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Influence of mortar gap on natural vibration frequencies of high-speed railway track-bridge system 被引量:4
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作者 LIU Shao-hui JIANG Li-zhong +1 位作者 ZHOU Wang-bao FENG Yu-lin 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第8期2807-2819,共13页
Based on Hamilton’s principle, the differential equations of free vibration of track-bridge systems with mortar gap are derived. Hence, a method for calculating the natural frequencies of track-bridge systems is prop... Based on Hamilton’s principle, the differential equations of free vibration of track-bridge systems with mortar gap are derived. Hence, a method for calculating the natural frequencies of track-bridge systems is proposed. The influence of the flexural stiffness of the track-bridge system, the vertical and longitudinal stiffness of the mortar layer,gap position and gap length on the natural frequencies of a track-bridge system is discussed. The results show that the natural frequencies of the track-bridge system are more sensitive to the change of the flexural stiffness of the bridge layer. The change of the longitudinal stiffness of the mortar layer and gap position has no obvious effect on the trackbridge system’s natural frequencies, while the interlayer vertical stiffness has a larger impact. The gap length has a more significant effect on the 4th-5th order natural frequencies of the track-bridge system. The range of the natural frequencies that are affected by the gap widens as the gap length increases. 展开更多
关键词 shear deformation track-bridge system mortar gap vibration frequencies
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Ab initio potential energy surface and anharmonic vibration spectrum of NF_(3)^(+)
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作者 陈艳南 徐建刚 +3 位作者 范江鹏 马双雄 郭甜 张云光 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期327-333,共7页
Potential energy surfaces(PESs), vibrational frequencies, and infrared spectra are calculated for NF_(3)^(+) using ab initio calculations, based on UCCSD(T)/cc-p VTZ combined with vibrational configuration interaction... Potential energy surfaces(PESs), vibrational frequencies, and infrared spectra are calculated for NF_(3)^(+) using ab initio calculations, based on UCCSD(T)/cc-p VTZ combined with vibrational configuration interaction(VCI). Based on an iterative algorithm, the surfaces(SURF) program adds automatic points to the lattice representation of the potential function, the one-dimensional and two-dimensional PESs are calculated after reaching a convergence threshold, finally the smooth image of the potential energy surface is fitted. The PESs accurately account for the interaction between the different modes, with the mode q_(6) symmetrical stretching vibrations having the greatest effect on the potential energy change of the whole system throughout the potential energy surface shift. The anharmonic frequencies are obtained when the VCI matrix is diagonalized. Fundamental frequencies, overtones, and combination bands of NF_(3)^(+) are calculated, which generate the degenerate phenomenon between their frequencies. Finally, the calculated anharmonic frequency is used to plot the infrared spectra.Modal antisymmetric stretching ν_(5) and symmetric stretching ν_(6) exhibit a phenomenon of large-intensity borrowing. This study can provide data to support the characterization in the laboratory. 展开更多
关键词 ab initio methods potential energy surfaces vibration frequencies coupled resonance infrared spectra
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Research on modeling and self-excited vibration mechanism in magnetic levitation-collision interface coupling system
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作者 Jinghu TANG Chaofeng LI +1 位作者 Jin ZHOU Zhiwei WU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第5期873-890,共18页
The modeling and self-excited vibration mechanism in the magnetic levitation-collision interface coupling system are investigated.The effects of the control and interface parameters on the system's stability are a... The modeling and self-excited vibration mechanism in the magnetic levitation-collision interface coupling system are investigated.The effects of the control and interface parameters on the system's stability are analyzed.The frequency range of self-excited vibrations is investigated from the energy point of view.The phenomenon of self-excited vibrations is elaborated with the phase trajectory.The corresponding control strategies are briefly analyzed with respect to the vibration mechanism.The results show that when the levitation objects collide with the mechanical interface,the system's vibration frequency becomes larger with the decrease in the collision gap;when the vibration frequency exceeds the critical frequency,the electromagnetic system continues to provide energy to the system,and the collision interface continuously dissipates energy so that the system enters the self-excited vibration state. 展开更多
