Waxy crude oil exhibits complex rheological behavior below the pour point temperature, such as viscoelasticity, yield stress, and thixotropy, owing to the formation of a three-dimensional spongelike interlock network ...Waxy crude oil exhibits complex rheological behavior below the pour point temperature, such as viscoelasticity, yield stress, and thixotropy, owing to the formation of a three-dimensional spongelike interlock network structure. This viscoelasto-thixotropic behavior is an important rheologieal behavior of waxy crude oils, determining the flow recovery and safe restart of crude oil pipelines. Up to now, the thixotropic models for waxy crude have been all viscoplastic models, without considering the viscoelastic part before the yield point. In this work, based on analyzing the variation of the elastic stress and viscous stress in the Mujumbar model, a new viscoelasto-plastic model is proposed, whose shear stress is separated into an elastic component and a viscous component. The elastic stress is the product of the shear modulus and elastic strain; the shear modulus is proportional to the structural parameter. For the elastic strain, we followed the line of Zhu and his coauthors and assumed that it may be expressed by an algebraic equation. The model is validated by stepwise shear rate tests and hysteresis loop tests on Daqing and Zhongyuan waxy crude. The results show that the model＇s fitting and predictive capability is satisfactory.展开更多
Based on the continuum physics and taking into account variation of the heat dissipation, Helmholtz free ener-gy, internal energy and exothermicity with the thermodynamic process, in this paper, the functional equatio...Based on the continuum physics and taking into account variation of the heat dissipation, Helmholtz free ener-gy, internal energy and exothermicity with the thermodynamic process, in this paper, the functional equations of the general-ized stress and entropy associated ivith the time and temperature are derived for the irreversible process of thermoviscoelastic-plastic materials. As an example, the response functionals of Maxwell viscoelastic materials are obtained.展开更多
基金the financial support from the National Natural Science Foundation of China (Grant No.51134006)Science Foundation of China University of Petroleum (Beijing) (Grant No.LLYJ-2011-55)
文摘Waxy crude oil exhibits complex rheological behavior below the pour point temperature, such as viscoelasticity, yield stress, and thixotropy, owing to the formation of a three-dimensional spongelike interlock network structure. This viscoelasto-thixotropic behavior is an important rheologieal behavior of waxy crude oils, determining the flow recovery and safe restart of crude oil pipelines. Up to now, the thixotropic models for waxy crude have been all viscoplastic models, without considering the viscoelastic part before the yield point. In this work, based on analyzing the variation of the elastic stress and viscous stress in the Mujumbar model, a new viscoelasto-plastic model is proposed, whose shear stress is separated into an elastic component and a viscous component. The elastic stress is the product of the shear modulus and elastic strain; the shear modulus is proportional to the structural parameter. For the elastic strain, we followed the line of Zhu and his coauthors and assumed that it may be expressed by an algebraic equation. The model is validated by stepwise shear rate tests and hysteresis loop tests on Daqing and Zhongyuan waxy crude. The results show that the model＇s fitting and predictive capability is satisfactory.
文摘Based on the continuum physics and taking into account variation of the heat dissipation, Helmholtz free ener-gy, internal energy and exothermicity with the thermodynamic process, in this paper, the functional equations of the general-ized stress and entropy associated ivith the time and temperature are derived for the irreversible process of thermoviscoelastic-plastic materials. As an example, the response functionals of Maxwell viscoelastic materials are obtained.
