Characteristics and identification of weathering crust of Pennsylvanian volcanic rocks in Shixi area,Junggar Basin

Based on drill core and thin section observation,major geochemical element analysis and con-ventional well log analysis,this study summarizes the characteristics and thickness of weathering crust of Pennsylvanian volcanic rocks(Carboniferous)in Shixi area,Junggar Basin.The weathering crust is identified and divided into three types according to the petrological characteristics and well log interpretations in Shixi area,and the isopach of weathering crust is mapped.The results show that:(1)With the increase of depth,the weathering weakens,and the rocks become less fractured with decreased porosity;(2)the weathering crust of the Upper Carboniferous volcanic rocks can be divided into strongly weathered and mildly weathered layers in Shixi area;(3)the weathering crust is relatively thicker in Dinan uplift and Shixi uplift.This study provides research basis for further evaluation of Upper Carboniferous volcanic reservoir,and will benefit for well location deployment and potential oilfield development in the Shixi area.

U-Pb Dating of Volcanic Rocks and Granites along the Wuyishan Belt:Constraints on Timing of Late Mesozoic Tectonic Events in Southeast China

Five volcanic rock samples and two granite samples taken from the volcanic basins in western Fujian and southern Jiangxi were dated by using the zircon laser albation-inductively coupled plasma mass spectrometry U-Pb method.Together with previously dated ages,the dates obtained provide important constraints on the timing of late Mesozoic tectonic events in SE China.The volcanic rock samples yield ages of 183.1±3.5 Ma,ca.141 Ma to 135.8+1.1 Ma,100.4±1.5 to 97.6±1.1 Ma, confirming three episodes of late Mesozoic volcanic activities,which peaked at 180±5 Ma,140±5 Ma and 100±5 Ma,respectively,along the Wuyishan belt.Moreover,based on field investigations of these volcano-sedimentary basins,we have recognized two compressional tectonic events along this belt.The early one was characterized by Upper Triassic to Middle Jurassic NNE-trending folds that were intruded by late Jurassic granites;and the late one caused the Lower Cretaceous volcano-sedimentary layer to be tilted.The dated age 152.9±1.4 Ma of the granitic samples from the Hetian granitic pluton in the Changting Basin and that from the Baishiding granitic pluton,100.2±1.8 Ma,in the Jianning Basin, give the upper boundaries of these two tectonic events respectively.Hence,the late Mesozoic tectonic evolution of SE China was alternated between extension and compression.

Petrogenesis of Cenozoic Potassic Volcanic Rocks in the Nangqen Basin

The Nangqên basin is one of the Tertiary pull-apart basins situated in the east of the Qiangtang block. Similar to the adjacent Dengqên basin and Baxoi basin, there occurred a series of potassic volcanic and sub-volcanic rocks, ranging from basic, intermediate to intermediate-acid in lithology. Based on the study of petrology, mineralogy and geochemistry, including REEs, trace elements, isotopic elements and chronology, the authors concluded that the Cenozoic potassic volcanic rocks in the Nangqên basin were formed in the post-collisional intraplate tectonic settings. The relations between the basic, intermediate and intermediate-acid rocks are neither differentiation nor evolution, but instead the geochemical variability is mainly attributable to the different partial melting degrees of the mantle sources formed at depths of 50(80 km.The sources of the potassic rocks are enriched metasomatic mantle that has experienced multiple mixing of components mainly derived from the crust. The recycling model can be described as follows: after they had subducted to the mantle wedge, the crust-derived rocks were metasomatized with the mantle materials. In view of the fact that the ratio of crust-derived rocks increases by the age of volcanism, it can be concluded that the sources of the potassic rocks moved upwards progressively with time.The underplating of small scattered magmas upwelling from the asthenosphere may have induced partial melting of the sources of the volcanic rocks in some pull-apart basins in the Hengduanshan area and the intense tectonic movements of large-scale strike-slip belts provided conduits for the ascending melts.

