To fully utilize secondary resources,it will inevitably generate a large amount of deinking sludge using waste paper as raw material for paper making.The sludge contains small fibers and dissolved substances of variou...To fully utilize secondary resources,it will inevitably generate a large amount of deinking sludge using waste paper as raw material for paper making.The sludge contains small fibers and dissolved substances of various chemicals.After adding flocculant and settling treatment,deinked sludge is formed.However,its organic matter content can reach a high level of 40%to 50%,and it can also be reused,effectively avoiding the harmful impact of papermaking sludge on the environment.展开更多
Deinking of secondary fiber of ONP and effluent treatment with white rot fungus were studied in this paper. Results showed that white rot fungus exerted significant effect on deinking of ONP and CODcr decrease and deg...Deinking of secondary fiber of ONP and effluent treatment with white rot fungus were studied in this paper. Results showed that white rot fungus exerted significant effect on deinking of ONP and CODcr decrease and degradation of pollutants of deinking effluent .展开更多
This article focused on deinking agents for enzymatic deinking of MOW (mixed office wastepaper). The deinking performances of many series of surfactants were discussed at the experimental conditions, and finally some ...This article focused on deinking agents for enzymatic deinking of MOW (mixed office wastepaper). The deinking performances of many series of surfactants were discussed at the experimental conditions, and finally some surfactants, which had good deinking effect, were selected. Then two-composed deinking agents were discussed. The deinkability of the deinking agents, e.g. deinking agents containing T-123 50% and P-10 50%, T-123 70% and O-15 30%, were better than that of the imported product.展开更多
Deinking is an important process in waste paper recycling process,and this study mainly focuses on the properties of the deinking agent and process optimization.DIA-30 prepared in our laboratory,and FS and LD,were the...Deinking is an important process in waste paper recycling process,and this study mainly focuses on the properties of the deinking agent and process optimization.DIA-30 prepared in our laboratory,and FS and LD,were the three representative deinking agents studied herein.Brightness,effective residual ink concentration(ERIC),dirt,macro-stickies,fiber loss during repulping,flotation,and washing processes were measured to evaluate the performance of the deinking agents and optimize process conditions.Each of the deinking agents exhibited different advantages:DIA-30 was optimal for deinking efficiency,brightness enhancement,as well as dirt and macrostickies removal,whereas LD was optimal for ink removal during flotation process but performed poorly in terms of brightness enhancement.FS showed a relatively balanced performance compared to those of DIA-30 and LD in the deinking process,but DIA-30 is the best option for deinking due to its outstanding comprehensive properties.The optimal repulping conditions for the deinking of 100%old magzines(OMG)using DIA-30 are as follows:repulping temperature,60℃;pulp consistency,13 wt%;repulping time,20 min;H2O2 dosage,0.5 wt%(oven-dried pulp);NaOH dosage,1.2 wt%(oven-dried pulp);Na2SiO3 dosage,0.3 wt%(oven-dried pulp);and optimum DIA-30 dosage,0.1 wt%.展开更多
The secondary fiber species,main composition of deinking agent,colloid chemistry behavior of deinking process etc. that may influence the deinking result of secondary fiber were analysed in this dissertation,and some ...The secondary fiber species,main composition of deinking agent,colloid chemistry behavior of deinking process etc. that may influence the deinking result of secondary fiber were analysed in this dissertation,and some thoughts that optimizing the currently deingking technology were also suggested.展开更多
Cellulase deinking process of non-impact printed wastes was studied. The optimized conditions were: cellulase charge 0.3%, temperature 50℃, pulping consistency 10%, enzyme treatment time 30 min,agitating speed 400 rp...Cellulase deinking process of non-impact printed wastes was studied. The optimized conditions were: cellulase charge 0.3%, temperature 50℃, pulping consistency 10%, enzyme treatment time 30 min,agitating speed 400 rpm. Qquality of the deinking pulp was assessed by measuring the number, average diameter, percent coverage of residual ink using Paperican ink scanner.展开更多
The ONP neutral deinking performances of fatty alcohol polyoxyethylene ether with different EO value were investigated in this paper. Meanwhile, the synergistic effects of different non-ionic surfactants, the co-opera...The ONP neutral deinking performances of fatty alcohol polyoxyethylene ether with different EO value were investigated in this paper. Meanwhile, the synergistic effects of different non-ionic surfactants, the co-operation of non-ionic surfactants with anionic surfactants,and the effects of different salts added into the above two systems on deinkability were also studied. The results showed the deinking performance of A7 was good. But the synergistic effect of A7 and A4 was better. In addition, the accession of salt W2 could improve the deinking efficiency, and the brightness of the deinked pulp was 1.0%ISO higher than that of A7 and A4.展开更多
