To improve the cruise flight performance of aircraft, two new configurations of plasma actuators(grid-type and super-dense array) were investigated to reduce the turbulent skin friction drag of a low-speed airfoil. Th...To improve the cruise flight performance of aircraft, two new configurations of plasma actuators(grid-type and super-dense array) were investigated to reduce the turbulent skin friction drag of a low-speed airfoil. The induced jet characteristics of the two actuators in quiescent air were diagnosed with high-speed particle image velocimetry(PIV), and their drag reduction efficiencies were examined under different operating conditions in a wind tunnel. The results showed that the grid-type plasma actuator was capable of producing a wall-normal jet array(peak magnitude: 1.07 m/s) similar to that generated in a micro-blowing technique, while the superdense array plasma actuator created a wavy wall-parallel jet(magnitude: 0.94 m/s) due to the discrete spanwise electrostatic forces. Under a comparable electrical power consumption level,the super-dense array plasma actuator array significantly outperformed the grid-type configuration,reducing the total airfoil friction drag by approximately 22% at a free-stream velocity of 20 m/s.The magnitude of drag reduction was proportional to the dimensionless jet velocity ratio(r), and a threshold r = 0.014 existed under which little impact on airfoil drag could be discerned.展开更多
Two-dimensional and three-dimensional shock control contour bumps are designed for a supercritical wing section with the aim of transonic wave drag reduction. The supercritical airfoil (NASA SC (02)-0714) is selec...Two-dimensional and three-dimensional shock control contour bumps are designed for a supercritical wing section with the aim of transonic wave drag reduction. The supercritical airfoil (NASA SC (02)-0714) is selected considering the fact that most modern jet transport aircrafts that operate in the transonic flow regime (cruise at transonic speeds) employ supercritical airfoil sections. Here it is to be noted that a decrease in the transonic wave drag without loss in lift would result in an increased lift to drag ratio, which is a key range parameter that can potentially increase both the range and endurance of the aircraft. The major geometric bump parameters such as length, height and span are altered for both the two-dimensional and three-dimensional bumps in order to obtain the optimum location and shape of the bump. Once an optimum standalone three-dimensional bump is acquired, an array of bumps is manually placed spanwise of an unswept supercritical wing and analyzed under fully turbulent flow conditions. Different configurations are tested with varying three-dimensional bump spacing in order to determine the contribution of bump spacing on overall performance. The results show a 14% drag reduction and a consequent 16% lift to drag ratio rise at the design Mach number for the optimum arrangement of bumps along the wing span.展开更多
We explores Hamiltonian reduction in pulse-controlled finite-dimensional quantum systems with near-degenerate eigenstates. A quantum system with a non-degenerate ground state and several near-degenerate excited states...We explores Hamiltonian reduction in pulse-controlled finite-dimensional quantum systems with near-degenerate eigenstates. A quantum system with a non-degenerate ground state and several near-degenerate excited states is controlled by a short pulse, and the objective is to maximize the collective population on all excited states when we treat all of them as one level. Two cases of the systems are shown to be equivalent to effective two-level systems. When the pulse is weak, simple relations between the original systems and the reduced systems are obtained. When the pulse is strong, these relations are still available for pulses with only one frequency under the first-order approximation.展开更多
Single-fuid nozzles and dual-fuid nozzles are the two typical jet crushing methods used in spray dust reduction. To distinguish the atomization mechanism of single-fuid and dual-fuid nozzles and improve dust control e...Single-fuid nozzles and dual-fuid nozzles are the two typical jet crushing methods used in spray dust reduction. To distinguish the atomization mechanism of single-fuid and dual-fuid nozzles and improve dust control efciency at the coal mining faces, the atomization characteristics and dust reduction performance of the two nozzles were quantitatively compared. Results of experiments show that, as water supply pressure increased, the atomization angle of the swirl pressure nozzle reaches a maximum of 62° at 6 MPa and then decreases, but its droplet size shows an opposite trend with a minimum of 41.7 μm. The water supply pressure helps to improve the droplet size and the atomization angle of the internal mixing air–liquid nozzle, while the air supply pressure has a suppressive efect for them. When the water supply pressure is 0.2 MPa and the air supply pressure reaches 0.4 MPa, the nozzle obtains the smallest droplet size which is 10% smaller than the swirl pressure nozzle. Combined with the dust reduction experimental results, when the water consumption at the working surface is not limited, using the swirl pressure nozzle will achieve a better dust reduction efect. However, the internal mixing air–liquid nozzle can achieve better and more economical dust reduction performance in working environments where water consumption is limited.展开更多
