A Hydrogen Iron Flow Battery with High Current Density and Long Cyclability Enabled Through Circular Water Management

The hydrogen-iron(HyFe)flow cell has great potential for long-duration energy storage by capitalizing on the advantages of both electrolyzers and flow batteries.However,its operation at high current density(high power)and over continuous cycling testing has yet to be demonstrated.In this paper,we discuss our design and demonstration of a water management strategy that supports high current and long cycling performance of a HyFe flow cell.Water molecules associated with the movement of protons from the iron electrode to the hydrogen electrode are sufficient to hydrate the membrane and electrode at a low current density of 100 mA cm^(-2)during the charge process.At higher charge current density,more aggressive measures must be taken to counter back-diffusion driven by the acid concentration gradient between the iron and hydrogen electrodes.Our water management approach is based on water vapor feeding in the hydrogen electrode,and water evaporation in the iron electrode,thus enabling the high current density operation of 300 mA cm^(-2).

Recent advances in design of hydrogen evolution reaction electrocatalysts at high current density:A review

The electrolysis of water powered by renewable energy sources offers a promising method of"green hydrogen"production,which is considered to be at the heart of future carbon-neutral energy systems.In the past decades,researchers have reported a number of hydrogen evolution reaction(HER)electrocatalysts with activity comparable to that of commercial Pt/C,but most of them are tested within a small current density range,typically no more than 500 mA cm^(-2).To realize the industrial application of hydrogen production from water electrolysis,it is essential to develop high-efficiency HER electrocatalysts at high current density(HCD≥500 mA cm^(-2)).Nevertheless,it remains challenging and significant to rational design HCD electrocatalysts for HER.In this paper,the design strategy of HCD electrocatalysts is discussed,and some HCD electrocatalysts for HER are reviewed in seven categories(alloy,metal oxide,metal hydroxide,metal sulfide/selenide,metal nitride,metal phosphide and other derived electrocatalysts).At the end of this article,we also pro-pose some viewpoints and prospects for the future development and research directions of HCD electrocatalysts for HER.

Analysis of thermohaline and current distribution characteristics of Zhejiang and Fujian waters in summer

This paper analyzed the distribution of thermohaline and circulation characteristics of Zhejiang and Fujian waters,based on the cross-sectional thermohaline data and on current data （up to 30 d duration） at fixed-point moorings,collected in the summer of 2006.We also performed low-pass filtering and spectrum analysis on the mooring submersible buoy data.Based on that analysis,we discussed the characteristics of low frequency currents and time-variations in these waters.The main conclusions are as follows.（1） There is a low salinity pinnate area near the Hangzhou Bay in summer,and outside the low salinity area,an obvious salinity front is present from surface to bottom near 123 E.There is also a temperature front below the surface at a corresponding position.（2） Bottom water of the Taiwan Warm Current comes from the subsurface of Kuroshio.（3） The direction of low frequency current at fixed anchor stations is N-NE or S,which mainly depends on the interaction of control currents in this waters.（4） Significant spectral peaks at all mooring stations are typically semidiurnal and diurnal tides.Semidiurnal tidal waves are the main ones in these waters,and have more energy closer to the shore.（5） Significant energy spectral peaks of middle period （3 to 8 d） of currents are responses to weather frequency.（6） Significant energy spectral peaks of long periods at the surface or bottom are probably responses to seasonal wind or bottom friction,while,the long period peaks of other depths can reflect cyclical changes of interactions between currents.We conclude that the pulsation period of the Taiwan Warm Current in these waters is 10-17 d.

