The effects of MgO and TiO_2 on the viscosity, activation energy for viscous flow, and break-point temperature of titanium-bearing slag were studied. The correlation between viscosity and slag structure was analyzed b...The effects of MgO and TiO_2 on the viscosity, activation energy for viscous flow, and break-point temperature of titanium-bearing slag were studied. The correlation between viscosity and slag structure was analyzed by Fourier transform infrared(FTIR) spectroscopy. Subsequently, main phases in the slag and their content changes were investigated by X-ray diffraction and Factsage 6.4 software package. The results show that the viscosity decreases when the MgO content increases from 10.00wt% to 14.00wt%. Moreover, the break-point temperature increases, and the activation energy for viscous flow initially increases and subsequently decreases. In addition, with increasing TiO_2 content from 5.00wt% to 9.00wt%, the viscosity decreases, and the break-point temperature and activation energy for viscous flow initially decrease and subsequently increase. FTIR analyses reveal that the polymerization degree of complex viscous units in titanium-bearing slag decreases with increasing MgO and TiO_2 contents. The mechanism of viscosity variation was elucidated. The basic phase in experimental slags is melilite. Besides, as the MgO content increases, the amount of magnesia–alumina spinel in the slag increases. Similarly, the sum of pyroxene and perovskite phases in the slag increases with increasing TiO_2 content.展开更多
Aiming at overcoming the low plasticity of magnesium alloy at room temperature, we researched viscous warm pressure bulging(VWPB) of AZ31B magnesium alloy based on the excellent thermal stability of viscous medium u...Aiming at overcoming the low plasticity of magnesium alloy at room temperature, we researched viscous warm pressure bulging(VWPB) of AZ31B magnesium alloy based on the excellent thermal stability of viscous medium under the warm forming condition. The potential improvements of plastic deformation ability and forming quality of AZ31B magnesium alloy are expected with the aid of thermal characteristics of viscous medium. During bulging process the velocity field variation and pressure stress field distribution of viscous medium are observed at different temperatures through which the effect of temperature on the mechanical property of viscous medium and AZ31B magnesium alloy are analyzed. The results show that the formability of AZ31B magnesium alloy increases first and then decreases as the temperature increases and it is the best at 200 ℃. On the other hand, the viscous medium which can build non-uniform pressure stress field also exhibits a good flow property at elevated temperature, and it is helpful to improving the formability of AZ31B magnesium alloy.展开更多
基金financial support by the Fundamental Research Funds for the Central Universities (No. N130602003)National High Technology Research and Development Program of China (No. 2012AA062302)the National Natural Science Foundation of China (No. 51574067)
文摘The effects of MgO and TiO_2 on the viscosity, activation energy for viscous flow, and break-point temperature of titanium-bearing slag were studied. The correlation between viscosity and slag structure was analyzed by Fourier transform infrared(FTIR) spectroscopy. Subsequently, main phases in the slag and their content changes were investigated by X-ray diffraction and Factsage 6.4 software package. The results show that the viscosity decreases when the MgO content increases from 10.00wt% to 14.00wt%. Moreover, the break-point temperature increases, and the activation energy for viscous flow initially increases and subsequently decreases. In addition, with increasing TiO_2 content from 5.00wt% to 9.00wt%, the viscosity decreases, and the break-point temperature and activation energy for viscous flow initially decrease and subsequently increase. FTIR analyses reveal that the polymerization degree of complex viscous units in titanium-bearing slag decreases with increasing MgO and TiO_2 contents. The mechanism of viscosity variation was elucidated. The basic phase in experimental slags is melilite. Besides, as the MgO content increases, the amount of magnesia–alumina spinel in the slag increases. Similarly, the sum of pyroxene and perovskite phases in the slag increases with increasing TiO_2 content.
基金Funded by the National Natural Science Foundation of China(No.51575364)the Natural Science Foundation of Liaoning Province(No.2013024014)
文摘Aiming at overcoming the low plasticity of magnesium alloy at room temperature, we researched viscous warm pressure bulging(VWPB) of AZ31B magnesium alloy based on the excellent thermal stability of viscous medium under the warm forming condition. The potential improvements of plastic deformation ability and forming quality of AZ31B magnesium alloy are expected with the aid of thermal characteristics of viscous medium. During bulging process the velocity field variation and pressure stress field distribution of viscous medium are observed at different temperatures through which the effect of temperature on the mechanical property of viscous medium and AZ31B magnesium alloy are analyzed. The results show that the formability of AZ31B magnesium alloy increases first and then decreases as the temperature increases and it is the best at 200 ℃. On the other hand, the viscous medium which can build non-uniform pressure stress field also exhibits a good flow property at elevated temperature, and it is helpful to improving the formability of AZ31B magnesium alloy.