To establish an analytical method for determination of four bisphenols (BPA, BPB, BPF, and BPS) and two alkylphenols (4-n-OP, 4-n-NP) in water by ultra performance liquid chromatography- tandem mass spectrometry ...To establish an analytical method for determination of four bisphenols (BPA, BPB, BPF, and BPS) and two alkylphenols (4-n-OP, 4-n-NP) in water by ultra performance liquid chromatography- tandem mass spectrometry (UPLC/MS/MS). The water samples were extracted and condensed with solid-phase extraction (SPE) using C18 cartridges and eluted by acetonitrile. Separation was carried out with Acquity BEH C8 column and detection were performed by UPLC/MS/MS. Quantification was calculated by using the internal standard BPA-d16 and 4-n-NP-d8. The linear correlation coefficients of these compounds in the range of 1.0-100.0μg/L were all over 0.999. The minimum detectable concentrations were 0.75-1.0 ng/L, and the recoveries ranged from 87.0% to 106.9%.展开更多
The relation between seed viability and waterstatus in seed was studied.The experimentwas carried out at Zhongshan University.Seeds of hybrid rice Shanyou 63 were collectedfrom Guangdong Academy of Agriculture Sci-enc...The relation between seed viability and waterstatus in seed was studied.The experimentwas carried out at Zhongshan University.Seeds of hybrid rice Shanyou 63 were collectedfrom Guangdong Academy of Agriculture Sci-ences in 1993 and then stored for one year inopen air or with silica gel.Before and afterstorage,the relative content of free water andbound water in seeds were measured with展开更多
On-line ion-exchange separation and preconcentration were combined with flow-injection hydride generation atomic absorption spectrometry (HGAAS) to determine ultra-trace amounts of antimony in water samples. Antimony(...On-line ion-exchange separation and preconcentration were combined with flow-injection hydride generation atomic absorption spectrometry (HGAAS) to determine ultra-trace amounts of antimony in water samples. Antimony(Ⅲ) was preconcentrated on a micro-column packed with CPG-8Q chelating ion-exchanger using time-based sample loading and eluted by 4 mol l^(-1) HCl directly into the hydride generation AAS system. A detection limit (3σ) of 0.0015μg l^(-1) Sb(Ⅲ) was obtained on the basis of a 20 fold enrichment and with a sampling frequency of 60h^(-1). The precision was 1.0% r.s.d.(n=11) at the 0.5μg l^(-1) Sb(Ⅲ) level. Recoveries for the analysis of antimony in tap water, snow water and sea water samples were in the range 97-102%.展开更多
A new rapid method for the analysis of chromate ion in water by using high performance capillary electrophoresis is described. The detection limit is 1.0 mu g/ml by using 100 m mol/l Tris-HCl buffer containing 2 m mol...A new rapid method for the analysis of chromate ion in water by using high performance capillary electrophoresis is described. The detection limit is 1.0 mu g/ml by using 100 m mol/l Tris-HCl buffer containing 2 m mol/l 1,6-hexanediamine which was used as an electroosmosis modifier to improve the separation and detection sensitivity.展开更多
The indirect voltammetric determination of trace sulfate (2.0×10^(-6)~4.0×10^(-5) mol/L ) with the adsorptive complex wave of lead(Ⅱ)-tetrakis (4-trimethylammonium phenyl) porphyrin (PbTTMAPP) is reported....The indirect voltammetric determination of trace sulfate (2.0×10^(-6)~4.0×10^(-5) mol/L ) with the adsorptive complex wave of lead(Ⅱ)-tetrakis (4-trimethylammonium phenyl) porphyrin (PbTTMAPP) is reported.This method has been used for the analysis of natural waters with satisfactory results.展开更多
A highly sensitive and fairly selective spectrofluorimetric method has been developed for the determination of germanium with morin in tap water and health drink. The fluorescent reaction and optimal conditions of ger...A highly sensitive and fairly selective spectrofluorimetric method has been developed for the determination of germanium with morin in tap water and health drink. The fluorescent reaction and optimal conditions of germanium with morin in phosphoric acid medium were studied. The detection limits of germanium in tap water and health drink were found to be 0.2 and 0.7μd/L respectively.展开更多