Activated red mud(RM)has been proved to be a promising base material for the selective catalysis reduction(SCR)of NOx.The inherent low reducibility and acidity limited its low-temperature activity.In this work,molybde...Activated red mud(RM)has been proved to be a promising base material for the selective catalysis reduction(SCR)of NOx.The inherent low reducibility and acidity limited its low-temperature activity.In this work,molybdenum oxide,tungsten oxide,and cerium oxide were used to reconfigure the redox sites and acid sites of red mud based catalyst.When activated red mud was reconfigured by cerium-tungsten oxide(Ce-W@RM),the NOx conversion kept above 90%at 219-480℃.The existence of Ce^(3+)/Ce^(4+) redox electron pairs provided more surface adsorbed oxygen(O_(α)) and served as a redox cycle.Positive interactions between Ce,W species and Fe oxide in red mud occurred,which led to the formation of unsaturated chemical bond and promoted the activation of adsorbed NH_(3) species.WO_(3) and Ce_(2)(WO_(4))_(3)(formed by solid-state reaction between Ce and W species)could provide more Brønsted acid sites(W-O modes of WO_(3),W=O or W-O-W modes of Ce_(2)(WO_(4))_(3)).CeO_(2) species could provide more Lewis acid sites.The Langmuir-Hinshelwood(L-H)routes and Eley-Rideal(E-R)routes occurred in the low-temperature SCR reaction on the Ce-W@RM surface.NH_(4)^(+) species on Brønsted acid sites,NH_(3) species on Lewis acid sites,bidentate nitrate and bridging nitrate species were key active intermediates species.展开更多
Pt-based nanoframes represent a class of promising catalysts towards oxygen reduction reaction. Herein, we, for the first time, successfully prepared Pt-Pd octahedral nanoframes with ultrathin ridges less than 2 nm in...Pt-based nanoframes represent a class of promising catalysts towards oxygen reduction reaction. Herein, we, for the first time, successfully prepared Pt-Pd octahedral nanoframes with ultrathin ridges less than 2 nm in thickness. The Pt-Pd octahedral nanoframes were obtained through site-selected deposition of Pt atoms onto the edge sites of Pd octahedral seeds, followed by selective removal of the Pd octahedral cores via chemical etching. Due to that a combination of three-dimensional opens geometrical structure and Pt-skin surface compositional structure, the Pt-Pd octahedral nanoframes/C catalyst shows a mass activity of 1.15 A/mgPt towards oxygen reduction reaction, 5.8 times enhancement in mass activity relative to commercial Pt/C catalyst (0.20 A/mgPt). Moreover, even after 8000 cycles of accelerated durability test, the Pt-Pd octahedral nanoframes/C catalyst still exhibits a mass activity which is more than three times higher than that of pristine Pt/C catalyst.展开更多
Time delays in the feedback control often dete- riorate the control performance or even cause the instability of a dynamic system. This paper presents a control strategy for the dynamic system with a constant or a slo...Time delays in the feedback control often dete- riorate the control performance or even cause the instability of a dynamic system. This paper presents a control strategy for the dynamic system with a constant or a slowly time-varying input delay based on a transformation, which sire-plifies the time-delay system the relation is discussed for into a delay-free one. Firstly, two existing reduction-based linear quadratic controls. One is continuous and the other is discrete. By extending the relation, a new reduction-based control is then developed with a numerical algorithm presented for practical control implementation. The controller suggested by the proposed method has such a promising property that it can be used for the cases of different values of an input time delay without redesign of controller. This property provides the potential for stabilizing the dynamic system with a time-varying input delay. Consequently, the application of the proposed method to the dynamic system with a slowly time-varying delay is discussed. Finally, numerical simulations are given to show the efficacy and the applicability of the method.展开更多
The spatial relations between the measurable wall quantities (streamwise shear stress τwx, spanwise shear stress τwz, and pressure fluctuations Pw) and the near-wall streamwise vortices (NWSV) are investigated v...The spatial relations between the measurable wall quantities (streamwise shear stress τwx, spanwise shear stress τwz, and pressure fluctuations Pw) and the near-wall streamwise vortices (NWSV) are investigated via direct numerical simulation (DNS) databases of fully developed turbulent channel flow at a low Reynolds number. In the stan- dard turbulent channel flow, the results show that all the wall measurable variables are closely associated with the NWSV. But after applying a stochastic interference, the relation based on τwx breaks down while the correlations based on Pw and τwz are still robust. Hence, two wall flow quantities based on Pw and τwz are proposed to detect the NWSV. As an appli- cation, two new control schemes are developed to suppress the near-wall vortical structures using the actuation of wall blowing/suction and obtain 16 % and 11% drag reduction, respectively.展开更多
In this paper, a low-dimensional multiple-input and multiple-output (MIMO) model predictive control (MPC) configuration is presented for partial differential equation (PDE) unknown spatially-distributed systems ...In this paper, a low-dimensional multiple-input and multiple-output (MIMO) model predictive control (MPC) configuration is presented for partial differential equation (PDE) unknown spatially-distributed systems (SDSs). First, the dimension reduction with principal component analysis (PCA) is used to transform the high-dimensional spatio-temporal data into a low-dimensional time domain. The MPC strategy is proposed based on the online correction low-dimensional models, where the state of the system at a previous time is used to correct the output of low-dimensional models. Sufficient conditions for closed-loop stability are presented and proven. Simulations demonstrate the accuracy and efficiency of the proposed methodologies.展开更多
