The synergetic influence of silane-grafting and polar additives (EVA) on the water tree resistance of the low density polyethylene has been investigated. A series of samples obtained before and after hydration have ...The synergetic influence of silane-grafting and polar additives (EVA) on the water tree resistance of the low density polyethylene has been investigated. A series of samples obtained before and after hydration have been characterized by measuring gel content, infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and dielectric measurements. The results obtained clearly show that the silane condensation occurred and that the silane-grafting and polar additives have synergetic effects on the water tree resistance of LDPE with little influence on its dielectric properties, e.g. the dielectric breakdown strength, dielectric permittivity and loss tangent.展开更多
借助流变仪研究了苯基三苯乙炔基硅烷(PTPES)、乙烯基三苯乙炔基硅烷(VTPES)、二苯基二苯乙炔基硅烷(BPBPES)3种单体及其聚合物(TSAR)的流变性能,并利用热分析技术分析了共聚物的反应动力学,建立了热分解机理函数。流变分析表明,3种单...借助流变仪研究了苯基三苯乙炔基硅烷(PTPES)、乙烯基三苯乙炔基硅烷(VTPES)、二苯基二苯乙炔基硅烷(BPBPES)3种单体及其聚合物(TSAR)的流变性能,并利用热分析技术分析了共聚物的反应动力学,建立了热分解机理函数。流变分析表明,3种单体加工窗口超过150℃,具有良好的加工性能;热重分析显示,800℃时聚合物残炭率在70%左右;8种动力学分析证实,聚合物热分解反应级数n=4,反应活化能E=131.2 k J/mol。展开更多
文摘The synergetic influence of silane-grafting and polar additives (EVA) on the water tree resistance of the low density polyethylene has been investigated. A series of samples obtained before and after hydration have been characterized by measuring gel content, infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and dielectric measurements. The results obtained clearly show that the silane condensation occurred and that the silane-grafting and polar additives have synergetic effects on the water tree resistance of LDPE with little influence on its dielectric properties, e.g. the dielectric breakdown strength, dielectric permittivity and loss tangent.
文摘借助流变仪研究了苯基三苯乙炔基硅烷(PTPES)、乙烯基三苯乙炔基硅烷(VTPES)、二苯基二苯乙炔基硅烷(BPBPES)3种单体及其聚合物(TSAR)的流变性能,并利用热分析技术分析了共聚物的反应动力学,建立了热分解机理函数。流变分析表明,3种单体加工窗口超过150℃,具有良好的加工性能;热重分析显示,800℃时聚合物残炭率在70%左右;8种动力学分析证实,聚合物热分解反应级数n=4,反应活化能E=131.2 k J/mol。