Multi-Model Approach for Assessing the Influence of Calibration Criteria on the Water Balance in Ouémé Basin

Hydrological models are very useful tools for evaluating water resources, and the hydroclimatic hazards associated with the water cycle. However, their calibration and validation require the use of performance criteria which choice is not straightforward. This paper aims to evaluate the influence of the performance criteria on water balance components and water extremes using two global rainfall-runoff models (HBV and GR4J) over the Ouémé watershed at the Bonou and Savè outlets. Three (3) Efficacy criteria (Nash, coefficient of determination, and KGE) were considered for calibration and validation. The results show that the Nash criterion provides a good assessment of the simulation of the different parts of the hydrograph. KGE is better for simulating peak flows and water balance elements than other efficiency criteria. This study could serve as a basis for the choice of performance criteria in hydrological modelling.

Separate-layer balanced waterflooding development technology for thick and complex carbonate reservoirs in the Middle East

Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic limestone reservoirs of Cretaceous in Iran-Iraq as an example,this paper proposes a balanced waterflooding development technology for thick and complex carbonate reservoirs.This technology includes the fine division of development units by concealed baffles and barriers,the combination of multi well type and multi well pattern,and the construction of balanced water injection and recovery system.Thick carbonate reservoirs in Iran-Iraq are characterized by extremely vertical heterogeneity,development of multi-genesis ultra-high permeability zones,and highly concealed baffles and barriers.Based on the technologies of identification,characterization,and sealing evaluation for concealed baffles and barriers,the balanced waterflooding development technology is proposed,and three types of balanced waterflooding development modes/techniques are formed,namely,conventional stratigraphic framework,fine stratigraphic framework,and deepened stratigraphic framework.Numerical simulations show that this technology is able to realize a fine and efficient waterflooding development to recover,in a balanced manner,the reserves of thick and complex carbonate reservoirs in Iran and Iraq.The proposed technology provides a reference for the development optimization of similar reservoirs.

Bimetallic Single‑Atom Catalysts for Water Splitting

Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society.The field of catalysis has been revolutionized by single-atom catalysts(SACs),which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports.Recently,bimetallic SACs(bimSACs)have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports.BimSACs offer an avenue for rich metal–metal and metal–support cooperativity,potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges,substrate activation with reversible redox cycles,simultaneous multi-electron transfer,regulation of spin states,tuning of electronic properties,and cyclic transition states with low activation energies.This review aims to encapsulate the growing advancements in bimSACs,with an emphasis on their pivotal role in hydrogen generation via water splitting.We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs,elucidate their electronic properties,and discuss their local coordination environment.Overall,we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction,the two half-reactions of the water electrolysis process.

Multisensory mechanisms of gait and balance in Parkinson’s disease:an integrative review

Understanding the neural underpinning of human gait and balance is one of the most pertinent challenges for 21st-century translational neuroscience due to the profound impact that falls and mobility disturbances have on our aging population.Posture and gait control does not happen automatically,as previously believed,but rather requires continuous involvement of central nervous mechanisms.To effectively exert control over the body,the brain must integrate multiple streams of sensory information,including visual,vestibular,and somatosensory signals.The mechanisms which underpin the integration of these multisensory signals are the principal topic of the present work.Existing multisensory integration theories focus on how failure of cognitive processes thought to be involved in multisensory integration leads to falls in older adults.Insufficient emphasis,however,has been placed on specific contributions of individual sensory modalities to multisensory integration processes and cross-modal interactions that occur between the sensory modalities in relation to gait and balance.In the present work,we review the contributions of somatosensory,visual,and vestibular modalities,along with their multisensory intersections to gait and balance in older adults and patients with Parkinson’s disease.We also review evidence of vestibular contributions to multisensory temporal binding windows,previously shown to be highly pertinent to fall risk in older adults.Lastly,we relate multisensory vestibular mechanisms to potential neural substrates,both at the level of neurobiology(concerning positron emission tomography imaging)and at the level of electrophysiology(concerning electroencephalography).We hope that this integrative review,drawing influence across multiple subdisciplines of neuroscience,paves the way for novel research directions and therapeutic neuromodulatory approaches,to improve the lives of older adults and patients with neurodegenerative diseases.