Super high molecular weight copolymers of AM/NaA/AMPS were prepared by oxidation–reduction[OR-P(AM/NaA/AMPS)]and controlled radical polymerization[CR-P(AM/NaA/AMPS)].The resulting copolymers were fully characterized,...Super high molecular weight copolymers of AM/NaA/AMPS were prepared by oxidation–reduction[OR-P(AM/NaA/AMPS)]and controlled radical polymerization[CR-P(AM/NaA/AMPS)].The resulting copolymers were fully characterized,and the reaction conditions for their preparation were optimized.OR-P(AM/NaA/AMPS),CR-P(AM/NaA/AMPS),and conventional partially hydrolyzed polyacrylamide(HPAM)in brine solution were comprehensively characterized by thermogravimetric analysis,scanning electron microscopy,atomic force microscopy,and dynamic light scattering.ORP(AM/NaA/AMPS)and CR-P(AM/NaA/AMPS)containing AMPS monomer showed better salt resistance,temperature tolerance,and viscosification property than the conventional HPAM polymer,making them more promising for enhanced oil recovery.Through comprehensive comparison and analysis,it was found that OR-P(AM/NaA/AMPS)was more conducive for high-temperature condition due to the existence of xanthone in OR-P(AM/NaA/AMPS).On the other hand,CR-P(AM/NaA/AMPS)was more suitable for high-mineral atmosphere,which could be attributed to its higher intrinsic viscosity.展开更多
Controllable design and synthesis of catalysts with the target active sites are extremely important for their applications such as for the oxygen reduction reaction(ORR)in fuel cells.However,the controllably synthesiz...Controllable design and synthesis of catalysts with the target active sites are extremely important for their applications such as for the oxygen reduction reaction(ORR)in fuel cells.However,the controllably synthesizing electrocatalysts with a single type of active site still remains a grand challenge.In this study,we developed a facile and scalable method for fabricating highly efficient ORR electrocatalysts with sole atomic Fe-N4 species as the active site.Herein,the use of cost-effective highly porous carbon as the support not only could avoid the aggregation of the atomic Fe species but also a feasible approach to reduce the catalyst cost.The obtained atomic Fe-N4 in activated carbon(aFe@AC)shows excellent ORR activity.Its half-wave potential is 59 mV more negative but 47 mV more positive than that of the commercial Pt/C in acidic and alkaline electrolytes,respectively.The full cell performance test results show that the aFe@AC sample is a promising candidate for direct methanol fuel cells.This study provides a general method to prepare catalysts with a certain type of active site and definite numbers.展开更多
The internal balance technique is effective for the model reduction in flexible structures, especially the ones with dense frequencies. However, due to the difficulty in extracting the internal balance modal coordinat...The internal balance technique is effective for the model reduction in flexible structures, especially the ones with dense frequencies. However, due to the difficulty in extracting the internal balance modal coordinates from the physical sensor readings, research on this topic has been mostly theoretical so far, and little has been done in experiments or engineering applications. This paper studies the internal balance method theoretically as well as experimentally and designs an active controller based on the reduction model. The research works on a digital signal processor (DSP) TMS320F2812- based experiment system with a flexible beam and proposes an approximate approach to access the internal balance modal coordinates. The simulation and test results have shown that the proposed approach is feasible and effective, and the designed controller is successful in restraining the beam vibration.展开更多
Dynamic model control technologies of secondary cooling and soft reduction of Baosteel are introduced. Model principle and control system architecture are summarized, as well as functions and features. Finally, applic...Dynamic model control technologies of secondary cooling and soft reduction of Baosteel are introduced. Model principle and control system architecture are summarized, as well as functions and features. Finally, applications of model technologies are discussed. The self-developed dynamic secondary cooling model and the dynamic soft reduction model have been applied on several casting machines inside and outside Baosteel, desired control effects were achieved with good stability and reliability. Temperature measurement results verified the correctness of model.展开更多
Studies conducted on crashes at rural intersections of state highways and local roads/streets with two-way stop control have proved that the problem was likely poor judgment by the stopped driver on the minor approach...Studies conducted on crashes at rural intersections of state highways and local roads/streets with two-way stop control have proved that the problem was likely poor judgment by the stopped driver on the minor approach of the speed of an oncoming vehicle and/or safe gap in traffic on the major highway. Several mitigating strategies have been suggested and studied in various studies to improve safety at the two-way stop control rural intersections and at other rural highway segments. There are also several low-cost techniques used, mostly in foreign countries, to slow drivers on major highways as they enter small towns and villages, e.g., narrowing pavement lines, establishing visual gateways, etc. Lowered speeds would decrease crash severity. In this study, four strategies including solar speed display units, mobile speed trailers, optical speed bars, and colored pavement were tested and assessed in some locations in Kansas. The results of this research indicate that both solar speed display units and mobile speed trailers are effective in speed reduction at the desired points, but optical speed bars and colored pavements do not yield reliable results. Additional studies and longer term studies, should be conducted.展开更多
