Both the additive and multiplicative models of crop yield and water supply are polynomial equations, and the number of parameters increases linearly when the growing period is specified. However, interactions among mu...Both the additive and multiplicative models of crop yield and water supply are polynomial equations, and the number of parameters increases linearly when the growing period is specified. However, interactions among multiple parameters occasionally lead to unreasonable estimations of certain parameters, which were water sensitivity coefficients but with negative value. Additionally, evapotranspiration must be measured as a model input. To facilitate the application of these models and overcome the aforementioned shortcomings, a simple model with only three parameters was derived in this paper based on certain general quantitative relations of crop yield (Y) and water supply (W). The new model, Y/Y-W*/(W*+w*), fits an S or a saturated curve of crop yield with the cumulative amount of water. Three parameters are related to biological factors: the yield potential (Y*), the water requirement to achieve half of the yield potential (half-yield water requirement, wh), and the water sensitivity coefficient (k). The model was validated with data from 24 maize lines obtained in the present study and 17 maize hybrids published by other authors. The results showed that the model was well fit to the data, and the normal root of the mean square error (NRMSE) values were 2.8 to 17.8% (average 7.2%) for the 24 maize lines and 2.7 to 12.7% (average 7.4%) for the 17 maize varieties. According to the present model, the maize water-sensitive stages in descending order were pollen shedding and silking, tasselling, jointing, initial grain filling, germination, middle grain filling, late grain filling, and end of grain filling. This sequence was consistent with actual observations in the maize field. The present model may be easily used to analyse the water use efficiency and drought tolerance of maize at specific stages.展开更多
Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society.The field of catalysis has been revolutionized by ...Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society.The field of catalysis has been revolutionized by single-atom catalysts(SACs),which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports.Recently,bimetallic SACs(bimSACs)have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports.BimSACs offer an avenue for rich metal–metal and metal–support cooperativity,potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges,substrate activation with reversible redox cycles,simultaneous multi-electron transfer,regulation of spin states,tuning of electronic properties,and cyclic transition states with low activation energies.This review aims to encapsulate the growing advancements in bimSACs,with an emphasis on their pivotal role in hydrogen generation via water splitting.We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs,elucidate their electronic properties,and discuss their local coordination environment.Overall,we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction,the two half-reactions of the water electrolysis process.展开更多
[Objective] This study was to investigate the effects of different irrigation amount on water consumption and water use efficiency of greenhouse cucumber.[Method]Under the condition of drip irrigation with different w...[Objective] This study was to investigate the effects of different irrigation amount on water consumption and water use efficiency of greenhouse cucumber.[Method]Under the condition of drip irrigation with different water amounts in sunlight greenhouse of the arid areas in Ningxia,the soil water was measured and the water consumption of crop was calculated.[Result]When irrigation amount was 563 mm,the water consumption as a whole gradually increased with the delay of growth period,reached peak during the thriving stage of fruit setting,and then gradually declined;in each treatment,the daily water consumption increased with the increasing of irrigation amount during each growth period.However,the consumption of soil moisture reduced with the significant increase of irrigation.563 mm of irrigation amount could meet the water requirements of cucumber and began to add water to soil,and water utilization efficiency could reach 33.4 kg/m3.[Conclusion]The research had provided theoretical basis for water management in the production process of greenhouse cucumber.展开更多
This study aimed to investigate the effects of different irrigation amounts on water consumption and water use efficiency of celery under the condition of drip irrigation, so as to provide a scientific basis for high-...This study aimed to investigate the effects of different irrigation amounts on water consumption and water use efficiency of celery under the condition of drip irrigation, so as to provide a scientific basis for high-yielding, high-quality and highefficiency cultivation and water-saving irrigation of greenhouse celery. Total five irrigation amounts were designed, 117.5 (T1), 160.0 (T2), 202.5 (T3), 245.0 (T4) and 287.5 (CK) mm/hm2, and the effects of different irrigation amounts on yield, water consumption and water use efficiency of celery were studied by plot experiment. The results showed that at the soil depth of 0-40 cm, the soil water storages of different treatments ranked as T3's〉T4's〉CK's〉T2's〉T1's, and the celery water consumptions ranked as CK's〉T4's〉T3's〉T2's〉T1's. At the same time, the soil water storage in different treatment group declined with the growth of celery, and finally increased at the harvest period. Among different irrigation amounts, the water use effi- ciency and irrigation water use efficiency all ranked as T1's〉T2's〉T3's〉T4's〉CK's. The water consumption of celery was positively related to irrigation amount (P〈 0.01), and was negatively related to water use efficiency (P〈0.01) and irrigation water use efficiency (P〈0.05). When the irrigation amount was below 253 mm/hm2, the celery yield was positively related to irrigation amount (P〈0.01). There was also a positive correlation between celery output and irrigation amount. Compared with those of CK, the benefit of the T4 treatment group was equal, and the water consumption was reduced by 14.78%. In high-efficiency solar greenhouse, the irrigation amount of drip-irrigated celery is recommended as 245 mm/hm2.展开更多
Based on the water resource balance,the correlation between both the Liaoning water resource and precipitation and total amount of water resource from 1991 to 2004 was analyzed by assuming Liaoning to be an enclosed r...Based on the water resource balance,the correlation between both the Liaoning water resource and precipitation and total amount of water resource from 1991 to 2004 was analyzed by assuming Liaoning to be an enclosed region.And the calculation methods were developed to quantitatively determine the increase of rainfall due to artificial precipitation,and consequently ascertain the contribution of artificial rainfall amount to water resources.展开更多
[Objective] This study was conducted to investigate the effects of different irrigation amounts on rice leaf physiology and water use efficiency. [Method] The irrigation test with three different treatments was carrie...[Objective] This study was conducted to investigate the effects of different irrigation amounts on rice leaf physiology and water use efficiency. [Method] The irrigation test with three different treatments was carried out in the Agrometeo- rological Experimental Station of Nanjing University of Information Science & Technology. [Reset] Under flood irrigation, the rice leaf temperature was lower than wet irrigation by 0.4-0.7 ℃; when the strength of photosynthetically active radiation was in the range of 800-1 800 gmol/(m^2·s), the average stomatal conductance of rice leaves under flood irrigation was higher than that of the wet irrigation treatment by 0.123-0.183 mol H2O/(m^2·s), and the leaf water use efficiency was higher than that of the wet irrigation treatment by 0.24 g/kg; after 10:00 every day, the water use efficiency under flood irrigation was always higher than that of the wet irrigation treatment; and compared with the wet irrigation treatment, the rice of the flood irrigation treatments had higher leaf water use efficiency, and final yields were also remarkably improved by 5.89%-13.97%. [Conclusion] This study will provide a practical reference basis for field management.展开更多