关键词 magnetic levitation coupling system self-excited vibration mechanical interface vibration frequency
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A critical review of wheel/rail high frequency vibration-induced vibration fatigue of railway bogie in China
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作者 Xingwen Wu Zhenxian Zhang +7 位作者 Wubin Cai Ningrui Yang Xuesong Jin Ping Wang Zefeng Wen Maoru Chi Shuling Liang Yunhua Huang 《Railway Sciences》 2024年第2期177-215,共39页
Purpose–This review aims to give a critical view of the wheel/rail high frequency vibration-induced vibration fatigue in railway bogie.Design/methodology/approach–Vibration fatigue of railway bogie arising from the ... Purpose–This review aims to give a critical view of the wheel/rail high frequency vibration-induced vibration fatigue in railway bogie.Design/methodology/approach–Vibration fatigue of railway bogie arising from the wheel/rail high frequency vibration has become the main concern of railway operators.Previous reviews usually focused on the formation mechanism of wheel/rail high frequency vibration.This paper thus gives a critical review of the vibration fatigue of railway bogie owing to the short-pitch irregularities-induced high frequency vibration,including a brief introduction of short-pitch irregularities,associated high frequency vibration in railway bogie,typical vibration fatigue failure cases of railway bogie and methodologies used for the assessment of vibration fatigue and research gaps.Findings–The results showed that the resulting excitation frequencies of short-pitch irregularity vary substantially due to different track types and formation mechanisms.The axle box-mounted components are much more vulnerable to vibration fatigue compared with other components.The wheel polygonal wear and rail corrugation-induced high frequency vibration is the main driving force of fatigue failure,and the fatigue crack usually initiates from the defect of the weld seam.Vibration spectrum for attachments of railway bogie defined in the standard underestimates the vibration level arising from the short-pitch irregularities.The current investigations on vibration fatigue mainly focus on the methods to improve the accuracy of fatigue damage assessment,and a systematical design method for vibration fatigue remains a huge gap to improve the survival probability when the rail vehicle is subjected to vibration fatigue.Originality/value–The research can facilitate the development of a new methodology to improve the fatigue life of railway vehicles when subjected to wheel/rail high frequency vibration. 展开更多
关键词 Wheel/rail high frequency vibration vibration fatigue Railway bogie Fatigue damage assessment
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Optimal configuration for vibration frequencies in a ring of harmonic oscillators: The nonidentical mass effect 被引量:1
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作者 Shuai Liu Guo-Yong Zhang +1 位作者 Zhiwei He Meng Zhan 《Frontiers of physics》 SCIE CSCD 2015年第3期89-100,共12页
The parameter diversity effect in coupled nonidentical elements has attracted persistent interest in nonlinear dynamics. Of fundamental importance is the so-called optimal configuration problem for how the spatial pos... The parameter diversity effect in coupled nonidentical elements has attracted persistent interest in nonlinear dynamics. Of fundamental importance is the so-called optimal configuration problem for how the spatial position of elements with different parameters precisely determines the dynamics of the whole system. In this work, we study the optimal configuration problem for the vibration spectra in the classical mass-spring model with a ring configuration, paying particular attention to how the configuration of different masses affects the second smallest vibration frequency (ω2) and the largest one (ωN). For the extreme values of ω2 and ωN, namely, (ω2)min, (ω2)max, (ωN)min, and (ωN)max, we find some explicit organization rules for the optimal configurations and some approximation rules when the explicit organization rules are not available. The different distributions of ω2 and ωN are compared. These findings are interesting and valuable for uncovering the underlying mechanism of the parameter diversity effect in more general cases. 展开更多
关键词 SYNCHRONIZATION vibration frequencies normal modes complex systems
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Geometrical structures, vibrational frequencies, force constants and dissociation energies of isotopic water molecules (H_2O, HDO, D_2O, HTO, DTO, and T_2O) under dipole electric field
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作者 史顺平 张全 +4 位作者 张莉 王蓉 朱正和 蒋刚 傅依备 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第6期174-181,共8页
