The primary objective of this study was to design and size a sustainable sanitation solution for the Ndiebene Gandiol 1 school located in the eponymous commune in northern Senegal. Field investigations led to the coll...The primary objective of this study was to design and size a sustainable sanitation solution for the Ndiebene Gandiol 1 school located in the eponymous commune in northern Senegal. Field investigations led to the collection of wastewater samples. Their analysis revealed specific pollutant loads, including loads of BOD5 3.6966 kgO<sub>2</sub>/day and COD of 12.8775 kgO<sub>2</sub>/day, which were central to the design phase. Following a rigorous assessment of the existing sanitation infrastructure, constructed wetland (CWs) emerged as the most appropriate ecological solution. This system, valued for its ability to effectively remove contaminants, was tailored to the specific needs of the site. Consequently, the final design of the filter extends over 217.16 m<sup>2</sup>, divided into two cells of 108.58 m<sup>2</sup> each, with dimensions of 12.77 m in length and 8.5 m in width. The depth of the filtering medium is approximately 0.60 m, meeting the standards while ensuring maximized purification. Typha, an indigenous and prolific plant known for its purification abilities, was selected as the filtering agent. Concurrently, non-crushed gravel was chosen for its proven filtration capacity. This study is the result of a combination of scientific rigor and design expertise. It provides a holistic view of sanitation for Ndiebene Gandiol. The technical specifications and dimensions of the constructed wetland filter embody an approach that marries indepth analysis and practical application, all aimed at delivering an effective and long-lasting solution to the local sanitation challenges. By integrating precise scientific data with sanitation design expertise, this study delivers a holistic solution for Ndiebene Gandiol. The detailed dimensions and specifications of the constructed wetland filter reflect a methodology that combines meticulous analysis with practical adaptation, aiming to provide an effective and sustainable response to the challenges of rural and school sanitation in the northern region of Senegal.展开更多
To meet the growing emission of water contaminants,the development of new materials that enhance the efficiency of the water treatment system is urgent.Ordered mesoporous materials provide opportunities in environment...To meet the growing emission of water contaminants,the development of new materials that enhance the efficiency of the water treatment system is urgent.Ordered mesoporous materials provide opportunities in environmental processing applications due to their exceptionally high surface areas,large pore sizes,and enough pore volumes.These properties might enhance the performance of materials concerning adsorption/catalysis capability,durability,and stability.In this review,we enumerate the ordered mesoporous materials as adsorbents/catalysts and their modifications in water pollution treatment from the past decade,including heavy metals(Hg^(2+),Pb^(2+),Cd^(2+),Cr^(6+),etc.),toxic anions(nitrate,phosphate,fluoride,etc.),and organic contaminants(organic dyes,antibiotics,etc.).These contributions demonstrate a deep understanding of the synergistic effect between the incorporated framework and homogeneous active centers.Besides,the challenges and perspectives of the future developments of ordered mesoporous materials in wastewater treatment are proposed.This work provides a theoretical basis and complete summary for the application of ordered mesoporous materials in the removal of contaminants from aqueous solutions.展开更多
The digital twins concept enhances modeling and simulation through the integration of real-time data and feedback.This review elucidates the foundational elements of digital twins,covering their concept,entities,domai...The digital twins concept enhances modeling and simulation through the integration of real-time data and feedback.This review elucidates the foundational elements of digital twins,covering their concept,entities,domains,and key technologies.More specifically,we investigate the transformative potential of digital twins for the wastewater treatment engineering sector.Our discussion highlights the application of digital twins to wastewater treatment plants(WWTPs)and sewage networks,hardware(i.e.,facilities and pipes,sensors for water quality and activated sludge,hydrodynamics,and power consumption),and software(i.e.,knowledge-based and data-driven models,mechanistic models,hybrid twins,control methods,and the Internet of Things).Furthermore,two cases are provided,followed by an assessment of current challenges in and perspectives on the application of digital twins in WWTPs.This review serves as an essential primer for wastewater engineers navigating the digital paradigm shift.展开更多
This review describes the mechanisms of natural coagulants.It provides a good understanding of the two key processes of coagulation-flocculation:adsorption and charge neutralization,as well as adsorption and bridging....This review describes the mechanisms of natural coagulants.It provides a good understanding of the two key processes of coagulation-flocculation:adsorption and charge neutralization,as well as adsorption and bridging.Various factors have influence the coagulation/flocculation process,including the effect of pH,coagulant dosage,coagulant type,temperature,initial turbidity,coagulation speed,flocculation speed,coagulation and flocculation time,settling time,colloidal particles,zeta potential,the effects of humic acids,and extraction density are explained.The bio-coagulants derived from plants are outlined.The impact of organic coagulants on water quality,focusing on their effects on the physicochemical parameters of water,heavy metals removal,and bacteriological water quality,is examined.The methods of extraction and purification of plant-based coagulants,highlighting techniques such as solvent extraction and ultrasonic extraction,are discussed.It also examines the parameters that influence these processes.The methods and principles of purification of coagulating agents,including dialysis,freeze-drying,ion exchange,electrophoresis,filtration,and centrifugation,are listed.Finally,it evaluates the sustainability of natural coagulants,focusing on the environmental,technical,and economic aspects of their use.At the end of this review,the readers should have a comprehensive understanding of the mechanisms,selection,extraction,purification,and sustainability of plant-based natural coagulants in water treatment.展开更多