N‑Doped Graphene‑Decorated NiCo Alloy Coupled with Mesoporous NiCoMoO Nano‑sheet Heterojunction for Enhanced Water Electrolysis Activity at High Current Density

Developing highly effective and stable non-noble metalbased bifunctional catalyst working at high current density is an urgent issue for water electrolysis(WE).Herein,we prepare the N-doped graphene-decorated NiCo alloy coupled with mesoporous NiCoMoO nano-sheet grown on 3D nickel foam(NiCo@C-NiCoMoO/NF)for water splitting.NiCo@C-NiCoMoO/NF exhibits outstanding activity with low overpotentials for hydrogen and oxygen evolution reaction(HER:39/266 mV;OER:260/390 mV)at±10 and±1000 mA cm^(−2).More importantly,in 6.0 M KOH solution at 60℃ for WE,it only requires 1.90 V to reach 1000 mA cm−2 and shows excellent stability for 43 h,exhibiting the potential for actual application.The good performance can be assigned to N-doped graphene-decorated NiCo alloy and mesoporous NiCoMoO nano-sheet,which not only increase the intrinsic activity and expose abundant catalytic activity sites,but also enhance its chemical and mechanical stability.This work thus could provide a promising material for industrial hydrogen production.

The patterns of surface capillary-gravity short-crested waves with uniform current fields in coastal waters

A fully three-dimensional surface gravitycapillary short-crested wave system is studied as two progressive wave-trains of equal amplitude and frequency, which are collinear with uniform currents and doubly-periodic in the horizontal plane, are propagating at an angle to each other. The first- and second-order asymptotic analytical solutions of the short-crested wave system are obtained via a perturbation expansion in a small parameter associated with the wave steepness, therefore depicting a series of typical three-dimensional wave patterns involving currents, shallow and deep water, and surface capillary waves, and comparing them with each other.

Seasonal variation of the Taiwan Warm Current Water and its underlying mechanism

Based on the historical observed data and the modeling results,this paper investigated the seasonal variations in the Taiwan Warm Current Water(TWCW)using a cluster analysis method and examined the contributions of the Kuroshio onshore intrusion and the Taiwan Strait Warm Current(TSWC)to the TWCW on seasonal time scales.The TWCW has obviously seasonal variation in its horizontal distribution,T-S characteristics and volume.The volume of TWCW is maximum(13746 km^3)in winter and minimum(11397 km^3)in autumn.As to the contributions to the TWCW,the TSWC is greatest in summer and smallest in winter,while the Kuroshio onshore intrusion northeast of Taiwan Island is strongest in winter and weakest in summer.By comparison,the Kuroshio onshore intrusion make greater contributions to the Taiwan Warm Current Surface Water(TWCSW)than the TSWC for most of the year,except for in the summertime(from June to August),while the Kuroshio Subsurface Water(KSSW)dominate the Taiwan Warm Current Deep Water(TWCDW).The analysis results demonstrate that the local monsoon winds is the dominant factor controlling the seasonal variation in the TWCW volume via Ekman dynamics,while the surface heat fl ux can play a secondary role via the joint ef fect of baroclinicity and relief.

Assimilation of surface currents into a regional model over Qingdao coastal waters of China

Surface currents measured by high frequency （HF） radar arrays are assimilated into a regional ocean model over Qingdao coastal waters based on Kalman filter method. A series of numerical experiments are per- formed to evaluate the performance of the data assimilation schemes. In order to optimize the analysis pro- cedure in the traditional ensemble Kalman filter （ENKF）, a different analysis scheme called quasiensemble Kaman filter （QENKF） is proposed. The comparisons between the ENKF and the QENKF suggest that both them can improve the simulated error and the spatial structure. The estimations of the background error covariance （BEC） are also assessed by comparing three different methods： Monte Carlo method; Canadian quick covariance （CQC） method and data uncertainty engine （DUE） method. A significant reduction of the root-mean-square （RMS） errors between model results and the observations shows that the CQC method is able to better reproduce the error statistics for this coastal ocean model and the corresponding external forcing. In addition, the sensibility of the data assimilation system to the ensemble size is also analyzed by means of different scales of the ensemble size used in the experiments. It is found that given the balance of the computational cost and the forecasting accuracy, the ensemble size of 50 will be an appropriate choice in the Qingdao coastal waters.

