A robust method for performance evaluation of the vapor cell for magnetometry

A robust performance evaluation method for vapor cells used in magnetometers is proposed in this work.The performance of the vapor cell determines the sensitivity of the magnetic measurement,which is the core parameter of a magnetometer.After establishing the relationship between intrinsic sensitivity and the total relaxation rate,the total relaxation rate of the vapor cell can be obtained to represent the intrinsic sensitivity of the magnetometer by fitting the parameters of the magnetic resonance experiments.The method for measurement of the total relaxation rate based on the magnetic resonance experiment proposed in this work is robust and insensitive to ambient noise.Experiments show that,compared with conventional sensitivity measurement,the total relaxation rate affected by magnetic noise below 0.9 n T,pump light frequency noise below 1.5 GHz,pump light power noise below 9%,probe light power noise below 3%and temperature fluctuation of 150±3℃deviates by less than 2%from the noise-free situation.This robust performance evaluation method for vapor cells is conducive to the construction of a multi-channel high-spatial-resolution cardio-encephalography system.

Analysis of the effect of the 2021 Semeru eruption on water vapor content and atmospheric particles using GNSS and remote sensing

Mount Semeru,an active volcano in East Java,Indonesia,erupted on December 4,2021,following extreme rainfall that caused an avalanche of hot pyroclastic flows and lava.The tropospheric conditions and dominant particle components in the atmosphere can be monitored using Global Navigation Satellite System(GNSS)technology and remote sensing satellites.GNSS signal propagation delay in Precise Point Positioning(PPP)processing can be used to determine Zenith Tropospheric Delay(ZTD)and Precipitable Water Vapor(PWV)variables so that atmospheric conditions can be generated.In addition,by using remote sensing satellite data,it is possible to obtain rainfall data with high temporal resolution as well as the dominant particle and gas content values during eruptions.During the eruption period,the high value of PWV was dominated by the high intensity of precipitation during the rainy season.High rainfall before the eruption caused activity inside the mountain to increase,which occurred in avalanche type eruption.Apart from that,the atmosphere around Semeru was also dominated by SO_(2)content,which spreaded for tens of kilometers.SO_(2)content began to be detected significantly by remote sensing sensors on December 7,2021.In this study,deformation and atmospheric monitoring were also carried out using low-cost GNSS at the Semeru Monitoring Station on September 9-15,2022.The results of the ZTD and ZWD values show the dominance of the wet component,which is directly proportional to rainfall activity in this period.

Jet formation and penetration performance of a double-layer charge liner with chemically-deposited tungsten as the inner liner

This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double-layer charge liners were fabricated by using CVD to deposit tungsten layers on the inner surfaces of pure T2 copper liners.The microstructures of the tungsten layers were analyzed using a scanning electron microscope(SEM).The feasibility analysis was carried out by pulsed X-rays,slug-retrieval test and static penetration tests.The shaped charge jet forming and penetration law of inner tungsten-coated double-layer liner were studied by numerical simulation method.The results showed that the double-layer liners could form well-shaped jets.The errors between the X-ray test results and the numerical results were within 11.07%.A slug-retrieval test was found that the retrieved slug was similar to a numerically simulated slug.Compared with the traditional pure copper shaped charge jet,the penetration depth of the double-layer shaped charge liner increased by 11.4% and>10.8% respectively.In summary,the test results are good,and the numerical simulation is in good agreement with the test,which verified the feasibility of using the CVD method to fabricate double-layer charge liners with a high-density and high-strength refractory metal as the inner liner.

Consistency of Tropospheric Water Vapor between Reanalyses and Himawari-8/AHI Measurements over East Asia

High spatiotemporal resolution radiances from the advanced imagers onboard the new generation of geostationary weather satellites provide a unique opportunity to evaluate the abilities of various reanalysis datasets to depict multilayer tropospheric water vapor(WV),thereby enhancing our understanding of the deficiencies of WV in reanalysis datasets.Based on daily measurements from the Advanced Himawari Imager(AHI)onboard the Himawari-8 satellite in 2016,the bias features of multilayer WV from six reanalysis datasets over East Asia are thoroughly evaluated.The assessments show that wet biases exist in the upper troposphere in all six reanalysis datasets;in particular,these biases are much larger in summer.Overall,we find better depictions of WV in the middle troposphere than in the upper troposphere.The accuracy of WV in the ERA5 dataset is the highest,in terms of the bias magnitude,dispersion,and pattern similarity.The characteristics of the WV bias over the Tibetan Plateau are significantly different from those over other parts of East Asia.In addition,the reanalysis datasets all capture the shift of the subtropical high very well,with ERA5 performing better overall.

