Adsorption mechanism of different coal ranks under variable temperature and pressure conditions

Variable temperature and pressure adsorption tests were conducted on four coal samples with different coal ranks, under simulated temperatures and pressures corresponding to coal reservoirs at different depths. The regularity of the variation in the amounts of adsorption by coals under variable temperature and pressure and 30 ℃ isothermal conditions are compared and the adsorption characteristics of coal under the composite effect of temperature and pressure were obtained. The adsorption test and data processing method of coal under variable temperature and pressure are presented and the effect of the mechanism of temperature and pressure on the adsorption capacity of coal has been studied. The research results are of significant importance in the investigation of coalbed methane storage mechanism and for the prediction of the amounts of coalbed methane at various depths.

Multivariable temperature measurement and control system of large-scaled vertical quench furnace based on temperature field

A temperature control system of 31m vertical forced air-circulation quench furnace is proposed, which is a kind of equipment critical for thermal treatment of aluminum alloy components that are widely used in aerospace industry. For the effective operation of the furnace, it is essential to analyze the radial temperature distribution of the furnace. A set of thermodynamic balance equations modeling is established firsdy. By utilizing the numerical analysis result to modify the temperature measurements, the control accuracy and precision of the temperature are truly guaranteed. Furthermore, the multivariable decoupling self-learning PID control algorithm based on the characteristics of strong coupling between the multi-zones in the large-scaled furnace is implemented to ensure the true homogeneity of the axial temperature distribution. Finally, the redundant structure composed of industrial control computers and touch panels leads to great improvement of system reliability.

Feedforward Variable Structural Proportional-Integral-Derivative for Temperature Control of Polymerase Chain Reaction

To track the rapidly changing temperature profiles of thermal cycling of polymerase chain reaction （PCR） accurately, an innovative feedforward variable structural proportional-integral-derivative （FVSPID） controller was developed. Based on the step response test data of the heat block, a reduced first order model was estabfished at different operating points. Based on the reduced model, the FVSPID controller combined a feedforward path with the variable structural proportional-integral-derivative （PID） control. The modified feedforward action provided directly the optimal predictive power for the desired setpoint to speed up the dynamic response. To cooperate with the feedforward action, a variable structural PID was applied, where the P mode was used in the case of the largest errors to speed up response, whereas the PD mode was used in the case of larger errors to suppress overshoot, and finally the PID mode was applied for small error conditions to eliminate the steady state offset. Experimental results illustrated that compared to the conventional PID controller, the FVSPID controller can not only reduce the time taken to complete a standard PCR protocol, but also improve the accuracy of gene amplification.

Effects of variable viscosity and temperature modulation on linear Rayleigh-Bénard convection in Newtonian dielectric liquid

The linear Rayleigh-Bénard electro-convective stability of the Newtonian dielectric liquid is determined theoretically subject to the temperature modulation with time.A perturbation method is used to compute the critical Rayleigh number and the wave number.The critical Rayleigh number is calculated as a function of the frequency of modulation,the temperature-dependent variable viscosity,the electric field dependent variable viscosity,the Prandtl number,and the electric Rayleigh number.The effects of all three cases of modulations are established to delay or advance the onset of the convection process.In addition,how the effect of variable viscosity controls the onset of convection is studied.

SOLID-STATE VARIABLE-TEMPERATURE NMR STUDY ON THE PHASE SEPARATION OF POLYETHER POLYURETHANE ZWITTERIONOMERS

Polyether-polyurethane zwitterionomers based on 4, 4'-diphenylmethane diisocyanate(MDI), methyl diethanolamine (MDEA), and polytetramethylene oxide glycol (PTMO) werestudied with variable-temperature wide-line ~1H NMR. It is found that upon ionization, degree ofphase separation in the polymer system decreased at first due to the loss of hard segmentregularity, while further ionization increased the degree of phase separation through increasinghard phase cohesion and difference of polarity between hard and soft segments.

Intertidal Biodiversity and Their Response to Climatic Variables, Temperature and pH—What We Know

As per the Essential Climate Variables (ESV) of World Meterological Organisation (WMO), the physical, chemical and biological variables critically contribute to the earth’s climate. Among them, the variables such as temperature and pH in the marine environment may affect seriously and in turn it has an impact on the biota, especially in the intertidal environment, where it has brunt force. According to United Nations Framework Convention on Climate Change (UNFCCC), the datasets should provide the empirical evidence needed to predict the climate change and evoluate the mitigation and adaptation measures. Under this context, a review was carried out to know what extent marine scientists understand this factor and what level the biodiversity was evoluated and its impact was analysed in this article. Based on the existing literature review, it was understood that only a few groups that also only few species from these groups were studied in this aspect. The remaining groups and their species and their basic trophic were not evolved in this aspect. So, the marine scientific community, environmentalist and policy makers should take stock on this aspect and give thrust on this study.

