Aqueous potassium-ion batteries(APIBs),recognized as safe and reliable new energy devices,are considered as one of the alternatives to traditional batteries.Layered MnO_(2),serving as the main cathode,exhibits a lower...Aqueous potassium-ion batteries(APIBs),recognized as safe and reliable new energy devices,are considered as one of the alternatives to traditional batteries.Layered MnO_(2),serving as the main cathode,exhibits a lower specific capacity in aqueous electrolytes compared to organic systems and operates through a different reaction mechanism.The application of highly conductive graphene may effectively enhance the capacity of APIBs but could complicate the potassium storage environment.In this study,a MnO_(2) cathode pre-intercalated with K~+ions and grown on graphene(KMO@rGO) was developed using the microwave hydrothermal method for APIBs.KMO@rGO achieved a specific capacity of 90 mA h g^(-1) at a current density of 0.1 A g^(-1),maintaining a capacity retention rate of>90% after 5000 cycles at 5 A g^(-1).In-situ and exsitu characterization techniques revealed the energy-storage mechanism of KMO@rGO:layered MnO_(2)traps a large amount of "dead" water molecules during K~+ions removal.However,the introduction of graphene enables these water molecules to escape during K~+ ions insertion at the cathode.The galvanostatic intermittent titration technique and density functional theory confirmed that KMO@rGO has a higher K~+ions migration rate than MnO_(2).Therefore,the capacity of this cathode depends on the interaction between dead water and K~+ions during the energy-storage reaction.The optimal structural alignment between layered MnO_(2) and graphene allows electrons to easily flow into the external circuit.Rapid charge compensation forces numerous low-solvent K~+ions to displace interlayer dead water,enhancing the capacity.This unique reaction mechanism is unprecedented in other aqueous battery studies.展开更多
The behavior of a water molecule entering carbon nanotubes (CNTs) is stud- ied. The Lennaxd-Jones potential function together with the continuum approximation is used to obtain the van der Waals interaction between ...The behavior of a water molecule entering carbon nanotubes (CNTs) is stud- ied. The Lennaxd-Jones potential function together with the continuum approximation is used to obtain the van der Waals interaction between a single-walled CNT (SWCNT) and a single water molecule. Three orientations are chosen for the water molecule as the center of mass is on the axis of nanotube. Extensive studies on the variations of force, energy, and velocity distributions axe performed by vaxying the nanotube radius and the orientations of the water molecule. The force and energy distributions are validated by those obtained from molecular dynamics (MD) simulations. The acceptance radius of the nanotube for sucking the water molecule inside is derived, in which the limit of the radius is specified so that the nanotube is favorable to absorb the water molecule. The velocities of a single water molecule entering CNTs axe calculated and the maximum entrance and the interior velocity for different orientations axe assigned and compared.展开更多
Nickel-iron layered double hydroxides(NiFe LDHs) have been identified as one of the best promising electrocatalysts-candidates for oxygen evolution reaction(OER). However, the catalytic activity effected by interlayer...Nickel-iron layered double hydroxides(NiFe LDHs) have been identified as one of the best promising electrocatalysts-candidates for oxygen evolution reaction(OER). However, the catalytic activity effected by interlayer water molecules is ignored and rarely reported. Herein, Ni(OH)_2, NiFe LDHs vertically aligned Ni foam are designed for OER. As a contrast, the corresponding electrocatalysts with the removal of the interlayer water molecules(Ni(OH)_2-AT, NiFe LDHs-AT) are developed to probe into the influence of the interlayer water molecules towards OER. As expected, NiFe LDH nanoplates exhibit excellent catalytic performance and durability for water electrolysis in alkaline conditions with lower overpotential and smaller Tafel slope compared to those of NiFe LDHs-AT, which are influenced mainly by stability of crystal structure due to the existence of interlayer water molecules. The discovery opens up a similar pathway by controlling the amount of water molecules to boost catalytic performance for studying other electrocatalysts with heteroatom dopant.展开更多
The dissociation limits of isotopic water molecules are derived for the ground state. The equilibrium geometries, the vibrational frequencies, the force constants and the dissociation energies for the ground states of...The dissociation limits of isotopic water molecules are derived for the ground state. The equilibrium geometries, the vibrational frequencies, the force constants and the dissociation energies for the ground states of all isotopic water molecules under the dipole electric fields from -0.05 a.u. to 0.05 a.u. are calculated using B3P86/6-311++G(3df,3pf). The results show that when the dipole electric fields change from -0.05 a.u. to 0.05 a.u., the bond length of H-O increases whereas the bond angle of H-O H decreases because of the charge transfer induced by the applied dipole electric field. The vibrational frequencies and the force constants of isotopic water molecules change under the influence of the strong external torque. The dissociation energies increase when the dipole electric fields change from -0.05 a.u. to 0.05 a.u. and the increased dissociation energies are in the order of H2O, HDO, HTO, D2O, DTO, and T2O under the same external electric fields.展开更多