Relationship between disorder,magnetism and band topology in Mn(Sb_(1-x)Bi_(x))_(2)Te_(4) single crystals

We investigate the evolution of magnetic properties as well as the content and distribution of Mn for Mn(Sb_(1-x)Bi_(x))_(2)Te_(4) single crystals grown by large-temperature-gradient chemical vapor transport method.It is found that the ferromagnetic MnSb_(2)Te_(4) changes to antiferromagnetism with Bi doping when x≥0.25.Further analysis implies that the occupations of Mn ions at Sb/Bi site Mn_(Sb/Bi) and Mn site Mn_(Mn) have a strong influence on the magnetic ground states of these systems.With the decrease of Mn_(Mn) increase of Mn_(Sb/Bi),the system will favor the ferromagnetic ground state.In addition,the rapid decrease of T_(C/N) with increasing Bi content when x ≤0.25 and the insensitivity of T_(N) to x when x> 0.25 suggest that the main magnetic interaction may change from the Ruderman-Kittel-Kasuya-Yosida type at low Bi doping region to the van-Vleck type in high Bi doped samples.

Linkage between precipitation isotopes and water vapor sources in the monsoon margin:Evidence from arid areas of Northwest China

The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is usually sensitive to climate change.The water resource management in the monsoon margin should be better planned by understanding the composition of precipitation isotope and its influencing factors.In this study,the precipitation samples were collected at five sampling sites(Baiyin City,Kongtong District,Maqu County,Wudu District,and Yinchuan City)of the monsoon margin in the northwest of China in 2022 to analyze the characteristics of stable hydrogen(δD)and oxygen(δ18O)isotopes.We analyzed the impact of meteorological factors(temperature,precipitation,and relative humidity)on the composition of precipitation isotope at daily level by regression analysis,utilized the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)-based backward trajectory model to simulate the air mass trajectory of precipitation events,and adopted the potential source contribution function(PSCF)and concentration weighted trajectory(CWT)to analyze the water vapor sources.The results showed that compared with the global meteoric water line(GMWL),the slope of the local meteoric water line(LMWL;δD=7.34δ^(18)O-1.16)was lower,indicating the existence of strong regional evaporation in the study area.Temperature significantly contributed toδ18O value,while relative humidity had a significant negative effect onδ18O value.Through the backward trajectory analysis,we found eight primary locations that were responsible for the water vapor sources of precipitation in the study area,of which moisture from the Indian Ocean to South China Sea(ITSC)and the western continental(CW)had the greatest influence on precipitation in the study area.The hydrogen and oxygen isotopes in precipitation are significantly influenced by the sources and transportation paths of air mass.In addition,the results of PSCF and CWT analysis showed that the water vapor source areas were primarily distributed in the south and northwest direction of the study area.

Two‑Dimensional Cr_(5)Te_(8)@Graphite Heterostructure for Efficient Electromagnetic Microwave Absorption

Two-dimensional(2D)transition metal chalcogenides(TMCs)hold great promise as novel microwave absorption materials owing to their interlayer interactions and unique magnetoelectric properties.However,overcoming the impedance mismatch at the low loading is still a challenge for TMCs due to the restricted loss pathways caused by their high-density characteristic.Here,an interface engineering based on the heterostructure of 2D Cr_(5)Te_(8) and graphite is in situ constructed via a one-step chemical vapor deposit to modulate impedance matching and introduce multiple attenuation mechanisms.Intriguingly,the Cr_(5)Te_(8)@EG(ECT)heterostructure exhibits a minimum reflection loss of up to−57.6 dB at 15.4 GHz with a thin thickness of only 1.4 mm under a low filling rate of 10%.The density functional theory calculations confirm that the splendid performance of ECT heterostructure primarily derives from charge redistribution at the abundant intimate interfaces,thereby reinforcing interfacial polarization loss.Furthermore,the ECT coating displays a remarkable radar cross section reduction of 31.9 dB m^(2),demonstrating a great radar microwave scattering ability.This work sheds light on the interfacial coupled stimulus response mechanism of TMC-based heterogeneous structures and provides a feasible strategy to manipulate high-quality TMCs for excellent microwave absorbers.