In this paper, the application of modified polyacylamide is discussed and the complex systems of PAC/modified PAM are used to treat the papermaking wastewater. The results showed that when cationic polyacylamide (CPAM...In this paper, the application of modified polyacylamide is discussed and the complex systems of PAC/modified PAM are used to treat the papermaking wastewater. The results showed that when cationic polyacylamide (CPAM) and amphoteric polyacylamide (AmPAM) were used at the dosage of 0.75ppm with PAC, of which the optimum dosage was 100ppm, the removed rate of CODcr was above 80% .展开更多
The aim of this research is to study the floatation deinking abilities of black mold enzyme and chemicals in newsprint paper application. In this experiment, the properties of deinked pulp from three different additiv...The aim of this research is to study the floatation deinking abilities of black mold enzyme and chemicals in newsprint paper application. In this experiment, the properties of deinked pulp from three different additives--chemicals, black mold enzyme, and chemicals together with black mold enzyme, are studied. The first part of the experiment was to find the optimal amount of chemicals and the optimal pH through the use of sodium hydroxide and surfactant. As a result, 0.2% of sodium hydroxide and 0.4% of surfactant on oven dried weight at pH 9 was found to be the optimal condition for the deinked pulp to yield the lowest ERIC （effective residual concentration） and the highest brightness. The second part of the experiment was to find the optimal amount of black mold enzyme used in the deinking process. As a result, the optimal condition for deinked pulp to retain the lowest ERIC and the highest brightness was 100 ppm of black mold enzyme and 10 minutes of enzyme reaction time. The third part of experiment was to study the de-inking ability of black mold enzyme and chemicals. Consequently, with 30 min of chemicals reaction time and 60 min of black mold reaction time, the deinked pulp retained low ERIC but higher brightness.展开更多
In this article, conditions for ONP chemical deinking were optimized firstly, and then on the optimized conditions deinking performances of some series surfactants were discussed. Pluronic block copolyether did not ha...In this article, conditions for ONP chemical deinking were optimized firstly, and then on the optimized conditions deinking performances of some series surfactants were discussed. Pluronic block copolyether did not have good deinking performances, polyoxyethylene alkyl ether, polyoxyethylene carboxylate and polyoxyethyleneoxypropylene alkyl ether could be used as one component of flotation deinking agents for ONP.展开更多
In this paper, the old newsprint and the common domestic old paper are subjected to deinking process. We mainly studied the relation between deinking efficiency of different recovery pulps and their colloid-chemical b...In this paper, the old newsprint and the common domestic old paper are subjected to deinking process. We mainly studied the relation between deinking efficiency of different recovery pulps and their colloid-chemical behavior such as Zeta potential and surface tension. Technical conditions that affect the deinking pulp’s colloid chemical behavior are also analyzed here.展开更多
The implementation of the European WFD （water framework directive） requires IWRM （integrated water resource management）, an important tool in managing available water resources in the presence of emerging constrai...The implementation of the European WFD （water framework directive） requires IWRM （integrated water resource management）, an important tool in managing available water resources in the presence of emerging constraints. Pressures caused by variability in water supply cycles, droughts, pollution, industrialization, increasing domestic and commercial demand, inadequate infrastructure, intense urbanization and population growth, and decrepit distribution networks have led to the increasing exploitation of industrial wastewater. Most industrial process has some negative impacts on the environment especially on a catchment scale i.e. water, air and soil quality. In the context of water resources and environmental protection measures, the term ＂sustainable development＂, a development that is compatible with the future gains and environmental protection, is regulated more and more by law. To comply with these emission-based limit values, so-called ＂end-of-pipe-techniques＂ are used. Experimental results show CBT （continuous biological treatment） processes present secondary measures to purify highly contaminated industrial wastewater.展开更多
Three kinds of cellulases with different components were applied to the deinking of mixed office waste paper, MOW. In the process of enzymatic deinking of MOW, not only improvement of toner particle removal was achiev...Three kinds of cellulases with different components were applied to the deinking of mixed office waste paper, MOW. In the process of enzymatic deinking of MOW, not only improvement of toner particle removal was achieved with the addition of enzymes but other properties of the deinked pulps were influenced. Drainage properties of the deinked pulp were improved after treated with enzymes. Higher enzyme dosage was needed compared with that only for deinking purpose if obvious drainage improvement of the deinked pulp were to be achieved. The enzymatic hydrolysis of fibers did not lead to distinct fiber length decrease, but declined the zero tensile strength of the pulp declined with addition of enzymes, which indicating the decrease of individual fiber strength. In addition, enzyme treatment resulted in the enhancement of specific surface area of fibers.展开更多