We present a method by which to determine the bulk viscosity of water from pulse duration measurements of stimulated Brillouin scattering (SBS). Beginning from a common model of Brillouin scattering, the bulk viscos...We present a method by which to determine the bulk viscosity of water from pulse duration measurements of stimulated Brillouin scattering (SBS). Beginning from a common model of Brillouin scattering, the bulk viscosity is shown to play an important role in Brillouin linewidth determination. Pulse durations of SBS back-reflected optical pulses are measured over the temperature range of 5-40℃. SBS linewidths are de- termined via Fourier transformation of the time-domain results, and the bulk viscosity of water is measured and derived from the obtained values. Our results show that the proposed method for measurement of pulse durations is an effective approach for determining bulk viscosity. The method can be easily extended to determine bulk viscosities of other Newtonian liquids.展开更多
A new temporal gravity field model called WHU-Grace01s solely recovered from Gravity Recovery and Climate Experiment (GRACE) K-Band Range Rate (KBRR) data based on dynamic integral approach is presented in this pa...A new temporal gravity field model called WHU-Grace01s solely recovered from Gravity Recovery and Climate Experiment (GRACE) K-Band Range Rate (KBRR) data based on dynamic integral approach is presented in this paper. After meticulously preprocessing of the GRACE KBRR data, the root mean square of its post residuals is about 0.2 micrometers per second, and seventy-two monthly temporal solutions truncated to degree and order 60 are computed for the period from January 2003 to December 2008. After applying the combi- nation filter in WHU-Grace01s, the global temporal signals show obvious periodical change rules in the large-scale fiver basins. In terms of the degree variance, our solution is smaller at high degrees, and shows a good consistency at the rest of degrees with the Release 05 models from Center for Space Research (CSR), GeoForschungsZentrum Potsdam (GFZ) and Jet Pro- pulsion Laboratory 0PL). Compared with other published models in terms of equivalent water height distribution, our solution is consistent with those published by CSR, GFZ, JPL, Delft institute of Earth Observation and Space system (DEOS), Tongji University (Tongji), Institute of Theoretical Geodesy (ITG), Astronomical Institute in University of Bern (AIUB) and Groupe de Recherche de Geodesie Spatiale (GRGS}, which indicates that the accuracy of WHU-Grace01s has a good consistency with the previously published GRACE solutions.展开更多
A new highly sensitive method for determination of trace silver in waste water with 9,10- dimethylacridinium fluorosulfonate (DAFA)-K_2S_2O_3, system was suggested. In the basic aqueous so- lution, trace of silver (I)...A new highly sensitive method for determination of trace silver in waste water with 9,10- dimethylacridinium fluorosulfonate (DAFA)-K_2S_2O_3, system was suggested. In the basic aqueous so- lution, trace of silver (I) showed strongly catalytic effect on the chemiluminescence system with the pre- sence of 2,2'-bipyridine. The range of the linear relationship between light intensity and concen- tration of silver (I) is 1.0×10^(-3)mol / L to 6.0×10^(-6) mol / L. The detection limit is 8.0×10^(-9)mol / L, and the RSD for 5.0×10^(-8) mol / LAg (I) is 6.5% (n=13). In the existence of potassium fluoride, the selectivity is higher. Combining the treatment with nitric acid, the method is applied to determine some environmental waste water and the results are similar to atomic absorption spectroscopy.展开更多
Bottled water consumption is increasing worldwide, despite its huge economic and environmental cost. We aim to describe personal and tap water quality determinants of bottled water use in the city of Barcelona. This c...Bottled water consumption is increasing worldwide, despite its huge economic and environmental cost. We aim to describe personal and tap water quality determinants of bottled water use in the city of Barcelona. This cross-sectional study used data from the Health Survey of Barcelona in 2006(N = 5417 adults). The use of bottled water to drink and to cook was evaluated in relation to age, gender, educational level, district and levels of trihalomethanes(THMs), free chlorine, conductivity, chloride, sodium, p H, nitrate and aluminium in municipal tap water using Robust Poisson Regression. The prevalence of bottled water use to drink and cook was 53.9% and 6.7%, respectively. Chemical parameters in water had a large variability(interquartile range of THMs concentrations: 83.2–200.8 μg/L)and were correlated between them, except aluminium. Drinking bottled water increased with educational level, while cooking with bottled water was higher among men than among women and decreased with age. After adjusting by these personal determinants, a dose–response relationship was found between concentrations of all chemicals except aluminium in tap water and bottled water use. The highest association was found for THMs,with a Prevalence Ratio of 2.00(95%CI = 1.86, 2.15) for drinking bottled water and 2.80(95%CI = 1.72, 4.58) for cooking with bottled water, among those with 〉 150 μg/L vs. 〈 100 μg/L THMs in tap water. Conclusion: More than half of Barcelona residents regularly drank bottled water, and the main determinant was the chemical composition of tap water,particularly THM level.展开更多