Fabrication of Graphene/Cu Composite by Chemical Vapor Deposition and Effects of Graphene Layers on Resultant Electrical Conductivity

Graphene(Gr)has unique properties including high electrical conductivity;Thus,graphene/copper(Gr/Cu)composites have attracted increasing attention to replace traditional Cu for electrical applications. However,the problem of how to control graphene to form desired Gr/Cu composite is not well solved. This paper aims at exploring the best parameters for preparing graphene with different layers on Cu foil by chemical vapor deposition(CVD)method and studying the effects of different layers graphene on Gr/Cu composite’s electrical conductivity. Graphene grown on single-sided and double-sided copper was prepared for Gr/Cu and Gr/Cu/Gr composites. The resultant electrical conductivity of Gr/Cu composites increased with decreasing graphene layers and increasing graphene volume fraction. The Gr/Cu/Gr composite with monolayer graphene owns volume fraction of less than 0.002%,producing the best electrical conductivity up to59.8 ×10^(6)S/m,equivalent to 104.5% IACS and 105.3% pure Cu foil.

Influence of vapor pressure deficit on vegetation growth in China

Vapor pressure deficit(VPD)plays a crucial role in determining plant physiological functions and exerts a substantial influence on vegetation,second only to carbon dioxide(CO_(2)).As a robust indicator of atmospheric water demand,VPD has implications for global water resources,and its significance extends to the structure and functioning of ecosystems.However,the influence of VPD on vegetation growth under climate change remains unclear in China.This study employed empirical equations to estimate the VPD in China from 2000 to 2020 based on meteorological reanalysis data of the Climatic Research Unit(CRU)Time-Series version 4.06(TS4.06)and European Centre for Medium-Range Weather Forecasts(ECMWF)Reanalysis 5(ERA-5).Vegetation growth status was characterized using three vegetation indices,namely gross primary productivity(GPP),leaf area index(LAI),and near-infrared reflectance of vegetation(NIRv).The spatiotemporal dynamics of VPD and vegetation indices were analyzed using the Theil-Sen median trend analysis and Mann-Kendall test.Furthermore,the influence of VPD on vegetation growth and its relative contribution were assessed using a multiple linear regression model.The results indicated an overall negative correlation between VPD and vegetation indices.Three VPD intervals for the correlations between VPD and vegetation indices were identified:a significant positive correlation at VPD below 4.820 hPa,a significant negative correlation at VPD within 4.820–9.000 hPa,and a notable weakening of negative correlation at VPD above 9.000 hPa.VPD exhibited a pronounced negative impact on vegetation growth,surpassing those of temperature,precipitation,and solar radiation in absolute magnitude.CO_(2) contributed most positively to vegetation growth,with VPD offsetting approximately 30.00%of the positive effect of CO_(2).As the rise of VPD decelerated,its relative contribution to vegetation growth diminished.Additionally,the intensification of spatial variations in temperature and precipitation accentuated the spatial heterogeneity in the impact of VPD on vegetation growth in China.This research provides a theoretical foundation for addressing climate change in China,especially regarding the challenges posed by increasing VPD.

Determination of Latent Heats of Vaporization and Fusion

Water is the most abundant liquid on the surface of the earth. It is a liquid whose properties are quite surprising, both as a pure liquid and as a solvent. Water is a very cohesive liquid: its melting and vaporization temperatures are very high for a liquid that is neither ionic nor metallic, and whose molar mass is low. Thus, water remains liquid at atmospheric pressure up to 100C while similar molecules such as H2S, H2Se, H2Te for example would give a vaporization temperature close to 80C. This cohesion is in fact ensured by hydrogen bonds between water molecules. This type of bonds between neighboring molecules, hydrogen bonds, is quite often found in chemistry [1] [2]. Any change in the state of aggregation of a substance occurs with the absorption or release of a certain amount of latent heat of transformation. Latent heat of fusion, vaporization or sublimation is the ratio of the energy supplied as heat to the mass of the substance that is melted, vaporized or sublimated. As a result of the reversibility of the processes, the fusion heat is equal to the heat released in the reverse process: crystallization and solidification heat. And likewise the heat of vaporization is equal to the heat of condensation. This equality of heat is often used to determine experimentally either of these quantities. There are two main measurement methods: 1) Direct measurement using the calorimeter, 2) Indirect measure based on the use of the VantHoff relationship. The objective of this work is to measure the latent heat of water vaporization and verify the compatibility of the experimental values with the values given by the tables using the indirect method.

