Biodiesels produced from various feedstocks have been considered as alternative fuels used in internal combustion engines without major modifications.This research focuses on producing biodiesel from waste cooking oil...Biodiesels produced from various feedstocks have been considered as alternative fuels used in internal combustion engines without major modifications.This research focuses on producing biodiesel from waste cooking oil(WCOSD)by the catalytic cracking method using MgO as the catalyst and comparing the engine operating characteristics of the test engine when using WCOSD and traditional diesel(CD)as test fuels.As a result,the brake power of the test engine fueled WCOSD,and traditional diesel is similar.However,the engine fuel consumption in the case of using WCOSD is slight increases in some operating conditions.Also,the nitrogen oxides emissions of the test engine fueled WCOSD are higher than those of CD at all tested conditions.The trend is opposite for hydrocarbon emission as the HC emission of the engine fueled by WCOSD reduces 26.3%on average.The smoke emission of the test engine in case of using WCOSD is lower 17%on average than that of CD.However,the carbon monoxide emissions are lower at the low and medium loads and higher at the full loads.These results show that the new biodiesel has the same characteristics as those of commercial biodiesel and can be used as fuel for diesel engines.展开更多
Internal combustion engines with application in automobiles and other relevant industries constitute significant environmental pollution via the release of toxic exhaust gasses like carbon monoxide (CO), hydrocarbons ...Internal combustion engines with application in automobiles and other relevant industries constitute significant environmental pollution via the release of toxic exhaust gasses like carbon monoxide (CO), hydrocarbons (HC), particulate matter (PM), and nitrogen oxide (NO<sub>x</sub>). Engine researchers and manufacturers are challenged to develop external and internal measures to ensure environmentally friendly solutions to accommodate and conform to the growing list of emission standards. Therefore, this work presents an experimental investigation of the NO<sub>x</sub> emission profile of a diesel engine that is fuelled and fitted with waste frying oil-based biodiesel and catalytic converter. Using a single-cylinder, four-stroke air-cooled CI engine at a constant speed of 1900 rpm and different loadings of 25%, 50%, 75%, and 100%;fitted with a catalytic converter at the exhaust outlet of the engine and linked to a dynamometer and a gas analyser, an experiment was conducted at biodiesel/diesel volume blends of B0 (0/10), B5 (5/95), B20 (20/80), B30 (30/70), B70 (70/30), B100 (100/0);and 30% concentration (v/v), 0.5 litre/hr flow rate of aqueous urea from the catalytic converter. The results show an increasing NO<sub>x</sub> emission as the biodiesel component increased in the blend. The catalytic converter showed a downward NO<sub>x</sub> reduction with a significant 68% reduction in efficiency at high exhaust gas temperatures. It is concluded that the combined utilisation of waste frying oil-based biodiesel and the catalytic converter yields substantial NO<sub>x</sub> emission reduction.展开更多
This study investigated the effects of sawdust as a soil amendment on certain growth parameters of Solanum esculentum Linn. grown in soil polluted with various concentrations of waste engine oil, and changes in the ph...This study investigated the effects of sawdust as a soil amendment on certain growth parameters of Solanum esculentum Linn. grown in soil polluted with various concentrations of waste engine oil, and changes in the physicochemical proper- ties of the soil. The purpose was to assess the soil remediation potentials of sawdust in waste engine oil-polluted soil. The experiment was divided into three regimes： control （air-dried soil without waste engine oil and with clean sawdust）, pol- luted （waste engine oil-contaminated soil）, and amended （oil-polluted soil amended with sawdust）. Enough 3-kg soil samples were sieved and air-dried to prepare five treatment levels of waste engine oil-contaminated soil （30 mL, 1%; 60 mL, 2%; 90 mL, 3%; 120 mL, 4%; and 150 mL, 5%）, as well as five additional treatment levels （the same amounts ofoil contamination） in soil amended with sawdust. The treatment levels were replicated five times in a completely randomized design. A nursery bed was planted with a