To improve the performance of an active mass damper control system,the controller should be designed based on a reduced-order model. An improved method based on balanced truncation method was proposed to reduce the di...To improve the performance of an active mass damper control system,the controller should be designed based on a reduced-order model. An improved method based on balanced truncation method was proposed to reduce the dimension of high-rise buildings,and was compared with other widely used reduction methods by using a framework with ten floors. This optimized method has improvement of reduction process and choice of the order. Based on the reduced-order model obtained by the improved method and pole-assignment algorithm,a controller was designed. Finally,a comparative analysis of structural responses,transfer functions,and poles was conducted on an actual high-rise building. The results show the effectiveness of the improved method.展开更多
This paper investigates impact of noise and signal averaging on patient control in anesthesia applications, especially in networked control system settings such as wireless connected systems, sensor networks, local ar...This paper investigates impact of noise and signal averaging on patient control in anesthesia applications, especially in networked control system settings such as wireless connected systems, sensor networks, local area networks, or tele-medicine over a wide area network. Such systems involve communication channels which introduce noises due to quantization, channel noises, and have limited communication bandwidth resources. Usually signal averaging can be used effectively in reducing noise effects when remote monitoring and diagnosis are involved. However, when feedback is intended, we show that signal averaging will lose its utility substantially. To explain this phenomenon, we analyze stability margins under signal averaging and derive some optimal strategies for selecting window sizes. A typical case of anesthe-sia depth control problems is used in this development.展开更多
The impact of environmental regulation on technology innovation is a hot spot in current research where a large number of empirical studies are based on Porter Hypothesis(PH). However, there are still controversies in...The impact of environmental regulation on technology innovation is a hot spot in current research where a large number of empirical studies are based on Porter Hypothesis(PH). However, there are still controversies in academia about the establishment of "weak" and "narrow" versions of PH. Based on the panel data of application for patent of energy conservation and emission reduction(ECER) technology of Chinese city scale during 2008-2014, comprehensive energy price, pollutant emission, etc., mixed regression model and systematic generalized method of moments method were adopted, respectively,to study the impact of market-oriented and command-and-control policy tool on China's ECER technology innovation. The results show that the environmental regulation hindered the technological innovation in the immediate phase; however, it turned out to be positive in the first-lag phase. Hence, the establishment of "weak" PH is time-bounded. The command-and-control policy tool played a more positive role in promoting technological innovation in the first-lag phase than market-oriented policy tool. Therefore, "narrow" PH is not tenable. The reason is that the main participants of China's ECER technology innovation are state-owned companies and public institutions. Regionally speaking, the impact which command-and-control policy tool has on technological innovation at sight was nonsignificant in the eastern, the central, and the western regions of China whilst market-oriented policy tool had a negative effect. And market-oriented policy tool in the central region had strongest negative effect, which would diminish in the eastern region and become weakest in the western region. This was related to regional energy consumption level and the market economic vitality.展开更多
The main technical content of full mechanized corn production in Daiyue District is explained,and the problems of disease and insect pest control in the middle and late growth stage of corn in full mechanized producti...The main technical content of full mechanized corn production in Daiyue District is explained,and the problems of disease and insect pest control in the middle and late growth stage of corn in full mechanized production are analyzed."One prevention double reduction"of corn performed by unmanned aerial vehicle(UAV)and self-propelled sprayer is compared and analyzed,and some suggestions are put forward for further popularization and application of full mechanized corn production.展开更多
At present,China’s atmospheric environmental protection work has achieved initial results,but environmental protection is facing increasing pressure,and the environmental situation is still not optimistic.In response...At present,China’s atmospheric environmental protection work has achieved initial results,but environmental protection is facing increasing pressure,and the environmental situation is still not optimistic.In response to the call of the state,efforts have been intensified in environmental protection and ecological civilization construction,and supply-side structural reform has been actively promoted,and the Implementation Plan for Tianjin’s Comprehensive Discharge of Industrial Pollution Sources to Meet Standards has been promoted.When the total amount of pollutants discharged in key areas far exceeds the environmental capacity,regional heavy pollution weather will still occur once adverse meteorological conditions are encountered.In accordance with the Law of the People’s Republic of China on the Prevention and Control of Atmospheric Pollution,when the deterioration of air quality to a certain extent,to protect public health,key gas related industries should carry out emergency emission reduction in accordance with the local emergency plan while the local government starts the emergency response of heavy pollution weather.Direct economic loss of emergency response to heavy pollution weather is enormous.On the basis of meeting the total amount of emissions required by the state,the project aims to achieve the effect of"emission reduction and production increase"by precise emission reduction according to local characteristics.展开更多
