Mechanism of nitrogen loss driven by soil and water erosion in water source areas

Nitrogen(N)present in drinking water as dissolved nitrates can directly affect people’s health,making it important to control N pollution in water source areas.N pollution caused by agricultural fertilizers can be controlled by reducing the amount of fertilizer applied,but pollution caused by soil and water erosion in hilly areas can only be controlled by conservation forests.The catchment area around Fushi Reservoir was selected as a test site and mechanisms of N loss from a vertical spatial perspective through field observations were determined.The main N losses occurred from June to September,accounting for 85.9-95.9%of the annual loss,with the losses in June and July accounting for 46.0%of the total,and in August and September for 41.9%.The N leakage from the water source area was effectively reduced by 38.2%through the optimization of the stand structure of the conservation forests.Establishing well-structured forests for water conservation is crucial to ensure the security of drinking water.This preliminary research lays the foundation for revealing then loss mechanisms in water source areas and improving the control of non-point source pollution in these areas.

Impact of climate change and human activities on the spatiotemporal dynamics of surface water area in Gansu Province, China

Understanding the dynamics of surface water area and their drivers is crucial for human survival and ecosystem stability in inland arid and semi-arid areas.This study took Gansu Province,China,a typical area with complex terrain and variable climate,as the research subject.Based on Google Earth Engine,we used Landsat data and the Open-surface Water Detection Method with Enhanced Impurity Control method to monitor the spatiotemporal dynamics of surface water area in Gansu Province from 1985 to 2022,and quantitatively analyzed the main causes of regional differences in surface water area.The findings revealed that surface water area in Gansu Province expanded by 406.88 km2 from 1985 to 2022.Seasonal surface water area exhibited significant fluctuations,while permanent surface water area showed a steady increase.Notably,terrestrial water storage exhibited a trend of first decreasing and then increasing,correlated with the dynamics of surface water area.Climate change and human activities jointly affected surface hydrological processes,with the impact of climate change being slightly higher than that of human activities.Spatially,climate change affected the'source'of surface water to a greater extent,while human activities tended to affect the'destination'of surface water.Challenges of surface water resources faced by inland arid and semi-arid areas like Gansu Province are multifaceted.Therefore,we summarized the surface hydrology patterns typical in inland arid and semi-arid areas and tailored surface water'supply-demand'balance strategies.The study not only sheds light on the dynamics of surface water area in Gansu Province,but also offers valuable insights for ecological protection and surface water resource management in inland arid and semi-arid areas facing water scarcity.

Riparian habitat quality as an indicator of land use/land cover effects on riverine water quality

Riparian land use/land cover(LULC)plays a crucial role in maintaining riverine water quality by altering the transport of pollutants and nutrients.Nevertheless,establishing a direct relationship between water quality and LULC is challenging due to the multi-indicator nature of both factors.Water quality encompasses a multitude of physical,chemical,and biological parameters,while LULC represents a diverse array of land use types.Riparian habitat quality(RHQ)serves as an indicator of LULC.Yet,it remains to be seen whether RHQ can act as a proxy of LULC for assessing the impact of LULC on riverine water quality.This study examines the interplay between RHQ,LULC and water quality,and develops a comprehensive indicator to predict water quality.We measured several water quality parameters,including pH(potential of hydrogen),TN(total nitrogen),TP(total phosphorus),T_(water)(water temperature),DO(dissolved oxygen),and EC(electrical conductivity)of the Yue and Jinshui Rivers draining to the Han River during 2016,2017 and 2018.The water quality index(WQI)was further calculated.RHQ is assessed by the InVEST(Integrated Valuation of Ecosystem Services and Tradeoffs)model.Our study found noticeable seasonal differences in water quality,with a higher WQI observed in the dry season.The RHQ was strongly correlated with LULC compositions.RHQ positively correlated with WQI,and DO concentration and vegetation land were negatively correlated with T_(water),TN,TP,EC,cropland,and construction land.These correlations were stronger in the rainy season.Human-dominated land,such as construction land and cropland,significantly contributed to water quality degradation,whereas vegetation promoted water quality.Regression models showed that the RHQ explained variations in WQI better than LULC types.Our study concludes that RHQ is a new and comprehensive indicator for predicting the dynamics of riverine water quality.