Available irrigation resources are becoming increasingly scarce in the North China Plain (NCP),and nitrogen-use efficiency of crop production is also relatively low.Thus,it is imperative to improve the water-use effic...Available irrigation resources are becoming increasingly scarce in the North China Plain (NCP),and nitrogen-use efficiency of crop production is also relatively low.Thus,it is imperative to improve the water-use efficiency (WUE) and nitrogen fertilizer productivity on the NCP.Here,we conducted a two-year field experiment to explore the effects of different irrigation amounts (S60,60 mm;S90,90 mm;S120,120 mm;S150,150 mm) and nitrogen application rates (150,195 and 240 kg ha^(–1);denoted as N1,N2 and N3,respectively) under micro-sprinkling with water and nitrogen combined on the grain yield(GY),yield components,leaf area index (LAI),flag leaf chlorophyll content,dry matter accumulation (DM),WUE,and nitrogen partial factor productivity (NPFP).The results indicated that the GY and NPFP increased significantly with increasing irrigation amount,but there was no significant difference between S120 and S150;WUE significantly increased first but then decreased with increasing irrigation and S120 achieved the highest WUE.The increase in nitrogen was beneficial to improving the GY and WUE in S60 and S90,while the excessive nitrogen application (N3) significantly reduced the GY and WUE in S120 and S150 compared with those in the N2 treatment.The NPFP significantly decreased with increasing nitrogen rate under the same irrigation treatments.The synchronous increase in spike number (SN) and 1 000-grain weight (TWG)was the main reason for the large increase in GY by micro-sprinkling with increasing irrigation,and the differences in SN and TGW between S120 and S150 were small.Under S60 and S90,the TGW increased with increasing nitrogen application,which enhanced the GY,while N2 achieved the highest TWG in S120 and S150.At the filling stage,the LAI increased with increasing irrigation,and greater amounts of irrigation significantly increased the chlorophyll content in the flag leaf,which was instrumental in increasing DM after anthesis and increasing the TGW.Micro-sprinkling with increased amounts of irrigation or excessive nitrogen application decreased the WUE mainly due to the increase in total water consumption (ET)and the small increase or decrease in GY.Moreover,the increase in irrigation increased the total nitrogen accumulation or contents (TNC) of plants at maturity and reduced the residual nitrate-nitrogen in the soil (SNC),which was conducive to the increase in NPFP,but there was no significant difference in TNC between S120 and S150.Under the same irrigation treatments,an increase in nitrogen application significantly increased the residual SNC and decreased the NPFP.Overall,micro-sprinkling with 120 mm of irrigation and a total nitrogen application of 195 kg ha^(–1) can lead to increases in GY,WUE and NPFP on the NCP.展开更多
Different mesoporous activated carbons were prepared by both chemical and physical activation processes and were examined for methane uptake in the presence of water.Methane isotherms were obtained at wet condition by...Different mesoporous activated carbons were prepared by both chemical and physical activation processes and were examined for methane uptake in the presence of water.Methane isotherms were obtained at wet condition by wetting samples with water at mass ratio of water/carbon(R) close to 1.0.To compare,the amount of methane storage were also measured at dry situation.The maximum amount of methane stored was attained as 237 V/V at R=1.0 by hydrate formation at the methane critical pressure.In the next step,mass ratios of water/carbon were changed to investigate various amount of water for methane storage enhancement.Two other values of mass ratio of water/carbon(R=0.8 and 1.4) were selected and methane isotherms were obtained at the same conditions.Maximum values of 210 and 248 V/V were reached for methane storage,respectively.It was also observed that,in the pressure range lower than hydrate pressure,by increasing water ratio the hydrate formation pressure was decreased and methane uptake was much less than that of dry condition due to pore filling by water.展开更多
A novel approach was developed for the determination of ultratrace amounts of copper in water samples by using electrothermal atomic absorption spectrometry (ETAAS) after cloud point extraction ( CPE ). 1-( 2-Pyr...A novel approach was developed for the determination of ultratrace amounts of copper in water samples by using electrothermal atomic absorption spectrometry (ETAAS) after cloud point extraction ( CPE ). 1-( 2-Pyridylazo ) -2- naphthol was used as the chelating reagent and Triton X-114 as the mieellar-forming surfactant. CPE was conducted in a pH 8. 0 medium at 40 ℃ for 10 rain. After the separation of the phases by contrifugafion, the surfactant-rieh phase was diluted with 1 mL of a methanol solution of 0. 1 mol/L HNO3. Then 20μL of the diluted surfactant-rieh phase was injected into the graphite furnace for atomization in the absence of any matrix modifier. Various experimental conditions that affect the extraction and atomization processes were optimized. A detection limit of 5 ng/L was obtained after preconeentration. The linear dynamic range of the copper mass concentration was found to be 0-2.0 ng/mL, and the relative standard deviation was found to be less than 3. 1% for a sample containing 1.0 ng/mL Cu ( Ⅱ ). This developed method was successfully applied to the determination of uhratraee amounts of Cu in drinking water, tap water, and seawater samples.展开更多
The dynamics of water and salt in soil were monitored in the 2010 and 2011 growing seasons of cotton to evaluate the salinity risk of soil under drip irrigation in arid environments for different management practices ...The dynamics of water and salt in soil were monitored in the 2010 and 2011 growing seasons of cotton to evaluate the salinity risk of soil under drip irrigation in arid environments for different management practices of drip system uniformity and irrigation amount. In the experiments, three Christiansen uniformity coefficients (CU) of approximately 65, 80, and 95% (referred to as low, medium, and high uniformity, respectively) and three irrigation amounts of 50, 75, and 100% of full irrigation were used. The distribution of the soil water content and bulk electrical conductivity (ECb) was monitored continuously with approximately equally spaced frequency domain reflectometry (FDR) sensors located along a dripline. Gravimetric samples of soil were collected regularly to determine the distribution of soil salinity. A great fluctuation in CU of water content and ECb at 60 cm depth was observed for the low uniformity treatment during the irrigation season, while a relatively stable variation pattern was observed for the high uniformity treatment. The ECb CU was substantially lower than the water content CU and its value was greatly related to the water content CU and the initial ECb CU. The spatial variation of seasonal mean soil water content and seasonal mean soil bulk electrical conductivity showed a high dependence on the variation pattern of emitter discharge rate along a dripline for the low and medium uniformity treatments. A greater irrigation amount produced a significantly lower soil salinity at the end of the irrigation season, while the influence of the system uniformity on the soil salinity was insignificant at a probability level of 0.1. In arid regions, the determination of the target drip irrigation system uniformity should consider the potential salinity risk of soil caused by nonuniform water application as the influence of the system uniformity on the distribution of the soil salinity was progressively strengthened during the growing season of crop.展开更多
