Impermeability of tunnel structural material after exposure to high temperature determines residual service life and security. The present study explores impermeability deterioration and water absorption change (expre...Impermeability of tunnel structural material after exposure to high temperature determines residual service life and security. The present study explores impermeability deterioration and water absorption change (expressed as w(T, t)) of tunnel structural material after exposure to 200℃, 300℃, 400℃, 500℃, and 600℃respectively. Structural cementitious material was devised according to the requirements of segment used in Yangtze River tunnel of Wuhan which has been in constructing. Effect of high temperature on impermeability is evaluated by impermeability deterioration factor (abbr. IDF) and w(T, t).Testing results indicate that impermeability of concrete decreases with the increase of temperature up to 600℃, and serious impermeability deterioration occurs at temperature above 300℃. Furthermore, concrete with higher impermeability is more sensitive to high temperature above 400℃.展开更多
基金Funded by National High-Tech Research and Development Program of China(No.2005AA332010)
文摘Impermeability of tunnel structural material after exposure to high temperature determines residual service life and security. The present study explores impermeability deterioration and water absorption change (expressed as w(T, t)) of tunnel structural material after exposure to 200℃, 300℃, 400℃, 500℃, and 600℃respectively. Structural cementitious material was devised according to the requirements of segment used in Yangtze River tunnel of Wuhan which has been in constructing. Effect of high temperature on impermeability is evaluated by impermeability deterioration factor (abbr. IDF) and w(T, t).Testing results indicate that impermeability of concrete decreases with the increase of temperature up to 600℃, and serious impermeability deterioration occurs at temperature above 300℃. Furthermore, concrete with higher impermeability is more sensitive to high temperature above 400℃.
文摘将经过多级破碎分选所得的废线路板粉末过60目筛,以2 mol/L HCl溶液、超纯水洗涤,并用丙酮脱水。将预处理后的滤渣、滤纸填入萃取池,或者用新滤纸包裹后置于索氏提取管内,添加5μL内标物,分别用加速溶剂萃取法(ASE)或索氏提取(SE)法进行萃取,依次采用多层硅胶柱和活性炭柱对萃取提取物进行净化、洗脱,得到二噁英测试样品。用同位素稀释-高分辨气相色谱-质谱联用仪分析样品中二噁英的含量。考察两种提取方法及不同氯代数对15种^(13)C-2,3,7,8-PCDD/Fs回收率的影响,比较两种方法的准确度和精密度。结果表明,ASE和SE对15种^(13)C-2,3,7,8-PCDD/Fs的回收率分别为54.3%~113.0%和28.3%~77.7%,实测废线路板中二噁英毒性当量(Toxic equivalent quangtity,TEQ)分别为0.075 ng TEQ/kg和0.266 ng TEQ/kg。在方法精密度允许范围内,ASE相对具有简单快速、溶剂用量少和准确的优势。