This study presents an assessment of wastewater ecological treatment processes utilizing a horizontal flow bio-reactor at the Ndiebene Gandiol 1 school. It primarily aims to juxtapose the filtration efficacy of two di...This study presents an assessment of wastewater ecological treatment processes utilizing a horizontal flow bio-reactor at the Ndiebene Gandiol 1 school. It primarily aims to juxtapose the filtration efficacy of two distinct vegetative cells, Vetiver and Typha, in the pursuit of sustainable wastewater management strategies for rural scholastic institutions. A synergistic approach was employed, integrating on-site surveys for site-specific insights and laboratory analyses to quantify the pollutant loads pre- and post-treatment. Our findings indicate that both Vetiver and Typha-infused filter beds significantly reduce most contaminants, with particular success in diminishing chemical oxygen demand (COD) and biological oxygen demand (BOD5). Vetiver was notable for its superior reduction of COD, achieving an average effluent concentration of 74 mg/L, in contrast to Typha’s 155 mg/L. Conversely, Typha excelled in suspended solids removal, registering 1 mg/L against Vetiver’s 3 mg/L. While both systems notably surpassed the target metrics across several indicators, including fecal coliform reduction, our results pinpoint the need for refinement in phosphate remediation. Conclusively, the study underscores the efficacy of both Vetiver and Typha systems in rural wastewater treatment contexts, with their integrative application potentially paving the way for enhanced system robustness and efficiency. The outcomes herein highlight the imperative for continued research to further hone these ecological treatment modalities, especially concerning phosphate elimination.展开更多
In Saint-Louis, Senegal, a constructed wetland with horizontal flow reed beds (FHa and FHb) has demonstrated significant efficacy in treating municipal wastewater. Analyzing various treatment stages, the system showed...In Saint-Louis, Senegal, a constructed wetland with horizontal flow reed beds (FHa and FHb) has demonstrated significant efficacy in treating municipal wastewater. Analyzing various treatment stages, the system showed only a slight temperature variation, from an influent average of 26.3°C to an effluent of 24.7°C. Electrical conductivity decreased from 1331 mS/cm to 974.5 mS/cm post-primary treatment, with suspended solids (SS) dramatically reduced from 718.9 mg/L to 5.7 mg/L in the final effluent. Biochemical oxygen demand (BOD5) and chemical oxygen demand (COD) saw a notable decrease, from initial levels of 655.6 mg/L and 1240 mg/L to 2.3 mg/L and 71.3 mg/L, respectively. Nitrogenous compounds (N-TN) and phosphates () also decreased significantly, indicating the system’s nutrient removal capacity. Microbiological analysis revealed a reduction in fecal coliforms from 7.5 Ulog/100ml to 1.8 Ulog/100ml and a complete elimination of helminth eggs. The presence of Phragmites and Typha was instrumental in enhancing these reductions. The system’s compliance with the Senegalese standards for disposal into natural environments, WHO recommendations for unrestricted water reuse in irrigation, and the European legislation for water reuse was established. The effluent quality met the stringent criteria for various classes of agricultural reuse, illustrating the system’s potential for sustainable water management. This wetland model presents a robust solution for water-stressed regions, ensuring environmental protection while supporting agricultural needs. The study calls for ongoing research to further refine the system for optimal, reliable wastewater treatment and water resource sustainability.展开更多
This paper researched a promising biological treatment of methyl violet waste water by methods of activated sludge.Effects of temperature and pH were studied on this process.Kinetic equation ...This paper researched a promising biological treatment of methyl violet waste water by methods of activated sludge.Effects of temperature and pH were studied on this process.Kinetic equation of the substrate biodegradation was investigated in the experimental range.It was studied and simulated that flow within the bubble region of this bioreactor according to the κ ε two fluid equation.Simulation results agree well with experimental data.展开更多
[Objective] The aim was to research the influences of different formulations on oxidation resistance of PVDF hollow fiber membrane.[Method]The immersion precipitation phase inversion method was employed to make castin...[Objective] The aim was to research the influences of different formulations on oxidation resistance of PVDF hollow fiber membrane.[Method]The immersion precipitation phase inversion method was employed to make casting solution with different formulations into hollow fiber membrane.The membrane was immersed in 1% NaClO solution for testing its performance changes.[Result]The membrane made by materials with bigger molecular weight had better oxidation resistance performance;the surfactant tween-80 could increase water flux,but lead to lower rupture intension;Pore-forming agent PEG400 do better than PVP in the oxidation resistance of membrane.[Conclusion]This study will provide a good idea for the development of the PVDF membrane with high oxidation resistance.展开更多
The emulsion stability of oilfield produced water is related to the oil-water interfacial film strength and the zeta potential of the oil droplets. We investigated the effects of water treatment agents (corrosion inh...The emulsion stability of oilfield produced water is related to the oil-water interfacial film strength and the zeta potential of the oil droplets. We investigated the effects of water treatment agents (corrosion inhibitor SL-2, scale inhibitor HEDP, germicide 1227, and flocculant polyaluminium chloride PAC) on the stability of oilfield produced water. The influence of these treatment agents on oil-water interfacial properties and the mechanism of these agents acting on the oilfield produced water were studied by measuring the interfacial shear viscosity, interfacial tension and zeta electric potential. The results indicated that the scale inhibitor HEDP could increase the oil-water interfacial film strength, and it could also increase the absolute value of the zeta potential of oil droplets. HEDP played an important role in the stability of the emulsion. Polyaluminum chloride (PAC) reduced the stability of the emulsion by considerably decreasing the absolute value of the zeta potential of oil droplets. Corrosion inhibitor SL-2 and germicide 1227 could decrease the oil-water interfacial tension, whereas they had little influence on oil-water interfacial shear viscosity and oil-water interfacial electricity properties.展开更多