Numerical study on water waves and wave-induced longshore currents in Obaky coastal water

In this paper, the water waves and wave-induced longshore currents in Obak6y coastal water which is located at the Mediterranean coast of Turkey were numerically studied. The numerical model is based on the parabolic mild-slope equation for coastal water waves and the nonlinear shallow water equation for the wave-induced currents. The wave transformation under the effects of shoaling, refraction, diffraction and breaking is considered, and the wave provides radiation stresses for driving currents in the model. The numerical results for the water wave-induced longshore currents were validated by the measured data to demonstrate the efficiency of the numerical model. Then the water waves and longshore currents induced by the waves from main directions were numerically simulated and analyzed based on the numerical results. The numerical results show that the movement of the longshore currents was different while the wave proDaRated to a coastal zone from different directions.

Kuroshio warm filament and the source of the warm water of the Tsushima Current

Characteristics and evolution of the Kuroshio frontal eddies and warm filaments are analyzed according to two series of satellite images (March 5 to 7, 1986 and April 14 to 16, 1988). The results show that the frontal eddies in the East China Sea are generated at the shelf break and move along the continental slope at a speed of 15 cm/s with the Kuroshio. The frontal eddies occur about every 10 d and evolve to be warm filaments a few hundred km in length and 30-40 km in width in the area west of the Yaku-shima. Meanwhile, the existence of the warm filament was also found in the area by analysing the hydrographic data in the area west of Kyushu during May 24-June 5, 1988.The Kuroshio warm filaments move westward opposite to the Kuroshio and then turn northward at the shelf break and become the main source of the warm water of the Tsushima Warm Current. A simple dynamic explanation for the process is presented in this paper.

Water Dissociation Phenomena on a Bipolar Membrane──Current-voltage Curve in Relation with IonicTransport and Limiting Current Density

The water dissociation mechanism on a bipolar membrane under the electrical field was investigated and characterized in terms of ionic transport and limiting current density. It is considered that the depletion layer exists at the junction of a bipolar membrane, which is coincided with the viewpoint of the most literatures, but we also consider that the thickness and conductivity of this layer is not only related with the increase of the applied voltage but also with the limiting current density. Below the limiting current density, the thickness of the depletion layer keeps a constant and the conductivity decreases with the increase of the applied voltage; while above the limiting current density, the depletion thickness will increase with the increase of the applied voltage and the conductivity keeps a very low constant. Based on the data reported in the literatures and independent determinations, the limiting current density was calculated and the experimental curves Ⅰ-Ⅴ in the two directions were com

On the origin of the Tsushima Warm Current Water

The origin of the Tsushima Warm Current Water(TWCW) in summer is studied mainly on the basis of the CTD data and the observations of satellite-traced surface drifters of Coastal Ocean Process Experiment of the East China Sea(COPEX-ECS) conducted by Korea Ocean Research and Development Institute. The main results are as follows: (1) The structures of the TWCW show obvious regional varitaions. The TWCW can be divided into three layers in the northern Okinawa Trough west of Kyushu and into two layers on the continental shelf and in the Tsushima/Korea Strait. (2) The surface TWCW, charactered by a sub-high salinity (33. 5～ 34. 10), comes mainly from the coastal water composed largely of the Changjiang Diluted Water, the surface Kuroshio water and the shelf water in the area south of the East China Sea (ECS). (3) The middle TWCW is sub-grouped into two parts: the water of salinity (S) larger than 34. 50 located below the thermocline originates from the climbed sub-surface Kuroshio water;the TWCW lying in the thermocline is a mixture of the Kuroshio water and the shelf water with low salinity. (4) In the strait, the water from the source area is denatured obviously due to mixing unceasingly wth the shelf water and coastal water. The high salinity water of S >34. 5 appears only in the bottom layer with depths>50m.

