Due to high price of Straight Vegetable Oil （SVO） for bio-diesel production, the use of Waste Cooking Oil （WCO） will be cost effective. Furthermore, utilization of WCO will refrain waterways pollution and endanger...Due to high price of Straight Vegetable Oil （SVO） for bio-diesel production, the use of Waste Cooking Oil （WCO） will be cost effective. Furthermore, utilization of WCO will refrain waterways pollution and endanger ecosystem. In Malaysia, more than 50-tone of WCO from various sources was produced every day. This study evaluates combustion performance and exhaust emission characteristics of several WCOs with different sources. Modification on fuel properties has been done to improve the combustion and exhaust emission of using WCO as diesel fuel. Regular diesel fuel also has been used for comparison in the test. A 0.6 liter, single-cylinder, air-cooled direct injection diesel engine was used to perform this experiment. Experiment was done at variable engine loads at constant speed.展开更多
Internal combustion engines with application in automobiles and other relevant industries constitute significant environmental pollution via the release of toxic exhaust gasses like carbon monoxide (CO), hydrocarbons ...Internal combustion engines with application in automobiles and other relevant industries constitute significant environmental pollution via the release of toxic exhaust gasses like carbon monoxide (CO), hydrocarbons (HC), particulate matter (PM), and nitrogen oxide (NO<sub>x</sub>). Engine researchers and manufacturers are challenged to develop external and internal measures to ensure environmentally friendly solutions to accommodate and conform to the growing list of emission standards. Therefore, this work presents an experimental investigation of the NO<sub>x</sub> emission profile of a diesel engine that is fuelled and fitted with waste frying oil-based biodiesel and catalytic converter. Using a single-cylinder, four-stroke air-cooled CI engine at a constant speed of 1900 rpm and different loadings of 25%, 50%, 75%, and 100%;fitted with a catalytic converter at the exhaust outlet of the engine and linked to a dynamometer and a gas analyser, an experiment was conducted at biodiesel/diesel volume blends of B0 (0/10), B5 (5/95), B20 (20/80), B30 (30/70), B70 (70/30), B100 (100/0);and 30% concentration (v/v), 0.5 litre/hr flow rate of aqueous urea from the catalytic converter. The results show an increasing NO<sub>x</sub> emission as the biodiesel component increased in the blend. The catalytic converter showed a downward NO<sub>x</sub> reduction with a significant 68% reduction in efficiency at high exhaust gas temperatures. It is concluded that the combined utilisation of waste frying oil-based biodiesel and the catalytic converter yields substantial NO<sub>x</sub> emission reduction.展开更多
The objective of the study was actually the investigation of the effect of various organic wastes on the ability of urine in absorbing CO2. Urine alone or mixed with olive-oil-mill waste waters (O), poultry litter (P)...The objective of the study was actually the investigation of the effect of various organic wastes on the ability of urine in absorbing CO2. Urine alone or mixed with olive-oil-mill waste waters (O), poultry litter (P) or meat bone meal (M) was used on the absorption of CO2 from a gas bottle. The absorption capacity (1.35 - 2.85 gCO2/gNH4) was bigger than other solvents such as ammonia and amines. The range of CO2 absorption was significantly bigger for the organic mixtures P and PM with urine (9.1 - 11.8) g/L than urine alone 6.5 g/L. These organic wastes could be used to increase CO2 absorption in urine and reduce gas emissions.展开更多
The activity of Mo_(2) C-based catalyst on vegetable oil conversion into biofuel could be greatedly promoted by tuning the carbon content,while its modification mechanism on the surface properties remained elusive.Her...The activity of Mo_(2) C-based catalyst on vegetable oil conversion into biofuel could be greatedly promoted by tuning the carbon content,while its modification mechanism on the surface properties remained elusive.Herein,the exposed active sites,the particle size and Lewis acid amount of Ni-Mo_(2) C/MCM-41 catalysts were regulated by varying CH_(4) content in carbonization gas.The activity of Ni-Mo_(2) C/MCM-41 catalysts in jatropha oil(JO)conversion showed a volcano-like trend over the catalysts with increasing CH_(4) content from 15%to 50%in the preparation process.The one prepared by 25%CH_(4) content(NiMo_(2) C(25)/MCM-41)exhibited the outstanding catalytic performance with 83.9 wt%biofuel yield and95.2%C_(15)-C_(18) selectivity.Such a variation of activity was ascribed to the most exposed active sites,the smallest particle size,and the lowest Lewis acid amount from Ni^(0) on the Ni-Mo_(2) C(25)/MCM-41 catalyst surface.Moreover,the Ni-Mo_(2) C(25)/MCM-41 catalyst could also effectively catalyze the conversion of crude waste cooking oil(WCO)into green diesel.This study offers an effective strategy to improve catalytic performance of molybdenum carbide catalyst on vegetable oil conversion.展开更多
Utilizing oil extracted from waste engine oil and waste plastics, by pyrolysis, as a filel for internal combustion engines has been demonstrated to be one of the best available waste management methods. Separate blend...Utilizing oil extracted from waste engine oil and waste plastics, by pyrolysis, as a filel for internal combustion engines has been demonstrated to be one of the best available waste management methods. Separate blends of fuel from waste engine oil and waste plastic oil was prepared by mixing with diesel and experimental investigation is conducted to study engine performance, combustion and exhaust emissions. It is observed that carbon monoxide （CO） emission increases by 50% for 50% waste plastic oil （50WPO：50D） and by 58% for 50% waste engine oil （50WEO：50D） at full load as compared to diesel. Unburnt hydrocarbon （HC） emission increases by 16% for 50WPO：50D and by 32% for 50WEO：50D as compared to diesel at maximum load. Smoke is fotmd to decrease at all loading conditions for 50WPO：50D operation, but it is comparatively higher for 50WEO：50D operation. 50WPO：50D operation shows higher brake thermal efficiency for all loads as compared to 50WEO：50D and diesel fuel operation. Exhaust gas temperature is higher at all loads tbr 50WPO：50D and 50WEO：50D as compared to diesel fuel operation.展开更多
文摘Due to high price of Straight Vegetable Oil （SVO） for bio-diesel production, the use of Waste Cooking Oil （WCO） will be cost effective. Furthermore, utilization of WCO will refrain waterways pollution and endanger ecosystem. In Malaysia, more than 50-tone of WCO from various sources was produced every day. This study evaluates combustion performance and exhaust emission characteristics of several WCOs with different sources. Modification on fuel properties has been done to improve the combustion and exhaust emission of using WCO as diesel fuel. Regular diesel fuel also has been used for comparison in the test. A 0.6 liter, single-cylinder, air-cooled direct injection diesel engine was used to perform this experiment. Experiment was done at variable engine loads at constant speed.
