Evaluating the characteristics of geological structures in karst groundwater inflow, Nowsud Tunnel

Highly permeable geological structures such as dissolution channels, open fractures, and faults create environmental challenges regard to hydrological and hydrogeological aspects of underground construction, often causing significant groundwater inflow during drilling due to the limitations of empirical and analytical methods. This study aims to identify the geological factors influencing water flow into the tunnel. High-flow zones' geological features have been identified and examined for this purpose. According to the geological complexity of the Nowsud tunnel, presence of different formations with different permeability and karstification have led to a high volume of underground inflow water (up to 4700 L/s) to the tunnel. The Nowsud tunnel faces significant geological and hydrogeological challenges due to its passage through the Ilam formation's LI2 unit, characterized by dissolution channels, faults, and fractures. The highest inflow rate (4700 L/s) occurred in the Hz-9 zone within the Zimkan anticline. The relationship between geological features and groundwater inflow indicates that anticlines are more susceptible to inflow than synclines. Additionally, different types of faults exhibit varying hydraulic effects, with strike-slip faults having the most significant impact on groundwater inflow, thrust faults conducting less water into the tunnel, and inflow through normal faults being negligible compared to the other two types of faults. The novelty of this paper lies in its detailed analysis of geological features influencing groundwater inflow into the Nowsud tunnel, providing empirical data on high-flow zones and differentiating the hydraulic effects of various fault types, which enhances the understanding and prediction of groundwater inflow in underground constructions.

Bimetallic Single‑Atom Catalysts for Water Splitting

Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society.The field of catalysis has been revolutionized by single-atom catalysts(SACs),which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports.Recently,bimetallic SACs(bimSACs)have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports.BimSACs offer an avenue for rich metal–metal and metal–support cooperativity,potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges,substrate activation with reversible redox cycles,simultaneous multi-electron transfer,regulation of spin states,tuning of electronic properties,and cyclic transition states with low activation energies.This review aims to encapsulate the growing advancements in bimSACs,with an emphasis on their pivotal role in hydrogen generation via water splitting.We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs,elucidate their electronic properties,and discuss their local coordination environment.Overall,we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction,the two half-reactions of the water electrolysis process.

Detection and treatment of water inflow in karst tunnel：A case study in Daba tunnel

In a karst tunnel, fissures or cracks that are filled with weathered materials are a type of potential water outlet as they are easily triggered and converted into groundwater outlets under the influence of high groundwater pressure. A terrible water inrush caused by potential water outlets can seriously hinder the project construction. Potential water outlets and water sources that surrounding the tunnel must be detected before water inflow can be treated. This paper provides a successful case of the detection and treatment of water inflow in a karst tunnel and proposes a potential water outlet detection(PWOD) method in which heavy rainfall(>50 mm/d) is considered a trigger for a potential water outlet. The Daba tunnel located in Hunan province, China, has been constructed in a karst stratum where the rock mass has been weathered intensely by the influence of two faults. Heavy rain triggered some potential water outlets, causing a serious water inrush. The PWOD method was applied in this project for the treatment of water inflow, and six potential water outlets in total were identified through three heavy rains. Meanwhile, a geophysical prospecting technique was also used to detect water sources. The connections between water outlets and water sources were identified with a 3-D graphic that included all of them. According to the distribution of water outlets and water sources, the detection area was divided into three sections and separately treated by curtain grouting.

Seepage field distribution and water inflow laws of tunnels in water-rich regions

Currently,the water inrush hazards during tunnel construction,the water leakage during tunnel operation,and the accompanying disturbances to the ecological environment have become the main problems that affect the structural safety of tunnels in water-rich regions.In this paper,a tunnel seepage model testing system was used to conduct experiments of the grouting circle and primary support with different permeability coefficients.The influences of the supporting structures on the water inflow laws and the distribution of the water pressure in the tunnel were analyzed.With the decrease in the permeability coefficient of the grouting circle or the primary support,the inflow rate of water into the tunnel showed a non-linear decreasing trend.In comparison,the water inflow reduction effect of grouting circle was much better than that of primary support.With the increase of the permeability coefficient of the grouting ring,the water pressure behind the primary lining increases gradually,while the water pressure behind the grouting ring decreases.Thus,the grouting of surrounding rock during the construction of water-rich tunnel can effectively weaken the hydraulic connection,reduce the influence range of seepage,and significantly reduce the decline of groundwater.Meanwhile,the seepage tests at different hydrostatic heads and hydrodynamic heads during tunnel operation period were also conducted.As the hydrostatic head decreased,the water pressure at each characteristic point decreased approximately linearly,and the water inflow rate also had a gradual downward trend.Under the action of hydrodynamic head,the water pressure had an obvious lagging effect,which was not conducive to the stability of the supporting structures,and it could be mitigated by actively regulating the drainage rate.Compared with the hydrostatic head,the hydrodynamic head could change the real-time rate of water inflow to the tunnel and broke the dynamic balance between the water pressure and water inflow rate,thereby affecting the stress state on the supporting structures.