基金supported by the Preventive medicine and public health research project of Anhui,China(No.2011Y0103)the Natural Science Foundation of Anhui,China(No.11040606M216)
文摘To establish an analytical method for determination of four bisphenols (BPA, BPB, BPF, and BPS) and two alkylphenols (4-n-OP, 4-n-NP) in water by ultra performance liquid chromatography- tandem mass spectrometry (UPLC/MS/MS). The water samples were extracted and condensed with solid-phase extraction (SPE) using C18 cartridges and eluted by acetonitrile. Separation was carried out with Acquity BEH C8 column and detection were performed by UPLC/MS/MS. Quantification was calculated by using the internal standard BPA-d16 and 4-n-NP-d8. The linear correlation coefficients of these compounds in the range of 1.0-100.0μg/L were all over 0.999. The minimum detectable concentrations were 0.75-1.0 ng/L, and the recoveries ranged from 87.0% to 106.9%.
文摘The relation between seed viability and waterstatus in seed was studied.The experimentwas carried out at Zhongshan University.Seeds of hybrid rice Shanyou 63 were collectedfrom Guangdong Academy of Agriculture Sci-ences in 1993 and then stored for one year inopen air or with silica gel.Before and afterstorage,the relative content of free water andbound water in seeds were measured with
文摘On-line ion-exchange separation and preconcentration were combined with flow-injection hydride generation atomic absorption spectrometry (HGAAS) to determine ultra-trace amounts of antimony in water samples. Antimony(Ⅲ) was preconcentrated on a micro-column packed with CPG-8Q chelating ion-exchanger using time-based sample loading and eluted by 4 mol l^(-1) HCl directly into the hydride generation AAS system. A detection limit (3σ) of 0.0015μg l^(-1) Sb(Ⅲ) was obtained on the basis of a 20 fold enrichment and with a sampling frequency of 60h^(-1). The precision was 1.0% r.s.d.(n=11) at the 0.5μg l^(-1) Sb(Ⅲ) level. Recoveries for the analysis of antimony in tap water, snow water and sea water samples were in the range 97-102%.
文摘A new rapid method for the analysis of chromate ion in water by using high performance capillary electrophoresis is described. The detection limit is 1.0 mu g/ml by using 100 m mol/l Tris-HCl buffer containing 2 m mol/l 1,6-hexanediamine which was used as an electroosmosis modifier to improve the separation and detection sensitivity.
文摘The indirect voltammetric determination of trace sulfate (2.0×10^(-6)~4.0×10^(-5) mol/L ) with the adsorptive complex wave of lead(Ⅱ)-tetrakis (4-trimethylammonium phenyl) porphyrin (PbTTMAPP) is reported.This method has been used for the analysis of natural waters with satisfactory results.
文摘A highly sensitive and fairly selective spectrofluorimetric method has been developed for the determination of germanium with morin in tap water and health drink. The fluorescent reaction and optimal conditions of germanium with morin in phosphoric acid medium were studied. The detection limits of germanium in tap water and health drink were found to be 0.2 and 0.7μd/L respectively.
基金supported by the National Natural Sci-ence Foundation of China under Grants Nos.41206084 and 61177096
文摘We present a method by which to determine the bulk viscosity of water from pulse duration measurements of stimulated Brillouin scattering (SBS). Beginning from a common model of Brillouin scattering, the bulk viscosity is shown to play an important role in Brillouin linewidth determination. Pulse durations of SBS back-reflected optical pulses are measured over the temperature range of 5-40℃. SBS linewidths are de- termined via Fourier transformation of the time-domain results, and the bulk viscosity of water is measured and derived from the obtained values. Our results show that the proposed method for measurement of pulse durations is an effective approach for determining bulk viscosity. The method can be easily extended to determine bulk viscosities of other Newtonian liquids.