An investigation was carried out in the Y3 seamount area of the Western Pacific Ocean in December 2014,and the distribution of dissolved inorganic carbon(DIC)and its relationship with environmental factors in this are...An investigation was carried out in the Y3 seamount area of the Western Pacific Ocean in December 2014,and the distribution of dissolved inorganic carbon(DIC)and its relationship with environmental factors in this area were explored.The results show that DIC concentration was higher in the adjacent waters of the Y3 seamount area,and the uplift of DIC isolines at the stations was close to the seamount.Meanwhile,interaction between the North Equatorial Current(NEC)and the Y3 seamount affected the DIC distribution,i.e.,the upwelling in the same direction of the NEC was obvious,resulting in a decreasing trend of average concentration of DIC in the 200 m water column from the top to the two sides in this direction but in the cross direction.The DIC concentration increased with the water depth increase,and its distribution was affected by various environmental factors.In the surface water,high temperature was a decisive factor for the decrease of the DIC concentration,but the photosynthesis of phytoplankton showing only a weak influence.In the North Pacific Tropic Water(NPTW),DIC production rate from organic matter decomposition was higher than that of DIC consumption by phytoplankton photosynthesis,leading to a continual increase of DIC.In the North Pacific Intermediate Water(NPIW),organic matter decomposition played a leading role in the increase of DIC.In the deep water,decomposition of organic matter weakened,and the dissolution of CaCO3 controlled the carbonate system,and DIC had the smallest variation range.展开更多
A propagation experiment was conducted in the South China Sea in 2014 with a flat bottom and seamounts respectively by using explosive sources. The effects of seamounts on sound propagation are analyzed by using the b...A propagation experiment was conducted in the South China Sea in 2014 with a flat bottom and seamounts respectively by using explosive sources. The effects of seamounts on sound propagation are analyzed by using the broadband signals. It is observed that the transmission loss (TL) decreases up to 7 dB for the signals in the first shadow zone due to the seamount reflection. Moreover, the TL might increase more than 30 dB in the converge zone due to the shadowing by seamounts. Abnormal TLs and pulse arrival structures at different ranges are explained by using the ray and wave theory. The experimental TLs and arrival pulses are compared with the numerical results and found to be in good agreement.展开更多
A novel luminescent coordination compound Eu(TTA)3(DEDAF)(1, TTA = 1,1,1-trifluoro-3-(2-thenoyl)acetone, DEDAF = 9,9-diethyl-4,5-diazafluoren) has been synthesized and fully characterized by infrared spectrum,...A novel luminescent coordination compound Eu(TTA)3(DEDAF)(1, TTA = 1,1,1-trifluoro-3-(2-thenoyl)acetone, DEDAF = 9,9-diethyl-4,5-diazafluoren) has been synthesized and fully characterized by infrared spectrum, elemental analysis, UV-vis spectrum, etc. X-ray single-crystal diffraction analysis reveals that compound 1 shows a mononuclear structure with the europium atom in coordinating to one DAF and three TTA ligands. The mononuclear structure units are assembled into a 3-D polymer by hydrogen bonds and π-π interactions. Photoluminescent property of 1 was investigated in detail at room temperature. Complex 1 emits strong red luminescence. However, it could be quenched even by small amount of water. The fluorescence intensity at 614 nm decreases linearly with the water content increasing(vol% in acetonitrile) in the range of 0.025~0.2% under 278 nm excitation. Thermogravimetric analysis has also been studied, which demonstrates good thermal stability of 1.展开更多
Kuwait has recently implemented a vigorous campaign that aims to reclaim and reuse all treated wastewater in an at- tempt to alleviate water scarcity problem and to preserve seawater quality. This paper assesses the p...Kuwait has recently implemented a vigorous campaign that aims to reclaim and reuse all treated wastewater in an at- tempt to alleviate water scarcity problem and to preserve seawater quality. This paper assesses the present status of wastewater treatment, reclamation and reuse in Kuwait, and discusses the impact of wastewater reuse on the amounts of pollutants discharged into the sea. Through analysis of the historical records of the wastewater treatment plants, it has been found that reuse of reclaimed wastewater in Kuwait has greatly reduced the amounts of pollutants discharged into the sea. Results showed that more than 50% reduction in volumes of wastewater discharged into the sea had been achieved from year 2000 to year 2010. However, this study has predicted that the amounts of wastewater discharged into the sea will start increasing again by the year 2020 due to shortages of storage capacity for reclaimed wastewater and due to the limitation of wastewater reuse applications to basically agricultural and landscape irrigations. In contrary, the on-going works and future plans of the Ministry of Public Works (MPW) are expected to overcome this problem and lead to a zero discharge of wastewater into the sea.展开更多
The upstream water catchments are the main source providing sediments in rivers and sedimentary basins. The balance between the erosion phenomenon and the amount of sediment entering into the basin relies on the geome...The upstream water catchments are the main source providing sediments in rivers and sedimentary basins. The balance between the erosion phenomenon and the amount of sediment entering into the basin relies on the geometrical specifications and the morphology of the river along the water catchment direction and the amount and type of the sediments. The sedimentary feed of rivers and basins are changed for the sake of natural factors or human disturbances. The river and basin react against this change in that their shape, morphology, plan and profile get changed due to the increase or decrease of the input sediment into the basin. It is essential to know the sediment amount produced by erodability and sedimentation of upstream basins and effects of projects and also to evaluate the amount of sedimentary load in base studies, civil projects, optimizing rivers and dam construction studies specially calculating the amount of sediment amount entering into the dams’ reservoirs in order to take engineering decisions and related alternatives. Sediment Weight Model and PSIAC Experimental Model are recognized as two common methods calculating the amount of the produced sediment caused by erosion applied in this research. Holistically, these methods have been used and compared. Although the results are almost close to one another, more sediment load has been produced in PSIAC method. As more affective parameters are used to cause erosion and produce sediment in PSIAC experimental model, it is recommended to refer to the results of this method because they are closer to reality.展开更多
The development of modern agriculture requires the reduction of water and chemical N fertilizer inputs.Increasing the planting density can maintain higher yields,but also consumes more of these restrictive resources.H...The development of modern agriculture requires the reduction of water and chemical N fertilizer inputs.Increasing the planting density can maintain higher yields,but also consumes more of these restrictive resources.However,whether an increased maize density can compensate for the negative effects of reduced water and N supply on grain yield and N uptake in the arid irrigated areas remains unknown.This study is part of a long-term positioning trial that started in 2016.A split-split plot field experiment of maize was implemented in the arid irrigated area of northwestern China in 2020 to 2021.The treatments included two irrigation levels:local conventional irrigation reduced by 20%(W1,3,240 m^(3)ha^(-1))and local conventional irrigation(W2,4,050 m^(3)ha^(-1));two N application rates:local conventional N reduced by 25%(N1,270 kg ha^(-1))and local conventional N(360 kg ha^(-1));and three planting densities:local conventional density(D1,75,000 plants ha^(-1)),density increased by 30%(D2,97,500 plants ha-1),and density increased by 60%(D3,120,000 plants ha^(-1)).Our results showed that the grain yield and aboveground N accumulation of maize were lower under the reduced water and N inputs,but increasing the maize density by 30% can compensate for the reductions of grain yield and aboveground N accumulation caused by the reduced water and N supply.When water was reduced while the N application rate remained unchanged,increasing the planting density by 30% enhanced grain yield by 13.9% and aboveground N accumulation by 15.3%.Under reduced water and N inputs,increasing the maize density by 30% enhanced N uptake efficiency and N partial factor productivity,and it also compensated for the N harvest index and N metabolic related enzyme activities.Compared with W2N2D1,the N uptake efficiency and N partial factor productivity increased by 28.6 and 17.6%under W1N1D2.W1N2D2 had 8.4% higher N uptake efficiency and 13.9% higher N partial factor productivity than W2N2D1.W1N2D2 improved urease activity and nitrate reductase activity by 5.4% at the R2(blister)stage and 19.6% at the V6(6th leaf)stage,and increased net income and the benefit:cost ratio by 22.1 and 16.7%,respectively.W1N1D2 and W1N2D2 reduced the nitrate nitrogen and ammoniacal nitrogen contents at the R6 stage in the 40-100 cm soil layer,compared with W2N2D1.In summary,increasing the planting density by 30% can compensate for the loss of grain yield and aboveground N accumulation under reduced water and N inputs.Meanwhile,increasing the maize density by 30% improved grain yield and aboveground N accumulation when water was reduced by 20% while the N application rate remained constant in arid irrigation areas.展开更多
Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon emissions.Among water electrolysis technologies,t...Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon emissions.Among water electrolysis technologies,the anion exchange membrane(AEM) water electrolysis has gained intensive attention and is considered as the next-generation emerging technology due to its potential advantages,such as the use of low-cost non-noble metal catalysts,the relatively mature stack assembly process,etc.However,the AEM water electrolyzer is still in the early development stage of the kW-level stack,which is mainly attributed to severe performance decay caused by the core component,i.e.,AEM.Here,the review comprehensively presents the recent progress of advanced AEM from the view of the performance of water electrolysis cells.Herein,fundamental principles and critical components of AEM water electrolyzers are introduced,and work conditions of AEM water electrolyzers and AEM performance improvement strategies are discussed.The challenges and perspectives are also analyzed.展开更多
Conversion of solar energy into H_(2) by photoelectrochemical(PEC)water splitting is recognized as an ideal way to address the growing energy crisis and environmental issues.In a typical PEC cell,the construction of p...Conversion of solar energy into H_(2) by photoelectrochemical(PEC)water splitting is recognized as an ideal way to address the growing energy crisis and environmental issues.In a typical PEC cell,the construction of photoanodes is crucial to guarantee the high efficiency and stability of PEC reactions,which fundamentally rely on rationally designed semiconductors(as the active materials)and substrates(as the current collectors).In this review work,we start with a brief introduction of the roles of substrates in the PEC process.Then,we provide a systematic overview of representative strategies for the controlled fabrication of photoanodes on rationally designed substrates,including conductive glass,metal,sapphire,silicon,silicon carbide,and flexible substrates.Finally,some prospects concerning the challenges and research directions in this area are proposed.展开更多
Due to the dissimilarity among different producing layers,the influences of inter-layer interference on the production performance of a multi-layer gas reservoir are possible.However,systematic studies of inter-layer ...Due to the dissimilarity among different producing layers,the influences of inter-layer interference on the production performance of a multi-layer gas reservoir are possible.However,systematic studies of inter-layer interference for tight gas reservoirs are really limited,especially for those reservoirs in the presence of water.In this work,five types of possible inter-layer interferences,including both absence and presence of water,are identified for commingled production of tight gas reservoirs.Subsequently,a series of reservoir-scale and pore-scale numerical simulations are conducted to quantify the degree of influence of each type of interference.Consistent field evidence from the Yan'an tight gas reservoir(Ordos Basin,China)is found to support the simulation results.Additionally,suggestions are proposed to mitigate the potential inter-layer interferences.The results indicate that,in the absence of water,commingled production is favorable in two situations:when there is a difference in physical properties and when there is a difference in the pressure system of each layer.For reservoirs with a multi-pressure system,the backflow phenomenon,which significantly influences the production performance,only occurs under extreme conditions(such as very low production rates or well shut-in periods).When water is introduced into the multi-layer system,inter-layer interference becomes nearly inevitable.Perforating both the gas-rich layer and water-rich layer for commingled production is not desirable,as it can trigger water invasion from the water-rich layer into the gas-rich layer.The gas-rich layer might also be interfered with by water from the neighboring unperforated water-rich layer,where the water might break the barrier(eg weak joint surface,cement in fractures)between the two layers and migrate into the gas-rich layer.Additionally,the gas-rich layer could possibly be interfered with by water that accumulates at the bottom of the wellbore due to gravitational differentiation during shut-in operations.展开更多
Continuous efforts are underway to reduce carbon emissions worldwide in response to global climate change.Water electrolysis technology,in conjunction with renewable energy,is considered the most feasible hydrogen pro...Continuous efforts are underway to reduce carbon emissions worldwide in response to global climate change.Water electrolysis technology,in conjunction with renewable energy,is considered the most feasible hydrogen production technology based on the viable possibility of large-scale hydrogen production and the zero-carbon-emission nature of the process.However,for hydrogen produced via water electrolysis systems to be utilized in various fields in practice,the unit cost of hydrogen production must be reduced to$1/kg H_(2).To achieve this unit cost,technical targets for water electrolysis have been suggested regarding components in the system.In this paper,the types of water electrolysis systems and the limitations of water electrolysis system components are explained.We suggest guideline with recent trend for achieving this technical target and insights for the potential utilization of water electrolysis technology.展开更多
基金supported by grants provided by the National Sci-Tech Key Program of Development of Transgenic Animals and Plants,Ministry of Science and Technology,China(2014ZX08003-004)
文摘Both the additive and multiplicative models of crop yield and water supply are polynomial equations, and the number of parameters increases linearly when the growing period is specified. However, interactions among multiple parameters occasionally lead to unreasonable estimations of certain parameters, which were water sensitivity coefficients but with negative value. Additionally, evapotranspiration must be measured as a model input. To facilitate the application of these models and overcome the aforementioned shortcomings, a simple model with only three parameters was derived in this paper based on certain general quantitative relations of crop yield (Y) and water supply (W). The new model, Y/Y-W*/(W*+w*), fits an S or a saturated curve of crop yield with the cumulative amount of water. Three parameters are related to biological factors: the yield potential (Y*), the water requirement to achieve half of the yield potential (half-yield water requirement, wh), and the water sensitivity coefficient (k). The model was validated with data from 24 maize lines obtained in the present study and 17 maize hybrids published by other authors. The results showed that the model was well fit to the data, and the normal root of the mean square error (NRMSE) values were 2.8 to 17.8% (average 7.2%) for the 24 maize lines and 2.7 to 12.7% (average 7.4%) for the 17 maize varieties. According to the present model, the maize water-sensitive stages in descending order were pollen shedding and silking, tasselling, jointing, initial grain filling, germination, middle grain filling, late grain filling, and end of grain filling. This sequence was consistent with actual observations in the maize field. The present model may be easily used to analyse the water use efficiency and drought tolerance of maize at specific stages.