Characteristics and Effects of Inorganic Nitrogen in East Water-source and Inflow Rivers of Chaohu Lake

[Objective] To study the characteristics and effects of inorganic nitrogen in east water-source and inflow rivers of Chaohu Lake. [Method] The speciation and distribution characteristics of dissolvable inorganic nitrogen （DIN） in east water-source and inflow rivers of Chaohu Lake were investigated, and their effects on water qual- ity were examined. [Result] The concentrations of NH3-N and NO2--N were the high in flood season, and low in non-flood season, while the concentration of NO3--N pre- sented the opposite trend; the concentration of NO3--N was the highest in Shuangqiao estuary, where the pollution was the worst. DIN in Zhegao estuary and Xiaozhegao estuary was mainly caused by domestic sewage and industrial wastewaters; surface runoff and pollution from ships contribute the most to the DIN content in Shuangqiao estuary. [Conclusion] This study provided basic data and theoretical basis for the control and management of eutrophication in Chaohu Lake.

Water inflow forecasting for tunnel considering nonlinear variation of permeability coefficient

To assess the water inflow which is more suitable to the actual conditions of tunnel,an empirical correlation about the permeability coefficient changing with depth is introduced.Supposing that the surrounding rock is heterogeneous isotropy,the formula for calculating water inflow of tunnel with the nonlinear variation of permeability coefficient is deduced.By the contrast analysis with the existing formulas,the presented method has the similar value to them;moreover,the presented method has more simple form and easy to use.Due to parameter analysis,the water inflow decreases after considering the nonlinear variation of permeability coefficient.When the attenuation coefficient a>0,the water inflow increases first till reaches the maximum at a certain depth,then decreases and is close to 0 finally if deep enough.Thus,it is better to keep away from the certain depth where it is with the maximum water inflow for safe operation and economical construction,and reduce the water damage.Based on the analysis,the radius of tunnel has less impact on the amount of water inflow,and the water inflow just increases by 6.7% when the radius of tunnel increases by 1 m.

Influence of Ramjets’ Water Inflow on Supercavity Shape and Cavitator Drag Characteristics

Water ramjets using outer water as an oxidizer have been demonstrated as a potential propulsion mode for underwater High Speed Supercavitating Vehicles (HSSVs) because of their higher energy density, power density, and specific impulse, but water flux changes the shapes of supercavity. To uncover the cavitator drag characteristics and the supercavity shape of HSSVs with water inflow for ramjets, supercavitation flows around a disk cavitator with inlet hole are studied using the homogenous model. By changing the water inflow in the range of 0-10 L/s through cavitators having different water inlet areas, a series of numerical simulations of supercavitation flows was performed. The water inflow flux of ramjets significantly influences the drag features of disk cavitators and the supercavity shape, but it has little influence on the slender ratio of supercavitaty. Furthermore, as the water inlet area increases, the drag coefficient of the cavitators' front face decreases, but this increase does not influence the diameter of the supercavity's maximum cross section and the drag coefficient of the entire cavitator significantly. In addition, with increasing waterflux of the ramjet, both the drag coefficient of cavitators and the maximum diameter of supercavities decrease stably. This research will be helpful for layout optimization and supercavitaty scheme design of HSSVs with water inflow for ramjets.

Support Vector Machines(SVM)-Markov Chain Prediction Model of Mining Water Inflow

This study was conducted to establish a Support Vector Machines(SVM)-Markov Chain prediction model for prediction of mining water inflow. According to the raw data sequence, the Support Vector Machines(SVM) model was built, and then revised by means of a Markov state change probability matrix. Through dividing the state and analyzing absolute errors and relative errors and other indexes of the measured value and the fitted value of SVM, the prediction results were improved. Finally,the model was used to calculate relative errors. Through predicting and analyzing mining water inflow, the prediction results of the model were satisfactory. The results of this study enlarge the application scope of the Support Vector Machines(SVM) prediction model and provide a new method for scientific forecasting water inflow in coal mining.