It is important to know the mechanisms of water molecules across carbon-based nanochannels, which is not only beneficial for understanding biological activities but also for designing various smart devices. Here we re...It is important to know the mechanisms of water molecules across carbon-based nanochannels, which is not only beneficial for understanding biological activities but also for designing various smart devices. Here we review the recent progress of research tbr water transfer across carbon-based nanochannels. In this review, we summarize the recent methods which can affect water molecules across these nanochannels. The methods include exterior factors (i.e., dipolar molecules and gradient electric fields) and interior factors (namely, cone-shaped structures, nonstraight nanochannels, and channel defects). These factors can control water permeation across nanochannels efficiently.展开更多
Experimental and theoretical studies of the author (period: 1968-present) have shown that true sources of </span><span style="font-family:"">the </span><span style="font-family...Experimental and theoretical studies of the author (period: 1968-present) have shown that true sources of </span><span style="font-family:"">the </span><span style="font-family:"">magnetic field are magnetic fundamental particles (magnetic charges), and not moving electrons. The main reason for <span>ignoring real magnetic charges, as well as true antielectrons in physical</span> science is the hard conditions for confinement of these particles in atoms and substance</span><span style="font-family:"">s</span><span style="font-family:"">, which </span><span style="font-family:"">is </span><span style="font-family:"">radically different from the confinement of electrons. Magnetic charges together with electric charges form the shells atoms which are <span>electromagnetic, and not electronic. Namely</span></span><span style="font-family:"">,</span><span style="font-family:""> electromagnetic shells are</span><span style="font-family:""> sources of gravitational field which is </span><span style="font-family:"">a </span><span style="font-family:"">vortex electromagnetic field and de<span>scribed by the vortex</span></span><span style="font-family:""> rot [<i>E</i> - <i>H</i>]</span><span style="font-family:"">. Depending on the state polarization o</span><span style="font-family:"">f vortex vectors </span><span style="font-family:"">rot [<i>E</i> - <i>H</i>]</span><span style="font-family:""> in compositions of atomic gravitational fields it </span><span style="font-family:"">is </span><span style="font-family:"">subdivided into paragravitational (PGF) and ferrogravitational fields </span><span style="font-family:"">(FGF). The overwhelming number of atoms emits PGF. Between the masses (bodies, atoms, nucleons and others) emitting PGF areas of negative gravitational “Dark Energy” are realized the forces of which press the masses towards each other. Namely</span><span style="font-family:"">,</span><span style="font-family:""> the compression of atoms by the forces of paragravitational “Dark Energy” underlies the chemical bond. The exception here is the ionic bond in ionic crystals. However, all ions have electromagnetic shells that generate the gravitational field. Consequently, ionic bonding is a relatively rare addition to gravito-chemical bond processes. The direct gravito-chemical bond of carbon atom</span><span style="font-family:"">s</span><span style="font-family:""> with hydrogen (<sup>1</sup>H) is physically forbidden due to </span><span style="font-family:"">the </span><span style="font-family:"">manifestation of the effect of ferrogravitational levitation between them and the repulsion of atoms from each other. Paradoxically, but all existing ideas about the structural device of hydrocarbons are based on such physically forbidden bonds which, moreover, must be realized through ionic <span>bonds which in reality do not exist. Chemical bonding of carbon and hydrogen </span>atoms to form hydrocarbons molecules is possible only if the hydrogen atoms are in the molecular form (<sup>1</sup>H<sub>2</sub>). In the composition of water, within the framework of the chemical formula H<sub>2</sub>O, two stable isomorphic molecular structures are formed. The chemical bond in the first structure is similar to the hydrocarbon scenario described above, </span><span style="font-family:""><i></span><i><span style="font-family:"">i.e.</span></i><i><span style="font-family:""></i></span></i><span style="font-family:""> in the process of combining paragravitational oxygen with a hydrogen molecule <sup>1</sup>H<sub>2</sub>. The second molecular structure in water is <span>formed under conditions of ferropolarization of the gravitational field of</span> oxygen atom</span><span style="font-family:"">s</span><span style="font-family:""> under the influence of FGF of neighboring <sup>1</sup>H atoms. In this case, the chemical bond is realized under the conditions of ferropolarization</span><span style="font-family:""> </span><span style="font-family:"">of the vortex vectors </span><span style="font-family:"">rot [<i>E</i> - <i>H</i>]</span><span style="font-family:""> of the gravitational fields of all atoms in</span><span style="font-family:""> the molecule and the co-directionality of them vectors </span><span style="font-family:""><i></span><b><i><span style="font-family:"">P</span></i></b><i><sub><span style="font-family:"">fp</span></sub></i><i><sub><span style="font-family:""></i></span></sub></i><span style="font-family:""> ferropolarization. The gravito-physical properties of the presented molecular structures in the composition of water make it possible to name them, respectively, as heavy and light clusters.展开更多