Current Situation and Comprehensive Control Measures of Water Environment in the Chaohu Lake

Based on the analysis of current situation of water environment in the Chaohu Lake,general ideas and measures of controlling the water environment were proposed. In respect of control ideas,controlling outbreaks of blue-green algae should be as one of control goals; it is needed to combine reducing the quantity of blue-green algae with decreasing eutrophication level to make the decrease in the quantity of blue-green algae larger than their natural increase until outbreaks of blue-green algae are eliminated; all kinds of techniques should be combined closely,integrated and innovated,and corresponding safeguard measures should be adopted. In respect of control measures,controlling sources of pollution and intercepting pollutants are basic measures,of which improving sewage treatment capacity and standard greatly is a key measure,and actively controlling pollution from large-scale livestock and poultry breeding is one of main measures; rivers polluted heavily should be controlled,and using microorganisms to purify small and moderate rivers can be as one of preferred techniques; blue-green algae should be dredged deeply to reducing their quantity; water should be transferred from the Yangtze River to the Chaohu Lake or the Hauihe River to purify water bodies and increase environmental capacity; reed wetland should be restored on a large scale to increase vegetation coverage from 5% to 20%; dredging should be combined with the elevation of basement of restored reed wetland.

On the Taiwan Warm Current Water

Using our data from special observation in the source area of the Taiwan Warm Current from 19S2 to 1985) and historical data, the authors conducted studies to clarify the temperature and salinity characteristics, variability, and origin of the Taiwan Warm Current Water, and its influence on the expanding direction of the Changjiang Diluted Water.The main results of these studies are briefly given below. (1) The Taiwan Warm Current Water can be divided into two parts:the Surface Water of the Taiwan Warm Current and the Deep Water of the Taiwan Warm Current; the former is formed due to the mixing of the Kuroshio Surface Water flowing northward along the east coast of Taiwan with the Taiwan Strait Water; the latter completed originates from Kuroshio Subsurface Water to the east of Taiwan. It is characterized by lower temperature and higher salinity in summer and the characteristics of temperature and salinity are more stable. The maximum seasonal variational range and maximum secular variational range of

Effects of wave-current interaction on the waves, cold-water mass and transport of diluted water in the Beibu Gulf

Wave-current interaction and its effects on the hydrodynamic environment in the Beibu Gulf(BG) have been investigated via employing the Coupled Ocean–Atmosphere–Wave–Sediment Transport(COAWST) modeling system. The model could simulate reasonable hydrodynamics in the BG when validated by various observations.Vigorous tidal currents refract the waves efficiently and make the seas off the west coast of Hainan Island be the hot spot where currents modulate the significant wave height dramatically. During summer, wave-enhanced bottom stress could weaken the near-shore component of the gulf-scale cyclonic-circulation in the BG remarkably, inducing two major corresponding adjustments: Model results reveal that the deep-layer cold water from the southern BG makes critical contribution to maintaining the cold-water mass in the northern BG Basin.However, the weakened background circulation leads to less cold water transported from the southern gulf to the northern gulf, which finally triggers a 0.2℃ warming in the cold-water mass area;In the top areas of the BG, the suppressed background circulation reduces the transport of the diluted water to the central gulf. Therefore, more freshwater could be trapped locally, which then triggers lower sea surface salinity(SSS) in the near-field and higher SSS in the far-field.

Evaluation of flow regime of turbidity currents entering Dez Reservoir using extended shallow water model

In this study, the performance of the extended shallow water model （ESWM） in evaluation of the flow regime of turbidity currents entering the Dez Reservoir was investigated. The continuity equations for fluid and particles and the Navier-Stokes equations govern the entire flow of turbidity currents. The shallow water equations governing the flow of the depositing phase of turbidity currents are derived from these equations. A case study was conducted on the flow regime of turbidity currents entering the Dez Reservoir in Iran from January 2002 to July 2003. Facing a serious sedimentation problem, the dead storage of the Dez Reservoir will be full in the coming 10 years, and the inflowing water in the hydropower conduit system is now becoming turbid. Based on the values of the dimensionless friction number （ Nf ≤1 ） and dimensionless entrainment number （ NE≤ 1 ） of turbidity currents, and the coefficient of determination between the observed and predicted deposit depths （R2 = 0.86） for the flow regime of negligible friction and negligible entrainment （NFNE）, the flow regime of turbidity currents coming into the Dez Reservoir is considered to be NFNE. The results suggest that the ESWM is an appropriate approach for evaluation of the flow regime of turbidity currents in dam reservoirs where the characteristics of turbidity currents, such as the deposit depth, must be evaluated.

