Isothermal diffusion of water vapor in unsaturated soils based on Fick’s second law

In arid regions, water vapor diffusion predominates the total water migration in unsaturated soil, which significantly influences agriculture and engineering applications. With the aim of revealing the diffusion mechanism of water vapor in unsaturated soil, a water vapor migration test device was developed to conduct the water vapor migration indoor test. The test results demonstrate that the characteristics of water vapor diffusion in unsaturated soil conformed to Fick’s second law. A mathematical model for water vapor diffusion under isothermal conditions in unsaturated soil was established based on Fick’s law. Factors including the initial moisture content gradient, initial moisture content distribution, soil type and temperature that affect the water vapor diffusion coefficient were analyzed. The results show that there was good agreement between the moisture content calculated by the mathematical model and obtained by the indoor experiment. The vapor diffusion coefficient increased with increasing initial moisture content gradient and temperature. When the initial moisture content gradient is constant, the vapor diffusion coefficient increases with the increase of matrix suction ratio in dry and wet soil section. The effect of soil type on the water vapor diffusion coefficient was complex, as both the moisture content and soil particle sizes affected the water vapor diffusion.