丁森 钱仕 《表面技术》 EI CAS CSCD 北大核心 2024年第8期156-162,190,共8页
目的在医用钛表面制备石墨烯薄膜,研究生长时间对石墨烯薄膜理化性能和生物学性能的影响。方法采用等离子体增强化学气相沉积设备,在医用钛表面制备石墨烯薄膜,控制石墨烯薄膜生长时间为5、10、30 min。通过拉曼光谱、扫描电子显微镜、... 目的在医用钛表面制备石墨烯薄膜,研究生长时间对石墨烯薄膜理化性能和生物学性能的影响。方法采用等离子体增强化学气相沉积设备,在医用钛表面制备石墨烯薄膜,控制石墨烯薄膜生长时间为5、10、30 min。通过拉曼光谱、扫描电子显微镜、接触角测量仪和电化学工作站对石墨烯薄膜的结构、表面形貌、表面润湿性和耐腐蚀性进行表征,通过小鼠成骨细胞培养评价石墨烯薄膜的细胞相容性。结果薄膜的拉曼结果呈现石墨烯的D、G和2D特征峰。生长时间为10 min和30 min的石墨烯薄膜在医用钛表面呈现垂直纳米片状态。随着生长时间的延长,医用钛表面石墨烯薄膜的水接触角逐渐增大。3组样品中,生长时间为5 min的样品具有最小的腐蚀电流密度(1.822×10^(‒7)A/cm^(2)),生长时间为10 min的样品具有最高的腐蚀电位(‒0.404 V);生长时间为5 min和10 min的样品有利于细胞的黏附与铺展,生长时间为30 min的样品对小鼠成骨细胞活性具有一定的抑制作用。结论石墨烯薄膜可以有效提高医用钛的耐腐蚀性。石墨烯薄膜生长时间影响其形貌,进而改变水接触角。不同生长时间的石墨烯薄膜对小鼠成骨细胞的黏附和铺展表现出明显的差异。 展开更多
关键词 等离子体增强化学气相沉积 医用钛 石墨烯 耐腐蚀性 细胞相容性
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Co-N共掺杂碳纳米管-多孔碳构筑及其氧还原电催化性能
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作者 刘文浩 陈美妤 +3 位作者 唐哲言 赵宏伟 李莉香 安百钢 《当代化工》 CAS 2024年第8期1780-1785,1791,共7页
采用一步化学气相沉积法,以乙腈蒸气为氮源,以钴离子交换合成的沸石(CoY)为模板,制备了Co-N共掺杂碳纳米管-多孔碳氧还原催化剂(Co-N/CNT-C)。利用SEM、TEM、XRD、BET和电化学测试对催化剂组成、结构和电催化性能进行了表征。结果表明:C... 采用一步化学气相沉积法,以乙腈蒸气为氮源,以钴离子交换合成的沸石(CoY)为模板,制备了Co-N共掺杂碳纳米管-多孔碳氧还原催化剂(Co-N/CNT-C)。利用SEM、TEM、XRD、BET和电化学测试对催化剂组成、结构和电催化性能进行了表征。结果表明:Co-N/CNT-C-600在碱性电解质中的半波电位和极限电流密度与商业Pt/C催化剂相近,达到0.80 V和4.31 mA·cm^(-2),且循环稳定性和耐久性优于Pt/C催化剂。优异的催化性能归因于以下两点:Co-N/CNT-C-600中大量碳纳米管作为纳米级电子导体,有效加速了反应过程中的电子传递速率;被锚定在碳纳米管和多孔碳内部的催化活性位点,有效防止了连续电极反应过程中金属离子的迁移和团聚。 展开更多
关键词 分子筛 化学气相沉积 钴-氮共掺杂 纳米材料 电化学 催化剂 燃料电池
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MoO_(3)界面修饰提升刮涂钙钛矿太阳电池性能
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作者 果馨 姚鑫 刘祖刚 《太阳能学报》 EI CAS CSCD 北大核心 2024年第4期101-106,共6页