Nowadays, intensive breeding of poultry and livestock of large scale has made the treatment of its waste and wastewater an urgent environmental issue, which motivated this study. A wetland of 688 mz was constructed on...Nowadays, intensive breeding of poultry and livestock of large scale has made the treatment of its waste and wastewater an urgent environmental issue, which motivated this study. A wetland of 688 mz was constructed on an egg duck farm, and water hyacinth (Eichhornia crassipes) was chosen as an aquatic plant for the wetland and used as food for duck production. The objectives of this study were to test the role of water hyacinth in purifying nutrient-rich wastewater and its effects on the ducks' feed intake, egg laying performance and egg quality. This paper shows that the constructed wetland removed as much as 64.44% of chemical oxygen demand (COD), 21.78% of total nitrogen (TN) and 23.02% of total phosphorus (TP). Both dissolved oxygen (DO) and the transparency of the wastewater were remarkably improved, with its transparency 2.5 times higher than that of the untreated wastewater. After the ducks were fed with water hyacinth, the average daily feed intake and the egg-laying ratio in the test group were 5.86% and 9.79% higher, respectively, than in the control group; the differences were both significant at the 0.01 probability level. The egg weight in the test group was 2.36% higher than in the control group (P 〈 0.05), but the feed conversion ratios were almost the same. The eggshell thickness and strength were among the egg qualities significantly increased in ducks fed with water hyacinth. We concluded that a water hyacinth system was effective for purifying wastewater from an intensive duck farm during the water hyacinth growing season, as harvested water hyacinth had an excellent performance as duck feed. We also discussed the limitations of the experiment.展开更多
The efficiencies of two types of constructed wetlands for the treatment of low-concentration polluted eutrophic land- scape river water were studied in the western section of the Qingyuan River at the Minhang campus o...The efficiencies of two types of constructed wetlands for the treatment of low-concentration polluted eutrophic land- scape river water were studied in the western section of the Qingyuan River at the Minhang campus of Shanghai Jiaotong University.The first wetland was a single-stage system using gravel as a filtration medium,and the second was a three- stage system filled with combinations of gravel,zeolite,and fly ash.Results from parallel operations of the wetlands showed that the three-stage constructed wetland could remove organics,nitrogen, and phosphorus successfully.At the same time,it could also decrease ammoniacal odour in the effluent.Compared to the single-stage constructed wetland,it had better nutrient removal efficiencies with a higher removal of 19.37%-65.27% for total phosphorus (TP) and 21.56%- 62.94% for total nitrogen (TN),respectively,during the operation period of 14 weeks.In terms of removal of chemical oxygen demand (COD), turbidity,and blue-green algae,these two wetland systems had equivalent performances.It was also found that in the western section of the test river,in which the two constructed wetlands were located, the water quality was much better than that in the eastern and middle sections without constructed wetland because COD,TN, and TP were all in a relatively lower level and the eutrophication could be prevented completely in the western section.展开更多
The elemental composition and bacteria attached in particles were investigated during granular activated carbon (GAC) filtration.The experimental results showed that trapped influent particles could form new,larger ...The elemental composition and bacteria attached in particles were investigated during granular activated carbon (GAC) filtration.The experimental results showed that trapped influent particles could form new,larger particles on GAC surface.The sloughing of individuals off GAC surface caused an increase in effluent particles in the size range from 5 to 25 μm.The selectivity for element removal in GAC filters caused an increasing proportion of metallic elements in the effluent particles.The distribution of molar ratio indicated a complicated composition for large particles,involving organic and inorganic substances.The organic proportion accounted for 40% of total carbon attached to the particles.Compared with dissolved carbon,there was potential for the formation of trihalomethanes by organic carbon attached to particles,especially for those with size larger than 10 μm.The pure carbon energy spectrum was found only in the GAC effluent and the size distribution of carbon fines was mainly above 10 μm.The larger carbon fines provided more space for bacterial colonization and stronger protection for attached bacteria against disinfection.The residual attached bacteria after chorine disinfection was increased to 10 2-10 3 CFU/mL within 24 hours at 25°C.展开更多
The biological aerated filter (BAF) was used to treat the oil-field produced water. The removal efficiency for oil, COD, BOD and suspended solids (SS) was 76.3%-80.3%, 31.6%-57.9%, 8.6.3%-96.3% and76.4%--82.7%, re...The biological aerated filter (BAF) was used to treat the oil-field produced water. The removal efficiency for oil, COD, BOD and suspended solids (SS) was 76.3%-80.3%, 31.6%-57.9%, 8.6.3%-96.3% and76.4%--82.7%, respectively when the hydraulic loading rates varied from 016m·h^-1 to 1.4m·h^-1. The greatest partof removal, for example more than 80% of COD removal, occurred on the top 100cm of the media in BAF. The kinetic .performance of BAF indicated that the relationship of BOD removal efficiency with the hydraulic loadingrates, in biological aerated filters could be described by c1/c1=l-exp(-2.44/L^0.59). This equation could be used topredict the B OD.removal efficiency at different hydraulic loading rates.展开更多
The supercritical water gasification of phenolic wastewater without oxidant was performed to degrade pollutants and produce hydrogen-enriched gases. The simulated o-cresol wastewater was gasified at 440-650℃ and 27.6...The supercritical water gasification of phenolic wastewater without oxidant was performed to degrade pollutants and produce hydrogen-enriched gases. The simulated o-cresol wastewater was gasified at 440-650℃ and 27.6 MPa in a continuous Inconel 625 reactor with the residence time of 0.42-1.25 min. The influence of the reaction temperature, residence time, pressure, catalyst, oxidant and the pollutant concentration on the gasification efficiency was investigated. Higher temperature and longer residence time enhanced the o-cresol gasification. The TOC removal rate and hydrogen gasification rate were 90.6% and 194.6%, respectively, at the temperature of 650℃ and the residence time of 0.83 min. The product gas was mainly composed of H2, CO2, CFL and CO, among which the total molar percentage of H2 and CFL was higher than 50%. The gasification efficiency decreased with the pollutant concentration increasing. Both the catalyst and oxidant could accelerate the hydrocarbon gasification at a lower reaction temperature, in which the catalyst promoted H2 production and the oxidant enhanced CO2 generation. The intermediates of liquid effluents were analyzed and phenol was found to be the main composition. The results indicate that the supercritical gasification is a promising way for the treatment of hazardous organic wastewater.展开更多