Zircon U–Pb Geochronology and Petrogenesis of Early–Midlle Permian Arc–Related Volcanic Rocks in Central Jilin: Implications for the Tectonic Evolution of the Eastern Segment of Central Asian Orogenic Belt

This paper presents age and geochemical data of a recently identified Late Paleozoic volcanic sequence in central Jilin Province, with aims to discuss the petrogenesis and to constrain the tectonic evolution of the Central Asian Orogenic Belt in this area. Firstly, the volcanic rocks have zircon U-Pb ages of 290–270 Ma. Secondly, they are characterized by(a) ranging in composition from the low-K tholeiite series to high-K calc-alkaline series;(b) enrichment in light rare earth elements and depletion of heavy rare earth elements, with negative Eu anomalies;and(c) negative Nb, Ta, and Ti anomalies. Finally, the volcanic rocks yield εHf(t) values of +7.1 to +17. These data suggest that the central Jilin volcanic rocks were possibly derived from predominant partial melting of a depleted lithospheric mantle that might have been modified by subducted slab–derived fluids. Combined with previous studies, the Late Paleozoic–Early Mesozoic magmatism in Central Jilin can be divided into two stages:(a) a volcanic arc stage(290–270 Ma) represented by low-K to high–K, tholeiite to calc–alkaline plutons and(b) a syn–collisional stage(260–240 Ma) represented by high-K calc–alkaline I-type granites. Furthermore, the timing and the tectonic setting of the above magmatic rocks show that the arc was probably produced by the northward subduction of the Paleo-Asian Ocean and that the final closure of the Paleo-Asian Ocean occurred prior to the Early Triassic.

Geochronology, Geochemistry, Whole Rock Sr-Nd and Zircon Hf-O Isotopes of the Early Neoproterozoic Volcanic Rocks in Jiangshan, Eastern Part of the Jiangnan Orogen: Constraints on Petrogenesis and Tectonic Implications

This paper presents the results of combined studies of geochronology, geochemistry, whole rock Sr-Nd and zircon Hf-O isotopes carried out upon the rhyodacite and ignimbrite of Shangshu village, Shangyu town and Shanghupeng village of Jiangshan City in Zhejiang Province, along the northwestern side of the Jiangshan–Shaoxing suture. SHRIMP zircon U-Pb dating of samples in the three areas yielded weighted mean 206 Pb/238 U ages of 842.8 ± 6.9 Ma and 850.0 ± 7.3 Ma, 839 ± 9 Ma and 832.2 ± 8.1 Ma, 828.3 ± 8.5 Ma and 836.9 ± 9.9 Ma, respectively. These ages are older than the volcanic rocks of the Shangshu Formation dated at around 780 Ma distributed in Fuyang City, Hangzhou City, Kaihua County, etc. The volcanic rocks generally have high SiO2(54.08–76.80 wt%) and Al2 O3(12.40–21.31 wt%), low Fe2 O3(0.68–8.92 wt%), MgO(0.29–2.49 wt%), CaO(0.12–2.86 wt%), TiO2(0.10–1.59 wt%) and P2 O5(0.01–0.39 wt%), with variable total alkalis(K2 O + Na2 O =5.42–8.29 wt%). There exists a clear negative correlation between SiO2 and P2 O5. The volcanic rocks have A/CNK ratios of 1.03–2.77 and thus are peraluminous. They are characterized by enrichment in LREE, Rb, Ba, Zr, Hf, K, Th, La, U and depletion in Nb, Sr, P, Ti, with distinct LREE and HREE fractionation of(La/Yb)N values of 5.68–11.67, and with a moderate negative Eu anomaly(&Eu=0.58–0.89). Whole-rock geochemical data shows that the Jiangshan volcanic rocks are possibly I-type granitic rocks, even though they have some characteristics of A&S-type granites due to the magma fractional crystallization and water-rock interaction. Zircon δ18 O values are 3.97‰–5.49‰(average 4.50‰), 2.90‰–5.21‰(average 4.32‰) for ignimbrite from Shangshu village section, and Shanghupeng village section, respectively. They are slightly lower than the average δ18 O values of igneous zircons in equilibrium with mantle magmas(5.3 ± 0.6‰(2σ)), the lower δ18 O value also demonstrating the presence of high temperature water-rock interactions. The ignimbrite rocks have positive εNd(t)(4.02, 3.37, 3.91, 4.74, 2.85, 4.39, totals from the three areas) and εNd(t)(in-situ zircon)(4.3–14.6, a weighted mean of 8.4;6.6–12.7, a weighted mean of 9.0;8.1–12.0, a weighted mean of 9.5, respectively, from the three areas). In conjunction with the trace element studies, they indicate that the source region of the Jiangshan volcanic rocks was mainly composed of juvenile lower crustal material, mixed with some mantle-sourced magma. Detailed elemental and isotopic data suggest that the Jiangshan volcanic rocks were formed in a continental arc setting. There is a series of ca. 860–830 Ma volcanic rocks formed in a back-arc extensional setting in the southern margin of the eastern Jiangnan Orogen, along the northwest side of the Jiangshan–Shaoxing suture. The first stage rift-related anorogenic magmatism may have occurred as early as ca. 860 Ma in the eastern Jiangnan Orogen.

