A double-layer aluminum consisting of an aluminum core and a shellof SiO2 and polyacrylic acid was synthesized.This modified aluminum was used to improve the corrosion resistance and dispersive property of aluminum in...A double-layer aluminum consisting of an aluminum core and a shellof SiO2 and polyacrylic acid was synthesized.This modified aluminum was used to improve the corrosion resistance and dispersive property of aluminum in waterborne media.TEM,FTIR,XPS,and EDX determination showed that PAA and SiO2 were coated on the surface of aluminum.Evolved hydrogen detection showed that the corrosion resistance of composite particle had been markedly improved.Maximum corrosion inhibition efficiency of SiO2 coated aluminum(SiO2@Al)was 95.1% while that of double-layer coated aluminum(PAA/SiO2@Al)was 98.8%.Meanwhile,polyacrylic acid layer improved the agglomeration of aluminum significantly.According to the dispersibility test,the particle size of 50% volume fraction [d(0.5)] of aluminum,SiO2@Aland PAA/SiO2@Alwere 42,53,and 34 μm,respectively.展开更多
In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt+2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic ...In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt+2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic corrosion behavior of Pt/Ru-modified bond coating exposed to NaCl plus water vapor has been investigated under atmospheric pressure at 1050℃.The result shows that the cyclic corrosion life of Pt/Ru-modified bond coating is longer than that of the conventional Pt-modified aluminide coating in the presence of NaCl plus water vapor.The addition of Ru makes the coating possess the increased strength and suppress the rumpling behavior.The absence of rumpling may be responsible for the improved corrosion resistance of Pt/Ru-modified aluminide coating.展开更多
基金Funded by the National Natural Science Foundation of China(31170558)the Fundamental Research Funds for the Central Universities(410500006)
文摘A double-layer aluminum consisting of an aluminum core and a shellof SiO2 and polyacrylic acid was synthesized.This modified aluminum was used to improve the corrosion resistance and dispersive property of aluminum in waterborne media.TEM,FTIR,XPS,and EDX determination showed that PAA and SiO2 were coated on the surface of aluminum.Evolved hydrogen detection showed that the corrosion resistance of composite particle had been markedly improved.Maximum corrosion inhibition efficiency of SiO2 coated aluminum(SiO2@Al)was 95.1% while that of double-layer coated aluminum(PAA/SiO2@Al)was 98.8%.Meanwhile,polyacrylic acid layer improved the agglomeration of aluminum significantly.According to the dispersibility test,the particle size of 50% volume fraction [d(0.5)] of aluminum,SiO2@Aland PAA/SiO2@Alwere 42,53,and 34 μm,respectively.
基金supported by the Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT)(IRT0512)the Program for New Century Excellent Talents in University(NCET)+1 种基金the National Natural Science Foundation of China(Nos.50671002and50971013)the National Institute for Materials Science (NIMS) internship program
文摘In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt+2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic corrosion behavior of Pt/Ru-modified bond coating exposed to NaCl plus water vapor has been investigated under atmospheric pressure at 1050℃.The result shows that the cyclic corrosion life of Pt/Ru-modified bond coating is longer than that of the conventional Pt-modified aluminide coating in the presence of NaCl plus water vapor.The addition of Ru makes the coating possess the increased strength and suppress the rumpling behavior.The absence of rumpling may be responsible for the improved corrosion resistance of Pt/Ru-modified aluminide coating.