Characteristics of water inflow and chemical grouting treatment of a Liu Yuanzi Coal Mine shaft in the Ordos Basin

During shaft constructing, a borehole water inflow of 30 m3/h was encountered in Liu Yuanzi Coal Mine in the southwestern Ordos Basin, whose aquifer is mainly cretaceous. On the basis of regional hydrogeological conditions, a mercury intrusion method and scanning electron microscope were used in this study. We conclude that the loose, porous and easily collapsible clay particles of the cretaceous aquifer rock mass were the major geological cause for water hazards during the construction of the shaft. We propose an approach of chemical grouting from the working surface and in the end succeeded in blocking the water.

Geochemical characteristics and source analysis of inflow of mine water in Wang’ershan Gold Mine, Shandong

Through a systematic observation of water level and temperature, and a comprehensive analysis of the data on major/trace elements, nitrite, hydrogen-oxygen isotopes, the conclusion has been drawn that there are two relatively independent groundwater systems (cool water and hot water), and the geochemical indicators of hot/cool waters are described. The cool water system is relatively enriched in Ca2+, Mg2+ and HCO3-. Its TDS is relatively low, about 1400–1800 mg/L. The hot water system is relatively enriched in K+, Na+, Cl- and SO42-. Its TDS is relatively high, about 2200–2300 mg/L. The cool water system is enriched in Ba, Ga, Cd, and the hot water system is enriched in B, Ti, Cr, Ni, Cu, Mo, Rb, and Cs, relatively. Especially, the contents of Rb and Cs in the hot water system are more than five times as high as those in the cool water system. The NO3- contents of cool water discharged from the gold mine are relatively high, and those of hot water are extremely low. The δD and δ18O values follow an increasing order of surface water>mine cool water>mine hot water. The cool water comes mainly from the lateral supply of phreatic water, while the hot water comes mainly from the vertical supply of deeply circulating structure-fracture water. The ratio of cool water over hot water was estimated to be about 1:1 by a water quality model..

Application of homogenization techniques for inflow transport approximation on light water reactor analysis

The transport cross-section based on inflow transport approximation can significantly improve the accuracy of light water reactor(LWR)analysis,especially for the treatment of the anisotropic scattering effect.The previous inflow transport approximation is based on the moderator cross-section and normalized fission source,which is approximated using transport theory.Although the accuracy of reactivity is increased,the P0 flux moment has a large error in the Monte Carlo code.In this study,an improved inflow transport approximation was introduced with homogenization techniques,applying the homogenized cross-section and accurate fission source.The numerical results indicated that the improved inflow transport approximation can increase the P0 flux moment accuracy and maintain the reactivity calculation precision with the previous inflow transport approximation in typical LWR cases.In addition to this investigation,the improved inflow transport approximation is related to the temperature factors.The improved inflow transport approximation is flexible and accurate in the treatment of the anisotropic scattering effect,which can be directly used in the temperature-dependent nuclear data library.

Theory and Practice of Water Pollution Prevention and Control for Inflowing Rivers in Taihu Valley

The pollutants from the 15 rivers inflowing into Lake Taihu accounted for about 80% of the total amount of the pollutants inflowing into Lake Taihu. Therefore, overall treatment of the inflowing rivers of Taihu Lake is of great importance to the improvement of water environment in the valley and the eutrophication status in th lake. Firstly, the basic ideas, key taches and main methods for water pollution control of inflow rivers of Taihu Lake was put forward in this article, Basic on these theories, the pollutant source status in the comprehensive treatment zone of the 15 major inflow rivers was analysized, the countermeasures of pollution control and main regulation projects were introduced, and the total abatement of pollutants was predicted. With the implement of regulation projects, the number of rivers with water quality worse than Grade V among the 15 major inflow rivers had come from 9 to 3, and the eutrophication status of Taihu Lake had changed from medium level to light level. The overall treatment of the major inflow rivers of the Taihu Lake had achieved initial success.

Evolution and modeling of mine water inflow and hazard characteristics in southern coalfields of China:A case of Meitanba mine

In this paper,the hydrogeological characteristics in the southern coalfields of China are first briefly outlined.Then,taking the Meitanba mine as an example,the evolution and modeling of mine water inflow are studied.Finally,the hazard characteristics related to mine water and mud inrush are analyzed.The results show that the main mine water sources in the Meitanba mine area are groundwater,surface water and precipitation.The evolution of mine water inflow with time indicates that the water inflow is closely related to the development of karst structures,the amount of water from rainfall infiltration,and the scope of groundwater depression cone.The mine water inflow increases with time due to the increase in mining depth and the expansion of groundwater depression cone.Using the big well method and following the potential superposition principle,a hydrogeological model considering multi-well interactions has been developed to predict the mine water inflow.Based on the monitored data in the Meitanba mine area over a period of nearly 60 years,it is found that with increasing mining depth,the number of water and mud inrush points tended to decrease.However,the average water and mud flow rate per point tended to increase.