Connotation and principles of ecological compensation in water source reserve areas based on the theory of externality

Understanding the connotation and principles of ecological compensation in water source reserve areas is the basis and guarantee for establishing and improving the ecological compensation mechanism of water source reserve areas.First,this paper reviews the three stages of ecological compensation research progress.Based on the review,using the theory of externality,the ecological environment system of water source reserve areas is then analyzed.This paper argues that the connotation of ecological compensation in water source reserve areas is a kind of institutional arrangement,which is designed to internalize externalities.Finally,based on the understanding of the connotation of ecological compensation in water source reserve areas,five principles for establishing and improving the ecological compensation mechanism are proposed,including the principle of fairness and justice,the principle of equivalence of equality and responsibility,the principle of flexibility and effectiveness,the principle of "earmark funds,and implementation by law," and the principle of government compensation supplemented with market compensation.

Protection Planning for Rural Centralized Drinking Water Source Areas in Chongqing

Protection planning is made for rural centralized drinking water source areas according to current situations of rural drinking water and existing problems of centralized drinking water source areas in Chongqing,and in combination with survey,analysis and evaluation of urban-rural drinking water source areas in whole city.There are engineering measures and non-engineering measures,to guarantee drinking water security of rural residents,improve rural ecological environment,realize sustainable use of water resource,and promote sustainable development of society.Engineering measures include conservation and protection of water resource,ecological restoration,isolation,and comprehensive control of pointsource and area-source pollution.Non-engineering measures include construction of monitoring system for drinking water source area,construction of security information system for rural centralized drinking water source area,and construction of emergency mechanism for water pollution accidents in rural water source areas.

Tourism Development Models Based on Ecological Utilization and Protection of Water Conservancy Scenic Areas

In view of major confl icts between ecological conditions of scenic areas and tourism development, tourism development models and approaches of six major water conservancy scenic areas were summarized on the basis of investigating interaction mechanism, ecological utilization and protection of scenic areas, including reservoir development and construction model, wetland development and construction model, natural river and lake development and construction model, city river and lake development and construction model, irrigated area development and construction model, water and soil conservation development and construction model. The research fruits are of instructive signif icance for the management and development of scenic areas.

New perspective of Miocene marine hydrocarbon source rocks in deep-water area in Qiongdongnan Basin of northern South China Sea

Drilling wells reveal that the organic matter abundance of Miocene marine source rocks in shallow water area of the Qiongdongnan Basin is relatively low with poor hydrocarbon generation poten- tial. However, in some drilling wells of deep water area close to the central depression belt, Miocene marine source rocks with better organic matter abundance and hydrocarbon generation have been found, which have achieved better source rock standard based on the analysis of geochemical charac- teristics. Although there are no exploratory wells in deep water area of the research region, through the comparative analysis of geochemical data of several typical exploratory wells respectively from shallow water area in the basin, central depression belt margin in deep-water area of the basin and Site 1148 of deep sea drilling in the South China Sea Basin, it reveals that the tendency of the quality of source rocks becomes positive gradually from delta to bathyal environment, which then becomes negative as in deep oceanic environment. Owing to the lack of terrestrial organic matter input, the important controlling factors of Miocene marine source rocks in the Qiongdongnan Basin are ocean productivity and preservation conditions of organic matter. The element geochemistry data indicate that the tendency of the paleoproductivity and the preservation conditions of organic matter become positive as water depth increase from shallow area to bathyal area close to central depression belt. So it is speculated that there must exist high quality source rocks in the central depression area where the preservation conditions of organic matter are much better. Besides, in theory, in oxygen-poor zone of oceanic environment at the water depth 400–1 000 m, the preservation conditions of organic matter are well thus forming high-quality marine source rocks. The result- ing speculation, it is reasonable to consider that there are high hydrocarbon generation potential source rocks in bathyal environment of the Qiongdongnan Basin, especially at the water depth 400– 1 000 m.