The emission of microplastics into nature poses a threat to aquatic and terrestrial ecosystems. Their penetration of the food chain presents a danger to human health as well. Wastewater treatment plants can be seen as...The emission of microplastics into nature poses a threat to aquatic and terrestrial ecosystems. Their penetration of the food chain presents a danger to human health as well. Wastewater treatment plants can be seen as the last barrier between microplastics and the environment. This review focuses on the impact of waste treatment plants in retaining microplastics. Studies show that no wastewater treatment method leads to a complete retention of microplastics, and so wastewater treatment plants themselves are viewed as point sources for the discharge of microplastics into the aquatic environment. Problems associated with the utilization of microplastic loaded sewage sludge are also discussed in the review.展开更多
A pilot-scale study of advanced drinking water treatment was carried out in test site, and a combination of ozonation, granular activated carbon (GAC) and nanofiltration was employed as the experimental process. By op...A pilot-scale study of advanced drinking water treatment was carried out in test site, and a combination of ozonation, granular activated carbon (GAC) and nanofiltration was employed as the experimental process. By optimizing the operational parameters of ozonation and GAC, a large quantity of micro-pollutants in drinking water was removed, which made the post-positioned nanofiltration operate more reliably. It was evident that nanofiltration shows good performance for removing residual organic matter, meantime partial minerals can also be retained by nanofiltration. Therefore the quality of drinking water can be further improved. In addition, NF membrane fouling and scaling can be solved by concentrate recycling, anti-scalant dosing and chemical rinsing effectively. By GAC adsorption for the residue chlorine and ozone self-decomposition, their oxidation on NF membrane material can be eliminated completely.展开更多
The quantitative change and size distribution of particles in the effluents from a sand filter and a granular activated carbon (GAC) filter in a drinking water treatment plant were investigated. The average total co...The quantitative change and size distribution of particles in the effluents from a sand filter and a granular activated carbon (GAC) filter in a drinking water treatment plant were investigated. The average total concentration of particles in the sand filter effluent during a filter cycle was 148 particles/mL, 27 of which were larger than 2 μm in size. The concentration in the GAC effluent (561 particles/mL) was significantly greater than that in the sand filter effluent. The concentration of particles larger than 2 μm in the GAC filter effluent reached 201 particles/mL, with the amount of particles with sizes between 2 μm and 15 μm increasing. The most probable number (MPN) of carbon fines reached 43 unit/L after six hours and fines between 0.45 μm and 8.0 μm accounted for more than 50%. The total concentration of outflowing bacteria in the GAC filter effluent, 350 CFU (colony-forming units) /mL, was greater than that in the sand filter effluent, 210 CFU/mL. The desorbed bacteria concentration reached an average of 310 CFU/mg fines. The disinfection efficiency of desorbed bacteria was lower than 40% with 1.5 mg/L of chlorine. The disinfection effect showed that the inactivation rate with 2.0 mg/L of chloramine (90%) was higher than that with chlorine (70%). Experimental results indicated that the high particle concentration in raw water and sedimentation effluent led to high levels of outflowing particles in the sand filter effluent. The activated carbon fines in the effluent accounted for a small proportion of the total particle amount, but the existing bacteria attached to carbon fines may influence the drinking water safety. The disinfection efficiency of desorbed bacteria was lower than that of free bacteria with chlorine, and the disinfection effect on bacteria attached to carbon fines with chloramine was better than that with only chlorine.展开更多
The coagulation process is one of the most important stages in water treatment plant, which involves many complex physical and chemical phenomena. Moreover, coagulant dosing rate is non-linearly correlated to raw wate...The coagulation process is one of the most important stages in water treatment plant, which involves many complex physical and chemical phenomena. Moreover, coagulant dosing rate is non-linearly correlated to raw water characteristics such as turbidity, conductivity, PH, temperature, etc. As such, coagulation reaction is hard or even impossible to control satisfactorily by conventional methods. Based on neural network and rule models, an expert system for determining the optimum chemical dosage rate is developed and used in a water treatment work, and the results of actual runs show that in the condition of satisfying the demand of drinking water quality, the usage of coagulant is lowered.展开更多
In order to remove the low turbidity present in surface water, a novel metal-polysilicate coagulant was used to treat the raw water taken from Tanjiang River in Guangdong Province. This study on the effects of Al/Fe ...In order to remove the low turbidity present in surface water, a novel metal-polysilicate coagulant was used to treat the raw water taken from Tanjiang River in Guangdong Province. This study on the effects of Al/Fe molar ratio on the performance of a complex compound formed by polysilicic acid, aluminium and ferric salt (PAFS) showed that PAFS with Al/Fe ratio of 10:3 seemed to have the best coagulation performance in removing turbidity and color. Experimental results showed that under the conditions of polymerization time of 15 d, sedimentation time of 12 min, and pH of 6?8, PAFS with Al/Fe molar ratio of 10:3 had the best coagulation efficiency and lowest residual Al concentration. The turbid- ity decreased from 23.8 NTU to 3.23 NTU and the residual Al concentration was only 0.165 mg/L in the product water. It could be speculated that colloidal impurities and particulate Al were removed by adsorption bridging and electrical neu- tralization of long chain inorganic polymer coagulants.展开更多
Large quantities of sludge are produced during water treatment processes. Recently, sludge has been treated as waste and disposed of in landfills, which increases the environmental burdens and the operational cost. Th...Large quantities of sludge are produced during water treatment processes. Recently, sludge has been treated as waste and disposed of in landfills, which increases the environmental burdens and the operational cost. Therefore, sludge reuse has become a significant environmental issue. In this study, adsorption of copper ions (Cu^2+) onto calcined sludge was investigated under various operational conditions (with varying temperature, Cu^2+ initial concentration, pH, and sludge dosage). The prepared sludge material was characterized with transmission electron microscopy (TEM), X-ray diffraction (XRD), dynamic light scattering (DLS), and Brunauer-Emmett-Teller (BET) surface area. The sorption capacity of sludge was directly proportional to the initial Cu^2+ concentration and inversely proportional to the sludge dosage. The optimum operational pH and solution temperature were 6.6 and 80℃, respectively. The experimental results followed a Langmuir isotherm and pseudo-first-order adsorption kinetics. Thermodynamic parameters such as activation energy, change in free energy, enthalpy, and entropy were calculated. Thermodynamic analyses indicated that the sorption of copper ions onto the calcined sludge was driven by a physical adsorption process. The prepared sludge was proven to be an excellent adsorbent material for the removal of Cu^2+ from an aqueous solution under optimum conditions.展开更多