Prediction of the maximum water inflow in Pingdingshan No.8 mine based on grey system theory

In order to prevent and control the water inflow of mines, this paper built a new initial GM（1, 1） model to torecast the maximum water inflow according to the principle of new information. The effect of the new initial GM（1, 1） model is not ideal by the concrete example. Then according to the principle of making the sum of the squares of the difference between the calculated sequences and the original sequences, an optimized GM（1, I） model was established. The result shows that this method is a new prediction method which can predict the maximum water inflow accurately. It not only conforms to the guide- line of prevention primarily, but also provides reference standards to managers on making prevention measures.

Grey forewarning and prediction for mine water inflowing catastrophe periods

Based on the theory of grey system, established GM （1, 1） grey catastrophe predict model for the first time in order to forecast the catastrophe periods of mine water inflowing （not the volume of water inflowing）. After establishing the grey predict system of the catastrophe regularity of 10 month-average volume of water inflowing, the grey forewarning for mine water inflowing catastrophe periods was established which was used to analyze water disaster in 400 meter level of Wennan Colliery. Based on residual analysis, it shows that the result of grey predict system is almost close to the actual value. And the scene actual result also shows the reliability of prediction. Both the theoretical analysis and the scene actual result indicate feasibility and reliability of the method of grey catastrophe predict system.

An Inexpensive and Simple Experimental Approach for the Estimation of Solute Import into Groundwater and Subsequent Export Using Inflow/Outflow Data

In agricultural catchments where groundwater (GW) base flow discharge contributes substantially towards stream flow, the information linking GW inflow/outflow with contaminant import/export is scarce. However, this information is essential to address aquatic ecosystem health hazard/risk associated with nitrate export and subsequent loading in sensitive surface water bodies (SWB). The objectives of this study were to assess the temporal dynamics of (i) rain water inflow/outflow behaviour in three agricultural catchments in the humid tropics of far-northeast Queensland of Australia, (ii) solute import via inflow and subsequent export in outflow, and (iii) the association between GW inflow/outflow and solute import/export. Approximately 71% of the average seasonal rainfall percolated (inflow) into the porous basaltic regolith of the Johnstone River Catchment (JRC) compared with 44% into the alluvial regolith in the Mulgrave River Catchment (MRC) and 29% into the metamorphic regolith in the Tully River Catchment (TRC), respectively. The outflows from the basaltic, alluvial, and metamorphic regoliths were 56%, 36%, and 55% of the inflows, respectively. The cumulative nitrate import per season was 25 k/ha in the JRC compared with 11 kg/ha in MRC and 34 kg/ha in TRC. The corresponding exports were 24 kg/ha, 8 kg/ha 26 kg/ha in JRC, MRC, and TRC, respectively. The total dissolved solute (TDS) exports were 82%, 77%, 75%, of the corresponding imports in JRC, MRC, and TRC, respectively. Simple correlations indicated that nitrate export was positively correlated with the outflow in each one of the regolith and similar trends were observed between inflow and import. The import/export mass balance for nitrate shows that 73% to 96% of the imports were exported during the same rainy season, suggesting the potential for nitrate associated ecosystem health hazard/risk in sensitive SWB receiving the outflows.

Progress and prospects of EOR technology in deep,massive sandstone reservoirs with a strong bottom-water drive

The Triassic massive sandstone reservoir in the Tahe oilfield has a strong bottom-water drive and is characterized by great burial depth,high temperature and salinity,a thin pay zone,and strong heterogeneity.At present,the water-cut is high in each block within the reservoir;some wells are at an ultrahigh water-cut stage.A lack of effective measures to control water-cut rise and stabilize oil production have necessitated the application of enhanced oil recovery(EOR)technology.This paper investigates the development and technological advances for oil reservoirs with strong edge/bottom-water drive globally,and compares their application to reservoirs with characteristics similar to the Tahe oilfield.Among the technological advances,gas injection from the top and along the direction of structural dip has been used to optimize the flow field in a typical bottom-water drive reservoir.Bottom-water coning is restrained by gas injection-assisted water control.In addition,increasing the lateral driving pressure differential improves the plane sweep efficiency which enhances oil recovery in turn.Gas injection technology in combination with technological measures like channeling prevention and blocking,and water plugging and profile control,can achieve better results in reservoir development.Gas flooding tests in the Tahe oilfield are of great significance to identifying which EOR technology is the most effective and has the potential of large-scale application for improving development of deep reservoirs with a strong bottomwater drive.