Physiology and health assessment,risk balance,and model for endstage liver disease scores:Postoperative outcome of liver transplantation

BACKGROUND Liver transplantation aims to increase the survival of patients with end-stage liver diseases and improve their quality of life.The number of organs available for transplantation is lower than the demand.To provide fair organ distribution,predictive mortality scores have been developed.AIM To compare the Acute Physiology and Chronic Health Evaluation IV(APACHE IV),balance of risk(BAR),and model for end-stage liver disease(MELD)scores as predictors of mortality.METHODS Retrospective cohort study,which included 283 adult patients in the postoperative period of deceased donor liver transplantation from 2014 to 2018.RESULTS The transplant recipients were mainly male,with a mean age of 58.1 years.Donors were mostly male,with a mean age of 41.6 years.The median cold ischemia time was 3.1 hours,and the median intensive care unit stay was 5 days.For APACHE IV,a mean of 59.6 was found,BAR 10.7,and MELD 24.2.The 28-day mortality rate was 9.5%,and at 90 days,it was 3.5%.The 28-day mortality prediction for APACHE IV was very good[area under the curve(AUC):0.85,P<0.001,95%CI:0.76-0.94],P<0.001,BAR(AUC:0.70,P<0.001,95%CI:0.58–0.81),and MELD(AUC:0.66,P<0.006,95%CI:0.55-0.78),P<0.008.At 90 days,the data for APACHE IV were very good(AUC:0.80,P<0.001,95%CI:0.71–0.90)and moderate for BAR and MELD,respectively,(AUC:0.66,P<0.004,95%CI:0.55–0.77),(AUC:0.62,P<0.026,95%CI:0.51–0.72).All showed good discrimination between deaths and survivors.As for the best value for liver transplantation,it was significant only for APACHE IV(P<0.001).CONCLUSION The APACHE IV assessment score was more accurate than BAR and MELD in predicting mortality in deceased donor liver transplant recipients.

Study on the Water Balance in Three Dominant Plants with Simulated Precipitation Change in Maowusu Sandland

The distribution pattern and productivity of Maowusu sandland terrestrial ecosystem are greatly affected with the future severe global change, especially global precipitation change. Considering the predicative global precipitation change and the appropriate relevant strategy for the sustainable development of the China dry territory, the authors have investigated the response of water balance to global precipitation change by creating an artificial control of four levels of water supply treating 3 dominant plants in Mauwusu sandland. The results showed that the seasonal changes of water storage and moisture of different sandland layer depths were affected by different water supply treatments and different plants. The water storage of the three plant growing sandlands and the moisture of different sandland layer depths increased as water supply was increased. The moisture of different water supply treatments and plants increased with the increase of sandland layer depth. The water storage and moisture of the same layer depth of Hedysarum mongolicum Turcz. growing sandland were larger than that of Salix psammophila C. Wang et Ch. Y. Yang growing sandland, which were in turn higher than that of Artemisia ordosica Krasch. growing sandland in the same water supply treatment. Water supply significantly affected the seasonal changes of evaporation and transpiration of the three plant growing sandlands. With the increased levels of water supply, viz. 157.5 mm, 315.0 mm, 472.5 mm and 630.0 mm, the total evaporation was 123.66 mm, 258.68 mm, 376.30 mm, 458.57 mm, respectively, and the total transpiration of A. ordosica was 50.80 mm, 68.93 mm, 108.39 mm, 163.36 mm, respectively, and that of S. psammophila , 47.37 mm, 68.17 mm, 93.65 mm, 135.97 mm, respectively, and that of H. mongolicum 46.73 mm, 67.37 mm, 86.07 mm, 109.64 mm, respectively. Evaporation was significantly higher than transpiration in the experiment.

Balance of Water Supply-demand in Paddy Fields in Hilly Regions in Sichuan Province

[Objective] The aim was to study the effects of water supply and consumption on water saving and drought resistance. [Method] Controlling field experiment was conducted to explore water balance between supply and demand in paddy fields in hilly regions in Sichuan Province. [Result] Rainfall in hilly areas was 3 611.10 m3/hm2; water for irrigation was 6 299.25 m3/hm2; evapotranspiration of rice was 6 424.95 m3/hm2; deep leakage was 2 459.55 m3/hm2; overflowing amount was 1 026.00 m3/hm2. In addition, water consumption totaled 8 884.50 m3/hm2 during rice production; water use was 0.99 kg/m3 and use efficiency of irrigated water was 1.40 kg/m3. [Conclusion] Water supply and consumption should be further organized to save water and fight against drought in hilly areas in Sichuan Province.

The Study on Urban Vertical Greening and Balance Water Supply Technology

The paper had analyzed the technology, maintenance and recognition of vertical greening in urban space, and proposed a solution for balance water supply for balconies and streetlights, that is, magnetic auxiliary shallow water level controller, the patent of which had been applied. Magnetic auxiliary shallow water level controller had met water supply of some special parts of urban vertical greening and was sure to accelerate urban vertical greening.