The dissociation limits of isotopic water molecules are derived for the ground state. The equilibrium geometries, the vibrational frequencies, the force constants and the dissociation energies for the ground states of... The dissociation limits of isotopic water molecules are derived for the ground state. The equilibrium geometries, the vibrational frequencies, the force constants and the dissociation energies for the ground states of all isotopic water molecules under the dipole electric fields from -0.05 a.u. to 0.05 a.u. are calculated using B3P86/6-311++G(3df,3pf). The results show that when the dipole electric fields change from -0.05 a.u. to 0.05 a.u., the bond length of H-O increases whereas the bond angle of H-O H decreases because of the charge transfer induced by the applied dipole electric field. The vibrational frequencies and the force constants of isotopic water molecules change under the influence of the strong external torque. The dissociation energies increase when the dipole electric fields change from -0.05 a.u. to 0.05 a.u. and the increased dissociation energies are in the order of H2O, HDO, HTO, D2O, DTO, and T2O under the same external electric fields. 展开更多
关键词 isotopic water molecules equilibrium geometry vibrational frequencies force constants dissociation energies
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Structures,Electron Affinities and Vibrational Frequencies of SF_5OX/SF_5OX^-(X=F,Cl,Br)
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作者 程素珍 徐文国 卢士香 《Journal of Beijing Institute of Technology》 EI CAS 2009年第3期333-338,共6页
The molecular structures,electron affinities,vibrational frequencies and IR intensities of the SF5OX/SF5OX-(X=F,Cl,Br)species have been determined by four different density functional theory(DFT)methods(B3LYP,BHL... The molecular structures,electron affinities,vibrational frequencies and IR intensities of the SF5OX/SF5OX-(X=F,Cl,Br)species have been determined by four different density functional theory(DFT)methods(B3LYP,BHLYP,BP86,BLYP)in conjunction with DZP++ basis set.The BHLYP method predicts the best geometry parameters.The adiabatic electron affinities(EAad)predicted by the B3LYP/DZP++ method are 4.36 eV(SF5OF),4.13 eV(SF5OCl),4.12 eV(SF5OBr),respectively.Large electron affinity implies the corresponding anions are stable.The total intensities in the near IR "window" of the anions SF5OX-(X=F,Cl,Br)at B3LYP level are 1 602 km/mol(SF5OF-),1 868 km/mol(SF5OCl-)and 1 916 km/mol(SF5OBr-),respectively,larger than those of the corresponding neutrals.It suggests that SF5OX/SF5OX-(X=F,Cl,Br)may be used to "warm" Mars. 展开更多
关键词 electron affinity density functional theory (DFT) vibrational frequency
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A high frequency vibration compensation approach for ultrahigh resolution SAR imaging based on sinusoidal frequency modulation Fourier-Bessel transform 被引量:1
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作者 CHEN Siyu WANG Yong CAO Rui 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2023年第4期894-905,共12页
Ultrahigh resolution synthetic aperture radar(SAR)imaging for ship targets is significant in SAR imaging,but it suffers from high frequency vibration of the platform,which will induce defocus into SAR imaging results.... Ultrahigh resolution synthetic aperture radar(SAR)imaging for ship targets is significant in SAR imaging,but it suffers from high frequency vibration of the platform,which will induce defocus into SAR imaging results.In this paper,a novel compensation method based on the sinusoidal frequency modulation Fourier-Bessel transform(SFMFBT)is proposed,it can estimate the vibration errors,and the phase shift ambiguity can be avoided via extracting the time frequency ridge consequently.By constructing the corresponding compensation function and combined with the inverse SAR(ISAR)technique,well-focused imaging results can be obtained.The simulation imaging results of ship targets demonstrate the validity of the proposed approach. 展开更多
关键词 synthetic aperture radar(SAR) high frequency vibration compensation sinusoidal frequency modulation FourierBessel transform(SFMFBT)
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Vibration Frequency in Micro-Vibration Therapy in Nursing Care: A Cross-Sectional Study
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作者 Teppei Yamashita Shinsuke Sasaki Mari Azuma 《Open Journal of Nursing》 2023年第4期226-232,共7页
This study investigated the vibration frequency in micro-vibration therapy (MVT) performed as a part of nursing care in Japan. We surveyed 31 nurses (25 women and 6 men) who performed MVT with accelerometers attached ... This study investigated the vibration frequency in micro-vibration therapy (MVT) performed as a part of nursing care in Japan. We surveyed 31 nurses (25 women and 6 men) who performed MVT with accelerometers attached to the backs of their hands, and the data obtained were analyzed. The mean vibration frequency was 8.3 Hz (standard deviation [SD]: 1.9 Hz) bilaterally, with a left-right difference of 0.8 Hz (SD: 1.1 Hz, right > left). Furthermore, vibration frequency was correlated with duration of MVT use (rs = 0.5, P < 0.01). The vibration frequency was higher in men (9.2 Hz, SD: 2.4 Hz) than in women (8.1 Hz, SD: 1.8 Hz), but this difference was not significant (P = 0.34). The vibrations of MVT are of a lower frequency than those of other vibration therapies. 展开更多