Recycling of crustal materials and implications for lithospheric thinning: Evidence from Mesozoic volcanic rocks in the Hailar-Tamtsag Basin, NE China

Late Mesozoic Nb-rich basaltic andesites and high-Mg adakitic volcanic rocks from the Hailar-Tamtsag Basin,northeast China,provide important insights into the recycling processes of crustal materials and their role in late Mesozoic lithospheric thinning.The Late Jurassic Nb-rich basaltic andesites(154±4 Ma)are enriched in large-ion lithophile and light rare earth elements,slightly depleted in high-field-strength elements,and have high TiO_(2),P_(2)O_(5),and Nb contents,and(Nb/Th)PM and Nb/U ratios,which together with the relatively depleted Sr-Nd-Hf isotopic compositions indicate a derivation from a mantle wedge metasomatized by hydrous melts from subducted oceanic crust.The Early Cretaceous high-Mg adakitic volcanic rocks(129-117 Ma)are characterized by low Y and heavy rare earth element contents,and high Sr contents and Sr/Y ratios,similar to those of rocks derived from partial melting of an eclogitic source.They also have high Rb/Sr,K_(2)O/Na_(2)O,and Mg#values,and high MgO,Cr,and Ni contents.These geochemical features suggest that the adakitic lavas were derived from partial melting of delaminated lower continental crust,followed by interaction of the resulting melts with mantle material during their ascent.Our data,along with available geological,paleomagnetic,and geophysical evidence,lead us to propose that recycling of Paleo-Pacific oceanic crustal materials into the upper mantle due to flat-slab subduction and rollback of the Paleo-Pacific Plate during the late Mesozoic likely provided the precondition for lithospheric thinning in northeast China,with consequent lithospheric delamination causing recycling of continental crustal materials and further lithospheric thinning.

Sodium-rich volcanic rocks and their relationships with iron deposits in the Aqishan-Yamansu belt of Eastern Tianshan,NW China

The volcanic rocks hosting the iron deposits in the Aqishan–Yamansu metallogenic belt are sodium-rich.The geochronology,petrography,and geochemistry of minerals and sodium-rich rocks as well as the relationship between these rocks and the iron deposits are studied.Geochemically,the ore-hosting volcanic rocks are sodiumrich(the averages of Na2O and Na2O/K2O are 4.31 wt.%and 8.56,respectively)and belong to the calc-alkaline series.They are enriched in LREEs and LILEs(Ba,U,K,and Sr),but depleted in HFSEs(Nb,Ta,and Ti).SHRIMP zircon U–Pb dating of the crystal tuff in the Aqishan Formation and the dacite in the Tugutu Bulak Formation yields ages of 337.5
2.3 Ma(n?15,MSWD?0.85)and 313.0
3.3 Ma(n?13,MSWD?0.74),respectively,indicating that the sodium-rich volcanic rocks formed from the early–late Carboniferous.Electron microprobe data from plagioclases demonstrate that albites and/or oligoclases were formed in the basic–intermediate–acid volcanic rocks.Two stages of albitization are identified,and the latter is likely attributed to the dissolution of iron in the Aqishan–Yamansu belt.The sodium-rich volcanic rocks probably formed by the interaction between volcanic lava and seawater after volcanoes erupted on the seafloor;meanwhile,the albites formed by element substitution in a low-metamorphic environment.The spatiotemporal coupling relationship between sodium-rich volcanic rocks and iron deposits in the Aqishan–Yamansu belt is favorable.Iron dissolved from the dark minerals of basic–intermediate volcanic rocks through sodium metasomatism is one of the material sources for the iron deposits.