hybrid tomato variety （Roma V F） obtained from National Horticultural Research Institute （NIHORT） in Ibadan, Nigeria. During the maturation period, the growth parameters such as plant height, number of leaves, and number of branches per plant were determined and then the harvested plants were oven dried at 70 ℃for 48 hours to determine their dry weights. The effects of the sawdust amendment on the soil were assessed by determining the soil pH （glass electrode pH meter）, total nitrogen （Kjeldahl method）, total phosphorus （Bray-1 solution）, and potassium （on the leacheate by a flame photometer）. Chromium, lead, and cadmium contents were determined using an atomic absorption spectrophotometer. Analysis of variance and a Duncan multiple-range test were employed to test significant differences in the soil properties of the three regimes. The growth performance ofSolanum esculentum Linn. in the amended regime （soil with sawdust） at the 150-mL waste engine oil-contamination level was significantly higher than in the polluted regime （soil without sawdust）. After plant harvest, the pH of the soil was shown to be clearly affected by the addition of waste engine oil. The control soil （air-dried only, no sawdust, no oil） had the highest pH value, 6.60, which was significantly different from the pH values at other levels of waste engine oil contamination. However, when amended with sawdust, the control soil had a significantly lower pH value than the unamended control soil. This study further demonstrates that sawdust has the potential of amending waste engine oil-contaminated soil for increasing tomato growth performance because it is capable of increasing the soil nutrient content and reducing the soil total hydrocarbon content.展开更多
The physical performance of recycled asphalt was used as the main evaluation index to study the optimal range of a self-made rejuvenator.Through the penetration,viscosity and gel permeation chromatography(GPC)tests,th...The physical performance of recycled asphalt was used as the main evaluation index to study the optimal range of a self-made rejuvenator.Through the penetration,viscosity and gel permeation chromatography(GPC)tests,the diffusion degree of the rejuvenator under different temperatures and time process was analyzed,and the diffusion efficiency of the rejuvenator was evaluated from the macro and micro perspective.The regeneration mechanism of the rejuvenator in the aged asphalt was also analyzed using the Fourier transform infrared spectroscopy(FTIR),scanning electron microscope(SEM)and chemical composition tests.The research results showed that the optimum rejuvenator content was about 3%.Higher temperature and longer time were beneficial to improving the permeability and diffusion of the rejuvenator.During the aging process,the light components were reduced,and more macromolecular asphaltenes were generated as well as a large number of carbonyl and sulfoxide.After diffusion and regeneration,the light components in the asphalt were supplemented,the wrinkles and gullies of the aged asphalt were almost improved to the surface state of the matrix asphalt.展开更多
Ship auxiliary engines contribute large amounts of air pollutants when at berth.Biodiesel,including that from waste cooking oil(WCO),can favor a reduction in the emission of primary pollutant when used with internal c...Ship auxiliary engines contribute large amounts of air pollutants when at berth.Biodiesel,including that from waste cooking oil(WCO),can favor a reduction in the emission of primary pollutant when used with internal combustion engines.This study investigated the emissions of gaseous intermediate-volatile organic compounds(IVOCs)between WCO biodiesel and marine gas oil(MGO)to further understand the differences in secondary organic aerosol(SOA)production of exhausts.Results revealed that WCO exhaust exhibited similar IVOC composition and volatility distribution to MGO exhaust,despite the differences between fuel contents.While WCO biodiesel could reduce IVOC emissions by 50%as compared to MGO,and thus reduced the SOA production from IVOCs.The compositions and volatility distributions of exhaust IVOCs varied to those of their fuels,implying that fuel-component-based SOA predicting model should be used with more cautions when assessing SOA production of WCO and MGO exhausts.WCO biodiesel is a cleaner fuel comparing to conventional MGO on ship auxiliary engines with regard to the reductions in gaseous IVOC emissions and corresponding SOA productions.Although the tests were conducted on test bench,the results could be considered as representative due to the widely applications of the test engine and MGO fuel on real-world ships.展开更多