关键词 Micro-vibration Therapy Nursing Care vibration Frequency
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Methanol Perturbing Modeling Cell Membranes Investigated using Linear and Nonlinear Vibrational Spectroscopy 被引量:1
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作者 田康振 李红春 叶树集 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第1期27-34,I0003,共9页
Cell membranes play a crucial role in many biological functions of cells. A small change in the composition of cell membranes can strongly influence the functions of membrane-associated proteins, such as ion and water... Cell membranes play a crucial role in many biological functions of cells. A small change in the composition of cell membranes can strongly influence the functions of membrane-associated proteins, such as ion and water channels, and thus mediate the chemical and physical balance in cells. Such composition change could originate from the introduction of short-chain alcohols, or other anesthetics into membranes. In this work, we have applied sum frequency generation vibrational spectroscopy (SFG-VS), supplemented by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), to investigate interaction between methanol and 1,2-dimyristoyl-d54-sn-glycero-3-phosphocholine (d54-DMPC) lipid bilayers. Lipid's hydrocarbon interior is deuterated while its head group is hydrogenated. At the same time, CH3 symmetric stretch from methanol and lipid head amine group has different frequency, thus we can distinguish the behaviors of methanol, lipid head amine group, and lipid hydrocarbon interior. Based on the spectral feature of the bending mode of the water molecules replaced by methanol, we determined that the methanol molecules are intercalated into the region between amine and phosphate groups at the lipid hydrophilic head. The dipole of CH3 groups of methanol and lipid head, and the water O-H M1 adopt the same orientation directions. The introduction of methanol into the lipid hydrophilic head group can strongly perturb the entire length of the alkyl chains, resulting that the signals of CD2 and CD3 groups from both leaflets can not cancel each other. 展开更多
关键词 Sum frequency generation vibrational spectroscopy Cell membrane METHANOL INTERACTION MECHANISM
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Application of coupled analysis methods for prediction of blast-induced dominant vibration frequency 被引量:10
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作者 Li Haibo Li Xiaofeng +2 位作者 Li Jianchun Xia Xiang Wang Xiaowei 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2016年第1期153-162,共10页
Blast-induced dominant vibration frequency (DVF) involves a complex, nonlinear and small sample system considering rock properties, blasting parameters and topography. In this study, a combination of grey relational... Blast-induced dominant vibration frequency (DVF) involves a complex, nonlinear and small sample system considering rock properties, blasting parameters and topography. In this study, a combination of grey relational analysis and dimensional analysis procedures for prediction of dominant vibration frequency are presented. Six factors are selected from extensive effect factor sequences based on grey relational analysis, and then a novel blast-induced dominant vibration frequency prediction is obtained by dimensional analysis. In addition, the prediction is simplified by sensitivity analysis with 195 experimental blast records. Validation is carried out for the proposed formula based on the site test database of the first- period blasting excavation in the Guangdong Lufeng Nuclear Power Plant (GLNPP). The results show the proposed approach has a higher fitting degree and smaller mean error when compared with traditional predictions. 展开更多
关键词 grey relational analysis dimensional analysis sensitivity analysis dominant vibration frequency PREDICTION
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Effect of vibration frequency on primary phase and properties of grey cast iron fabricated by lost foam casting 被引量:7
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作者 Bo-tao Xiao Zi-tian Fan +2 位作者 Wen-ming Jiang Jun-huai Xiang Xue-fang Yan 《China Foundry》 SCIE 2020年第1期1-7,共7页