Latest Zircon U-Pb Geochronology of the Qingshan Group Volcanic rocks along the Tan-Lu Fault Zone of Shandong Province, Eastern China

Objective Shandong Province is divided into two parts by the Tan–Lu fault zone:the western part(Luxi)and the eastern part(Jiaodong).Large-scale volcanic activity occurred during the Late Mesozoic in Shandong Province,eastern China(Fig.1b),and was controlled by the Tan–Lu fault zone and its secondary faults.Mesozoic volcanic rocks in Shandong Province mainly occur within the Cretaceous

New Discovery of the Early Cretaceous Volcanic Rocks on the Barton Peninsula,King George Island,Antarctica and Its Geological Significance

Ages determined with the 40Ar/39Ar isotopic system affirms the Early Cretaceous volcanic activity in the Barton Peninsula, King George Island, Antarctica. Two specimens of basaltic andesite collected from the lowermost volcanic sequence of the peninsula were irradiated and analyzed in different experiments, yielding an identical age spectrum, and two magmatic thermal events of the Early Cretaceous (120.4±1.6 Ma, 119±1 Ma) and Early Tertiary (5 3.1±1.5 Ma, 52±1 Ma) are distinguished. The former is interpreted to represent the primary cooling age of basaltic andesite, whereas the latter is the thermal reset age caused by the intrusion of granitic pluton. These new ages clearly indicate that volcanism was active during the Early Cretaceous on the Barton Peninsula and that intensive hy-drothermal alteration and mineralization of Mesozoic volcanic rocks resulted from Tertiary magmatism.

Geochemistry and Petrogenesis of Volcanic Rocks from the Continent-Ocean Transition Zone in Northern South China Sea and Their Tectonic Implications

Miocene–Pliocene(22–5 Myr) volcanism and associated seamounts are abundant in the continent-ocean transition(COT) zone in the margin of the north South China Sea(SCS). The petrogenesis of volcanic rocks from these seamounts and regional tectonic evolution of COT zone are poorly known. In this paper, we obtained whole-rock major and trace element compositions and Sr-Nd-Pb isotopic data for these volcanic rocks from the Puyuan and Beipo seamounts within COT zone, in northeastern SCS. Based on the geochemical analyses, the volcanic rocks are classified as alkaline ocean island basalts(OIB) and enriched mid-ocean ridge basalts(E-MORB). The OIBs from the Puyuan seamount are alkaline trachybasalts and tephrites that show enrichment of the light rare earth elements(LREE) relative to heavy rare earth elements(HREE) and more radiogenic Sr-Nd isotopic compositions, and have significant ‘Dupal isotopic anomaly'. In contrast, the E-MORBs from the Beipo seamount are tholeiitic basalts that have less enrichment in LREE and less radiogenic Sr-Nd isotopic compositions than the counterparts from the Puyuan seamount. Petrological and geochemical differences between the OIBs and MORBs from these two seamounts can be explained by different mantle sources and tectonic evolution stages of the COT zone. Syn-spreading OIB type basalts from the Puyuan seamount were derived from an isotopically ‘enriched', and garnet facies-dominated pyroxenitic mantle transferred by the Hainan mantle plume. In contrast, post-spreading E-MORB type basalts from the Beipo seamount are considered to be derived from the melting of isotopically ‘depleted' pyroxenite mantle triggered by lithosphere bending and subsequent post-rifting at the lower continental slope of the northern margin.