Clipping Effect on Growth and Plant Water Use Response to Diurnal Variation of Vapor Pressure Deficit in Cenchrus biflorus Roxb

Cenchrus biflorus called Karangiya in the Hausa language is an annual pastoral grass which is a valuable herbaceous fodder in dry land region in the context of climate change. However, little is known about the plant water use under the effects of cut in West Africa Sahel like Niger where the plant is a multipurpose grass species. Therefore, this study investigated the impact of grazing (simulated by shoot cuts) on biomass production. Cenchrus biflorus Roxb was grown on field plots and in pots and subjected to shoot cuts at different levels (3 cm and 5 cm from soil surface). The effect of shoot cuts on drought tolerance was evaluated by assessing the response of transpiration to the diurnal variation of vapor pressure deficit (VPD). Results showed that the biomass production varied in response to shoot cuts depending on the culture system, and the level or frequency of cuts. The mean biomass production increased significantly especially in field plots for 5 cm cuts compared to those at 3 cm and the control treatment. In addition, transpiration was highly increased in response to the VPD increase. Shoot cuts significantly reduced transpiration, whatever the level, largely because they reduced leaf surface. We concluded that moderate grazing (cuts to 5cm) can improve biomass production and allow better adaptation to water deficit as they significantly reduced water loss through transpiration. The study recommends the cropping of the Cenchrus biflorus as climate solution as it performs better under water deficit for improving grazing resilience in Niger.

Meteorological applications of precipitable water vapor measurements retrieved by the national GNSS network of China

In this study, the Global Navigation Satellite System （GNSS） network of China is discussed, which can be used to monitor atmospheric precipitable water vapor （PWV）. By the end of 2013, the network had 952 GNSS sites, including 260 belonging to the Crustal Movement Observation Network of China （CMONOC） and 692 belonging to the China Meteorological Administration GNSS network （CMAGN）. Additionally, GNSS observation collecting and data processing procedures are presented and PWV data quality control methods are investigated. PWV levels as determined by GNSS and radiosonde are compared. The results show that GNSS estimates are generally in good agreement with measurements of radio- sondes and water vapor radiometers （WVR）. The PWV retrieved by the national GNSS network is used in weather forecasting, assimilation of data into numerical weather prediction models, the validation of PWV estimates by radiosonde, and plum rain monitoring. The network is also used to monitor the total ionospheric electron content.

Retrieval of Water Vapor Profiles with Radio Occultation Measurements Using an Artificial Neural Network

A new method applying an artificial neural network （ANN） to retrieve water vapor profiles in the troposphere is presented. In this paper, a fully-connected, three-layer network based on the backpropagation algorithm is constructed. Month, latitude, altitude and bending angle are chosen as the input vectors and water vapor pressure as the output vector. There are 130 groups of occultation measurements from June to November 2002 in the dataset. Seventy pairs of bending angles and water vapor pressure profiles are used to train the ANN, and the sixty remaining pairs of profiles are applied to the validation of the retrieval. By comparing the retrieved profiles with the corresponding ones from the Information System and Data Center of the Challenging Mini-Satellite Payload for Geoscientific Research and Application （CHAMP-ISDC）, it can be concluded that the ANN is relatively convenient and accurate. Its results can be provided as the first guess for the iterative methods or the non-linear optimal estimation inverse method.