基金supported by the National 973Program of China(2013CB733302)the National Natural Science Foundation of China(41131067,41174020,41374023,41474019)+2 种基金the Open Research Fund Program of the State Key Laboratory of Geodesy and Earth's Dynamics(SKLGED2015-1-3-E)the open fund of State Key Laboratory of Geographic Information Engineering(SKLGIE2013-M-1-3)the open fund of Key Laboratory of Geospace Environment and Geodesy,Ministry of Education(13-02-05)
文摘A new temporal gravity field model called WHU-Grace01s solely recovered from Gravity Recovery and Climate Experiment (GRACE) K-Band Range Rate (KBRR) data based on dynamic integral approach is presented in this paper. After meticulously preprocessing of the GRACE KBRR data, the root mean square of its post residuals is about 0.2 micrometers per second, and seventy-two monthly temporal solutions truncated to degree and order 60 are computed for the period from January 2003 to December 2008. After applying the combi- nation filter in WHU-Grace01s, the global temporal signals show obvious periodical change rules in the large-scale fiver basins. In terms of the degree variance, our solution is smaller at high degrees, and shows a good consistency at the rest of degrees with the Release 05 models from Center for Space Research (CSR), GeoForschungsZentrum Potsdam (GFZ) and Jet Pro- pulsion Laboratory 0PL). Compared with other published models in terms of equivalent water height distribution, our solution is consistent with those published by CSR, GFZ, JPL, Delft institute of Earth Observation and Space system (DEOS), Tongji University (Tongji), Institute of Theoretical Geodesy (ITG), Astronomical Institute in University of Bern (AIUB) and Groupe de Recherche de Geodesie Spatiale (GRGS}, which indicates that the accuracy of WHU-Grace01s has a good consistency with the previously published GRACE solutions.
文摘A new highly sensitive method for determination of trace silver in waste water with 9,10- dimethylacridinium fluorosulfonate (DAFA)-K_2S_2O_3, system was suggested. In the basic aqueous so- lution, trace of silver (I) showed strongly catalytic effect on the chemiluminescence system with the pre- sence of 2,2'-bipyridine. The range of the linear relationship between light intensity and concen- tration of silver (I) is 1.0×10^(-3)mol / L to 6.0×10^(-6) mol / L. The detection limit is 8.0×10^(-9)mol / L, and the RSD for 5.0×10^(-8) mol / LAg (I) is 6.5% (n=13). In the existence of potassium fluoride, the selectivity is higher. Combining the treatment with nitric acid, the method is applied to determine some environmental waste water and the results are similar to atomic absorption spectroscopy.
文摘Bottled water consumption is increasing worldwide, despite its huge economic and environmental cost. We aim to describe personal and tap water quality determinants of bottled water use in the city of Barcelona. This cross-sectional study used data from the Health Survey of Barcelona in 2006(N = 5417 adults). The use of bottled water to drink and to cook was evaluated in relation to age, gender, educational level, district and levels of trihalomethanes(THMs), free chlorine, conductivity, chloride, sodium, p H, nitrate and aluminium in municipal tap water using Robust Poisson Regression. The prevalence of bottled water use to drink and cook was 53.9% and 6.7%, respectively. Chemical parameters in water had a large variability(interquartile range of THMs concentrations: 83.2–200.8 μg/L)and were correlated between them, except aluminium. Drinking bottled water increased with educational level, while cooking with bottled water was higher among men than among women and decreased with age. After adjusting by these personal determinants, a dose–response relationship was found between concentrations of all chemicals except aluminium in tap water and bottled water use. The highest association was found for THMs,with a Prevalence Ratio of 2.00(95%CI = 1.86, 2.15) for drinking bottled water and 2.80(95%CI = 1.72, 4.58) for cooking with bottled water, among those with 〉 150 μg/L vs. 〈 100 μg/L THMs in tap water. Conclusion: More than half of Barcelona residents regularly drank bottled water, and the main determinant was the chemical composition of tap water,particularly THM level.