Geochemical Characteristics of the Tayuan Volcanic Rocks in the Daxinganling Metallogenic Belt

1 Introduction Daxinganling region is one of the most important nonferrous metal metallogenetic province(Wu et al.,2011;Li et al.,2014).The northern Daxinganling was a geological blank area in China formerly(Li et al.,2017).However,the region has a huge resource potential.Forty metal deposits have been found in the area recently。

Relationship between Permian volcanic rocks distribution and karst paleogeomorphology of Maokou Formation and its significance for petroleum exploration in western Sichuan Basin, SW China

Based on outcrop, drilling, logging, geochemical analysis and seismic data, the karst landform and distribution of Permian volcanic rocks at the end of the sedimentary period of the Maokou Formation in the western Sichuan Basin are examined, and their petroleum geological significance is discussed. Affected by normal faults formed in the early magmatic activities and extension tectonic background in the late sedimentary period of the Maokou Formation, a local karst shallow depression under the background of karst slope came up in the Jianyang area of the western Sichuan Basin, where the residual thickness of the Maokou Formation was thinner. Basic volcanic rocks like pyroclastic rock of eruptive facies, basalt of overflow facies, diabase porphyrite of intrusive facies and sedimentary tuff of volcanic sedimentary facies were formed after karstification. However, under the effects of faulting and karst paleogeomorphology, the volcanic rocks in different areas had different accumulation features. In the Jianyang area, with long eruption time, the volcanic rocks were thick and complex in lithology, and accumulated in the karst depressions. In the Zhongjiang-Santai area located in the karst slope, there’s no fault developed, only thin layers of basalt and sedimentary tuff turned up. The karst landform controls the build-up of thick explosive facies volcanic rocks and also the development of karst reservoirs in the Maokou Formation, and the western Sichuan area has oil and gas exploration potential in volcanic rocks and the Maokou Formation.

Formation mechanism of high-quality reservoirs in intermediate volcanic rocks:A case study of Longfengshan area in Songliao Basin

The basin margin slope area of Changling fault depression in Songliao Basin is dominated by intermediate-basic volcanic rocks of Huoshiling Formation,and there is still a lack of in-depth understanding of the development pattern and formation mechanism of high-quality reservoirs in intermediate-basic volcanic rocks in this area.Taking the intermediate volcanic rocks in Longfengshan area of Changling fault depression as an example,a comprehensive study was undertaken via core observations,thin section porosity analysis,rock physical property tests,scanning electron microscopy and X-ray diffraction analysis,combined with well log and seismic d ata.As a result,formation mechanism of a high quality reservoir was made clear based on dissolution modification effects of the volcanic rocks,and the development model of the high quality reservoir under t he dual control of lithology and fluid was established.The research shows that the volcanic rocks in this area consist of six lithologies:andesitic hydrothermal breccia,andesite,andesitic volcanic breccia,andesitic tuff,dacitic tuff and sedimentary tuff,which are controlled by structure,eruptive source,eruptive action and palaeotopography.The proximal facies of the volcanic edifice were located on the basin margin,distributed along faults mainly consisting of overflow facies intermixed with eruptive facies,and gradually transformed into thick eruptive facies(middle-source facies)and volcanic sedimentary facies(distal facies).The reservoir space of volcanic rocks was dominated by dissolution pores,which were formed by weathering and dissolution by organic acidic fluids.The thermal debris flow subphase in the middle-source facies of the volcanic edifice had a large amount of easily dissolved volcanic ash,which was close to the source rock in the centre of the basin and was a favourable area for the development of dissolution pores.This study is providing a guide for oil and gas exploration in the intermediate-basic volcanic rocks in the slope of Changling fault depression in Songliao Basin.