Utilizing oil extracted from waste engine oil and waste plastics, by pyrolysis, as a filel for internal combustion engines has been demonstrated to be one of the best available waste management methods. Separate blend...Utilizing oil extracted from waste engine oil and waste plastics, by pyrolysis, as a filel for internal combustion engines has been demonstrated to be one of the best available waste management methods. Separate blends of fuel from waste engine oil and waste plastic oil was prepared by mixing with diesel and experimental investigation is conducted to study engine performance, combustion and exhaust emissions. It is observed that carbon monoxide （CO） emission increases by 50% for 50% waste plastic oil （50WPO：50D） and by 58% for 50% waste engine oil （50WEO：50D） at full load as compared to diesel. Unburnt hydrocarbon （HC） emission increases by 16% for 50WPO：50D and by 32% for 50WEO：50D as compared to diesel at maximum load. Smoke is fotmd to decrease at all loading conditions for 50WPO：50D operation, but it is comparatively higher for 50WEO：50D operation. 50WPO：50D operation shows higher brake thermal efficiency for all loads as compared to 50WEO：50D and diesel fuel operation. Exhaust gas temperature is higher at all loads tbr 50WPO：50D and 50WEO：50D as compared to diesel fuel operation.展开更多
Biodiesel is derived from waste cooking oil (WCO) by transesterification. Methylester was prepared by mixing diesel and biodiesel oils as 20% by volume. Nano particles asTiO2, Al2O3 and CNTs were blended with biodiese...Biodiesel is derived from waste cooking oil (WCO) by transesterification. Methylester was prepared by mixing diesel and biodiesel oils as 20% by volume. Nano particles asTiO2, Al2O3 and CNTs were blended with biodiesel blend at different concentrations of 25,50, and 100 mg/l to enhance the physicochemical fuel characteristics to obtain clean and effi-cient combustion performance. An experimental setup was incorporated into a diesel engine toinvestigate the influence of these nano-materials on engine performance, exergy analysis, combustion characteristics and emissions using WCO biodiesel-diesel mixture. Enriching methylester mixture with 100 ppm titanium, alumina and CNTs (B20T100, B20A100 andB20C100) increased the thermal efficiency by 4%, 6% and 11.5%, respectively compared toB20. Biodiesel blending with nano additives B20T100, B20A100 and B20C100 decreasedthe emissions of CO (11%, 24% and 30%, respectively), HC (8%, 17% and 25%, respectively)and smoke (10%, 13% and 19%, respectively) compared to B20. However, the noticeable increase of NOx was estimated by 5%, 12% and 27% for B20T100, B20A100 and B20C100,respectively. Finally, the results showed the rise in peak cylinder pressure by 5%, 9% and 11% and increase in heat release rate by 4%, 8% and 13% for B20T100, B20A100 andB20C100, respectively. The fuel exergy of B20T100, B20A100 and B20C100 are lower thanbiodiesel blend B20 by 6.5%, 16% and 23% but the exergetic efficiency are increased by 7%,19% and 30% at full load about B20.展开更多
文摘Biodiesels produced from various feedstocks have been considered as alternative fuels used in internal combustion engines without major modifications.This research focuses on producing biodiesel from waste cooking oil(WCOSD)by the catalytic cracking method using MgO as the catalyst and comparing the engine operating characteristics of the test engine when using WCOSD and traditional diesel(CD)as test fuels.As a result,the brake power of the test engine fueled WCOSD,and traditional diesel is similar.However,the engine fuel consumption in the case of using WCOSD is slight increases in some operating conditions.Also,the nitrogen oxides emissions of the test engine fueled WCOSD are higher than those of CD at all tested conditions.The trend is opposite for hydrocarbon emission as the HC emission of the engine fueled by WCOSD reduces 26.3%on average.The smoke emission of the test engine in case of using WCOSD is lower 17%on average than that of CD.However,the carbon monoxide emissions are lower at the low and medium loads and higher at the full loads.These results show that the new biodiesel has the same characteristics as those of commercial biodiesel and can be used as fuel for diesel engines.