基金support from the Czech Science Foundation,project EXPRO,No 19-27454Xsupport by the European Union under the REFRESH—Research Excellence For Region Sustainability and High-tech Industries project number CZ.10.03.01/00/22_003/0000048 via the Operational Programme Just Transition from the Ministry of the Environment of the Czech Republic+1 种基金Horizon Europe project EIC Pathfinder Open 2023,“GlaS-A-Fuels”(No.101130717)supported from ERDF/ESF,project TECHSCALE No.CZ.02.01.01/00/22_008/0004587).
文摘Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society.The field of catalysis has been revolutionized by single-atom catalysts(SACs),which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports.Recently,bimetallic SACs(bimSACs)have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports.BimSACs offer an avenue for rich metal–metal and metal–support cooperativity,potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges,substrate activation with reversible redox cycles,simultaneous multi-electron transfer,regulation of spin states,tuning of electronic properties,and cyclic transition states with low activation energies.This review aims to encapsulate the growing advancements in bimSACs,with an emphasis on their pivotal role in hydrogen generation via water splitting.We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs,elucidate their electronic properties,and discuss their local coordination environment.Overall,we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction,the two half-reactions of the water electrolysis process.
基金Supported by National Key Technology R&D Program of China(2007BAD88B06)~~
文摘[Objective] This study was to investigate the effects of different irrigation amount on water consumption and water use efficiency of greenhouse cucumber.[Method]Under the condition of drip irrigation with different water amounts in sunlight greenhouse of the arid areas in Ningxia,the soil water was measured and the water consumption of crop was calculated.[Result]When irrigation amount was 563 mm,the water consumption as a whole gradually increased with the delay of growth period,reached peak during the thriving stage of fruit setting,and then gradually declined;in each treatment,the daily water consumption increased with the increasing of irrigation amount during each growth period.However,the consumption of soil moisture reduced with the significant increase of irrigation.563 mm of irrigation amount could meet the water requirements of cucumber and began to add water to soil,and water utilization efficiency could reach 33.4 kg/m3.[Conclusion]The research had provided theoretical basis for water management in the production process of greenhouse cucumber.
基金Supported by Special Fund for Agro-scientific Research in the Public Interest of China(201303133-3)Tianjin Science and Technology Plan Project(14ZCDGNC00108)Agricultural Science and Technology Achievements Transformation and Extension Project of Tianjin City(201203030)~~
文摘This study aimed to investigate the effects of different irrigation amounts on water consumption and water use efficiency of celery under the condition of drip irrigation, so as to provide a scientific basis for high-yielding, high-quality and highefficiency cultivation and water-saving irrigation of greenhouse celery. Total five irrigation amounts were designed, 117.5 (T1), 160.0 (T2), 202.5 (T3), 245.0 (T4) and 287.5 (CK) mm/hm2, and the effects of different irrigation amounts on yield, water consumption and water use efficiency of celery were studied by plot experiment. The results showed that at the soil depth of 0-40 cm, the soil water storages of different treatments ranked as T3's〉T4's〉CK's〉T2's〉T1's, and the celery water consumptions ranked as CK's〉T4's〉T3's〉T2's〉T1's. At the same time, the soil water storage in different treatment group declined with the growth of celery, and finally increased at the harvest period. Among different irrigation amounts, the water use effi- ciency and irrigation water use efficiency all ranked as T1's〉T2's〉T3's〉T4's〉CK's. The water consumption of celery was positively related to irrigation amount (P〈 0.01), and was negatively related to water use efficiency (P〈0.01) and irrigation water use efficiency (P〈0.05). When the irrigation amount was below 253 mm/hm2, the celery yield was positively related to irrigation amount (P〈0.01). There was also a positive correlation between celery output and irrigation amount. Compared with those of CK, the benefit of the T4 treatment group was equal, and the water consumption was reduced by 14.78%. In high-efficiency solar greenhouse, the irrigation amount of drip-irrigated celery is recommended as 245 mm/hm2.
文摘Based on the water resource balance,the correlation between both the Liaoning water resource and precipitation and total amount of water resource from 1991 to 2004 was analyzed by assuming Liaoning to be an enclosed region.And the calculation methods were developed to quantitatively determine the increase of rainfall due to artificial precipitation,and consequently ascertain the contribution of artificial rainfall amount to water resources.
文摘[Objective] This study was conducted to investigate the effects of different irrigation amounts on rice leaf physiology and water use efficiency. [Method] The irrigation test with three different treatments was carried out in the Agrometeo- rological Experimental Station of Nanjing University of Information Science & Technology. [Reset] Under flood irrigation, the rice leaf temperature was lower than wet irrigation by 0.4-0.7 ℃; when the strength of photosynthetically active radiation was in the range of 800-1 800 gmol/(m^2·s), the average stomatal conductance of rice leaves under flood irrigation was higher than that of the wet irrigation treatment by 0.123-0.183 mol H2O/(m^2·s), and the leaf water use efficiency was higher than that of the wet irrigation treatment by 0.24 g/kg; after 10:00 every day, the water use efficiency under flood irrigation was always higher than that of the wet irrigation treatment; and compared with the wet irrigation treatment, the rice of the flood irrigation treatments had higher leaf water use efficiency, and final yields were also remarkably improved by 5.89%-13.97%. [Conclusion] This study will provide a practical reference basis for field management.