Application of a Stereo Constructed Wetland Mode to the Treatment of Slightly Polluted Source Water

[Objective] The study aimed to discuss the application of a stereo constructed wetland to the treatment of slightly polluted source water. [Method] In this study, a new stereo constructed wetland mode was put forward, and a pilot project of water ecological purification in Xinsheng River, the diversion channel of Shijiuyang Waterwork in Jiaxing City, were analyzed. Afterwards, the impact factors of water purification by the technology were discussed from water quality and quantity, season and climate, species configuration, management and maintenance. [Result] Under three different hydraulic loading conditions, the pilot project effectively improved water SD and DO level, and reduced SS, CODCr, NH3-N, TN and TP significantly in summer and autumn, so that effluent water quality reached surface water standard at Grade III. [Conclusion] The stereo constructed wetland mode composed of constructed wetland and underwater forest used to treat slightly polluted source water is feasible and has a good promotion prospect.

Chemical kinetics evaluation and its application of natural gas generation derived from the Yacheng Formation in the deep-water area of the Qiongdongnan Basin,China

The natural gas generation process is simulated by heating source rocks of the Yacheng Formation, including the onshore-offshore mudstone and coal with kerogens of Type II2-III in the Qiongdongnan Basin. The aim is to quantify the natural gas generation from the Yacheng Formation and to evaluate the geological prediction and kinetic parameters using an optimization procedure based on the basin modeling of the shallow-water area. For this, the hydrocarbons produced have been grouped into four classes（C1, C2, C3 and C4-6）. The results show that the onset temperature of methane generation is predicted to occur at 110℃ during the thermal history of sediments since 5.3 Ma by using data extrapolation. The hydrocarbon potential for ethane, propane and heavy gaseous hydrocarbons（C4-6） is found to be almost exhausted at geological temperature of 200℃ when the transformation ratio（TR） is over 0.8, but for which methane is determined to be about 0.5 in the shallow-water area. In contrast, the end temperature of the methane generation in the deep-water area was over 300℃ with a TR over 0.8. It plays an important role in the natural gas exploration of the deep-water basin and other basins in the broad ocean areas of China. Therefore, the natural gas exploration for the deep-water area in the Qiongdongnan Basin shall first aim at the structural traps in the Ledong, Lingshui and Beijiao sags, and in the forward direction of the structure around the sags, and then gradually develop toward the non-structural trap in the deep-water area basin of the broad ocean areas of China.

Legislation on protection of drinking water sources and local management practices in the Pearl River Delta region of China

The protection of drinking water sources is vital to urban development and public health.In this study,the current situation of the mandatory protection area for drinking water source in the Pearl River Delta region was investigated using a method combining Google Earth with the field survey.The gaps between management practices and legislation requirements were analyzed.Finally,several countermeasures for water resource protection were proposed as follows:to promote delineation in a more scientific way,to safeguard the sanctity of the law,to make better plan on water saving,and to encourage public participation in supervision and management.

Impacts of water surface area of watershed on design flood

In order to analyze the impact of the water surface area of a watershed on the design flood, the watershed was classified into a land watershed and a water surface watershed for flood flow calculation at the same time interval. Then, the design flood of the whole watershed was obtained by adding the two flood flows together. Using this method, we calculated design floods with different water surface areas of three reservoirs and analyzed the impact of water surface area on the flood volume and peak flow. The results indicate that larger water surface areas lead to greater impacts on the flood volume and peak flow. For the same watershed area, the impact of water surface area on the flood volume and peak flow is positively proportional to the flood frequency, i.e., the higher the frequency, the greater the impact becomes.

