Three kinds of craft waste liquids, which are by-products in the pulp industry and contain much lignin, were used as dispersing additives for preparing Horonai coal CWM(coal water mixture). The experiments showed t...Three kinds of craft waste liquids, which are by-products in the pulp industry and contain much lignin, were used as dispersing additives for preparing Horonai coal CWM(coal water mixture). The experiments showed that the CWM exhibited the lowest viscosity when it was diluted with an appropriate amount of water with the waste eiquids added. The experiments also indicated that the maximum coal concentration in the practically applicable CWMs whose apparent viscosity has to be below 1000 mPa·s increased from 56.5% to 62.5%(mass fraction), and 56.5% is the maximum coal mass fraction of the CWM prepared without additives. These data show the effectiveness of the waste liquids as the additives for preparing CWMs. The zeta potential of coal particles in the CWMs changed with the addition of lignin. From the change, the steric repulsion effect of the lignin adsorbed on the coal particles is concluded to be mainly responsible for the CWM dispersion. The waste liquids contain less sulfur than PSSNa(polystyrene sulfonate sodium salt), a typical dispersant which is currently used for preparing the commercial CWM, when the sulfur content in the unit mass of the solid matters within the waste liquids is compared with that in unit mass of PSSNa. This fact suggests that the waste liquids are more advantageous than PSSNa as far as air pollutants are concerned.展开更多
A bi-component alcoholysis agent containing propylene glycol(PG)and ethanolamine(ETA)was used to catalyst the degradation of the waste polyurethane rigid foam.The oligomer polyols obtained through degradation were use...A bi-component alcoholysis agent containing propylene glycol(PG)and ethanolamine(ETA)was used to catalyst the degradation of the waste polyurethane rigid foam.The oligomer polyols obtained through degradation were used as raw materials to produce recycled polyurethane rigid foam composites with lignin as reinforcing filler.The effect of alcoholysis mass ratio on degradation was investigated by analyzing the viscosity,hydroxyl content and chemical structure of the degradation products.The effect of lignin addition on the properties of regenerated polyurethane rigid foam were investigated by analyzing water absorption rate,compressive strength,porosity,thermal stability,thermal conductivity coefficient,morphology and thermal stability of the recycled polyurethane rigid foam.Results show that different mass ration of PG to ETA significantly affects the degradation of waste polyurethane rigid foam.Besides,only with the addition of appropriate amount of lignin,the regenerated polyurethane rigid foam composites can meet the Chinese national standard“rigid polyurethane foam for building thermal insulation”(GB/T21558-2008).At this point,the composite is with good mechanical and thermal prperties,including high compressive strength,excellent thermal insulation performance,complete cell morphology and good thermal stability.展开更多
New powdered sorbent Lignosorb based on the hydrophobized hydrolysis lignin has been developed at the Belarusian State University. Hydrolysis lignin is a commercial waste product of biomass processing in the hydrolysi...New powdered sorbent Lignosorb based on the hydrophobized hydrolysis lignin has been developed at the Belarusian State University. Hydrolysis lignin is a commercial waste product of biomass processing in the hydrolysis production of ethanol. In spite of the various proposals for hydrolysis lignin usage, the wide application has not found yet. Special area of hydrophobized hydrolysis lignin usage as a sorbent for oil spills removal and oil products waste recovery is discussed. Lignosorb, thanks to the rather high bulk density, can be applied manually or mechanically by conventional sprayers. It does not sink after oil adsorption and transforms liquid oil film on the water surface into the solid mass. The solid product is a complete mass and is easily collected from the surface of water. Lignosorb when blended with oil products waste in the volume forms the granular free-running product. The rheological properties of the Lignosorb suspensions in oil products at different sorbent to oil product ratio have been estimated. Saturated by different oil products Lignosorb one can granulate or pellet and utilize as a composite solid fuel including the co-firing regime of combustion. It has the higher heating value of 32.1 - 38.8 MJ/kg while the coal has 20.9 - 30.1 MJ/kg. It has been shown that composite fuel burning has less longstanding inflammation stage, more long stable burning stage and less longstanding phase of smoldering in the comparison to wood and Lignosorb burning.展开更多