Energy Balance-Based SWAT Model to Simulate the Mountain Snowmelt and Runoff——Taking the Application in Juntanghu Watershed(China) as an Example

In order to predict long-term flooding under extreme weather conditions in central Asia, an energy balance-based distributed snowmelt runoff model was developed and coupled with the Soil and Water Assessment Tool(SWAT) model. The model was tested at the Juntanghu watershed on the northern slope of the Tian Shan Mountains, Xinjiang,China. We compared the performances of temperature-index method and energy balanced method in SWAT model by taking Juntanghu river basin as an application example(as the simulation experiment was conducted in Juntanghu River, we call the energy balanced method as SWAT-JTH). The results suggest that the SWAT snowmelt model had overall Nash-Sutcliffe efficiency(NSE) coefficients ranging from 0.61 to 0.85 while the physical based approach had NSE coefficients ranging from 0.58 to0.69. Overall, on monthly scale, the SWAT model provides better results than that from the SWAT-JTH model. However, results generated from both methods seem to be fairly close at a daily scale. Thestructure of the temperature-index method is simple and produces reasonable simulation results if the parameters are well within empirical ranges. Although the data requirement for the energy balance method in current observation is difficult to meet and the existence of uncertainty is associated with the experimental approaches of physical processes, the SWAT-JTH model still produced a reasonably high NSE. We conclude that using temperature-index methods to simulate the snowmelt process is sufficient, but the energy balance-based model is still a good choice to simulate extreme weather conditions especially when the required data input for the model is acquired.

A Study of the Balanced Scorecard： The Rockwater Case

Over the past decades，various performance appraisal methods have been raised and developed by many scholars and managers for years.It seems that each kind of performance appraisal techniques has its strengths and limitations and none of them is able to avoid all of the pitfalls.Today，driven by the power of innovation，dozens of new companies are trying to reinvent the performance management tools market.This paper analyzes how the Balanced Scorecard (BSC) implemented to provide line managers with a performance appraisal system in the private sector companies through the case study of Rockwater，and critically identify its main strengths and limitations，and then make some recommendations for improvement.

A Distributed Monthly Water Balance Model for Analyzing Impacts of Land Cover Change on Flow Regimes

The Miyun Reservoir is the most important water source for Beijing Municipality, the capital of China with a population of more than 12 million. In recent decades, the inflow to the reservoir has shown a decreasing trend, which has seriously threatened water use in Beijing. In order to analyze the influents of land use and cover change (LUCC) upon inflow to Miyun Reservoir, terrain and land use information from remote sensing were utilized with a revised evapotranspiration estimation formula; a water loss model under conditions of human impacts was introduced; and a distributed monthly water balance model was established and applied to the Chaobai River Basin controlled by the Miyun Reservoir. The model simulation suggested that not only the impact of land cover change on evapotranspiration, but also the extra water loss caused by human activities, such as the water and soil conservation development projects should be considered. Although these development projects were of great benefit to human and ecological protection, they could reallocate water resources in time and space, and in a sense thereby influence the stream flow.

Estimation of water balance in the source region of the Yellow River based on GRACE satellite data

Water storage has important significance for understanding water cycles of global and local domains and for monitoring climate and environmental changes. As a key variable in hydrology, water storage change represents the sum of precipitation, evaporation, surface runoff, soil water and groundwater exchanges. Water storage change data during the period of 2003-2008 for the source region of the Yellow River were collected from Gravity Recovery and Climate Experiment （GRACE） satellite data. The monthly actual evaporation was estimated according to the water balance equation. The simulated actual evaporation was significantly consistent and correlative with not only the observed pan （20 cm） data, but also the simulated results of the version 2 of Simple Biosphere model. The average annual evaporation of the Tangnaihai Basin was 506.4 mm, where evaporation in spring, summer, autumn and winter was 130.9 mm, 275.2 mm, 74.3 mm and 26.1 mm, and accounted for 25.8%, 54.3%, 14.7% and 5.2% of the average annual evaporation, respectively, The precipitation increased slightly and the actual evaporation showed an obvious decrease. The water storage change of the source region of the Yellow River displayed an increase of 0.51 mm per month from 2003 to 2008, which indicated that the storage capacity has significantly increased, probably caused by the degradation of permafrost and the increase of the thickness of active layers. The decline of actual evaporation and the increase of water storage capacity resulted in the increase of river runoff.