Geochemistry and Petrogenesis of Tertiary Volcanic Rocks of the Eastern Roodbar, Alborz Mountain, North of Iran

In the Alborz Mountains of the eastern Roodbar (north of Iran), Tertiary volcanic rocks have a variety of composition between olivine basalt, basaltic andesite, pyroxene andesite and andesite. The presence of different xenoliths and xenocrysts is among the evidence of crustal contamination of these rocks. The positive correlations of CaO/Al2O3 vs to MgO and Al2O3 vs. SiO2 are of signs of the olivine and clinopyroxene fractionation in the variation trend of the area rocks. Positive correlations K2O/P2O5 vs with SiO2 and La/Sm vs. K2O/P2O5 demonstrate contamination of magma with the continental crust. The incompatible trace element patterns and their comparison with crustal contents indicate contamination of the rocks of the area with the lower and upper continental crust. Linear trends in the variation diagram of Nb/Y vs. Zr/Y, introduce two different source regions: a MORB source and the other continental crust for the rocks which are the genesis. The variations of Y/Nb vs. Zr/Nb and Rb/Y vs. Nb/Y reveal a crustal contamination of the magma originated from the MORB source. Geochemical studies represent that the area’s rocks were derived from the 15% melting of a mantle source of MORB type with spinel facies within a continental environment, which was contaminated by varying degrees of continental crustal rocks.

Olivine and Cr-spinel as indicators of the petrogenesis and partial melting conditions of the high-MgO ultramafic volcanic rocks from NW Ad Dhala Province—Yemen

The high-MgO ultramafic volcanic rocks in the NW Ad Dhala province are classified as meimechite according to the IUGS classification scheme.This province represents the southeastern outcrops of the Yemen Volcanic Group(YVG),which constitutes part of the AfroArabian continental large igneous province(LIP) and located within the boundary of the Afar mantle plume.In this study,we present the chemical compositions of olivine and Cr-spinel in meimechite rocks from Bagah Village in NW Ad Dhala province,aiming to characterize the genesis and partial melting conditions and to estimate the crystallization temperatures of these high-MgO rocks.Olivine crystals are characterized by high forsterite,ranges from Mg-rich core(up to Fo_(89.69)) to relatively Fe-rich rim(down to Fo_(78.57)),high CaO,MgO and MnO whereas Cr-spinel crystals have high TiO_(2) and Cr# values ranging from 0.49 to 0.63 which indicate that they are crystallized from primary magma and are typical of volcanic olivine and Crspinel that formed in intraplate tectonic setting.Olivine and Cr-spinel compositional data and primary melt composition(MgO ~ 23 wt.%) are compatible with the derivation of studied meimechite rocks from peridotite mantle source by small degrees of partial melting under conditions of high temperature and pressure at great depths,mostly within the garnet stability field.Also,these data provide a compelling indicator for the important role of upwelling Afar mantle plume in the genesis of these high-MgO ultramafic volcanic rocks.Finally,based on the different olivine-liquid equilibrium methods and Al-in-olivine thermometer approach the estimated crystallization temperature ranges from 1450 to 1490℃,and mantle potential temperature(Tp) ranges from 1617 to 1677℃,at high pressure(3-4.8 GPa).These high temperatures substantiate the existence of the Afar thermal mantle plume and its important role in the genesis of the studied meimechite rocks.

The possible source of uranium mineralization in felsic volcanic rocks,Eastern Desert,Egypt of the Arabian-Nubian Shield:Constraints from whole-rock geochemistry and spectrometric prospection