Temperature effects on atmospheric continuous-variable quantum key distribution

Compared with the fiber channel,the atmospheric channel offers the possibility of a broader geographical coverage and more flexible transmission for continuous-variable quantum key distribution(CVQKD).However,the fluctuation of atmospheric conditions will lead to the loss of performance in atmospheric quantum communication.In this paper,we study how temperature affects atmospheric CVQKD.We mainly consider the temperature effects on the transmittance and interruption probability.From the numerical simulation analysis,it can be shown that the performance of atmospheric CVQKD is improved as temperature increases,with the other factors fixed.Moreover,the results in this work can be used to evaluate the feasibility of the experimental implementation of the atmospheric CVQKD protocols.

Variable Temperature Laser Light Scattering Microscopy (VTLLSM) Studies on 10-100 μm Size High Purity Gold and Commercial Grade Zinc Grains

The VTLLS microscopy studies were made on high purity gold and commercial grade zinc grains in a temperature range of 30-230?C. Differential area ω and surface activity Sa were estimated from photomicrographs. The ω vs dT/dt (rate of heating) curve was seen to differ from those of silver and titanium. The nature of curve between normalized ω and dT/dt was seen to be non-exponential. The characteristic relation between sectorized differential area ωsec and mean temperature was examined. The present study further establishes the simplicity and versatility of the VTLLS technique, in studying the defect-sub-structure of metal particles such as Au and Zn in presence of an imposed temperature gradient in a reasonable way. As such an attempt was made to connect the ω and defect-sub-structure related parameters.

Rank-Ordering of Topographic Variables Correlated with Temperature

Spatial variations in temperature may be ascribed to many variables. Among these, variables pertaining to topography are prominent. Thus various topographic variables were calculated from 50 m-resolution digital terrain models (DTMs) for three study areas in France and for Slovenia. The “classic” geomatic variables (altitude, aspect, gradient, etc.) are supplemented by the description of landforms (amplitude of humps and hollows). Special care is taken in managing collinearity among variables and building windows with different dimensions. Statistical processing involves linear regressions of daily temperatures taken as the response variables and six topographic variables (explanatory variables). Altitude accounts significantly for the spatial variation in temperatures in 90% of cases, except in the Gironde, a lowlying area (50%). The scale of landforms also appears to be highly correlated to the measured temperature. Variations in the frequency with which topographic descriptors account for temperatures are examined from several standpoints. Altitude is less frequently taken as an explanatory variable for spatial variation of temperatures in winter (75%) than in spring (80%) and late summer (85%). Minimum temperatures are influenced on average much more by the amplitude of humps and hollows (56%) than maximum temperatures (38%) are. The frequency with which these two landforms account for the spatial variation of temperature is reversed between the minima and maxima.

Temperature Inversions,Meteorological Variables and Air Pollutants and Their Influence on Acute Respiratory Disease in the Guadalajara Metropolitan Zone,Jalisco,Mexico

The presence of temperature inversions (TI), concentration of air pollutants (AP) and meteorological variables (MV) affect the welfare of the population, creating public health problems (acute respiratory diseases ARDs, among others). The Guadalajara Metropolitan Zone (GMZ) experiences high levels of air pollution, which associated with the presence of temperature inversions and meteorological variations is conducive to the incidence of ARDs in children. The aim of this work is to evaluate the TI, MV, AP and their influence on the ARDs in children under five years in the GMZ from 2003 to 2007. In this period, the moderate and strong TI are the most frequent presenting from November to May. The AP shows a variable behavior during the year and between years, with the highest concentration of particles less than 10 microns (PM10), followed by ozone (O3), nitrogen dioxide (NO2), nitrogen oxides (NOX), carbon monoxide (CO) and sulfur dioxide (SO2), the most affected areas are the southeast of the GMZ. Annual arithmetic mean is 213,510 ± 41,209 ARDs consultations. The most important diseases are acute respiratory infections (98.0%), followed by pneumonia and bronchopneumonia (1.1%), asthma and status asthmaticus (0.5%) and streptococcal pharyngitis and tonsillitis (0.4%). Months with most inquiries were from October to March, mainly in the southeast, south and center of the city, coinciding with high levels of AP. Statistical analysis shows that the TI have significant correlation with ARDs in three years, temperature (Temp) in two, relative humidity (RH) in two, wind speed (WS) in three, wind direction (WD) in two, while that air pollutants NOX and NO2 showed significant correlation with ARDs throughout the period. CO and SO2 showed significance in two years, while the PM10 and O3 in one.