Study on the Reservoir Water Quality Change Rule in Northern China

Water quality index of reservoir source water were tracked during three years in a north frigid area,the effect on supplied water quality was also studied.Based on the analysis of the monitoring data during the same season,the reservoir source water had typical and seasonal variation characteristics that was divided into four periods including the icebound period,spring period(or peach blossom period),stable period in summer and autumn and winter period.The icebound period was charactered by the typical low temperature and turbidity,pH and oxygen consumption decreased gradually showed that the gradually anaerobic trend existed in the reservoir.In May as the reservoir completely thawed,upstream water inflow and the total pollutant in the reservoir gradually increased,but the bottom of reservoir bottom was stable in the anaerobic state temporarily.The state completely disappeared,various index increased significantly in the middle of July.The water had high chroma characteristics,chroma and turbidity increased significantly in the summer and autumn(7-11months),but stability of water quality was poor because of rainfall.The reservoir gradually froze after the middle of November and the flow of water decreased.The peak of chroma appeared a month later than the water temperature.Due to the water turbidity was low,and the floc was small and light,the conventional water purification process design based on removal of turbidity achieved removal of chroma through a lot dosing of coagulant.

Application of SEDEA to evaluation of degree of harmony between water resources and economic development

This paper introduces the method of data envelopment analysis （DEA） for evaluation of the degree of harmony between water resources and economic development of the water conservancy area of China＇s South-to-North Water Diversion Project （SNWDP）. For this evaluation, a super-efficiency DEA （SEDEA） model was developed based on the super-efficiency method. To verify the applicability of the SEDEA model, both the SEDEA model and a normal-efficiency DEA （NEDEA） model were used to evaluate the degree of harmony between water resources and economic development of typical cities in the SNWDP water conservancy area. The results show that the SEDEA model ranks the degree of harmony of typical cities more efficiently than the NEDEA model, and thus can better evaluate the degree of harmony between water resources and economic development of different cities than the NEDEA model. Furthermore, the SEDEA model can be applied as an operational research tool in regional water resources management.

Br/Cl,I/Cl and chlorine isotopic compositions of pore water in shallow sediments：implications for the fluid sources in the Dongsha area,northern South China Sea

The Dongsha area is one of the most promising target areas for gas hydrate exploration in the South China Sea（SCS）.The study of pore water geochemistry has played a key role in Chinese gas hydrate exploration.Br/Cl,I/Cl and δ37Cl in pore water were applied here in tracing gas hydrate occurrence,chemical evolution of pore fluids and water/rock interactions in low temperature sediment environments.The samples were collected from Sites HD255 PC and HD309 PC in the Dongsha area in 2004.At Site HD255 PC,we found the elevated Br/Cl,I/Cl and decreased SO_4/Cl at the depth of 4–5 m,suggestive of a laterally migrated fluid probably generated from the gas hydrate occurrence.The range of δ37Cl is –0.54‰ to ＋0.96‰,and positive δ^（37）Cl at 4–5 m interval should be related with different diffusion rates between ^（35）Cl and ^（37）Cl.At Site HD309 PC,a laterally migrated fluid was also found at the depth of 3–4 m,with the Br/Cl two times to that of the seawater and decreased I/Cl,indicating the fluid has no relationship with the gas hydrate.In this site,the chlorine isotopic composition varies from –0.7‰ to＋1.9‰.Extra high Br/Cl might relate with the deep generated fluid.At higher temperature and pressure,the Br/Cl of the fluid is elevated during the hydrous silicate formation,while positive δ37Cl is also associated with the same mechanism.

Provenance analysis of surface sediments in the Holocene mud area of the southern coastal waters off Shandong Peninsula,China

The sedimentary record of mud areas is an important carrier of information on the Holocene evolution of marine environments. Based on fine interpretations of the shallow stratigraphic section data, a small mud deposit area has been found in the southern coastal waters off Shandong Peninsula. This mud area is mainly distributed in coastal waters north of Laoshantou to the vicinity of Rushan Estuary. Overall, it is parallel to the coastline and spreads in a banded pattern, gradually thinning from offshore to the sea. The isopach map of depth distribution is parallel with the shoreline, and the depocenter lies in coastal waters of the Aoshan Bay where the maximum thickness is up to 22.5 m. Accelerator mass spectrometry（AMS） ^（14）C dating shows that the mud area was formed in the Holocene. The test data of surface sediments from the mud area, including particle size, mineral characteristics, and rare earth element contents, are used in comparisons with the composition of materials from the major surrounding medium and small rivers flowing into the sea and the Huanghe（Yellow） River. In this paper, the sedimentary characteristics and provenance of the mud deposit area are discussed. The results show that the formation of this mud area resulted from the joint action of the Huanghe River and surrounding rivers flowing into the sea.