The present work deals with the detailed geology,mineralogy,geochemistry,and spectrometric prospection of the felsic volcanic rocks at the Eastern Desert,Egypt of the Arabian-Nubian Shield.Felsic volcanic rocks are an essential source for rare earth elements(REEs)and uranium occurrences in this area.They are compositionally uniform with tholeiitic to calc-alkaline affinities,peraluminous and belong to the series of rhyolite with high-K melt.They exhibit more enrichment in high field strength elements(HFSE,e.g.Zr,Ta,Nd,Th,and U)and large-ion lithophile elements(LILE,e.g.Pb and Rb)compared to the country rocks of the studied area,with REE ranging from 188.20 to 442.70 ppm and strong depletion in Ti,Sr,P with deep negative Eu oddities.The felsic volcanic rocks were mostly generated from the partial melting of quartz-amphibolite facies accreted during the Neoproterozoic.Positive oddities of Zr-U-Th for the felsic volcanic rocks determine the involvement of crustal materials.Felsic volcanic rocks are found in A-type suites of magma and represent highly fractionated rocks derived from rhyolitic magma,with insignificant interaction with continental crust in the low-pressure environment and during fractional crystallization.Felsic volcanic rocks have higher values of radioactivity in which eU range from 0.5 to 121 ppm and eTh from 1.0 to 415.10 ppm.The high values of eU and eTh can be ascribed to the mineralization of uranium and the presence of accessory minerals of radiogenic nature such as uranophane,uranothorite,zircon,and monazite.Uranophane is considered as the mineral with most enriched uranium contents in the studied felsic volcanic rocks in which(UO2=87.30 wt%).Also,they are enriched with REE-bearing accessory minerals comprising allanite,titanite,and apatite.The geological investigations of the felsic volcanic rocks in the studied areas are inappropriate to clear the feasible economic potentialities of rare earth elements and U occurrences;itemized and invaluable explorational work is as yet needed.Whilst,the environmental impact of mineralization,owing to U and Th and their radiogenic daughter products,is observed and must be elaborated minutely.

Chronological and Geochemical Characterisitics of Volcanic Rocks of the Yingcheng Formation in the Southern Songliao Basin: Constraints on the Early Cretaceous Evolution of the Songliao Basin

The discoveries of oil and gas reservoirs in the volcanic rocks of the Songliao Basin(SB) have attracted the attention of many researchers. However, the lack of studies on the genesis of the volcanic rocks has led to different opinions being presented for the genesis of the SB. In order to solve this problem, this study selected the volcanic rocks of the Yingcheng Formation in the Southern Songliao Basin(SSB) as the research object, and determined the genesis and tectonic setting of the volcanic rocks by using LA-ICP-MS zircon U-Pb dating and a geochemical analysis method(major elements, trace elements, and Hf isotopes). The volcanic rocks of the Yingcheng Formation are mainly composed of rhyolites with minor dacites and pyroclastic rocks. Our new zircon U-Pb dating results show that these volcanic rocks were erupted in the Early Cretaceous(113–118 Ma). The primary zircons from the rhyolites have εHf(t) values of +4.70 to +12.46 and twostage model age(TDM2) of 876–374 Ma. The geochemical data presented in this study allow these rhyolites to be divided into I-type rhyolites and A-type rhyolites, both of which were formed by the partial melting of the crust. They have SiO2 contents of 71.62 wt.%–75.76 wt.% and Al2 O3 contentsof 10.88 wt.% to 12.92 wt.%. The rhyolites have distinctively higher REE contents than those of ordinary granites, with obvious negative Eu anomalies. The light to heavy REE fractionation is not obvious, and the LaN/YbN(average value = 9.78) is less than 10. The A-type rhyolites depleted in Ba, Sr, P, and Ti, with relatively low Nb/Ta, indicating that the rocks belong A2 subtype granites formed in an extensional environment. The adakitic dacites are characterized by high Sr contents(624 to 1,082 ppm), low Y contents(10.6 to 12.6 ppm), high Sr/Y and Sr/Yb ratios, and low Mg# values(14.77 to 36.46), indicating that they belong to "C" type adakites. The adakitic dacite with high Sr and low Yb were likely generated by partial melting of the lower crust under high pressure conditions at least 40 km depth. The I-type rhyolites with low Sr and high Yb, and the A-type rhyolites with very low Sr and high Yb, were formed in the middle and upper crust under low pressure conditions, respectively. In addition, the formation depths of the former were approximately 30 km, whereas those of the latter were less than 30 km. The geochemical characteristics reveal that the volcanic rocks of Yingcheng Formation were formed in an extensional environment which was related to the retreat of subducted Paleo-Pacific Plate. At the late Early Cretaceous Period, the upwelling of the asthenosphere mantle and the lithosphere delamination caused by the retreat of the subducted Paleo-Pacific Plate, had resulted in lithosheric extension in the eastern part of China. Subsequently, a large area of volcanic rocks had formed. The SB has also been confirmed to be a product of the tectonic stress field in that region.