基金supported by National Natural Science Foundation of China (Nos.12002384, U2341277,and 52025064)Foundation Strengthening Program (No.2021JJ-0786)。
文摘To improve the cruise flight performance of aircraft, two new configurations of plasma actuators(grid-type and super-dense array) were investigated to reduce the turbulent skin friction drag of a low-speed airfoil. The induced jet characteristics of the two actuators in quiescent air were diagnosed with high-speed particle image velocimetry(PIV), and their drag reduction efficiencies were examined under different operating conditions in a wind tunnel. The results showed that the grid-type plasma actuator was capable of producing a wall-normal jet array(peak magnitude: 1.07 m/s) similar to that generated in a micro-blowing technique, while the superdense array plasma actuator created a wavy wall-parallel jet(magnitude: 0.94 m/s) due to the discrete spanwise electrostatic forces. Under a comparable electrical power consumption level,the super-dense array plasma actuator array significantly outperformed the grid-type configuration,reducing the total airfoil friction drag by approximately 22% at a free-stream velocity of 20 m/s.The magnitude of drag reduction was proportional to the dimensionless jet velocity ratio(r), and a threshold r = 0.014 existed under which little impact on airfoil drag could be discerned.
文摘Two-dimensional and three-dimensional shock control contour bumps are designed for a supercritical wing section with the aim of transonic wave drag reduction. The supercritical airfoil (NASA SC (02)-0714) is selected considering the fact that most modern jet transport aircrafts that operate in the transonic flow regime (cruise at transonic speeds) employ supercritical airfoil sections. Here it is to be noted that a decrease in the transonic wave drag without loss in lift would result in an increased lift to drag ratio, which is a key range parameter that can potentially increase both the range and endurance of the aircraft. The major geometric bump parameters such as length, height and span are altered for both the two-dimensional and three-dimensional bumps in order to obtain the optimum location and shape of the bump. Once an optimum standalone three-dimensional bump is acquired, an array of bumps is manually placed spanwise of an unswept supercritical wing and analyzed under fully turbulent flow conditions. Different configurations are tested with varying three-dimensional bump spacing in order to determine the contribution of bump spacing on overall performance. The results show a 14% drag reduction and a consequent 16% lift to drag ratio rise at the design Mach number for the optimum arrangement of bumps along the wing span.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China (No.61074052 and No.61072032). Herschel Rabitz acknowledges the support from Army Research Office (ARO).
文摘We explores Hamiltonian reduction in pulse-controlled finite-dimensional quantum systems with near-degenerate eigenstates. A quantum system with a non-degenerate ground state and several near-degenerate excited states is controlled by a short pulse, and the objective is to maximize the collective population on all excited states when we treat all of them as one level. Two cases of the systems are shown to be equivalent to effective two-level systems. When the pulse is weak, simple relations between the original systems and the reduced systems are obtained. When the pulse is strong, these relations are still available for pulses with only one frequency under the first-order approximation.
基金funded by the National Natural Science Foundation of China(52274237)the Fundamental Research Funds for the Central Universities(2021ZDPYYQ007)+1 种基金the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX22_2656)the Graduate Innovation Program of China University of Mining and Technology(2022WLKXJ026).
文摘Single-fuid nozzles and dual-fuid nozzles are the two typical jet crushing methods used in spray dust reduction. To distinguish the atomization mechanism of single-fuid and dual-fuid nozzles and improve dust control efciency at the coal mining faces, the atomization characteristics and dust reduction performance of the two nozzles were quantitatively compared. Results of experiments show that, as water supply pressure increased, the atomization angle of the swirl pressure nozzle reaches a maximum of 62° at 6 MPa and then decreases, but its droplet size shows an opposite trend with a minimum of 41.7 μm. The water supply pressure helps to improve the droplet size and the atomization angle of the internal mixing air–liquid nozzle, while the air supply pressure has a suppressive efect for them. When the water supply pressure is 0.2 MPa and the air supply pressure reaches 0.4 MPa, the nozzle obtains the smallest droplet size which is 10% smaller than the swirl pressure nozzle. Combined with the dust reduction experimental results, when the water consumption at the working surface is not limited, using the swirl pressure nozzle will achieve a better dust reduction efect. However, the internal mixing air–liquid nozzle can achieve better and more economical dust reduction performance in working environments where water consumption is limited.