The properties of gray cast iron(GCI)are affected by density of matrix,size of flake graphite and primary austenite.In this paper,the Y-type specimen of GCI was prepared by lost foam casting(LFC)with and without vibra... The properties of gray cast iron(GCI)are affected by density of matrix,size of flake graphite and primary austenite.In this paper,the Y-type specimen of GCI was prepared by lost foam casting(LFC)with and without vibration,and the influence of vibration frequency on the density of matrix,size of primary phase,and properties of the GCI was studied.The results show that the length of the flake graphite and the size of the primary austenite in GCI firstly decrease and then increase with the increase of the vibration frequency.With a vibration frequency of 35 Hz,the length of the flake graphite is the shortest,the primary austenite is the finest and the density of the matrix is the highest.In addition,the tensile strength,elongation and hardness of the GCI firstly increase and then decrease with the increase of the vibration frequency,due to the refinement of the primary phase and the increase of the matrix density.In order to analyze the refinement mechanism of the primary phase of the GCI fabricated by the LFC with vibration,the solidification temperature fields of the GCI fabricated by the LFC with the vibration frequency of 0 and 35 Hz were measured.The results show that the vibration reduces the eutectic point of the GCI and increases the supercooling degree during the eutectic transformation.As a result,the length of the flake graphite and the size of the primary austenite in GCI fabricated by LFC with the vibration frequency of 35 Hz decrease. 展开更多
关键词 vibration frequency lost foam casting grey cast iron flake graphite PROPERTIES
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Methanol Adsorption on TiO2 Film Studied by Sum Frequency Generation Vibrational Spectroscopy
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作者 冯冉冉 刘安安 +3 位作者 刘烁 施骄健 刘怡 任泽峰 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2015年第1期11-16,I0001,共7页
A broadband infrared surface sum frequency generation vibrational spectroscopy (SFG-VS) and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact h... A broadband infrared surface sum frequency generation vibrational spectroscopy (SFG-VS) and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact high vacuum cell, organic contaminants on TiO2 thin film surface prepared by RF magnetron sputtering were in situ removed under 266 nm irradiation in 10 kPa 02 atmosphere. We obtained the methanol spectrum in the CH3 stretching vibration region on TiO2 surface with changing the methanol pressure at room temperature. Features of both molecular and dissociative methanol, methoxy, adsorbed on this surface were resolved. The CH3 symmetric stretching vibration frequency and Fermi resonance of molecular methanol is red-shifted by about 6-8 cm-1 from low to high coverage. Moreover, the recombination of dissociative methanol and H on Surfaces in vacuum was also observed. Our results suggest two equilibria exist: between molecular methanol in the gas phase and that on surfaces, and between molecular methanol and dissociative methanol on surfaces. 展开更多
关键词 Surface sum frequency generation vibrational spectroscopy Surface photo-catalysis TIO2
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Various performance-enhancing effects from the same intensity of whole-body vibration training 被引量:2
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作者 Paohung Chung Chiang Liu +3 位作者 Hsinghsiang Wang Yu Liu Longren Chuang Tzyy-Yuang Shiang 《Journal of Sport and Health Science》 SCIE 2017年第3期333-339,共7页
Purpose:The purpose of this study was to compare the effects of an 8-week whole-body vibration training program in various frequency and amplitude settings under the same acceleration on the strength and power of the ... Purpose:The purpose of this study was to compare the effects of an 8-week whole-body vibration training program in various frequency and amplitude settings under the same acceleration on the strength and power of the knee extensors.Methods:Sixty-four young participants were randomly assigned to 1 of 4 groups with the same acceleration(4 g):high frequency and low amplitude(n = 16,32 Hz,1 mm) group,medium frequency and medium amplitude(n = 16,18 Hz,3 mm) group,low frequency and high amplitude(n = 16,3 Hz,114 mm) group,and control(n = 16,no vibration) group.All participants underwent 8 weeks of training with body mass dynamic squats,3 sessions a week.Results:The results showed that the high frequency and low amplitude group increased significantly in isometric contraction strength and 120°/s isokinetic concentric contraction strength;the medium frequency and medium amplitude group increased significantly in 60°/s and 120°/s isokinetic strength of both concentric and eccentric contraction;and the low frequency and high amplitude group increased significantly in 60°/s and 120°/s isokinetic eccentric contraction strength.Conclusion:All frequency and amplitude settings in the 8-week whole-body vibration training increased muscle strength,but different settings resulted in various neuromuscular adaptations despite the same intensity. 展开更多
关键词 Isokinetic contraction strength Muscle contraction speed Neuromuscular adaptation vibration acceleration vibration amplitude vibration frequency