Forced vibration analysis of nano-composite rotating pressurized microbeam reinforced by CNTs based on MCST with temperature-variable material properties

In this study, free and forced vibration analysis of nano-composite rotating pressurized microbeam reinforced by carbon nanotubes （CNTs） under magnetic field based on modify couple stress theory （MCST） with temperature-variable material propertiesis presented. Also, the boundary conditions at two ends of nano-composite rotating pressurized microbeam reinforced by CNTs are considered as simply supported. The governing equations are obtained based on the Hamilton＇s principle and then computed these equations by using Navier＇s solution. The magnetic field is inserted in the thickness direction of the nano-composite microbeam. The effects of various parameters such as angular velocity, temperature changes, and pressure between of the inside and outside, the magnetic field, material length scale parameter, and volume fraction of nanocomposite microbeam on the natural frequency and response systemare studied. The results show that with increasing volume fraction of nano-composite microbeam, thickness, material length scale parameter, and magnetic fields, the natural frequency increases. The results of this research can be used for optimization of micro-structures and manufacturing sensors, displacement fluid, and drug delivery.

The Effect of Time and Temperature Variables on Some Routine Coagulation Tests among Subjects of African Descent in Sokoto, North Western Nigeria

This study evaluated the effects of time and temperature variables on routine Pro-thrombin Time test and Activated Partial Thromboplastin Time (APTT) test among subjects of African descent in Sokoto, North Western Nigeria. Samples of 99 subjects made up of 49 male and 50 female subjects with mean age 38.3 ± 22.3 years. Coagulation tests were performed immediately specified times after phlebotomy up to 24 hours (0, 1, 2, 3, 4 and 24 hours at room temperature of 40 degrees C. Our data demonstrate that prothrombin time and APTT results are stable for up to 2 hours, remaining constant regardless of storage conditions. Post hoc tests using Bonferroni correction revealed that there were increases in PT time from 0 hour to 4 hours (17.82 ± 0.61 seconds vs 18.30 ± 0.59 seconds, respectively), from 0 hour to 24 hours (17.82 ± 0.61 seconds vs 18.48 ± 0.59 seconds, respectively), from 2 hours to 4 hours (17.89 ± 0.58 seconds vs 18.30 ± 0.59 seconds), from 2 hours to 24 hours (17.89 ± 0.58 seconds vs 18.48 ± 0.58 seconds), which were all statistically significant (p = 0.002 and p < 0.000, p < 0.000, p < 0.000, respectively). However, the increase in PT time from 0 hour to 2 hours (17.82 ± 0.61 seconds vs 17.89 ± 0.59 seconds, respectively) and from 4 hours to 24 hours (18.30 ± 0.59 vs 18.48 ± 0.59 seconds, respectively) were not statistically significant (p = 1, p = 0.428). A repeated measure ANOVA determined that mean PTTK time differed statistically significantly between time points F (3, 291) = 119.22, p < 0.001. Post hoc tests using Bonferroni correction revealed that there were increase in PTTK time from 0 hour to 2 hours (37.86 ± 1.04 seconds vs 39.94 ± 1.07 seconds, respectively), from 0 hour to 4 hours (37.86 ± 1.04 seconds vs 42.34 ± 1.11 seconds, respectively), from 0 hours to 24 hours (37.86 ± 1.04 seconds vs 44.93 ± 1.20 seconds), from 2 hours to 4 hours (39.94 ± 1.07 seconds vs 42.34 ± 1.11 seconds), from 2 hours to 24 hours (39.94 ± 1.07 seconds vs 44.93 ± 1.20 seconds) and from 4 hours to 24 hours (42.43 ± 1.11 vs 44.93 ± 1.20 seconds), which were all statistically significant at p < 0.001). Therefore, we conclude that there are no statistically significant differences in the PT and APTT between 0 and 2 hours. A longer timing (after 2 hours) from phlebotomy collection of blood from respondents elicited a statistically significant increase in the PT and APTT result. There were no statistically significant differences in the PT and APTT result determined 4 hours and 24 hours after phlebotomy. Longer timing from collection of blood from respondents elicited a statistically significant increment/increase in the clotting time using PTTK. Our data demonstrate that PT and APTT results are stable for 2 hours remaining constant regardless of storage conditions.