As the cost of quality waste paper continues to escalate in response to an increased global demand for the finite resource, loss of saleable fiber within flotation rejects becomes both environmentally and economically...As the cost of quality waste paper continues to escalate in response to an increased global demand for the finite resource, loss of saleable fiber within flotation rejects becomes both environmentally and economically unacceptable. The ability of surfactant spray technology to reduce yield loss without detriment to pulp brightness gains has been demonstrated during both laboratory- and pilot-scale flotation deinking investigations. This paper documents the successful transfer of this technology to a single flotation unit within the deinking line of a mill producing newsprint from 100% secondary fiber. Initial results suggest that the loss of fiber across the unit may be reduced by more than 50% without obvious detriment to final pulp quality.展开更多
文摘To fully utilize secondary resources,it will inevitably generate a large amount of deinking sludge using waste paper as raw material for paper making.The sludge contains small fibers and dissolved substances of various chemicals.After adding flocculant and settling treatment,deinked sludge is formed.However,its organic matter content can reach a high level of 40%to 50%,and it can also be reused,effectively avoiding the harmful impact of papermaking sludge on the environment.
文摘Deinking of secondary fiber of ONP and effluent treatment with white rot fungus were studied in this paper. Results showed that white rot fungus exerted significant effect on deinking of ONP and CODcr decrease and degradation of pollutants of deinking effluent .
文摘This article focused on deinking agents for enzymatic deinking of MOW (mixed office wastepaper). The deinking performances of many series of surfactants were discussed at the experimental conditions, and finally some surfactants, which had good deinking effect, were selected. Then two-composed deinking agents were discussed. The deinkability of the deinking agents, e.g. deinking agents containing T-123 50% and P-10 50%, T-123 70% and O-15 30%, were better than that of the imported product.
基金support from the science and technology project of Guangzhou city (Contract No. 201607020025)
文摘Deinking is an important process in waste paper recycling process,and this study mainly focuses on the properties of the deinking agent and process optimization.DIA-30 prepared in our laboratory,and FS and LD,were the three representative deinking agents studied herein.Brightness,effective residual ink concentration(ERIC),dirt,macro-stickies,fiber loss during repulping,flotation,and washing processes were measured to evaluate the performance of the deinking agents and optimize process conditions.Each of the deinking agents exhibited different advantages:DIA-30 was optimal for deinking efficiency,brightness enhancement,as well as dirt and macrostickies removal,whereas LD was optimal for ink removal during flotation process but performed poorly in terms of brightness enhancement.FS showed a relatively balanced performance compared to those of DIA-30 and LD in the deinking process,but DIA-30 is the best option for deinking due to its outstanding comprehensive properties.The optimal repulping conditions for the deinking of 100%old magzines(OMG)using DIA-30 are as follows:repulping temperature,60℃;pulp consistency,13 wt%;repulping time,20 min;H2O2 dosage,0.5 wt%(oven-dried pulp);NaOH dosage,1.2 wt%(oven-dried pulp);Na2SiO3 dosage,0.3 wt%(oven-dried pulp);and optimum DIA-30 dosage,0.1 wt%.
文摘The secondary fiber species,main composition of deinking agent,colloid chemistry behavior of deinking process etc. that may influence the deinking result of secondary fiber were analysed in this dissertation,and some thoughts that optimizing the currently deingking technology were also suggested.
文摘Cellulase deinking process of non-impact printed wastes was studied. The optimized conditions were: cellulase charge 0.3%, temperature 50℃, pulping consistency 10%, enzyme treatment time 30 min,agitating speed 400 rpm. Qquality of the deinking pulp was assessed by measuring the number, average diameter, percent coverage of residual ink using Paperican ink scanner.
文摘The ONP neutral deinking performances of fatty alcohol polyoxyethylene ether with different EO value were investigated in this paper. Meanwhile, the synergistic effects of different non-ionic surfactants, the co-operation of non-ionic surfactants with anionic surfactants,and the effects of different salts added into the above two systems on deinkability were also studied. The results showed the deinking performance of A7 was good. But the synergistic effect of A7 and A4 was better. In addition, the accession of salt W2 could improve the deinking efficiency, and the brightness of the deinked pulp was 1.0%ISO higher than that of A7 and A4.