Understanding the impact of mountain landscapes on water balance in the upper Heihe River watershed in northwestern China

Estimating the impact of mountain landscape on hydrology or water balance is essential for the sus- tainable development strategies of water resources. Specifically, understanding how the change of each landscape influences hydrological components will greatly improve the predictability of hydrological responses to mountain landscape changes and thus can help the government make sounder decisions. In the paper, we used the VIC （Variable Infiltration Capacity） model to conduct hydrological modeling in the upper Heihe River watershed, along with a frozen-soil module and a glacier melting module to improve the simulation. The improved model performed satisfactorily. We concluded that there are differences in the runoff generation of mountain landscape both in space and time. About 50% of the total runoff at the catchment outlet were generated in mid-mountain zone （2,900-4,000 m asl）, and water was mainly consumed in low mountain region （1,700-2,900 m asl） because of the higher requirements of trees and grasses. The runoff coefficient was 0.37 in the upper Heihe River watershed. Barren landscape produced the largest runoff yields （52.46% of the total runoff） in the upper Heihe River watershed, fol- lowed by grassland （34.15%）, shrub （9.02%）, glacier （3.57%）, and forest （0.49%）. In order to simulate the impact of landscape change on hydrological components, three landscape change scenarios were designed in the study. Scenario 1, 2 and 3 were to convert all shady slope landscapes at 2,000-3,300 m, 2,000-3,700 m, and 2,000-4,000 m asl respectively to forest lands, with forest coverage rate increased to 12.4%, 28.5% and 42.0%, respectively. The runoff at the catchment outlet correspondingly declined by 3.5%, 13.1% and 24.2% under the three scenarios. The forest landscape is very important in water conservation as it reduced the flood peak and increased the base flow. The mountains as ＂water towers＂ play important roles in water resources generation and the impact of mountain landscapes on hydrology is significant.

The Impact of Soil Freezing/Thawing Processes on Water and Energy Balances

A frozen soil parameterization coupling of thermal and hydrological processes is used to investigate how frozen soil processes affect water and energy balances in seasonal frozen soil. Simulation results of soil liquid water content and temperature using soil model with and without the inclusion of freezing and thawing processes are evaluated against observations at the Rosemount field station. By comparing the simulated water and heat fluxes of the two cases, the role of phase change processes in the water and energy balances is analyzed. Soil freezing induces upward water flow towards the freezing front and increases soil water content in the upper soil layer. In particular, soil ice obviously prevents and delays the infiltration during rain at Rosemount. In addition, soil freezingthawing processes alter the partitioning of surface energy fluxes and lead the soil to release more sensible heat into the atmosphere during freezing periods.

Hydrological behaviour and water balance analysis for Xitiaoxi catchment of Taihu Basin

With the rapid social and economic development of the Taihu region, Taihu Lake now faces an increasingly severe eutrophication problem. Pollution from surrounding catchments contributes greatly to the eutrophication of water bodies in the region. Investigation of surface flow and associated mass transport for the Xitiaoxi catchment is of a significant degree of importance as the Xitiaoxi catchment is one of the major catchments within the Taihu region. A SWAT-based distributed hydrological model was established for the Xitiaoxi catchment. The model was calibrated and verified using hydrometeorological data from 1988 to 2001. The results indicate that the modeled daily and annual stream flow match the observed data both in the calibration period and the verification period, with a linear regression coefficient R2 and a coefficient e for modeled daily stream flow greater than 0.8 at Hengtangcun and Fanjiacun gauge stations. The results show that the runoff process in the Xitiaoxi catchment is affected both by rainfall and human activities （e.g., reservoirs and polder areas）. Moreover, the human activities weaken flood peaks more noticeably during rainstorms. The Water balance analysis reveals the percentages of precipitation made up by surface flow, evapotranspiration, groundwater recharge＇ and the change of soil storage, all of which are considered useful to the further understanding of the hydrological processes in the Xitiaoxi catchment. This study provides a good base for further studies in mass transport modeling and comparison of modeling results from similar hydrological models.

THE BALANCE BETWEEN SUPPLY AND DEMAND OF WATER RESOURCES AND THE WATER-SAVING POTENTIAL FOR AGRICULTURE IN THE HEXI CORRIDOR