文摘Internal combustion engines with application in automobiles and other relevant industries constitute significant environmental pollution via the release of toxic exhaust gasses like carbon monoxide (CO), hydrocarbons (HC), particulate matter (PM), and nitrogen oxide (NO<sub>x</sub>). Engine researchers and manufacturers are challenged to develop external and internal measures to ensure environmentally friendly solutions to accommodate and conform to the growing list of emission standards. Therefore, this work presents an experimental investigation of the NO<sub>x</sub> emission profile of a diesel engine that is fuelled and fitted with waste frying oil-based biodiesel and catalytic converter. Using a single-cylinder, four-stroke air-cooled CI engine at a constant speed of 1900 rpm and different loadings of 25%, 50%, 75%, and 100%;fitted with a catalytic converter at the exhaust outlet of the engine and linked to a dynamometer and a gas analyser, an experiment was conducted at biodiesel/diesel volume blends of B0 (0/10), B5 (5/95), B20 (20/80), B30 (30/70), B70 (70/30), B100 (100/0);and 30% concentration (v/v), 0.5 litre/hr flow rate of aqueous urea from the catalytic converter. The results show an increasing NO<sub>x</sub> emission as the biodiesel component increased in the blend. The catalytic converter showed a downward NO<sub>x</sub> reduction with a significant 68% reduction in efficiency at high exhaust gas temperatures. It is concluded that the combined utilisation of waste frying oil-based biodiesel and the catalytic converter yields substantial NO<sub>x</sub> emission reduction.
文摘The objective of the study was actually the investigation of the effect of various organic wastes on the ability of urine in absorbing CO2. Urine alone or mixed with olive-oil-mill waste waters (O), poultry litter (P) or meat bone meal (M) was used on the absorption of CO2 from a gas bottle. The absorption capacity (1.35 - 2.85 gCO2/gNH4) was bigger than other solvents such as ammonia and amines. The range of CO2 absorption was significantly bigger for the organic mixtures P and PM with urine (9.1 - 11.8) g/L than urine alone 6.5 g/L. These organic wastes could be used to increase CO2 absorption in urine and reduce gas emissions.
基金financially supported by the National Natural Science Foundation of China(No.21972099)the National Natural Science Foundation of China(National Special Scientific Research Instrument and Equipment Development)(No.21427803-2)the 111 project(No.B17030)。
文摘The activity of Mo_(2) C-based catalyst on vegetable oil conversion into biofuel could be greatedly promoted by tuning the carbon content,while its modification mechanism on the surface properties remained elusive.Herein,the exposed active sites,the particle size and Lewis acid amount of Ni-Mo_(2) C/MCM-41 catalysts were regulated by varying CH_(4) content in carbonization gas.The activity of Ni-Mo_(2) C/MCM-41 catalysts in jatropha oil(JO)conversion showed a volcano-like trend over the catalysts with increasing CH_(4) content from 15%to 50%in the preparation process.The one prepared by 25%CH_(4) content(NiMo_(2) C(25)/MCM-41)exhibited the outstanding catalytic performance with 83.9 wt%biofuel yield and95.2%C_(15)-C_(18) selectivity.Such a variation of activity was ascribed to the most exposed active sites,the smallest particle size,and the lowest Lewis acid amount from Ni^(0) on the Ni-Mo_(2) C(25)/MCM-41 catalyst surface.Moreover,the Ni-Mo_(2) C(25)/MCM-41 catalyst could also effectively catalyze the conversion of crude waste cooking oil(WCO)into green diesel.This study offers an effective strategy to improve catalytic performance of molybdenum carbide catalyst on vegetable oil conversion.
文摘Utilizing oil extracted from waste engine oil and waste plastics, by pyrolysis, as a filel for internal combustion engines has been demonstrated to be one of the best available waste management methods. Separate blends of fuel from waste engine oil and waste plastic oil was prepared by mixing with diesel and experimental investigation is conducted to study engine performance, combustion and exhaust emissions. It is observed that carbon monoxide （CO） emission increases by 50% for 50% waste plastic oil （50WPO：50D） and by 58% for 50% waste engine oil （50WEO：50D） at full load as compared to diesel. Unburnt hydrocarbon （HC） emission increases by 16% for 50WPO：50D and by 32% for 50WEO：50D as compared to diesel at maximum load. Smoke is fotmd to decrease at all loading conditions for 50WPO：50D operation, but it is comparatively higher for 50WEO：50D operation. 50WPO：50D operation shows higher brake thermal efficiency for all loads as compared to 50WEO：50D and diesel fuel operation. Exhaust gas temperature is higher at all loads tbr 50WPO：50D and 50WEO：50D as compared to diesel fuel operation.