文摘The primary objective of this study was to design and size a sustainable sanitation solution for the Ndiebene Gandiol 1 school located in the eponymous commune in northern Senegal. Field investigations led to the collection of wastewater samples. Their analysis revealed specific pollutant loads, including loads of BOD5 3.6966 kgO<sub>2</sub>/day and COD of 12.8775 kgO<sub>2</sub>/day, which were central to the design phase. Following a rigorous assessment of the existing sanitation infrastructure, constructed wetland (CWs) emerged as the most appropriate ecological solution. This system, valued for its ability to effectively remove contaminants, was tailored to the specific needs of the site. Consequently, the final design of the filter extends over 217.16 m<sup>2</sup>, divided into two cells of 108.58 m<sup>2</sup> each, with dimensions of 12.77 m in length and 8.5 m in width. The depth of the filtering medium is approximately 0.60 m, meeting the standards while ensuring maximized purification. Typha, an indigenous and prolific plant known for its purification abilities, was selected as the filtering agent. Concurrently, non-crushed gravel was chosen for its proven filtration capacity. This study is the result of a combination of scientific rigor and design expertise. It provides a holistic view of sanitation for Ndiebene Gandiol. The technical specifications and dimensions of the constructed wetland filter embody an approach that marries indepth analysis and practical application, all aimed at delivering an effective and long-lasting solution to the local sanitation challenges. By integrating precise scientific data with sanitation design expertise, this study delivers a holistic solution for Ndiebene Gandiol. The detailed dimensions and specifications of the constructed wetland filter reflect a methodology that combines meticulous analysis with practical adaptation, aiming to provide an effective and sustainable response to the challenges of rural and school sanitation in the northern region of Senegal.
基金supported by the National Natural Science Foundation of China(52370041)National Natural Science Foundation of China(21976134 and 21707104)State Key Laboratory of Pollution treatment and Resource Reuse Foundation(NO.PCRRK21001).
文摘To meet the growing emission of water contaminants,the development of new materials that enhance the efficiency of the water treatment system is urgent.Ordered mesoporous materials provide opportunities in environmental processing applications due to their exceptionally high surface areas,large pore sizes,and enough pore volumes.These properties might enhance the performance of materials concerning adsorption/catalysis capability,durability,and stability.In this review,we enumerate the ordered mesoporous materials as adsorbents/catalysts and their modifications in water pollution treatment from the past decade,including heavy metals(Hg^(2+),Pb^(2+),Cd^(2+),Cr^(6+),etc.),toxic anions(nitrate,phosphate,fluoride,etc.),and organic contaminants(organic dyes,antibiotics,etc.).These contributions demonstrate a deep understanding of the synergistic effect between the incorporated framework and homogeneous active centers.Besides,the challenges and perspectives of the future developments of ordered mesoporous materials in wastewater treatment are proposed.This work provides a theoretical basis and complete summary for the application of ordered mesoporous materials in the removal of contaminants from aqueous solutions.
基金supported by the National Natural Science Foundation of China(52321005,52293443,and 52230004)the Shenzhen Science and Technology Program(KQTD20190929172630447)+1 种基金the Shenzhen Key Research Project(GXWD20220817145054002)the Talent Recruitment Project of Guandong(2021QN020106).
文摘The digital twins concept enhances modeling and simulation through the integration of real-time data and feedback.This review elucidates the foundational elements of digital twins,covering their concept,entities,domains,and key technologies.More specifically,we investigate the transformative potential of digital twins for the wastewater treatment engineering sector.Our discussion highlights the application of digital twins to wastewater treatment plants(WWTPs)and sewage networks,hardware(i.e.,facilities and pipes,sensors for water quality and activated sludge,hydrodynamics,and power consumption),and software(i.e.,knowledge-based and data-driven models,mechanistic models,hybrid twins,control methods,and the Internet of Things).Furthermore,two cases are provided,followed by an assessment of current challenges in and perspectives on the application of digital twins in WWTPs.This review serves as an essential primer for wastewater engineers navigating the digital paradigm shift.
文摘This review describes the mechanisms of natural coagulants.It provides a good understanding of the two key processes of coagulation-flocculation:adsorption and charge neutralization,as well as adsorption and bridging.Various factors have influence the coagulation/flocculation process,including the effect of pH,coagulant dosage,coagulant type,temperature,initial turbidity,coagulation speed,flocculation speed,coagulation and flocculation time,settling time,colloidal particles,zeta potential,the effects of humic acids,and extraction density are explained.The bio-coagulants derived from plants are outlined.The impact of organic coagulants on water quality,focusing on their effects on the physicochemical parameters of water,heavy metals removal,and bacteriological water quality,is examined.The methods of extraction and purification of plant-based coagulants,highlighting techniques such as solvent extraction and ultrasonic extraction,are discussed.It also examines the parameters that influence these processes.The methods and principles of purification of coagulating agents,including dialysis,freeze-drying,ion exchange,electrophoresis,filtration,and centrifugation,are listed.Finally,it evaluates the sustainability of natural coagulants,focusing on the environmental,technical,and economic aspects of their use.At the end of this review,the readers should have a comprehensive understanding of the mechanisms,selection,extraction,purification,and sustainability of plant-based natural coagulants in water treatment.