基金funded by the National Key Research and Development Program of China(2016YFD0300105 and 2016YFD0300401)the National Natural Science Foundation of China(31871563)the earmarked fund for China Agriculture Research System(CARS-3)。
文摘Available irrigation resources are becoming increasingly scarce in the North China Plain (NCP),and nitrogen-use efficiency of crop production is also relatively low.Thus,it is imperative to improve the water-use efficiency (WUE) and nitrogen fertilizer productivity on the NCP.Here,we conducted a two-year field experiment to explore the effects of different irrigation amounts (S60,60 mm;S90,90 mm;S120,120 mm;S150,150 mm) and nitrogen application rates (150,195 and 240 kg ha^(–1);denoted as N1,N2 and N3,respectively) under micro-sprinkling with water and nitrogen combined on the grain yield(GY),yield components,leaf area index (LAI),flag leaf chlorophyll content,dry matter accumulation (DM),WUE,and nitrogen partial factor productivity (NPFP).The results indicated that the GY and NPFP increased significantly with increasing irrigation amount,but there was no significant difference between S120 and S150;WUE significantly increased first but then decreased with increasing irrigation and S120 achieved the highest WUE.The increase in nitrogen was beneficial to improving the GY and WUE in S60 and S90,while the excessive nitrogen application (N3) significantly reduced the GY and WUE in S120 and S150 compared with those in the N2 treatment.The NPFP significantly decreased with increasing nitrogen rate under the same irrigation treatments.The synchronous increase in spike number (SN) and 1 000-grain weight (TWG)was the main reason for the large increase in GY by micro-sprinkling with increasing irrigation,and the differences in SN and TGW between S120 and S150 were small.Under S60 and S90,the TGW increased with increasing nitrogen application,which enhanced the GY,while N2 achieved the highest TWG in S120 and S150.At the filling stage,the LAI increased with increasing irrigation,and greater amounts of irrigation significantly increased the chlorophyll content in the flag leaf,which was instrumental in increasing DM after anthesis and increasing the TGW.Micro-sprinkling with increased amounts of irrigation or excessive nitrogen application decreased the WUE mainly due to the increase in total water consumption (ET)and the small increase or decrease in GY.Moreover,the increase in irrigation increased the total nitrogen accumulation or contents (TNC) of plants at maturity and reduced the residual nitrate-nitrogen in the soil (SNC),which was conducive to the increase in NPFP,but there was no significant difference in TNC between S120 and S150.Under the same irrigation treatments,an increase in nitrogen application significantly increased the residual SNC and decreased the NPFP.Overall,micro-sprinkling with 120 mm of irrigation and a total nitrogen application of 195 kg ha^(–1) can lead to increases in GY,WUE and NPFP on the NCP.
基金Shahid Hashemi Nejad Gas refinery for supporting this project
文摘Different mesoporous activated carbons were prepared by both chemical and physical activation processes and were examined for methane uptake in the presence of water.Methane isotherms were obtained at wet condition by wetting samples with water at mass ratio of water/carbon(R) close to 1.0.To compare,the amount of methane storage were also measured at dry situation.The maximum amount of methane stored was attained as 237 V/V at R=1.0 by hydrate formation at the methane critical pressure.In the next step,mass ratios of water/carbon were changed to investigate various amount of water for methane storage enhancement.Two other values of mass ratio of water/carbon(R=0.8 and 1.4) were selected and methane isotherms were obtained at the same conditions.Maximum values of 210 and 248 V/V were reached for methane storage,respectively.It was also observed that,in the pressure range lower than hydrate pressure,by increasing water ratio the hydrate formation pressure was decreased and methane uptake was much less than that of dry condition due to pore filling by water.
基金the Analysis and Testing Foundation of Zhejiang Province(No 04045)
文摘A novel approach was developed for the determination of ultratrace amounts of copper in water samples by using electrothermal atomic absorption spectrometry (ETAAS) after cloud point extraction ( CPE ). 1-( 2-Pyridylazo ) -2- naphthol was used as the chelating reagent and Triton X-114 as the mieellar-forming surfactant. CPE was conducted in a pH 8. 0 medium at 40 ℃ for 10 rain. After the separation of the phases by contrifugafion, the surfactant-rieh phase was diluted with 1 mL of a methanol solution of 0. 1 mol/L HNO3. Then 20μL of the diluted surfactant-rieh phase was injected into the graphite furnace for atomization in the absence of any matrix modifier. Various experimental conditions that affect the extraction and atomization processes were optimized. A detection limit of 5 ng/L was obtained after preconeentration. The linear dynamic range of the copper mass concentration was found to be 0-2.0 ng/mL, and the relative standard deviation was found to be less than 3. 1% for a sample containing 1.0 ng/mL Cu ( Ⅱ ). This developed method was successfully applied to the determination of uhratraee amounts of Cu in drinking water, tap water, and seawater samples.
基金supported by the National Natural Science Foundation of China (50979115)
文摘The dynamics of water and salt in soil were monitored in the 2010 and 2011 growing seasons of cotton to evaluate the salinity risk of soil under drip irrigation in arid environments for different management practices of drip system uniformity and irrigation amount. In the experiments, three Christiansen uniformity coefficients (CU) of approximately 65, 80, and 95% (referred to as low, medium, and high uniformity, respectively) and three irrigation amounts of 50, 75, and 100% of full irrigation were used. The distribution of the soil water content and bulk electrical conductivity (ECb) was monitored continuously with approximately equally spaced frequency domain reflectometry (FDR) sensors located along a dripline. Gravimetric samples of soil were collected regularly to determine the distribution of soil salinity. A great fluctuation in CU of water content and ECb at 60 cm depth was observed for the low uniformity treatment during the irrigation season, while a relatively stable variation pattern was observed for the high uniformity treatment. The ECb CU was substantially lower than the water content CU and its value was greatly related to the water content CU and the initial ECb CU. The spatial variation of seasonal mean soil water content and seasonal mean soil bulk electrical conductivity showed a high dependence on the variation pattern of emitter discharge rate along a dripline for the low and medium uniformity treatments. A greater irrigation amount produced a significantly lower soil salinity at the end of the irrigation season, while the influence of the system uniformity on the soil salinity was insignificant at a probability level of 0.1. In arid regions, the determination of the target drip irrigation system uniformity should consider the potential salinity risk of soil caused by nonuniform water application as the influence of the system uniformity on the distribution of the soil salinity was progressively strengthened during the growing season of crop.