Behavior of vapor/plasma within the keyhole and above the workpiece during CO_2 laser penetration welding

In this paper, a high-speed camera and an optical emission monitor were used to study the behavior of vapor/ plasma during CO2 laser welding of SUS304 stainless steel. Results of optical emission from vapor/plasma show that two characteristic frequency bands exist, 100 -500 Hz and 1 500 -3 500 Hz. At the same time, the changing images of vapor/ plasma and bottom pool also confirm that there are two different fluctuation frequency bands. One of the frequency bands represents the characteristic of vapor/plasma within the keyhole, and it is within 167 -500 Hz. Another frequency band is within 1 500 - 3 500 Hz, and it obviously derives from the shielding gas. Some factors may cause these frequency differences between the keyhole plasma and the shielding gas plasma. One of them is that the vapor/plasma pressure within the keyhole will increase slowly.

Moisture Analysis of a Squall Line Case Based on Precipitable Water Vapor Data from a Ground-Based GPS Network in the Yangtze River Delta

A squall line swept eastward across the area of the Yangtze River Delta and produced gusty winds and heavy rain from the afternoon to the evening of 24 August 2002. In this papers the roles of moisture in the genesis and development of the squall line were studied. Based on the precipitable water vapor （PWV） data from a ground-based GPS network over the Yangtze River Delta in China, plus data from a Pennsylvania State University/National Atmospheric Center （PSU/NCAR） mesoscale model （MM5） simulation, initialized by three-dimensional variational （3D-VAR） assimilation of the PWV data, some interesting features are revealed. During the 12 hours prior to the squall line arriving in the Shanghai area, a significant increase in PWV indicates a favorable moist environment for a squall line to develop. The vertical profile of the moisture illustrates that it mainly increased in the middle levels of the troposphere, and not at the surface. Temporal variation in PWV is a better precursor for squall line development than other surface meteorological parameters. The characteristics of the horizontal distribution of PWV not only indicated a favorable moist environment, but also evolved a cyclonic wind field for a squall line genesis and development. The ＂＋2 mm＂ contours of the three-hourly PWV variation can be used successfully to predict the location of the squall line two hours later.

Modeling the Adsorption Kinetics of Activated Carbon for Oil Vapor Recovery and Applications

Oil Vapor recovery is a critical process in downstream chemical industries, in oil and gas industries and in environmental protection. For that purpose, highly-efficient absorbent materials for vapor recovery are in high demand and their associated adsorption kinetics is of great importance for their performance. As oil vapor consists of multiple components with different physical and chemical properties, modeling the overall adsorption kinetics of activated carbon for multi-component oil vapor is essentially valuable for industrial applications. In this work, we developed a comprehensive model of multi-component gas adsorption kinetics on activated carbon in a packed-bed reactor and numerically solved the model by the finite element method. The predictions from the model are all in the reasonable range indicating good validity of the model. Some dimensionless parameters are also derived to further investigate the prediction results.

Evaluation of surface temperature and pressure derived from MERRA-2 and ERA5 reanalysis datasets and their applications in hourly GNSS precipitable water vapor retrieval over China

Temperature and pressure play key roles in Global Navigation Satellite System(GNSS) precipitable water vapor(PWV) retrieval. The National Aeronautics and Space Administration(NASA) and European Center for Medium-Range Weather Forecasts(ECMWF) have released their latest reanalysis product: the modern-era retrospective analysis for research and applications, version 2(MERRA-2) and the fifthgeneration ECMWF reanalysis(ERA5), respectively. Based on the reanalysis data, we evaluate and analyze the accuracy of the surface temperature and pressure products in China using the the measured temperature and pressure data from 609 ground meteorological stations in 2017 as reference values.Then the accuracy of the two datasets and their performances in estimating GNSS PWV are analyzed. The PWV derived from the pressure and temperature products of ERA5 and MERRA-2 has high accuracy. The annual average biases of pressure and temperature for ERA5 are-0.07 hPa and 0.45 K, with the root mean square error(RMSE) of 0.95 hPa and 2.04 K, respectively. The annual average biases of pressure and temperature for MERRA-2 are-0.01 hPa and 0.38 K, with the RMSE of 1.08 h Pa and 2.66 K, respectively.The accuracy of ERA5 is slightly higher than that of MERRA-2. The two reanalysis data show negative biases in most regions of China, with the highest to lowest accuracy in the following order: the south,north, northwest, and Tibet Plateau. Comparing the GNSS PWV calculated using MERRA-2(GNSS MERRA-2 PWV) and ERA5(GNSS ERA5 PWV) with the radiosonde-derived PWV from 48 co-located GNSS stations and the measured PWV of the co-location radiosonde stations, it is found that the accuracy of GNSS ERA5 PWV is better than that of GNSS MERRA-2 PWV. These results show the different applicability of surface temperature and pressure products from MERRA-2 and ERA5 data, indicating that both have important applications in meteorological research and GNSS water vapor monitoring in China.