Carboniferous tectono-magmatic evolution of the northern Luliang arc: evidence from geochemistry and petrography of Carboniferous volcanic rocks in the northern Luliang Uplift,NW China

The Northern Junggar Basin experienced extensive subduction and a complex tectono-magmatic evolution during the Late Paleozoic,resulting in a heterogeneous distribution of volcanic rocks in the Junggar Basin.In this study,the Carboniferous tectono-magmatic evolution of the northern Luliang arc was described by exploring the petrography and geochemistry of Carboniferous volcanic rocks collected from well Y-2 and outcrop WW' in the northern Luliang Uplift.The distribution,types,and formation ages of these volcanic rocks were characterized and the volcanic sequence in well Y-1 was divided into upper and lower parts according to vertical variations in selected geochemical data.Then the petrogenesis and tectonic settings of different volcanic rocks were evaluated and this was used to infer the tectonomagmatic evolution of the northern Luliang arc during the Carboniferous.The results indicate that:(1) Carboniferous high-K calc-alkali andesite-dacite associations are distributed in the west of the northern Luliang Uplift,and Lower Carboniferous calc-alkali basalt-dacite-rhyolite assemblages are preserved in its east.(2) The intermediateacid volcanic rocks in wells Y-1 and Y-2 were derived from calc-alkali basaltic magma through melting of the juvenile lower crust,and geochemical variations indicate increasing addition of slab melting in a subduction-related arc environment.The bimodal volcanic rocks from outcrop WW' were derived from lithospheric underplating of basaltic magma in an intra-arc extensional setting.(3) The closure of the eastern Keramaili Oceanic basin occurred before the Early Carboniferous,and the tectono-magmatic difference between the east and the west of the northern Luliang Uplift appeared before the Carboniferous period.

Development characteristics and petroleum geological significance of Permian pyroclastic flow volcanic rocks in Western Sichuan Basin,SW China

By examining field outcrops, drilling cores and seismic data, it is concluded that the Middle and Late Permian “Emeishan basalts” in Western Sichuan Basin were developed in two large eruption cycles, and the two sets of igneous rocks are in unconformable contact. The lower cycle is dominated by overflow volcanic rocks;while the upper cycle made up of pyroclastic flow volcanic breccia and pyroclastic lava is typical explosive facies accumulation. With high-quality micro-dissolution pores and ultra-fine dissolution pores, the upper cycle is a set of high-quality porous reservoir. Based on strong heterogeneity and great differences of pyroclastic flow subfacies from surrounding rocks in lithology and physical properties, the volcanic facies and volcanic edifices in Western Sichuan were effectively predicted and characterized by using seismic attribute analysis method and instantaneous amplitude and instantaneous frequency coherence analysis. The pyroclastic flow volcanic rocks are widely distributed in the Jianyang area. Centering around wells YT1, TF2 and TF8, the volcanic rocks in Jianyang area had 3edifice groups and an area of about 500 km^(2), which is the most favorable area for oil and gas exploration in volcanic rocks.

Magmatic Network Structure of Volcanic Rocks in the Shengli Oilfield, Eastern China

Types of polymerized molecular network structure and degree of bond breakdown for glass phases of magmatic inclusions and glassy matrix in volcanic rocks from the Shengli oilfield have been defined by the laser Raman spectroscopic investigation. There are significant differences in types of polymerized molecular network structure and degree of bond ’breakdown of the magmatic glass phases between the non-CO2 and COa gas pools: magmatic glass phases of fluid inclusions and matrix in volcanic rocks from the CO2 gas pool contain more sheet network molecules and have a greater degree of bond beakdown than those from the non-CO2 gas pool; and when gas bubbles occur in evolving magma, magma saturated with volatile components has more sheet network molecules. The results suggest the magma-degassing mechanism of the formation of CO2 gas pools in the Shengli oilfield.