文摘Internal combustion engines with application in automobiles and other relevant industries constitute significant environmental pollution via the release of toxic exhaust gasses like carbon monoxide (CO), hydrocarbons (HC), particulate matter (PM), and nitrogen oxide (NO<sub>x</sub>). Engine researchers and manufacturers are challenged to develop external and internal measures to ensure environmentally friendly solutions to accommodate and conform to the growing list of emission standards. Therefore, this work presents an experimental investigation of the NO<sub>x</sub> emission profile of a diesel engine that is fuelled and fitted with waste frying oil-based biodiesel and catalytic converter. Using a single-cylinder, four-stroke air-cooled CI engine at a constant speed of 1900 rpm and different loadings of 25%, 50%, 75%, and 100%;fitted with a catalytic converter at the exhaust outlet of the engine and linked to a dynamometer and a gas analyser, an experiment was conducted at biodiesel/diesel volume blends of B0 (0/10), B5 (5/95), B20 (20/80), B30 (30/70), B70 (70/30), B100 (100/0);and 30% concentration (v/v), 0.5 litre/hr flow rate of aqueous urea from the catalytic converter. The results show an increasing NO<sub>x</sub> emission as the biodiesel component increased in the blend. The catalytic converter showed a downward NO<sub>x</sub> reduction with a significant 68% reduction in efficiency at high exhaust gas temperatures. It is concluded that the combined utilisation of waste frying oil-based biodiesel and the catalytic converter yields substantial NO<sub>x</sub> emission reduction.
文摘This study investigated the effects of sawdust as a soil amendment on certain growth parameters of Solanum esculentum Linn. grown in soil polluted with various concentrations of waste engine oil, and changes in the physicochemical proper- ties of the soil. The purpose was to assess the soil remediation potentials of sawdust in waste engine oil-polluted soil. The experiment was divided into three regimes： control （air-dried soil without waste engine oil and with clean sawdust）, pol- luted （waste engine oil-contaminated soil）, and amended （oil-polluted soil amended with sawdust）. Enough 3-kg soil samples were sieved and air-dried to prepare five treatment levels of waste engine oil-contaminated soil （30 mL, 1%; 60 mL, 2%; 90 mL, 3%; 120 mL, 4%; and 150 mL, 5%）, as well as five additional treatment levels （the same amounts ofoil contamination） in soil amended with sawdust. The treatment levels were replicated five times in a completely randomized design. A nursery bed was planted with a hybrid tomato variety （Roma V F） obtained from National Horticultural Research Institute （NIHORT） in Ibadan, Nigeria. During the maturation period, the growth parameters such as plant height, number of leaves, and number of branches per plant were determined and then the harvested plants were oven dried at 70 ℃for 48 hours to determine their dry weights. The effects of the sawdust amendment on the soil were assessed by determining the soil pH （glass electrode pH meter）, total nitrogen （Kjeldahl method）, total phosphorus （Bray-1 solution）, and potassium （on the leacheate by a flame photometer）. Chromium, lead, and cadmium contents were determined using an atomic absorption spectrophotometer. Analysis of variance and a Duncan multiple-range test were employed to test significant differences in the soil properties of the three regimes. The growth performance ofSolanum esculentum Linn. in the amended regime （soil with sawdust） at the 150-mL waste engine oil-contamination level was significantly higher than in the polluted regime （soil without sawdust）. After plant harvest, the pH of the soil was shown to be clearly affected by the addition of waste engine oil. The control soil （air-dried only, no sawdust, no oil） had the highest pH value, 6.60, which was significantly different from the pH values at other levels of waste engine oil contamination. However, when amended with sawdust, the control soil had a significantly lower pH value than the unamended control soil. This study further demonstrates that sawdust has the potential of amending waste engine oil-contaminated soil for increasing tomato growth performance because it is capable of increasing the soil nutrient content and reducing the soil total hydrocarbon content.
基金Funded by the Science and Technology Project of Henan Department of Transportation(No.2020J-2-3)Shaanxi Transportation Science and Technology Project(Nos.17-05K,19-10K,19-28K)。
文摘The physical performance of recycled asphalt was used as the main evaluation index to study the optimal range of a self-made rejuvenator.Through the penetration,viscosity and gel permeation chromatography(GPC)tests,the diffusion degree of the rejuvenator under different temperatures and time process was analyzed,and the diffusion efficiency of the rejuvenator was evaluated from the macro and micro perspective.The regeneration mechanism of the rejuvenator in the aged asphalt was also analyzed using the Fourier transform infrared spectroscopy(FTIR),scanning electron microscope(SEM)and chemical composition tests.The research results showed that the optimum rejuvenator content was about 3%.Higher temperature and longer time were beneficial to improving the permeability and diffusion of the rejuvenator.During the aging process,the light components were reduced,and more macromolecular asphaltenes were generated as well as a large number of carbonyl and sulfoxide.After diffusion and regeneration,the light components in the asphalt were supplemented,the wrinkles and gullies of the aged asphalt were almost improved to the surface state of the matrix asphalt.