Uniform deposition of ultra-thin TiO_(2) film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration

The performance of pearlescent pigment significantly affected by the grain size and the roughness of deposited film. The effect of TiCl_(4) concentration on the initial deposition of TiO_(2) on mica by atmospheric pressure chemical vapor deposition(APCVD) was investigated. The precursor concentration significantly affected the deposition and morphology of TiO_(2) grains assembling the film. The deposition time for fully covering the surface of mica decreased from 120 to 10 s as the TiCl_(4) concentration increased from 0.38%to 2.44%. The grain size increased with the TiCl_(4) concentration. The AFM and TEM analysis demonstrated that the aggregation of TiO_(2) clusters at the initial stage finally result to the agglomeration of fine TiO_(2) grains at high TiCl_(4) concentrations. Following the results, it was suggested that the nucleation density and size was easy to be adjusted when the TiCl_(4) concentration is below 0.90%.

Decadal trends in precipitable water vapor over the Indus River Basin using ERA5 reanalysis data

Precipitable Water Vapor(PWV)constitutes a pivotal parameter within the domains of atmospheric science,and remote sensing due to its profound influence on Earth’s climate dynamics and weather patterns.It exerts a significant impact on atmospheric stability absorption and emission of radiation,thus engendering alterations in the Earth’s radiative equilibrium.As such,precise quantification of PWV holds the potential to enhance weather prognostication and fortify preparedness against severe meteorological phenomena.This study aimed to elucidate the spatial and temporal changes in seasonal and annual PWV across the Indus River Basin and its sub-basins using ERA5 reanalysis datasets.The present study used ERA5 PWV(entire atmospheric column),air temperature at 2 m(t2m)and 500 hPa(T_500hPa),evapotranspiration,and total cloud cover data from 1960 to 2021.Theil Sen slope estimator and Mann-Kendall test were used for trend analysis.Correlation and multiple regression methods were used to understand the association of PWV with other factors.The findings have unveiled the highest increase in mean PWV during the monsoon(0.40 mm/decade),followed by premonsoon(0.37 mm/decade),post-monsoon(0.27 mm/decade),and winter(0.19 mm/decade)throughout the study period.Additionally,the mean PWV exhibited the most pronounced positive trend in the sub-basin Lower Indus(LI),followed by Panjnad(P),Kabul(K),and Upper Indus(UI)across all seasons,except winter.Annual PWV has also risen in the Indus basin and its sub-basins over the last six decades.PWV exhibits a consistent upward trend up to an elevation of 3500 m within the basin which is most pronounced during the monsoon season,followed by the pre-monsoon.The escalating PWV within the basin is reasonably ascribed to increasing air temperatures,augmented evapotranspiration,and heightened cloud cover.These findings hold potential utility for pertinent authorities engaged in water resource management and planning.

Measurement and prediction of isothermal vapor–liquid equilibrium of a-pinene+camphene/longifolene+abietic acid+palustric acid+neoabietic acid systems

The vapor–liquid equilibrium(VLE)data of a-pinene+camphene+[abietic acid+palustric acid+neoabietic acid]and a-pinene+longifolene+[abietic acid+palustric acid+neoabietic acid]systems at 313.15 K,333.15 K and 358.15 K were measured by headspace gas chromatography(HSGC).These data was compared with the predictions value by conductor-like screening model for realistic solvation(COSMO-RS).Moreover,the calculated data of COSMO-RS and Non-Random Two-Liquids(NRTL)models showed good agreement with the experimental data.It was found that the three resin acids inhibited the volatility of a-pinene,camphene and longifolene and resulted in the decrease of total pressure.Moreover,HE(HB)contributes the most to the excess enthalpy and the hydrogen bonding interaction is the dominant intermolecular force of a-pinene,camphene and longifolene with the three resin acids.In addition,the geometric structures optimization and binding energy were obtained by the DFT to further illustrate the hydrogen bonding interaction and the effects of the addition of the three resin acids on the isothermal VLE.