文摘This study presents an assessment of wastewater ecological treatment processes utilizing a horizontal flow bio-reactor at the Ndiebene Gandiol 1 school. It primarily aims to juxtapose the filtration efficacy of two distinct vegetative cells, Vetiver and Typha, in the pursuit of sustainable wastewater management strategies for rural scholastic institutions. A synergistic approach was employed, integrating on-site surveys for site-specific insights and laboratory analyses to quantify the pollutant loads pre- and post-treatment. Our findings indicate that both Vetiver and Typha-infused filter beds significantly reduce most contaminants, with particular success in diminishing chemical oxygen demand (COD) and biological oxygen demand (BOD5). Vetiver was notable for its superior reduction of COD, achieving an average effluent concentration of 74 mg/L, in contrast to Typha’s 155 mg/L. Conversely, Typha excelled in suspended solids removal, registering 1 mg/L against Vetiver’s 3 mg/L. While both systems notably surpassed the target metrics across several indicators, including fecal coliform reduction, our results pinpoint the need for refinement in phosphate remediation. Conclusively, the study underscores the efficacy of both Vetiver and Typha systems in rural wastewater treatment contexts, with their integrative application potentially paving the way for enhanced system robustness and efficiency. The outcomes herein highlight the imperative for continued research to further hone these ecological treatment modalities, especially concerning phosphate elimination.
文摘In Saint-Louis, Senegal, a constructed wetland with horizontal flow reed beds (FHa and FHb) has demonstrated significant efficacy in treating municipal wastewater. Analyzing various treatment stages, the system showed only a slight temperature variation, from an influent average of 26.3°C to an effluent of 24.7°C. Electrical conductivity decreased from 1331 mS/cm to 974.5 mS/cm post-primary treatment, with suspended solids (SS) dramatically reduced from 718.9 mg/L to 5.7 mg/L in the final effluent. Biochemical oxygen demand (BOD5) and chemical oxygen demand (COD) saw a notable decrease, from initial levels of 655.6 mg/L and 1240 mg/L to 2.3 mg/L and 71.3 mg/L, respectively. Nitrogenous compounds (N-TN) and phosphates () also decreased significantly, indicating the system’s nutrient removal capacity. Microbiological analysis revealed a reduction in fecal coliforms from 7.5 Ulog/100ml to 1.8 Ulog/100ml and a complete elimination of helminth eggs. The presence of Phragmites and Typha was instrumental in enhancing these reductions. The system’s compliance with the Senegalese standards for disposal into natural environments, WHO recommendations for unrestricted water reuse in irrigation, and the European legislation for water reuse was established. The effluent quality met the stringent criteria for various classes of agricultural reuse, illustrating the system’s potential for sustainable water management. This wetland model presents a robust solution for water-stressed regions, ensuring environmental protection while supporting agricultural needs. The study calls for ongoing research to further refine the system for optimal, reliable wastewater treatment and water resource sustainability.
文摘This paper researched a promising biological treatment of methyl violet waste water by methods of activated sludge.Effects of temperature and pH were studied on this process.Kinetic equation of the substrate biodegradation was investigated in the experimental range.It was studied and simulated that flow within the bubble region of this bioreactor according to the κ ε two fluid equation.Simulation results agree well with experimental data.
基金Supported by Sichuan Provincial International S&T Cooperation Program(No.2008HH0012)Cooperation Research Program of Sichuan University and Hitachi Company(No.07H372)~~
文摘[Objective] The aim was to research the influences of different formulations on oxidation resistance of PVDF hollow fiber membrane.[Method]The immersion precipitation phase inversion method was employed to make casting solution with different formulations into hollow fiber membrane.The membrane was immersed in 1% NaClO solution for testing its performance changes.[Result]The membrane made by materials with bigger molecular weight had better oxidation resistance performance;the surfactant tween-80 could increase water flux,but lead to lower rupture intension;Pore-forming agent PEG400 do better than PVP in the oxidation resistance of membrane.[Conclusion]This study will provide a good idea for the development of the PVDF membrane with high oxidation resistance.
文摘The emulsion stability of oilfield produced water is related to the oil-water interfacial film strength and the zeta potential of the oil droplets. We investigated the effects of water treatment agents (corrosion inhibitor SL-2, scale inhibitor HEDP, germicide 1227, and flocculant polyaluminium chloride PAC) on the stability of oilfield produced water. The influence of these treatment agents on oil-water interfacial properties and the mechanism of these agents acting on the oilfield produced water were studied by measuring the interfacial shear viscosity, interfacial tension and zeta electric potential. The results indicated that the scale inhibitor HEDP could increase the oil-water interfacial film strength, and it could also increase the absolute value of the zeta potential of oil droplets. HEDP played an important role in the stability of the emulsion. Polyaluminum chloride (PAC) reduced the stability of the emulsion by considerably decreasing the absolute value of the zeta potential of oil droplets. Corrosion inhibitor SL-2 and germicide 1227 could decrease the oil-water interfacial tension, whereas they had little influence on oil-water interfacial shear viscosity and oil-water interfacial electricity properties.