基金supported by the National Natural Science Foundation of China(21906090)the National Key Research and Development Program(2017YFC0210200,2017YFC0212800)Primary Research&Development Project of Shandong Province(2018GSF117034,2019JZZY020305).
文摘Activated red mud(RM)has been proved to be a promising base material for the selective catalysis reduction(SCR)of NOx.The inherent low reducibility and acidity limited its low-temperature activity.In this work,molybdenum oxide,tungsten oxide,and cerium oxide were used to reconfigure the redox sites and acid sites of red mud based catalyst.When activated red mud was reconfigured by cerium-tungsten oxide(Ce-W@RM),the NOx conversion kept above 90%at 219-480℃.The existence of Ce^(3+)/Ce^(4+) redox electron pairs provided more surface adsorbed oxygen(O_(α)) and served as a redox cycle.Positive interactions between Ce,W species and Fe oxide in red mud occurred,which led to the formation of unsaturated chemical bond and promoted the activation of adsorbed NH_(3) species.WO_(3) and Ce_(2)(WO_(4))_(3)(formed by solid-state reaction between Ce and W species)could provide more Brønsted acid sites(W-O modes of WO_(3),W=O or W-O-W modes of Ce_(2)(WO_(4))_(3)).CeO_(2) species could provide more Lewis acid sites.The Langmuir-Hinshelwood(L-H)routes and Eley-Rideal(E-R)routes occurred in the low-temperature SCR reaction on the Ce-W@RM surface.NH_(4)^(+) species on Brønsted acid sites,NH_(3) species on Lewis acid sites,bidentate nitrate and bridging nitrate species were key active intermediates species.
基金This work is supported by Collaborative Innovation Center of Suzhou Nano Science and Technology, Ministry of Science and Technology of China (No.2014CB932700), the National Natural Science Foundation of China (No.21603208, No.21573206, and No.51371164), the China Postdoctoral Science Foundation (No.2015M580536, No.2016T90569), Key Research Program of Frontier Sciences, CAS (QYZDBSSW- SLH017), Strategic Priority Research Program B of the CAS (No.XDB01020000), Hefei Science Center, CAS (No.2015HSC-UP016), and Fundamental Research Funds for the Central Universities.
文摘Pt-based nanoframes represent a class of promising catalysts towards oxygen reduction reaction. Herein, we, for the first time, successfully prepared Pt-Pd octahedral nanoframes with ultrathin ridges less than 2 nm in thickness. The Pt-Pd octahedral nanoframes were obtained through site-selected deposition of Pt atoms onto the edge sites of Pd octahedral seeds, followed by selective removal of the Pd octahedral cores via chemical etching. Due to that a combination of three-dimensional opens geometrical structure and Pt-skin surface compositional structure, the Pt-Pd octahedral nanoframes/C catalyst shows a mass activity of 1.15 A/mgPt towards oxygen reduction reaction, 5.8 times enhancement in mass activity relative to commercial Pt/C catalyst (0.20 A/mgPt). Moreover, even after 8000 cycles of accelerated durability test, the Pt-Pd octahedral nanoframes/C catalyst still exhibits a mass activity which is more than three times higher than that of pristine Pt/C catalyst.
基金supported by the National Natural Science Foundation of China ( 10532050, 10702024 and 10702025) the Doctoral Fund of MOE of China (20070287029)
文摘Time delays in the feedback control often dete- riorate the control performance or even cause the instability of a dynamic system. This paper presents a control strategy for the dynamic system with a constant or a slowly time-varying input delay based on a transformation, which sire-plifies the time-delay system the relation is discussed for into a delay-free one. Firstly, two existing reduction-based linear quadratic controls. One is continuous and the other is discrete. By extending the relation, a new reduction-based control is then developed with a numerical algorithm presented for practical control implementation. The controller suggested by the proposed method has such a promising property that it can be used for the cases of different values of an input time delay without redesign of controller. This property provides the potential for stabilizing the dynamic system with a time-varying input delay. Consequently, the application of the proposed method to the dynamic system with a slowly time-varying delay is discussed. Finally, numerical simulations are given to show the efficacy and the applicability of the method.
基金supported by the National Natural Science Foundation of China(Nos.11402088 and 51376062)the Fundamental Research Funds for the Central Universities(No.2014MS33)State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(No.LAPS15005)
文摘The spatial relations between the measurable wall quantities (streamwise shear stress τwx, spanwise shear stress τwz, and pressure fluctuations Pw) and the near-wall streamwise vortices (NWSV) are investigated via direct numerical simulation (DNS) databases of fully developed turbulent channel flow at a low Reynolds number. In the stan- dard turbulent channel flow, the results show that all the wall measurable variables are closely associated with the NWSV. But after applying a stochastic interference, the relation based on τwx breaks down while the correlations based on Pw and τwz are still robust. Hence, two wall flow quantities based on Pw and τwz are proposed to detect the NWSV. As an appli- cation, two new control schemes are developed to suppress the near-wall vortical structures using the actuation of wall blowing/suction and obtain 16 % and 11% drag reduction, respectively.