基金the Science&Technology Basic Resources Investigation Program of China(No.2017TY100802)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA19060401)the National Natural Science Foundation of China(No.91958103)。
文摘An investigation was carried out in the Y3 seamount area of the Western Pacific Ocean in December 2014,and the distribution of dissolved inorganic carbon(DIC)and its relationship with environmental factors in this area were explored.The results show that DIC concentration was higher in the adjacent waters of the Y3 seamount area,and the uplift of DIC isolines at the stations was close to the seamount.Meanwhile,interaction between the North Equatorial Current(NEC)and the Y3 seamount affected the DIC distribution,i.e.,the upwelling in the same direction of the NEC was obvious,resulting in a decreasing trend of average concentration of DIC in the 200 m water column from the top to the two sides in this direction but in the cross direction.The DIC concentration increased with the water depth increase,and its distribution was affected by various environmental factors.In the surface water,high temperature was a decisive factor for the decrease of the DIC concentration,but the photosynthesis of phytoplankton showing only a weak influence.In the North Pacific Tropic Water(NPTW),DIC production rate from organic matter decomposition was higher than that of DIC consumption by phytoplankton photosynthesis,leading to a continual increase of DIC.In the North Pacific Intermediate Water(NPIW),organic matter decomposition played a leading role in the increase of DIC.In the deep water,decomposition of organic matter weakened,and the dissolution of CaCO3 controlled the carbonate system,and DIC had the smallest variation range.
基金Supported by the National Nature Science Foundation of China under Grant Nos 11434012 and 11174312
文摘A propagation experiment was conducted in the South China Sea in 2014 with a flat bottom and seamounts respectively by using explosive sources. The effects of seamounts on sound propagation are analyzed by using the broadband signals. It is observed that the transmission loss (TL) decreases up to 7 dB for the signals in the first shadow zone due to the seamount reflection. Moreover, the TL might increase more than 30 dB in the converge zone due to the shadowing by seamounts. Abnormal TLs and pulse arrival structures at different ranges are explained by using the ray and wave theory. The experimental TLs and arrival pulses are compared with the numerical results and found to be in good agreement.
基金supported by the Natural Science Foundation of Zhejiang Province(No.LY16B030009)National Natural Science Foundation of China(No.61205184)521 Talent Cultivation of Zhejiang Sci-Tech University(521 talent project of ZSTU)
文摘A novel luminescent coordination compound Eu(TTA)3(DEDAF)(1, TTA = 1,1,1-trifluoro-3-(2-thenoyl)acetone, DEDAF = 9,9-diethyl-4,5-diazafluoren) has been synthesized and fully characterized by infrared spectrum, elemental analysis, UV-vis spectrum, etc. X-ray single-crystal diffraction analysis reveals that compound 1 shows a mononuclear structure with the europium atom in coordinating to one DAF and three TTA ligands. The mononuclear structure units are assembled into a 3-D polymer by hydrogen bonds and π-π interactions. Photoluminescent property of 1 was investigated in detail at room temperature. Complex 1 emits strong red luminescence. However, it could be quenched even by small amount of water. The fluorescence intensity at 614 nm decreases linearly with the water content increasing(vol% in acetonitrile) in the range of 0.025~0.2% under 278 nm excitation. Thermogravimetric analysis has also been studied, which demonstrates good thermal stability of 1.
文摘Kuwait has recently implemented a vigorous campaign that aims to reclaim and reuse all treated wastewater in an at- tempt to alleviate water scarcity problem and to preserve seawater quality. This paper assesses the present status of wastewater treatment, reclamation and reuse in Kuwait, and discusses the impact of wastewater reuse on the amounts of pollutants discharged into the sea. Through analysis of the historical records of the wastewater treatment plants, it has been found that reuse of reclaimed wastewater in Kuwait has greatly reduced the amounts of pollutants discharged into the sea. Results showed that more than 50% reduction in volumes of wastewater discharged into the sea had been achieved from year 2000 to year 2010. However, this study has predicted that the amounts of wastewater discharged into the sea will start increasing again by the year 2020 due to shortages of storage capacity for reclaimed wastewater and due to the limitation of wastewater reuse applications to basically agricultural and landscape irrigations. In contrary, the on-going works and future plans of the Ministry of Public Works (MPW) are expected to overcome this problem and lead to a zero discharge of wastewater into the sea.
文摘The upstream water catchments are the main source providing sediments in rivers and sedimentary basins. The balance between the erosion phenomenon and the amount of sediment entering into the basin relies on the geometrical specifications and the morphology of the river along the water catchment direction and the amount and type of the sediments. The sedimentary feed of rivers and basins are changed for the sake of natural factors or human disturbances. The river and basin react against this change in that their shape, morphology, plan and profile get changed due to the increase or decrease of the input sediment into the basin. It is essential to know the sediment amount produced by erodability and sedimentation of upstream basins and effects of projects and also to evaluate the amount of sedimentary load in base studies, civil projects, optimizing rivers and dam construction studies specially calculating the amount of sediment amount entering into the dams’ reservoirs in order to take engineering decisions and related alternatives. Sediment Weight Model and PSIAC Experimental Model are recognized as two common methods calculating the amount of the produced sediment caused by erosion applied in this research. Holistically, these methods have been used and compared. Although the results are almost close to one another, more sediment load has been produced in PSIAC method. As more affective parameters are used to cause erosion and produce sediment in PSIAC experimental model, it is recommended to refer to the results of this method because they are closer to reality.