文摘Nowadays, intensive breeding of poultry and livestock of large scale has made the treatment of its waste and wastewater an urgent environmental issue, which motivated this study. A wetland of 688 mz was constructed on an egg duck farm, and water hyacinth (Eichhornia crassipes) was chosen as an aquatic plant for the wetland and used as food for duck production. The objectives of this study were to test the role of water hyacinth in purifying nutrient-rich wastewater and its effects on the ducks' feed intake, egg laying performance and egg quality. This paper shows that the constructed wetland removed as much as 64.44% of chemical oxygen demand (COD), 21.78% of total nitrogen (TN) and 23.02% of total phosphorus (TP). Both dissolved oxygen (DO) and the transparency of the wastewater were remarkably improved, with its transparency 2.5 times higher than that of the untreated wastewater. After the ducks were fed with water hyacinth, the average daily feed intake and the egg-laying ratio in the test group were 5.86% and 9.79% higher, respectively, than in the control group; the differences were both significant at the 0.01 probability level. The egg weight in the test group was 2.36% higher than in the control group (P 〈 0.05), but the feed conversion ratios were almost the same. The eggshell thickness and strength were among the egg qualities significantly increased in ducks fed with water hyacinth. We concluded that a water hyacinth system was effective for purifying wastewater from an intensive duck farm during the water hyacinth growing season, as harvested water hyacinth had an excellent performance as duck feed. We also discussed the limitations of the experiment.
基金the National High Technology Research and Development Program of China (863 Program)(No.2002AA601013).
文摘The efficiencies of two types of constructed wetlands for the treatment of low-concentration polluted eutrophic land- scape river water were studied in the western section of the Qingyuan River at the Minhang campus of Shanghai Jiaotong University.The first wetland was a single-stage system using gravel as a filtration medium,and the second was a three- stage system filled with combinations of gravel,zeolite,and fly ash.Results from parallel operations of the wetlands showed that the three-stage constructed wetland could remove organics,nitrogen, and phosphorus successfully.At the same time,it could also decrease ammoniacal odour in the effluent.Compared to the single-stage constructed wetland,it had better nutrient removal efficiencies with a higher removal of 19.37%-65.27% for total phosphorus (TP) and 21.56%- 62.94% for total nitrogen (TN),respectively,during the operation period of 14 weeks.In terms of removal of chemical oxygen demand (COD), turbidity,and blue-green algae,these two wetland systems had equivalent performances.It was also found that in the western section of the test river,in which the two constructed wetlands were located, the water quality was much better than that in the eastern and middle sections without constructed wetland because COD,TN, and TP were all in a relatively lower level and the eutrophication could be prevented completely in the western section.
基金supported by the National Natural Science Foundation of China (No. 50778062)the Hi-Tech Research and Development Program (863) of China (No.2006AA06Z311)
文摘The elemental composition and bacteria attached in particles were investigated during granular activated carbon (GAC) filtration.The experimental results showed that trapped influent particles could form new,larger particles on GAC surface.The sloughing of individuals off GAC surface caused an increase in effluent particles in the size range from 5 to 25 μm.The selectivity for element removal in GAC filters caused an increasing proportion of metallic elements in the effluent particles.The distribution of molar ratio indicated a complicated composition for large particles,involving organic and inorganic substances.The organic proportion accounted for 40% of total carbon attached to the particles.Compared with dissolved carbon,there was potential for the formation of trihalomethanes by organic carbon attached to particles,especially for those with size larger than 10 μm.The pure carbon energy spectrum was found only in the GAC effluent and the size distribution of carbon fines was mainly above 10 μm.The larger carbon fines provided more space for bacterial colonization and stronger protection for attached bacteria against disinfection.The residual attached bacteria after chorine disinfection was increased to 10 2-10 3 CFU/mL within 24 hours at 25°C.
基金Supported by the National Natural Science Foundation of China (No.59978020).
文摘The biological aerated filter (BAF) was used to treat the oil-field produced water. The removal efficiency for oil, COD, BOD and suspended solids (SS) was 76.3%-80.3%, 31.6%-57.9%, 8.6.3%-96.3% and76.4%--82.7%, respectively when the hydraulic loading rates varied from 016m·h^-1 to 1.4m·h^-1. The greatest partof removal, for example more than 80% of COD removal, occurred on the top 100cm of the media in BAF. The kinetic .performance of BAF indicated that the relationship of BOD removal efficiency with the hydraulic loadingrates, in biological aerated filters could be described by c1/c1=l-exp(-2.44/L^0.59). This equation could be used topredict the B OD.removal efficiency at different hydraulic loading rates.
文摘The supercritical water gasification of phenolic wastewater without oxidant was performed to degrade pollutants and produce hydrogen-enriched gases. The simulated o-cresol wastewater was gasified at 440-650℃ and 27.6 MPa in a continuous Inconel 625 reactor with the residence time of 0.42-1.25 min. The influence of the reaction temperature, residence time, pressure, catalyst, oxidant and the pollutant concentration on the gasification efficiency was investigated. Higher temperature and longer residence time enhanced the o-cresol gasification. The TOC removal rate and hydrogen gasification rate were 90.6% and 194.6%, respectively, at the temperature of 650℃ and the residence time of 0.83 min. The product gas was mainly composed of H2, CO2, CFL and CO, among which the total molar percentage of H2 and CFL was higher than 50%. The gasification efficiency decreased with the pollutant concentration increasing. Both the catalyst and oxidant could accelerate the hydrocarbon gasification at a lower reaction temperature, in which the catalyst promoted H2 production and the oxidant enhanced CO2 generation. The intermediates of liquid effluents were analyzed and phenol was found to be the main composition. The results indicate that the supercritical gasification is a promising way for the treatment of hazardous organic wastewater.
文摘The emission of microplastics into nature poses a threat to aquatic and terrestrial ecosystems. Their penetration of the food chain presents a danger to human health as well. Wastewater treatment plants can be seen as the last barrier between microplastics and the environment. This review focuses on the impact of waste treatment plants in retaining microplastics. Studies show that no wastewater treatment method leads to a complete retention of microplastics, and so wastewater treatment plants themselves are viewed as point sources for the discharge of microplastics into the aquatic environment. Problems associated with the utilization of microplastic loaded sewage sludge are also discussed in the review.