The Hexi Corridor is an important base of agriculture development inNorthwest China. According to recent statistics, there are 65. 94 x 10~8m^3 of water resourcesavailable in the Hexi Corridor. At present, net consumption in development and utilization is 43. 33x 10~8m^3. Water supply and demand reach a balance on the recent level of production, but loss ofevaporation and evapotranspiration is as much as 25. 69 x 1010~8m^3. So net use efficiency of waterresources is 59% Based on analyzing balance between water and land considering ecologicalenvironment at present, there exists the serious water shortage in the Shiyang River system whereirrigation lands have overloaded. There is a comparative balance between supply and demand of waterresource in the Heihe River system; and the Sule River system has some surplus water to extendirrigation land. Use of agriculture water accounts for 83. 3% and ecological forest and grass for 6.9% . The Hexi Corridor still has a great potential for water saving in agriculture production.Water-saving efficiency of irrigation is about 10% by using such traditional technologies as furrowand border-dike irrigation and small check irrigation, and water-saving with plastic film cover andtechniques of advanced sprinkler and drip/micro irrigation etc. can save more than 60% of irrigatedwater. Incremental irrigation area for water-saving potential in the Hexi Corridor has beenestimated as 56% - 197% to original irrigation area. So the second water sources can be developedfrom water saving agriculture in the Hexi Corridor under Development of the Western Part of China inlarge scale. This potential can be realized step by step through developing the water-savingmeasures, improving the ecological condition of oasis agriculture, and optimizing allocation ofwater resources in three river systems.

Soil Water Balance Measurement in Field Scale

A 5-year experiment on water balance has been conducted in a flat rainfed wheat field with an area of 66 × 100 m2 in Fengqiu, Henan Province in China. Based on the analysis of semi-variance functions conducted with soil moisture samples taken from 77 nodes of a 10 × 10m2 grid, the soil moisture distribution in the field was structural with a temporal stability. According to the autocorrelation range of the semi-variance function, S sites were selected for the determination of soil water conditions. The characteristic of probability density function of the differences of water storage in two sets of measurements showed that the distribution of these variables in the field was a normal one. The error in the estimation of the average of S random samples was 14% (α = 0.10), and the errors of water consumption by wheat during the experiments were estimated to be 6-13%.Since the experimental field was large enough to avoid any edge effect, the results obtained should tally with the actual situation. Yet the soil system was heterogeneous, so we must follow the principles of statistics and geostatistics when describing the system 's status with the average of the samples.

Influence of Potential Evapotranspiration on the Water Balance of Sugarcane Fields in Maui, Hawaii

The year-long warm temperatures and other climatic characteristics of the Pacific Ocean Islands have made Hawaii an optimum place for growing sugarcane;however, irrigation is essential to satisfy the large water demand of sugarcane. Under the Hawaiian tropical weather, actual evapotranspiration (AET) is the primary mechanism by which water is removed from natural and agricultural systems. The Hawaiian Commercial and Sugar Company (HC&S), the largest sugarcane grower of the Hawaiian Islands, has developed a locally optimized AET equation for the purpose of water management on its 184.3 km2 sugarcane plantation on the Island of Maui. In this paper, in order to assess the influence of AET on the hydrological water balance of the HC&S’ sugarcane cropping system, the performance of the HC&S method was compared with three physically-based methods: Penman-Monteith, Priestley-Taylor, and Hargreaves, as well as, to a set of historical pan evaporation data. A Soil and Water Assessment Tool (SWAT) project was setup to estimate the water balance in two sugarcane fields: a windy lowland field and a rocky highland field on a hill slope. Under Hawaiian weather conditions, wind speed was found to be the most influential climatic parameter over potential evapotranspiration (PET);therefore, the results with both Hargreaves and Priestley-Taylor underpredicted PET by approximately 30%, presumably because these methods do not take wind speed into account. The HC&S method was demonstrated to be the most accurate PET method compared to the other commonly used PET equations, with less than 10% error. Of the annual total water supply of 3400 mm, AET accounted for 75% - 80% of the total water consumption. These findings can be used to improve the irrigation efficiency as well as other management scenarios to optimize water use on the Island of Maui.

AN ANALYSIS OF THREE ELEMENTS OF WATER BALANCE IN THE CHANGJIANG RIVER BASIN

The general trend of three elements (precipitation, runoff and evaporation) of the water balance of the Changjiang River Basin is discussed from the regional distribution of the mean annual values of view, i.e. isogram. The distribution of precipitation is non-uniform. The distribution of runoff mainly supplied from precipitation is more uniform than that of precipitation. The distribution of the evaporation from land is much more uniform than that of precipitation and runoff. Time distribution of these three elements shows the characteristics of comparatively distinct yearly variation and few variation between years. The relationship between precipitation and runoff, and between precipitation and evaporation in the humid region in the Changjiang River is analyzed. The slopes of their straight line correlation are nearly equal. The internal relationship between variables should be paid attention to, otherwise, a pseudo correlation may be resulted in. The paper provides the method of quantitative

Thermodynamic Evaluation of Mineral Balance in Water Thickness of the Soda Lake Doroninskoe(Eastern Transbaikalia,Russia)

In recent years,lakes,including salted,attract the attention of researchers,also when reconstructing last climate changes using the bottom sediments(Solotchina et al.,2008,et al.).In this case the different geochemical