基金Supported by the Core Research for Evolutional Science and Technology(CREST) ,Japan Science and TechnologyCorporation(JST)
文摘Three kinds of craft waste liquids, which are by-products in the pulp industry and contain much lignin, were used as dispersing additives for preparing Horonai coal CWM(coal water mixture). The experiments showed that the CWM exhibited the lowest viscosity when it was diluted with an appropriate amount of water with the waste eiquids added. The experiments also indicated that the maximum coal concentration in the practically applicable CWMs whose apparent viscosity has to be below 1000 mPa·s increased from 56.5% to 62.5%(mass fraction), and 56.5% is the maximum coal mass fraction of the CWM prepared without additives. These data show the effectiveness of the waste liquids as the additives for preparing CWMs. The zeta potential of coal particles in the CWMs changed with the addition of lignin. From the change, the steric repulsion effect of the lignin adsorbed on the coal particles is concluded to be mainly responsible for the CWM dispersion. The waste liquids contain less sulfur than PSSNa(polystyrene sulfonate sodium salt), a typical dispersant which is currently used for preparing the commercial CWM, when the sulfur content in the unit mass of the solid matters within the waste liquids is compared with that in unit mass of PSSNa. This fact suggests that the waste liquids are more advantageous than PSSNa as far as air pollutants are concerned.
文摘A bi-component alcoholysis agent containing propylene glycol(PG)and ethanolamine(ETA)was used to catalyst the degradation of the waste polyurethane rigid foam.The oligomer polyols obtained through degradation were used as raw materials to produce recycled polyurethane rigid foam composites with lignin as reinforcing filler.The effect of alcoholysis mass ratio on degradation was investigated by analyzing the viscosity,hydroxyl content and chemical structure of the degradation products.The effect of lignin addition on the properties of regenerated polyurethane rigid foam were investigated by analyzing water absorption rate,compressive strength,porosity,thermal stability,thermal conductivity coefficient,morphology and thermal stability of the recycled polyurethane rigid foam.Results show that different mass ration of PG to ETA significantly affects the degradation of waste polyurethane rigid foam.Besides,only with the addition of appropriate amount of lignin,the regenerated polyurethane rigid foam composites can meet the Chinese national standard“rigid polyurethane foam for building thermal insulation”(GB/T21558-2008).At this point,the composite is with good mechanical and thermal prperties,including high compressive strength,excellent thermal insulation performance,complete cell morphology and good thermal stability.
文摘New powdered sorbent Lignosorb based on the hydrophobized hydrolysis lignin has been developed at the Belarusian State University. Hydrolysis lignin is a commercial waste product of biomass processing in the hydrolysis production of ethanol. In spite of the various proposals for hydrolysis lignin usage, the wide application has not found yet. Special area of hydrophobized hydrolysis lignin usage as a sorbent for oil spills removal and oil products waste recovery is discussed. Lignosorb, thanks to the rather high bulk density, can be applied manually or mechanically by conventional sprayers. It does not sink after oil adsorption and transforms liquid oil film on the water surface into the solid mass. The solid product is a complete mass and is easily collected from the surface of water. Lignosorb when blended with oil products waste in the volume forms the granular free-running product. The rheological properties of the Lignosorb suspensions in oil products at different sorbent to oil product ratio have been estimated. Saturated by different oil products Lignosorb one can granulate or pellet and utilize as a composite solid fuel including the co-firing regime of combustion. It has the higher heating value of 32.1 - 38.8 MJ/kg while the coal has 20.9 - 30.1 MJ/kg. It has been shown that composite fuel burning has less longstanding inflammation stage, more long stable burning stage and less longstanding phase of smoldering in the comparison to wood and Lignosorb burning.