基金This work is supported by Fok Ying Tung Education Foundation (No. 94004),Shanghai Natural Science Foundation(No.04ZR 14010)and Laboratory of Water Quality Science & Water Environment Recovery Engineering of Beijing.
文摘A pilot-scale study of advanced drinking water treatment was carried out in test site, and a combination of ozonation, granular activated carbon (GAC) and nanofiltration was employed as the experimental process. By optimizing the operational parameters of ozonation and GAC, a large quantity of micro-pollutants in drinking water was removed, which made the post-positioned nanofiltration operate more reliably. It was evident that nanofiltration shows good performance for removing residual organic matter, meantime partial minerals can also be retained by nanofiltration. Therefore the quality of drinking water can be further improved. In addition, NF membrane fouling and scaling can be solved by concentrate recycling, anti-scalant dosing and chemical rinsing effectively. By GAC adsorption for the residue chlorine and ozone self-decomposition, their oxidation on NF membrane material can be eliminated completely.
基金supported by the National Natural Science Foundation of China (Grant No 50638020)the National Key High-Tech Program (863) of China (Grant No 2006AA06Z311)the Natural Science Foundation of Jiangsu Province (Grant No BK2006170)
文摘The quantitative change and size distribution of particles in the effluents from a sand filter and a granular activated carbon (GAC) filter in a drinking water treatment plant were investigated. The average total concentration of particles in the sand filter effluent during a filter cycle was 148 particles/mL, 27 of which were larger than 2 μm in size. The concentration in the GAC effluent (561 particles/mL) was significantly greater than that in the sand filter effluent. The concentration of particles larger than 2 μm in the GAC filter effluent reached 201 particles/mL, with the amount of particles with sizes between 2 μm and 15 μm increasing. The most probable number (MPN) of carbon fines reached 43 unit/L after six hours and fines between 0.45 μm and 8.0 μm accounted for more than 50%. The total concentration of outflowing bacteria in the GAC filter effluent, 350 CFU (colony-forming units) /mL, was greater than that in the sand filter effluent, 210 CFU/mL. The desorbed bacteria concentration reached an average of 310 CFU/mg fines. The disinfection efficiency of desorbed bacteria was lower than 40% with 1.5 mg/L of chlorine. The disinfection effect showed that the inactivation rate with 2.0 mg/L of chloramine (90%) was higher than that with chlorine (70%). Experimental results indicated that the high particle concentration in raw water and sedimentation effluent led to high levels of outflowing particles in the sand filter effluent. The activated carbon fines in the effluent accounted for a small proportion of the total particle amount, but the existing bacteria attached to carbon fines may influence the drinking water safety. The disinfection efficiency of desorbed bacteria was lower than that of free bacteria with chlorine, and the disinfection effect on bacteria attached to carbon fines with chloramine was better than that with only chlorine.
基金This work was supported by the project 863 ofChina(No.863-511092)
文摘The coagulation process is one of the most important stages in water treatment plant, which involves many complex physical and chemical phenomena. Moreover, coagulant dosing rate is non-linearly correlated to raw water characteristics such as turbidity, conductivity, PH, temperature, etc. As such, coagulation reaction is hard or even impossible to control satisfactorily by conventional methods. Based on neural network and rule models, an expert system for determining the optimum chemical dosage rate is developed and used in a water treatment work, and the results of actual runs show that in the condition of satisfying the demand of drinking water quality, the usage of coagulant is lowered.
基金Project (No. E9825) supported by the Natural Science Foundation of Heilongjiang Province,China
文摘In order to remove the low turbidity present in surface water, a novel metal-polysilicate coagulant was used to treat the raw water taken from Tanjiang River in Guangdong Province. This study on the effects of Al/Fe molar ratio on the performance of a complex compound formed by polysilicic acid, aluminium and ferric salt (PAFS) showed that PAFS with Al/Fe ratio of 10:3 seemed to have the best coagulation performance in removing turbidity and color. Experimental results showed that under the conditions of polymerization time of 15 d, sedimentation time of 12 min, and pH of 6?8, PAFS with Al/Fe molar ratio of 10:3 had the best coagulation efficiency and lowest residual Al concentration. The turbid- ity decreased from 23.8 NTU to 3.23 NTU and the residual Al concentration was only 0.165 mg/L in the product water. It could be speculated that colloidal impurities and particulate Al were removed by adsorption bridging and electrical neu- tralization of long chain inorganic polymer coagulants.
文摘Large quantities of sludge are produced during water treatment processes. Recently, sludge has been treated as waste and disposed of in landfills, which increases the environmental burdens and the operational cost. Therefore, sludge reuse has become a significant environmental issue. In this study, adsorption of copper ions (Cu^2+) onto calcined sludge was investigated under various operational conditions (with varying temperature, Cu^2+ initial concentration, pH, and sludge dosage). The prepared sludge material was characterized with transmission electron microscopy (TEM), X-ray diffraction (XRD), dynamic light scattering (DLS), and Brunauer-Emmett-Teller (BET) surface area. The sorption capacity of sludge was directly proportional to the initial Cu^2+ concentration and inversely proportional to the sludge dosage. The optimum operational pH and solution temperature were 6.6 and 80℃, respectively. The experimental results followed a Langmuir isotherm and pseudo-first-order adsorption kinetics. Thermodynamic parameters such as activation energy, change in free energy, enthalpy, and entropy were calculated. Thermodynamic analyses indicated that the sorption of copper ions onto the calcined sludge was driven by a physical adsorption process. The prepared sludge was proven to be an excellent adsorbent material for the removal of Cu^2+ from an aqueous solution under optimum conditions.