在空穴传输层Spiro-OMeTAD和Ag电极之间引入三氧化钼(MoO_(3))空穴修饰层,并研究其对空气中刮涂的钙钛矿太阳电池光伏性能的影响,结合导电性测试、稳态光致发光光谱和水接触角测试等探究其影响机制。实验和测试结果表明MoO_(3)可提升空... 在空穴传输层Spiro-OMeTAD和Ag电极之间引入三氧化钼(MoO_(3))空穴修饰层,并研究其对空气中刮涂的钙钛矿太阳电池光伏性能的影响,结合导电性测试、稳态光致发光光谱和水接触角测试等探究其影响机制。实验和测试结果表明MoO_(3)可提升空穴传输能力和减小界面电阻,同时对下方的Spiro-OMeTAD及钙钛矿起到保护作用,可减缓空气中水氧侵蚀。基于MoO_(3)界面修饰层的在空气中刮涂制备的钙钛矿太阳电池光电转换效率由15.14%提升至18.30%,尤其是填充因子的平均值由60%提升至76%,电池稳定性得到改善,未封装电池在400 h后仍保持初始效率的90%。 展开更多
关键词 钙钛矿太阳电池 三氧化钼 热蒸镀 界面修饰 空穴传输 稳定性
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质子交换膜燃料电池均温板散热特性的数值分析
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作者 葛志晶 郑东明 +1 位作者 裴东号 曹军 《太阳能学报》 EI CAS CSCD 北大核心 2024年第6期109-116,共8页
以面向质子交换膜燃料电池电堆散热的超薄均温板为研究对象,用多孔介质传热模型、层流模型和Brinkman方程构建三维稳态数值模型,通过质量守恒确定气液界面的相变传质,研究在吸液芯饱和充液的常规工况下均温板的稳态特性。结果表明:超薄... 以面向质子交换膜燃料电池电堆散热的超薄均温板为研究对象,用多孔介质传热模型、层流模型和Brinkman方程构建三维稳态数值模型,通过质量守恒确定气液界面的相变传质,研究在吸液芯饱和充液的常规工况下均温板的稳态特性。结果表明:超薄结构以及支撑柱的存在使内部压降较大;随着冷凝段对流换热系数的增大,均温性变差,内部压降也显著增大;随着热流密度的增大,温差先增大后减小,热阻持续下降;孔隙率的变化对平衡终态影响较小;渗透率的增大将极大的降低吸液芯内的液体压降,有利于相变循环。 展开更多
关键词 质子交换膜燃料电池 两相流 传热 超薄均温板 数值分析
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管式PECVD制备原位掺杂多晶硅的性能研究
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作者 黄嘉斌 赵增超 +3 位作者 李明 陈俊 邓新新 周小荣 《太阳能学报》 EI CAS CSCD 北大核心 2024年第6期334-340,共7页
报道了管式等离子体增强化学气相沉积(PECVD)的各项沉积参数对硅太阳电池重掺杂多晶硅钝化接触(SiO_(x)/Poly-Si(n^(+)))的影响。TOPCon太阳电池的掺杂多晶硅是通过对沉积的非晶硅高温晶化来实现的,通过改变PECVD的沉积温度、Ar和PH_(3... 报道了管式等离子体增强化学气相沉积(PECVD)的各项沉积参数对硅太阳电池重掺杂多晶硅钝化接触(SiO_(x)/Poly-Si(n^(+)))的影响。TOPCon太阳电池的掺杂多晶硅是通过对沉积的非晶硅高温晶化来实现的,通过改变PECVD的沉积温度、Ar和PH_(3)的流量、沉积功率等沉积参数,可获得不同厚度、结晶度和掺杂浓度的掺杂非晶硅(a-Si(n^(+)))薄膜,然后通过高温退火得到不同的Poly-Si(n^(+))薄膜,从而导致SiO_(x)/Poly-Si(n^(+))钝化接触在钝化质量和载流子选择性等方面的不同特性。最后在沉积温度480℃、Ar流量8 L/min、PH_(3)流量0.8 L/min、沉积功率12000 W、退火温度920℃的条件下获得最佳双面SiO_(x)/Poly-Si(n^(+))/SiN_(x)钝化接触,少子寿命达到6445μs,隐含开路电压(iV_(oc))达到742.7 mV以上,单面饱和电流密度J_(0)低至4.2 fA/cm^(2)。 展开更多
关键词 硅基太阳电池 钝化 多晶硅 掺杂 等离子增强化学气相沉积
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