基金supported by National High Technology Research and Development Program of China (863 Program)(No. 2009AA04Z162)National Nature Science Foundation of China(No. 60825302, No. 60934007, No. 61074061)+1 种基金Program of Shanghai Subject Chief Scientist,"Shu Guang" project supported by Shang-hai Municipal Education Commission and Shanghai Education Development FoundationKey Project of Shanghai Science and Technology Commission, China (No. 10JC1403400)
文摘In this paper, a low-dimensional multiple-input and multiple-output (MIMO) model predictive control (MPC) configuration is presented for partial differential equation (PDE) unknown spatially-distributed systems (SDSs). First, the dimension reduction with principal component analysis (PCA) is used to transform the high-dimensional spatio-temporal data into a low-dimensional time domain. The MPC strategy is proposed based on the online correction low-dimensional models, where the state of the system at a previous time is used to correct the output of low-dimensional models. Sufficient conditions for closed-loop stability are presented and proven. Simulations demonstrate the accuracy and efficiency of the proposed methodologies.
基金supported by the National Science and Technology Major Project(No.2016ZX05011-003)The Certificate of China Postdoctoral Science Foundation(No.2016M592241).
文摘Super high molecular weight copolymers of AM/NaA/AMPS were prepared by oxidation–reduction[OR-P(AM/NaA/AMPS)]and controlled radical polymerization[CR-P(AM/NaA/AMPS)].The resulting copolymers were fully characterized,and the reaction conditions for their preparation were optimized.OR-P(AM/NaA/AMPS),CR-P(AM/NaA/AMPS),and conventional partially hydrolyzed polyacrylamide(HPAM)in brine solution were comprehensively characterized by thermogravimetric analysis,scanning electron microscopy,atomic force microscopy,and dynamic light scattering.ORP(AM/NaA/AMPS)and CR-P(AM/NaA/AMPS)containing AMPS monomer showed better salt resistance,temperature tolerance,and viscosification property than the conventional HPAM polymer,making them more promising for enhanced oil recovery.Through comprehensive comparison and analysis,it was found that OR-P(AM/NaA/AMPS)was more conducive for high-temperature condition due to the existence of xanthone in OR-P(AM/NaA/AMPS).On the other hand,CR-P(AM/NaA/AMPS)was more suitable for high-mineral atmosphere,which could be attributed to its higher intrinsic viscosity.
基金The authors would like to thank the Australian Research Council(ARC DP170103317,DP200103043)for financial support during the course of this study.Prof Jun Chen would like to thank the Australian National Fabrication Facility and EMC at the University of Wollongong for facilities/equipment access.
文摘Controllable design and synthesis of catalysts with the target active sites are extremely important for their applications such as for the oxygen reduction reaction(ORR)in fuel cells.However,the controllably synthesizing electrocatalysts with a single type of active site still remains a grand challenge.In this study,we developed a facile and scalable method for fabricating highly efficient ORR electrocatalysts with sole atomic Fe-N4 species as the active site.Herein,the use of cost-effective highly porous carbon as the support not only could avoid the aggregation of the atomic Fe species but also a feasible approach to reduce the catalyst cost.The obtained atomic Fe-N4 in activated carbon(aFe@AC)shows excellent ORR activity.Its half-wave potential is 59 mV more negative but 47 mV more positive than that of the commercial Pt/C in acidic and alkaline electrolytes,respectively.The full cell performance test results show that the aFe@AC sample is a promising candidate for direct methanol fuel cells.This study provides a general method to prepare catalysts with a certain type of active site and definite numbers.
基金Project supported by the National Natural Science Foundation of China(Nos.11072146 and 11002087)
文摘The internal balance technique is effective for the model reduction in flexible structures, especially the ones with dense frequencies. However, due to the difficulty in extracting the internal balance modal coordinates from the physical sensor readings, research on this topic has been mostly theoretical so far, and little has been done in experiments or engineering applications. This paper studies the internal balance method theoretically as well as experimentally and designs an active controller based on the reduction model. The research works on a digital signal processor (DSP) TMS320F2812- based experiment system with a flexible beam and proposes an approximate approach to access the internal balance modal coordinates. The simulation and test results have shown that the proposed approach is feasible and effective, and the designed controller is successful in restraining the beam vibration.
文摘Dynamic model control technologies of secondary cooling and soft reduction of Baosteel are introduced. Model principle and control system architecture are summarized, as well as functions and features. Finally, applications of model technologies are discussed. The self-developed dynamic secondary cooling model and the dynamic soft reduction model have been applied on several casting machines inside and outside Baosteel, desired control effects were achieved with good stability and reliability. Temperature measurement results verified the correctness of model.