Study on Control Scheme for Nonpoint Source Pollution in Dahe Reservoir Water Source Protection Area of Dianchi Lake Basin

[ Objective] The research aimed to study control scheme for nonpoint source pollution in Dahe Reservoir water source protection area of Dianchi Lake basin.[ Method] On the basis of the SPOT5 satellite remote sensing imagery in 2010 and field investigation of GPS record, ecological design for nonpoint source pollution control in Dahe Reservoir water source protection area of Dianchi Lake basin was conducted. Then, the effects of optimization measures were evaluated by the reductions of N and P outputs on different land-use types. E Resultl Control functions of the water source protection area on soil erosion and the emissions of N, P and other pollutants would be promoted after optimization. The optimization meas- ures had a significant effect for prevention and control of the non-point source pollution in the water source protection area. [ Conclusion] The re- search provided scientific basis for promoting ecological construction of the small green basin in Dahe Reservoir water source protection area of Di- anchi Lake basin.

Spatial and Temporal Dynamics of Surface Water in China from the 1980s to 2015 Based on Remote Sensing Monitoring

Climate change and human interference play significant roles on dynamic of water body abundance,and drive related hydrological,biochemical and social/economic processes.Documenting and monitoring surface water area with high resolution multi-temporal satellite imagery provide new perspective to evaluate the dynamics of surface water area,especially in continental and global scale.In this study,based on the Landsat images from 1980 s to 2015,we surveyed the spatial and temporal variation of surface water area,including rivers,lakes and reservoirs,in 10-yr temporal slice across China.Furthermore,the driving forces of the variation has been identified to reveal the interaction of water bodies and the changing environment.The results show that,the water surface area expanded over all three decades with strong spatial and temporal difference,despite the drier and warmer climate background;although lakes comprise the largest portion of the surface water area,the highest contributor of surface water expansion was new constructed reservoir located in the densely populated region;climatic parameters alteration,like precipitation and temperature,resulted in the water surface expansion in the northwestern basin by growing water input linked with rain and glacier melting;in the rest part of China,rise of water surface area was predominately attributed to human relocation of water resource,which yielded more new water storage area than the disappeared water body caused by less precipitation and stronger evapotranspiration.The conclusions highlight the integrative water resource management,especially in water conservation and restoration.

Water film area and dust removal efficiency of string grilles:a theoretical analysis

Based onmultiphase flowtheory and capillary mechanics,the dimensionless bond number expression of the influence of string grille wire spacing on droplet spreading is derived.Taking a liquid film formed by spreading droplets based on Kelvin correlation,the Young-Laplace equation,and the Hagen-Poiseuille law,an equation for calculating the thickness and height of the liquid film is established with temperature,relative humidity and molar volume of liquid phase as independent variables.According to the theory of string grille filtration and dust removal,a dust removal efficiency calculation model covering the wet string grille wire group is constructed based on the liquid film thickness,height,wire diameter,water film area,and vortex shedding frequency.Finally,a theoretical analysis of the influence of water film area on the efficiency of wet string grille dust removal is carried out based on the spray pressure and the ratio of string grille wire distance to wire diameter.It is found that the effect of spray pressure on water film area and dust removal efficiency is more significant than the string grille wire distance diameter ratio.Moreover,the optimized combination of wet string grille wire distance diameter ratio 0.84,wind speed 3m/s and spray pressure 0.8 MPa is found,which could provide an important reference for engineering applications.