Insights on advanced substrates for controllable fabrication of photoanodes toward efficient and stable photoelectrochemical water splitting

Conversion of solar energy into H_(2) by photoelectrochemical(PEC)water splitting is recognized as an ideal way to address the growing energy crisis and environmental issues.In a typical PEC cell,the construction of photoanodes is crucial to guarantee the high efficiency and stability of PEC reactions,which fundamentally rely on rationally designed semiconductors(as the active materials)and substrates(as the current collectors).In this review work,we start with a brief introduction of the roles of substrates in the PEC process.Then,we provide a systematic overview of representative strategies for the controlled fabrication of photoanodes on rationally designed substrates,including conductive glass,metal,sapphire,silicon,silicon carbide,and flexible substrates.Finally,some prospects concerning the challenges and research directions in this area are proposed.

Classification and technical target of water electrolysis for hydrogen production

Continuous efforts are underway to reduce carbon emissions worldwide in response to global climate change.Water electrolysis technology,in conjunction with renewable energy,is considered the most feasible hydrogen production technology based on the viable possibility of large-scale hydrogen production and the zero-carbon-emission nature of the process.However,for hydrogen produced via water electrolysis systems to be utilized in various fields in practice,the unit cost of hydrogen production must be reduced to$1/kg H_(2).To achieve this unit cost,technical targets for water electrolysis have been suggested regarding components in the system.In this paper,the types of water electrolysis systems and the limitations of water electrolysis system components are explained.We suggest guideline with recent trend for achieving this technical target and insights for the potential utilization of water electrolysis technology.

Grain yield and N uptake of maize in response to increased plant density under reduced water and nitrogen supply conditions

The development of modern agriculture requires the reduction of water and chemical N fertilizer inputs.Increasing the planting density can maintain higher yields,but also consumes more of these restrictive resources.However,whether an increased maize density can compensate for the negative effects of reduced water and N supply on grain yield and N uptake in the arid irrigated areas remains unknown.This study is part of a long-term positioning trial that started in 2016.A split-split plot field experiment of maize was implemented in the arid irrigated area of northwestern China in 2020 to 2021.The treatments included two irrigation levels:local conventional irrigation reduced by 20%(W1,3,240 m^(3)ha^(-1))and local conventional irrigation(W2,4,050 m^(3)ha^(-1));two N application rates:local conventional N reduced by 25%(N1,270 kg ha^(-1))and local conventional N(360 kg ha^(-1));and three planting densities:local conventional density(D1,75,000 plants ha^(-1)),density increased by 30%(D2,97,500 plants ha-1),and density increased by 60%(D3,120,000 plants ha^(-1)).Our results showed that the grain yield and aboveground N accumulation of maize were lower under the reduced water and N inputs,but increasing the maize density by 30% can compensate for the reductions of grain yield and aboveground N accumulation caused by the reduced water and N supply.When water was reduced while the N application rate remained unchanged,increasing the planting density by 30% enhanced grain yield by 13.9% and aboveground N accumulation by 15.3%.Under reduced water and N inputs,increasing the maize density by 30% enhanced N uptake efficiency and N partial factor productivity,and it also compensated for the N harvest index and N metabolic related enzyme activities.Compared with W2N2D1,the N uptake efficiency and N partial factor productivity increased by 28.6 and 17.6%under W1N1D2.W1N2D2 had 8.4% higher N uptake efficiency and 13.9% higher N partial factor productivity than W2N2D1.W1N2D2 improved urease activity and nitrate reductase activity by 5.4% at the R2(blister)stage and 19.6% at the V6(6th leaf)stage,and increased net income and the benefit:cost ratio by 22.1 and 16.7%,respectively.W1N1D2 and W1N2D2 reduced the nitrate nitrogen and ammoniacal nitrogen contents at the R6 stage in the 40-100 cm soil layer,compared with W2N2D1.In summary,increasing the planting density by 30% can compensate for the loss of grain yield and aboveground N accumulation under reduced water and N inputs.Meanwhile,increasing the maize density by 30% improved grain yield and aboveground N accumulation when water was reduced by 20% while the N application rate remained constant in arid irrigation areas.