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Effects of tension on vortex-induced vibration(ⅥⅤ) responses of a long tensioned cylinder in uniform flows 被引量:2
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作者 Ling Kang Fei Ge +1 位作者 Xiaodong Wu Youshi Hong 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2017年第1期1-9,共9页
The effects of tension on vortex-induced vibration (VIV) responses for a tension-dominated long cylinder with an aspect ratio of 550 in uniform flows are experimentally investigated in this paper. The results show tha... The effects of tension on vortex-induced vibration (VIV) responses for a tension-dominated long cylinder with an aspect ratio of 550 in uniform flows are experimentally investigated in this paper. The results show that elevated tension suppresses fluctuations of maximum displacement with respect to flow velocity and makes chaotic VIV more likely to appear. With respect to periodic VIV, if elevated tension is applied, the dominant vibration frequency in the in-line (IL) direction will switch from a fundamental vibration frequency to twice the value of the fundamental vibration frequency, which results in a ratio of the dominant vibration frequency in the IL direction to that in the cross-flow direction of 2.0. The suppression of the elevated tension in the fluctuation of the maximum displacement causes the axial tension to become an active control parameter for the VIV maximum displacement of a tension-dominated long riser or tether of an engineering structure in deep oceans. However, the axial tension must be optimized before being used since the high dominant vibration frequency due to the elevated tension may unfavorably affect the fatigue life of the riser or tether. 展开更多
关键词 Tension effect Maximum displacement Dominant vibration frequency CHAOS
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Cascaded quasi-zero stiffness nonlinear low-frequency vibration isolator inspired by human spine 被引量:4
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作者 Guoxin JIN Zhenghao WANG Tianzhi YANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2022年第6期813-824,共12页
Human motion induced vibration has very low frequency,ranging from 2 Hz to 5 Hz.Traditional vibration isolators are not effective in low-frequency regions due to the trade-off between the low natural frequency and the... Human motion induced vibration has very low frequency,ranging from 2 Hz to 5 Hz.Traditional vibration isolators are not effective in low-frequency regions due to the trade-off between the low natural frequency and the high load capacity.In this paper,inspired by the human spine,we propose a novel bionic human spine inspired quasi-zero stiffness(QZS)vibration isolator which consists of a cascaded multi-stage negative stiffness structure.The force and stiffness characteristics are investigated first,the dynamic model is established by Newton’s second law,and the isolation performance is analyzed by the harmonic balance method(HBM).Numerical results show that the bionic isolator can obtain better low-frequency isolation performance by increasing the number of negative structure stages,and reducing the damping values and external force values can obtain better low-frequency isolation performance.In comparison with the linear structure and existing traditional QZS isolator,the bionic spine isolator has better vibration isolation performance in low-frequency regions.It paves the way for the design of bionic ultra-low-frequency isolators and shows potential in many engineering applications. 展开更多
关键词 bionic spine inspired vibration isolator harmonic balance method(HBM) quasi-zero stiffness(QZS) ultra-low frequency vibration isolation
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A Highly Sensitive Femtosecond Time-Resolved Sum Frequency Generation Vibrational Spectroscopy System with Simultaneous Measurement of Multiple Polarization Combinations 被引量:2
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作者 谈军军 罗毅 叶树集 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2017年第6期671-677,I0002,共8页
Characterization of real-time and ultrafast motions of the complex molecules at surface and interface is critical to understand how interracial molecules function. It requires to develop surface-sensitive, fast-identi... Characterization of real-time and ultrafast motions of the complex molecules at surface and interface is critical to understand how interracial molecules function. It requires to develop surface-sensitive, fast-identification, and time-resolved techniques. In this study, we employ several key technical procedures and successfully develop a highly sensitive femtosecond time-resolved sum frequency generation vibrational spectroscopy (SFG-VS) system. This system is able to measure the spectra with two polarization combinations (ssp and ppp, or psp and ssp) simultaneously. It takes less than several seconds to collect one spectrum. To the best of our knowledge, it is the fastest speed of collecting SFG spectra reported by now. Using the time-resolved measurement, ultrafast vibrational dynamics of the N-H mode of α-helical peptide at water interface is determined. It is found that the membrane environment does not affect the N-H vibrational relaxation dynamics. It is expected that the time-resolved SFG system will play a vital role in the deep understanding of the dynamics and interaction of the complex molecules at surface and interface. Our method may also provide an important technical proposal for the people who plan to develop time-resolved SFG systems with simultaneous measurement of multiple polarization combinations. 展开更多