基金financial support of the National Natural Science Foundation of China(U21A20218 and 32101857)the‘Double First-Class’Key Scientific Research Project of Education Department in Gansu Province,China(GSSYLXM-02)+1 种基金the Fuxi Young Talents Fund of Gansu Agricultural University,China(Gaufx03Y10)the“Innovation Star”Program of Graduate Students in 2023 of Gansu Province,China(2023CXZX681)。
文摘The development of modern agriculture requires the reduction of water and chemical N fertilizer inputs.Increasing the planting density can maintain higher yields,but also consumes more of these restrictive resources.However,whether an increased maize density can compensate for the negative effects of reduced water and N supply on grain yield and N uptake in the arid irrigated areas remains unknown.This study is part of a long-term positioning trial that started in 2016.A split-split plot field experiment of maize was implemented in the arid irrigated area of northwestern China in 2020 to 2021.The treatments included two irrigation levels:local conventional irrigation reduced by 20%(W1,3,240 m^(3)ha^(-1))and local conventional irrigation(W2,4,050 m^(3)ha^(-1));two N application rates:local conventional N reduced by 25%(N1,270 kg ha^(-1))and local conventional N(360 kg ha^(-1));and three planting densities:local conventional density(D1,75,000 plants ha^(-1)),density increased by 30%(D2,97,500 plants ha-1),and density increased by 60%(D3,120,000 plants ha^(-1)).Our results showed that the grain yield and aboveground N accumulation of maize were lower under the reduced water and N inputs,but increasing the maize density by 30% can compensate for the reductions of grain yield and aboveground N accumulation caused by the reduced water and N supply.When water was reduced while the N application rate remained unchanged,increasing the planting density by 30% enhanced grain yield by 13.9% and aboveground N accumulation by 15.3%.Under reduced water and N inputs,increasing the maize density by 30% enhanced N uptake efficiency and N partial factor productivity,and it also compensated for the N harvest index and N metabolic related enzyme activities.Compared with W2N2D1,the N uptake efficiency and N partial factor productivity increased by 28.6 and 17.6%under W1N1D2.W1N2D2 had 8.4% higher N uptake efficiency and 13.9% higher N partial factor productivity than W2N2D1.W1N2D2 improved urease activity and nitrate reductase activity by 5.4% at the R2(blister)stage and 19.6% at the V6(6th leaf)stage,and increased net income and the benefit:cost ratio by 22.1 and 16.7%,respectively.W1N1D2 and W1N2D2 reduced the nitrate nitrogen and ammoniacal nitrogen contents at the R6 stage in the 40-100 cm soil layer,compared with W2N2D1.In summary,increasing the planting density by 30% can compensate for the loss of grain yield and aboveground N accumulation under reduced water and N inputs.Meanwhile,increasing the maize density by 30% improved grain yield and aboveground N accumulation when water was reduced by 20% while the N application rate remained constant in arid irrigation areas.
基金supported by the National Key Research and Development Program(2022YFB4202200)the Fundamental Research Funds for the Central Universities and sponsored by Shanghai Pujiang Program(22PJ1413100)。
文摘Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon emissions.Among water electrolysis technologies,the anion exchange membrane(AEM) water electrolysis has gained intensive attention and is considered as the next-generation emerging technology due to its potential advantages,such as the use of low-cost non-noble metal catalysts,the relatively mature stack assembly process,etc.However,the AEM water electrolyzer is still in the early development stage of the kW-level stack,which is mainly attributed to severe performance decay caused by the core component,i.e.,AEM.Here,the review comprehensively presents the recent progress of advanced AEM from the view of the performance of water electrolysis cells.Herein,fundamental principles and critical components of AEM water electrolyzers are introduced,and work conditions of AEM water electrolyzers and AEM performance improvement strategies are discussed.The challenges and perspectives are also analyzed.
基金Natural Science Foundation of Zhejiang Province,Grant/Award Number:LY23E020002National Natural Science Foundation of China,Grant/Award Number:52272085 and 51972178+1 种基金Natural Science Foundation of Ningbo,Grant/Award Number:2021J145China Postdoctoral Science Foundation,Grant/Award Number:2020M681966。
文摘Conversion of solar energy into H_(2) by photoelectrochemical(PEC)water splitting is recognized as an ideal way to address the growing energy crisis and environmental issues.In a typical PEC cell,the construction of photoanodes is crucial to guarantee the high efficiency and stability of PEC reactions,which fundamentally rely on rationally designed semiconductors(as the active materials)and substrates(as the current collectors).In this review work,we start with a brief introduction of the roles of substrates in the PEC process.Then,we provide a systematic overview of representative strategies for the controlled fabrication of photoanodes on rationally designed substrates,including conductive glass,metal,sapphire,silicon,silicon carbide,and flexible substrates.Finally,some prospects concerning the challenges and research directions in this area are proposed.
基金supported by the National Natural Science Foundation of China(Grant Nos.52304044,52222402,52234003,52174036)Sichuan Science and Technology Program(Nos.2022JDJQ0009,2023NSFSC0934)+2 种基金Key Technology R&D Program of Shaanxi Province(2023-YBGY-30)the Science and Technology Cooperation Project of the CNPC-SWPU Innovation Alliance(Grant No.2020CX030202)the China Postdoctoral Science Foundation(Grant No.2022M722638)。
文摘Due to the dissimilarity among different producing layers,the influences of inter-layer interference on the production performance of a multi-layer gas reservoir are possible.However,systematic studies of inter-layer interference for tight gas reservoirs are really limited,especially for those reservoirs in the presence of water.In this work,five types of possible inter-layer interferences,including both absence and presence of water,are identified for commingled production of tight gas reservoirs.Subsequently,a series of reservoir-scale and pore-scale numerical simulations are conducted to quantify the degree of influence of each type of interference.Consistent field evidence from the Yan'an tight gas reservoir(Ordos Basin,China)is found to support the simulation results.Additionally,suggestions are proposed to mitigate the potential inter-layer interferences.The results indicate that,in the absence of water,commingled production is favorable in two situations:when there is a difference in physical properties and when there is a difference in the pressure system of each layer.For reservoirs with a multi-pressure system,the backflow phenomenon,which significantly influences the production performance,only occurs under extreme conditions(such as very low production rates or well shut-in periods).When water is introduced into the multi-layer system,inter-layer interference becomes nearly inevitable.Perforating both the gas-rich layer and water-rich layer for commingled production is not desirable,as it can trigger water invasion from the water-rich layer into the gas-rich layer.The gas-rich layer might also be interfered with by water from the neighboring unperforated water-rich layer,where the water might break the barrier(eg weak joint surface,cement in fractures)between the two layers and migrate into the gas-rich layer.Additionally,the gas-rich layer could possibly be interfered with by water that accumulates at the bottom of the wellbore due to gravitational differentiation during shut-in operations.
基金supported by the Korea Institute of Energy Technology Evaluation and Planning(KETEP)grant from the Ministry of Trade,Industry&Energy,Republic of Korea(No.20213030040590)the National R&D Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Science and ICT(NRF-2021K1A4A8A01079455)。
文摘Continuous efforts are underway to reduce carbon emissions worldwide in response to global climate change.Water electrolysis technology,in conjunction with renewable energy,is considered the most feasible hydrogen production technology based on the viable possibility of large-scale hydrogen production and the zero-carbon-emission nature of the process.However,for hydrogen produced via water electrolysis systems to be utilized in various fields in practice,the unit cost of hydrogen production must be reduced to$1/kg H_(2).To achieve this unit cost,technical targets for water electrolysis have been suggested regarding components in the system.In this paper,the types of water electrolysis systems and the limitations of water electrolysis system components are explained.We suggest guideline with recent trend for achieving this technical target and insights for the potential utilization of water electrolysis technology.