基金financially supported by the National Natural Science Foundation of China(Nos.41403084,41807341,4171101108 and 41603090)the Project from Shanghai Committee of Science and Technology(No.16ZR1414800)
文摘Ship auxiliary engines contribute large amounts of air pollutants when at berth.Biodiesel,including that from waste cooking oil(WCO),can favor a reduction in the emission of primary pollutant when used with internal combustion engines.This study investigated the emissions of gaseous intermediate-volatile organic compounds(IVOCs)between WCO biodiesel and marine gas oil(MGO)to further understand the differences in secondary organic aerosol(SOA)production of exhausts.Results revealed that WCO exhaust exhibited similar IVOC composition and volatility distribution to MGO exhaust,despite the differences between fuel contents.While WCO biodiesel could reduce IVOC emissions by 50%as compared to MGO,and thus reduced the SOA production from IVOCs.The compositions and volatility distributions of exhaust IVOCs varied to those of their fuels,implying that fuel-component-based SOA predicting model should be used with more cautions when assessing SOA production of WCO and MGO exhausts.WCO biodiesel is a cleaner fuel comparing to conventional MGO on ship auxiliary engines with regard to the reductions in gaseous IVOC emissions and corresponding SOA productions.Although the tests were conducted on test bench,the results could be considered as representative due to the widely applications of the test engine and MGO fuel on real-world ships.
文摘Utilizing oil extracted from waste engine oil and waste plastics, by pyrolysis, as a filel for internal combustion engines has been demonstrated to be one of the best available waste management methods. Separate blends of fuel from waste engine oil and waste plastic oil was prepared by mixing with diesel and experimental investigation is conducted to study engine performance, combustion and exhaust emissions. It is observed that carbon monoxide （CO） emission increases by 50% for 50% waste plastic oil （50WPO：50D） and by 58% for 50% waste engine oil （50WEO：50D） at full load as compared to diesel. Unburnt hydrocarbon （HC） emission increases by 16% for 50WPO：50D and by 32% for 50WEO：50D as compared to diesel at maximum load. Smoke is fotmd to decrease at all loading conditions for 50WPO：50D operation, but it is comparatively higher for 50WEO：50D operation. 50WPO：50D operation shows higher brake thermal efficiency for all loads as compared to 50WEO：50D and diesel fuel operation. Exhaust gas temperature is higher at all loads tbr 50WPO：50D and 50WEO：50D as compared to diesel fuel operation.
文摘Biodiesel is derived from waste cooking oil (WCO) by transesterification. Methylester was prepared by mixing diesel and biodiesel oils as 20% by volume. Nano particles asTiO2, Al2O3 and CNTs were blended with biodiesel blend at different concentrations of 25,50, and 100 mg/l to enhance the physicochemical fuel characteristics to obtain clean and effi-cient combustion performance. An experimental setup was incorporated into a diesel engine toinvestigate the influence of these nano-materials on engine performance, exergy analysis, combustion characteristics and emissions using WCO biodiesel-diesel mixture. Enriching methylester mixture with 100 ppm titanium, alumina and CNTs (B20T100, B20A100 andB20C100) increased the thermal efficiency by 4%, 6% and 11.5%, respectively compared toB20. Biodiesel blending with nano additives B20T100, B20A100 and B20C100 decreasedthe emissions of CO (11%, 24% and 30%, respectively), HC (8%, 17% and 25%, respectively)and smoke (10%, 13% and 19%, respectively) compared to B20. However, the noticeable increase of NOx was estimated by 5%, 12% and 27% for B20T100, B20A100 and B20C100,respectively. Finally, the results showed the rise in peak cylinder pressure by 5%, 9% and 11% and increase in heat release rate by 4%, 8% and 13% for B20T100, B20A100 andB20C100, respectively. The fuel exergy of B20T100, B20A100 and B20C100 are lower thanbiodiesel blend B20 by 6.5%, 16% and 23% but the exergetic efficiency are increased by 7%,19% and 30% at full load about B20.