文摘In this paper, the application of modified polyacylamide is discussed and the complex systems of PAC/modified PAM are used to treat the papermaking wastewater. The results showed that when cationic polyacylamide (CPAM) and amphoteric polyacylamide (AmPAM) were used at the dosage of 0.75ppm with PAC, of which the optimum dosage was 100ppm, the removed rate of CODcr was above 80% .
文摘The aim of this research is to study the floatation deinking abilities of black mold enzyme and chemicals in newsprint paper application. In this experiment, the properties of deinked pulp from three different additives--chemicals, black mold enzyme, and chemicals together with black mold enzyme, are studied. The first part of the experiment was to find the optimal amount of chemicals and the optimal pH through the use of sodium hydroxide and surfactant. As a result, 0.2% of sodium hydroxide and 0.4% of surfactant on oven dried weight at pH 9 was found to be the optimal condition for the deinked pulp to yield the lowest ERIC （effective residual concentration） and the highest brightness. The second part of the experiment was to find the optimal amount of black mold enzyme used in the deinking process. As a result, the optimal condition for deinked pulp to retain the lowest ERIC and the highest brightness was 100 ppm of black mold enzyme and 10 minutes of enzyme reaction time. The third part of experiment was to study the de-inking ability of black mold enzyme and chemicals. Consequently, with 30 min of chemicals reaction time and 60 min of black mold reaction time, the deinked pulp retained low ERIC but higher brightness.
文摘In this article, conditions for ONP chemical deinking were optimized firstly, and then on the optimized conditions deinking performances of some series surfactants were discussed. Pluronic block copolyether did not have good deinking performances, polyoxyethylene alkyl ether, polyoxyethylene carboxylate and polyoxyethyleneoxypropylene alkyl ether could be used as one component of flotation deinking agents for ONP.
文摘In this paper, the old newsprint and the common domestic old paper are subjected to deinking process. We mainly studied the relation between deinking efficiency of different recovery pulps and their colloid-chemical behavior such as Zeta potential and surface tension. Technical conditions that affect the deinking pulp’s colloid chemical behavior are also analyzed here.
文摘The implementation of the European WFD （water framework directive） requires IWRM （integrated water resource management）, an important tool in managing available water resources in the presence of emerging constraints. Pressures caused by variability in water supply cycles, droughts, pollution, industrialization, increasing domestic and commercial demand, inadequate infrastructure, intense urbanization and population growth, and decrepit distribution networks have led to the increasing exploitation of industrial wastewater. Most industrial process has some negative impacts on the environment especially on a catchment scale i.e. water, air and soil quality. In the context of water resources and environmental protection measures, the term ＂sustainable development＂, a development that is compatible with the future gains and environmental protection, is regulated more and more by law. To comply with these emission-based limit values, so-called ＂end-of-pipe-techniques＂ are used. Experimental results show CBT （continuous biological treatment） processes present secondary measures to purify highly contaminated industrial wastewater.
文摘Three kinds of cellulases with different components were applied to the deinking of mixed office waste paper, MOW. In the process of enzymatic deinking of MOW, not only improvement of toner particle removal was achieved with the addition of enzymes but other properties of the deinked pulps were influenced. Drainage properties of the deinked pulp were improved after treated with enzymes. Higher enzyme dosage was needed compared with that only for deinking purpose if obvious drainage improvement of the deinked pulp were to be achieved. The enzymatic hydrolysis of fibers did not lead to distinct fiber length decrease, but declined the zero tensile strength of the pulp declined with addition of enzymes, which indicating the decrease of individual fiber strength. In addition, enzyme treatment resulted in the enhancement of specific surface area of fibers.
文摘As the cost of quality waste paper continues to escalate in response to an increased global demand for the finite resource, loss of saleable fiber within flotation rejects becomes both environmentally and economically unacceptable. The ability of surfactant spray technology to reduce yield loss without detriment to pulp brightness gains has been demonstrated during both laboratory- and pilot-scale flotation deinking investigations. This paper documents the successful transfer of this technology to a single flotation unit within the deinking line of a mill producing newsprint from 100% secondary fiber. Initial results suggest that the loss of fiber across the unit may be reduced by more than 50% without obvious detriment to final pulp quality.