MIXED FINITE ELEMENT METHODS FOR THE SHALLOW WATER EQUATIONS INCLUDING CURRENT AND SILT SEDIMENTATION (Ⅱ)——THE DISCRETE-TIME CASE ALONG CHARACTERISTICS

The mixed finite element(MFE) methods for a shallow water equation system consisting of water dynamics equations,silt transport equation,and the equation of bottom topography change were derived.A fully discrete MFE scheme for the discrete_time along characteristics is presented and error estimates are established.The existence and convergence of MFE solution of the discrete current velocity,elevation of the bottom topography,thickness of fluid column,and mass rate of sediment is demonstrated.

MIXED FINITE ELEMENT METHODS FOR THE SHALLOW WATER EQUATIONS INCLUDING CURRENT AND SILT SEDIMENTA-TION (Ⅰ)-THE CONTINUOUS-TIME CASE

An initial-boundary value problem for shallow equation system consisting of water dynamics equations,silt transport equation, the equation of bottom topography change,and of some boundary and initial conditions is studied, the existence of its generalized solution and semidiscrete mixed finite element(MFE) solution was discussed, and the error estimates of the semidiscrete MFE solution was derived.The error estimates are optimal.

Strong electronic coupling of CoNi and N-doped-carbon for efficient urea-assisted H2 production at a large current density

Exploiting efficient urea oxidation reaction(UOR)and hydrogen evolution reaction(HER)catalysts are significant for energy-saving H2 production through urea-assisted water electrolysis,but it is still challenging.Herein,carbon-encapsulated CoNi coupled with CoNiMoO(CoNi@CN-CoNiMoO)is prepared by solvothermal method and calcination to enhance the activity/stability of urea-assisted water electrolysis at large current density.It exhibits good activity for UOR(E10/1,000=1.29/1.40 V)and HER(E-10/-1000=-45/-245 mV)in 1.0 M KOH+0.5 M urea solution.For the UOR||HER system,CoNi@CN-CoNiMoO only needs 1.58 V at 500 mA cm-2 and shows good stability.Density functional theory calculation suggests that the strong electronic interaction at the interface between NiCo alloy and N-doping-carbon layers can optimize the adsorption/desorption energy of UOR/HER intermediates and accelerate the water dissociation,which can expedite urea decomposition and Volmer step,thus increasing the UOR and HER activity,respectively.This work provides a new solution to design UOR/HER catalysts for H2 production through urea-assisted water electrolysis.

Combined refraction and diffraction models for sea waves over complicated topography and with currents in shallow water

-Combined refraction and diffraction models in the form of linear parabolic approximation are derived through smallparameter method. More strictly theoretical basis and more accuracy in the models than Lozano's (1980) are obtained. Some theoretical defects in Liu's model (1985) with consideration of current are not only found but also eliminated. More strict and accurate models are, therefore, presented in this paper.The calculation results and analysis in applying the models to actual wave field with consideration of bottom friction will be given in the following paper.

A study on the source of the Tsushima Warm Current water

On the basis of the hydrographic data in the area west of Kyushu from four cruises of R/V Xiangyanghong No. 9 from 1987 to 1988 , the circulation features in the investigation area are described and the source of the Tsushima Warm Current water (TWCW) is explored by using the observed and geostrophic current results and tracking the Kuroshio Subsurface High Salinity Core (KSHSC).