关键词 Femtosecond time-resolved Sum frequency generation vibrational spectroscopy Ultrafast vibrational dynamics Multiple polarization combination measurement CHIRAL
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Calculations of the vibrational frequency and isotopic shift of UF_6 and U_2 F_6 被引量:1
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作者 张云光 查新未 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第7期262-267,共6页
Molecular structure, vibrational frequency and infrared intensity of UF6 are investigated by using the revised Perdew Burke-Enzerhof function with the triple-zeta polarized basis set. The calculation results are in go... Molecular structure, vibrational frequency and infrared intensity of UF6 are investigated by using the revised Perdew Burke-Enzerhof function with the triple-zeta polarized basis set. The calculation results are in good agreement with the experimental values and indicate the existence of a stable U2F6 molecule with a multiple bonded U2 unit. The calculation results also predict that the D3d symmetry of U2F6 is more stable than D3h. The optimized geometries, vibrational frequencies, and infrared intensities are also reported for U2F6 molecules in D3d symmetry. In addition, the isotopic shift of vibrational frequencies of the two molecules under isotopic substitution of uranium atom are also investigated with the same method. The U2F6 molecule is predicted to be better than UF6 for laser uranic isotope separation. 展开更多
关键词 molecular structure vibrational frequency infrared intensity isotopic shift
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The Effect of Cutout on Natural Frequencies of Thin Plate 被引量:1
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作者 杨国树 《Journal of Beijing Institute of Technology》 EI CAS 1996年第1期7-12,共6页
The laws that natural frequencies of rectangular plate with a cutout will change with size and position of cutout are obtained by analytic, numerical and experimental methods.
关键词 vibrational frequency thin plate CUTOUT
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DESIGN AND ANALYSIS OF NOVEL ACTIVE ACTUATOR TO CONTROL LOW FREQUENCY VIBRATIONS OF SHAFT SYSTEM 被引量:1
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作者 YU Yilong LIU Changwen +2 位作者 YANG Yanxiang WANG Shuang ZHANG Junhong 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2008年第6期41-47,共7页
Aiming at providing with high-load capability in active vibration control of large-scale rotor system, a new type of active actuator to simultaneously reduce the dangers of low frequency flexural and torsional vibrati... Aiming at providing with high-load capability in active vibration control of large-scale rotor system, a new type of active actuator to simultaneously reduce the dangers of low frequency flexural and torsional vibrations is designed. The actuator employs electro-hydraulic system and can provide a high and circumferential load. To initialize new research, the characteristics of various kinds of active actuators to control rotor shaft vibration are briefly introduced. The purpose of this paper is to introduce the preliminary results via presenting the structure, functions and operating principles, in particular, the working process of the electro-hydraulic system of the new actuator which includes a set of high speed electromagnetic valves and a series of sloping cone-shaped openings, and presenting the transmission relationships among the control parameters from control signals into the valves to active load onto shaft. The course of the work is dynamic, and a series of spatial forces and moments are put on the shaft to get an external resultant force to reduce excitations that induce vibration of shafts. By checking states of vibration, the actuator can control the impulse width and the interval of injection time for applying different control force to a vibration shaft in two circumference directions through the regulating action of a set of combination directional control valves. The results from simulating analysis and experiment show evidence of that this design can satisfy the case of active process of decreasing of flexural and torsional vibrations. 展开更多
关键词 Actuators Low frequency vibration Active control Large-scale rotation shafts System development
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