Adsorption Kineties of Pb￣(2+) and Cu￣(2+) on Variable Charge Soils andMinerals V .Effects of Temperature and Ionic Strength￣*1

The study results of the effects of temperature and ionic strength on the adsorption kineties of Pb￣2+ and Cu￣2+ bylatosol, red soil and kaolinte coated with Mn oxide showed that Pb￣2+ and Cu￣2+ adsorption by all samples, as awhole, increased with missing temperature. Temperature also increased both values of X_m (the amount of ionadsorbed at equilibrium) and k (kinetica constant) of Pb￣2+ and Cu￣2+. The activation energies of Pb￣2+ adsorption werekaolin-Mn >red soil>goethite and those of Cu￣2+ were latosol> red soil > kaolin-Mn >goethite. For a given singlesample the activation energy of Cu￣2+ was greater than that of Pb￣2+. Raising ionic strength decreased the adsorptionof Pb￣2+ and Cu￣2+ by latosol, red soil and kaolinite coated with Mn oxide but increased Pb￣2+ and Cu￣2+ adsorption bygoethite. The contrary results could be explained by the different changes in ion forms of Pb￣2+ or Cu￣2+ and in surfacecbarge characteristics of latosol, red soil, kaolin-Mn and goethite. Increasing supporting electrolyte concentration in-creased X_m and k in goethite systems but decreased X_m and k in kaolin-Mn systems. All the time-dependent data fit-ted the surface second-order equation very well.

Variable Daily Air Temperature Model for Analysis and Design

An analytical model, TA(t), for the observed outside air temperature change, Ta(t), with time is developed using two components: one for the variation caused by the Earth’s movement, plus any other quasi-stationary thermodynamic effects due to industrialization;and one for the random variation caused by stochastic and/or chaotic, local environmental changes. The first component, TR(t), describes a regular trend, expressed by periodic functions of time and constants unchanged with time. The second component, TS, is a random, stochastic variation. For the observed outside air temperature, the analytical model of TA(t)=TR(t) +TS is such as to give a statistically best approximation for the observed time period with = min. Several versions for the TR(t) functions are defined and tested in the study for an example location for 20 years. The best model for TR(t) t is found as a linear function with time plus a variable-coefficient Fourier series with linearly changing amplitude with time. It is found that the final analytical temperature, TA(t), can be used not only to represent the historical daily mean temperature but also to predict the future daily mean temperature at the given location. The upper and lower boundaries give safety limits for the temperature prediction. The stochastic component identified in the model is stable and stationary. The method of model identification for TA(t) can be used for determining input temperature functions for supporting engineering design;or for an unbiased scientific inquiry of temperature change with time in climate studies.

Investigation of the Behavior of a Photovoltaic Cell under Concentration as a Function of the Temperature of the Base and a Variable External Magnetic Field in 3D Approximation

The photovoltaic (PV) cell performances are connected to the base photogenerated carriers charge. Some studies showed that the quantity of the photogenerated carriers charge increases with the increase of the solar illumination. This situation explains the choice of concentration PV cell (C = 50 suns) in this study. However, the strong photogeneration of the carriers charge causes a high heat production by thermalization, collision and carriers charge braking due to the electric field induced by concentration gradient. This heat brings the heating of the PV cell base. That imposes the taking into account of the temperature influence in the concentrator PV cell operation. Moreover, with the proliferation of the magnetic field sources in the life space, it is important to consider its effect on the PV cell performances. Thus, when magnetic field and base temperature increase simultaneously, we observe a deterioration of the photovoltage, the electric power, the space charge region capacity, the fill factor and the conversion efficiency. However the photocurrent increases when the base temperature increases and the magnetic field strength decreases. It appears an inversion phenomenon in the evolution of the electrical parameters as a function of magnetic field for the values of magnetic field B> 4×10-4 T.

Lie group analysis for the effect of temperature-dependent fluid viscosity and thermophoresis particle deposition on free convective heat and mass transfer under variable stream conditions

This paper examines a steady two-dimensional flow of incompressible fluid over a vertical stretching sheet. The fluid viscosity is assumed to vary as a linear function of temperature. A scaling group of transformations is applied to the governing equa- tions. The system remains invariant due to some relations among the transformation parameters. After finding three absolute invariants, a third-order ordinary differential equation corresponding to the momentum equation and two second-order ordinary differential equations corresponding to energy and diffusion equations are derived. The equations along with the boundary conditions are solved numerically. It is found that the decrease in the temperature-dependent fluid viscosity makes the velocity decrease with the increasing distance of the stretching sheet. At a particular point of the sheet, the fluid velocity decreases but the temperature increases with the decreasing viscosity. The impact of the thermophoresis particle deposition plays an important role in the concentration boundary layer. The obtained results are presented graphically and discussed.