文摘Studies conducted on crashes at rural intersections of state highways and local roads/streets with two-way stop control have proved that the problem was likely poor judgment by the stopped driver on the minor approach of the speed of an oncoming vehicle and/or safe gap in traffic on the major highway. Several mitigating strategies have been suggested and studied in various studies to improve safety at the two-way stop control rural intersections and at other rural highway segments. There are also several low-cost techniques used, mostly in foreign countries, to slow drivers on major highways as they enter small towns and villages, e.g., narrowing pavement lines, establishing visual gateways, etc. Lowered speeds would decrease crash severity. In this study, four strategies including solar speed display units, mobile speed trailers, optical speed bars, and colored pavement were tested and assessed in some locations in Kansas. The results of this research indicate that both solar speed display units and mobile speed trailers are effective in speed reduction at the desired points, but optical speed bars and colored pavements do not yield reliable results. Additional studies and longer term studies, should be conducted.
文摘To improve the performance of an active mass damper control system,the controller should be designed based on a reduced-order model. An improved method based on balanced truncation method was proposed to reduce the dimension of high-rise buildings,and was compared with other widely used reduction methods by using a framework with ten floors. This optimized method has improvement of reduction process and choice of the order. Based on the reduced-order model obtained by the improved method and pole-assignment algorithm,a controller was designed. Finally,a comparative analysis of structural responses,transfer functions,and poles was conducted on an actual high-rise building. The results show the effectiveness of the improved method.
文摘This paper investigates impact of noise and signal averaging on patient control in anesthesia applications, especially in networked control system settings such as wireless connected systems, sensor networks, local area networks, or tele-medicine over a wide area network. Such systems involve communication channels which introduce noises due to quantization, channel noises, and have limited communication bandwidth resources. Usually signal averaging can be used effectively in reducing noise effects when remote monitoring and diagnosis are involved. However, when feedback is intended, we show that signal averaging will lose its utility substantially. To explain this phenomenon, we analyze stability margins under signal averaging and derive some optimal strategies for selecting window sizes. A typical case of anesthe-sia depth control problems is used in this development.
文摘The impact of environmental regulation on technology innovation is a hot spot in current research where a large number of empirical studies are based on Porter Hypothesis(PH). However, there are still controversies in academia about the establishment of "weak" and "narrow" versions of PH. Based on the panel data of application for patent of energy conservation and emission reduction(ECER) technology of Chinese city scale during 2008-2014, comprehensive energy price, pollutant emission, etc., mixed regression model and systematic generalized method of moments method were adopted, respectively,to study the impact of market-oriented and command-and-control policy tool on China's ECER technology innovation. The results show that the environmental regulation hindered the technological innovation in the immediate phase; however, it turned out to be positive in the first-lag phase. Hence, the establishment of "weak" PH is time-bounded. The command-and-control policy tool played a more positive role in promoting technological innovation in the first-lag phase than market-oriented policy tool. Therefore, "narrow" PH is not tenable. The reason is that the main participants of China's ECER technology innovation are state-owned companies and public institutions. Regionally speaking, the impact which command-and-control policy tool has on technological innovation at sight was nonsignificant in the eastern, the central, and the western regions of China whilst market-oriented policy tool had a negative effect. And market-oriented policy tool in the central region had strongest negative effect, which would diminish in the eastern region and become weakest in the western region. This was related to regional energy consumption level and the market economic vitality.
文摘The main technical content of full mechanized corn production in Daiyue District is explained,and the problems of disease and insect pest control in the middle and late growth stage of corn in full mechanized production are analyzed."One prevention double reduction"of corn performed by unmanned aerial vehicle(UAV)and self-propelled sprayer is compared and analyzed,and some suggestions are put forward for further popularization and application of full mechanized corn production.
文摘At present,China’s atmospheric environmental protection work has achieved initial results,but environmental protection is facing increasing pressure,and the environmental situation is still not optimistic.In response to the call of the state,efforts have been intensified in environmental protection and ecological civilization construction,and supply-side structural reform has been actively promoted,and the Implementation Plan for Tianjin’s Comprehensive Discharge of Industrial Pollution Sources to Meet Standards has been promoted.When the total amount of pollutants discharged in key areas far exceeds the environmental capacity,regional heavy pollution weather will still occur once adverse meteorological conditions are encountered.In accordance with the Law of the People’s Republic of China on the Prevention and Control of Atmospheric Pollution,when the deterioration of air quality to a certain extent,to protect public health,key gas related industries should carry out emergency emission reduction in accordance with the local emergency plan while the local government starts the emergency response of heavy pollution weather.Direct economic loss of emergency response to heavy pollution weather is enormous.On the basis of meeting the total amount of emissions required by the state,the project aims to achieve the effect of"emission reduction and production increase"by precise emission reduction according to local characteristics.