Effects of the extrusion parameters on microstructure,texture and room temperature mechanical properties of extruded Mg-2.49Nd-1.82Gd-0.2Zn-0.2Zr alloy

Microstructure,texture,and mechanical properties of the extruded Mg-2.49Nd-1.82Gd-0.2Zn-0.2Zr alloy were investigated at different extrusion temperatures(260 and 320℃),extrusion ratios(10:1,15:1,and 30:1),and extrusion speeds(3 and 6 mm/s).The experimental results exhibited that the grain sizes after extrusion were much finer than that of the homogenized alloy,and the second phase showed streamline distribution along the extrusion direction(ED).With extrusion temperature increased from 260 to 320℃,the microstructure,texture,and mechanical properties of alloys changed slightly.The dynamic recrystallization(DRX)degree and grain sizes enhanced as the extrusion ratio increased from 10:1 to 30:1,and the strength gradually decreased but elongation(EL)increased.With the extrusion speed increased from 3 to 6 mm/s,the grain sizes and DRX degree increased significantly,and the samples presented the typical<2111>-<1123>rare-earth(RE)textures.The alloy extruded at 260℃ with extrusion ratio of 10:1 and extrusion speed of 3 mm/s showed the tensile yield strength(TYS)of 213 MPa and EL of 30.6%.After quantitatively analyzing the contribution of strengthening mechanisms,it was found that the grain boundary strengthening and dislocation strengthening played major roles among strengthening contributions.These results provide some guidelines for enlarging the industrial application of extruded Mg-RE alloy.

On-Chip Micro Temperature Controllers Based on Freestanding Thermoelectric Nano Films for Low-Power Electronics

Multidimensional integration and multifunctional com-ponent assembly have been greatly explored in recent years to extend Moore’s Law of modern microelectronics.However,this inevitably exac-erbates the inhomogeneity of temperature distribution in microsystems,making precise temperature control for electronic components extremely challenging.Herein,we report an on-chip micro temperature controller including a pair of thermoelectric legs with a total area of 50×50μm^(2),which are fabricated from dense and flat freestanding Bi2Te3-based ther-moelectric nano films deposited on a newly developed nano graphene oxide membrane substrate.Its tunable equivalent thermal resistance is controlled by electrical currents to achieve energy-efficient temperature control for low-power electronics.A large cooling temperature difference of 44.5 K at 380 K is achieved with a power consumption of only 445μW,resulting in an ultrahigh temperature control capability over 100 K mW^(-1).Moreover,an ultra-fast cooling rate exceeding 2000 K s^(-1) and excellent reliability of up to 1 million cycles are observed.Our proposed on-chip temperature controller is expected to enable further miniaturization and multifunctional integration on a single chip for microelectronics.

Modeling the Seasonal Temperature from Hourly Data: Seasonal Divisions

In this work, we present a general theoretical study leading to analytical expression of the seasonal temperature at the near surface that is expected to evaluate any area seasonal temperature of the world using the least square method to fit the hourly data to the theoretical curve of the temperature. It is shown that the temperature is globally the result of two contributions: the contribution of the revolution movement of the terrestrial globe on its elliptical orbit around the sun, the contribution of the spin-orbit coupling for the rotation movement of the terrestrial globe around its polar axis and its revolution movement. The orbital behavior of the temperature is used to find the seasonal divisions of the climate for the local area considered. The whole expression of the temperature is very useful for the meteorological needs. The contribution of the human activities and natural instabilities are the results of discrepancies which increase errors (standard deviations).

The Hawking Hubble Temperature as the Minimum Temperature, the Planck Temperature as the Maximum Temperature, and the CMB Temperature as Their Geometric Mean Temperature

Using a rigorous mathematical approach, we demonstrate how the Cosmic Microwave Background (CMB) temperature could simply be a form of geometric mean temperature between the minimum time-dependent Hawking Hubble temperature and the maximum Planck temperature of the expanding universe over the course of cosmic time. This mathematical discovery suggests a re-consideration of Rh=ctcosmological models, including black hole cosmological models, even if it possibly could also be consistent with the Λ-CDM model. Most importantly, this paper contributes to the growing literature in the past year asserting a tightly constrained mathematical relationship between the CMB temperature, the Hubble constant, and other global parameters of the Hubble sphere. Our approach suggests a solid theoretical framework for predicting and understanding the CMB temperature rather than solely observing it.1.