The problems of traditional concrete such as brittleness,poor toughness and short service life of concrete engineering under acid rain or marine environment need to be solved urgently.Hydrated calcium silicate(C-S-H)i...The problems of traditional concrete such as brittleness,poor toughness and short service life of concrete engineering under acid rain or marine environment need to be solved urgently.Hydrated calcium silicate(C-S-H)is a key component to improve the mechanical properties and durability of concrete.However,the traditional method of concrete material design based on empirical models or comparative tests has become a bottleneck restricting the sustainable development of concrete.The synthesis method,molecular structure and properties of C-S-H were systematically described in this paper;The interface structure and interaction of graphene oxide/calcium silicate hydrate(C-S-H/GO)were discussed.On this basis,the saturated and unsaturated transport characteristics of ions and water molecules in C-S-H/GO nanochannels under the environment of ocean and acid rain were introduced.The contents of this review provide the basis for improving the multi-scale transmission theory and microstructure design of concrete.It has important guiding significance for analyzing and improving the service life of concrete in complex environment.展开更多
Chalcopyrite is a common copper-bearing mineral with antiferromagnetic properties.However,this property has rarely been considered in previous studies for detailed adsorption behaviors of molecules on chalcopyrite.Bas...Chalcopyrite is a common copper-bearing mineral with antiferromagnetic properties.However,this property has rarely been considered in previous studies for detailed adsorption behaviors of molecules on chalcopyrite.Based on density functional theory(DFT),new adsorption pathways by H_(2)O and O_(2)on the chalcopyrite metal terminated(112)surface((112)-M)is found in this work.First,through simulating the adsorption of an isolated water molecule and monolayer water molecules,it is confirmed that H_(2)O molecules tend to adsorb on the surface Fe atoms more than on the surface Cu atoms.Then,we studied various adsorption behaviors of the O_(2)molecule.It is found that the adsorption on the hollow FeAFe site is the most stable case;however,O_(2)is undissociated.Two adsorption cases will happen when H_(2)OAO_(2)adsorb simultaneously on the surface.For the S site,the H_(2)O molecule thoroughly dissociated and formed SAO species,and the other case is H_(2)O undissociated adsorbing at the Cu site.For the former case,it is interesting that H_(2)O is dissociated before O_(2).展开更多
The detection of macromolecular conformation is particularly important in many physical and biological applications. Here we theoretically explore a method for achieving this detection by probing the electricity of se...The detection of macromolecular conformation is particularly important in many physical and biological applications. Here we theoretically explore a method for achieving this detection by probing the electricity of sequential charged segments of macromolecules. Our analysis is based on molecular dynamics simulations, and we investigate a single file of water molecules confined in a half-capped single-walled carbon nanotube (SWCNT) with an external electric charge of +e or -e (e is the elementary charge). The charge is located in the vicinity of the cap of the SWCNT and along the centerline of the SWCNT. We reveal the picosecond timescale for the re-orientation (namely, from one unidirectional direction to the other) of the water molecules in response to a switch in the charge signal, -e -+ +e or +e -+ --e. Our results are well understood by taking into account the electrical interactions between the water molecules and between the water molecules and the external charge. Because such signals of re-orientation can be magnified and transported according to Tu et al. [2009 Proc. Natl. Aead. Sci. USA 106 18120], it becomes possible to record fingerprints of electric signals arising from sequential charged segments of a macromolecule, which are expected to be useful for recognizing the conformations of some particular macromolecules.展开更多
The realization of rapid and unidirectional single-file wate^molecule flow in nanochannels has posed a challenge to date. Here, we report unprecedentedly rapid unidirectional single-file water-molecule flow under a tr...The realization of rapid and unidirectional single-file wate^molecule flow in nanochannels has posed a challenge to date. Here, we report unprecedentedly rapid unidirectional single-file water-molecule flow under a translational terahertz electric field, which is obtained by developing a Debye double- relaxation theory. In addition, we demonstrate that all the single-file molecules undergo both stable translation and rotation, behaving like high-speed train wheels moving along a railway track. Inde- pendent molecular dynamics simulations help to confirm these theoretical results. The mechanism involves the resonant relaxation dynamics of H and O atoms. Purther, an experimental demon- stration is suggested and discussed. This work has implications for the design of high-efficiency nanochannels or smaller nanomachines in the field of nanotechnology, and the findings also aid in the understanding and control of water flow across biological nanochannels in biology-related research.展开更多
Lightweight,highly strong and bio-based structural materials remain a long-lasting challenge.Here,inspired by nacre,a lightweight and high mechanical performance cellulosic material was fabricated via a facile and eff...Lightweight,highly strong and bio-based structural materials remain a long-lasting challenge.Here,inspired by nacre,a lightweight and high mechanical performance cellulosic material was fabricated via a facile and effective top-down approach and the resulting material has a high tensile strength of149.21 MPa and toughness of 1.91 MJ/m^(3).More specifically,the natural balsawood(NW) was subjected to a simple chemical treatment,removing most lignin and partial hemicellulose,follow by freeze-drying,forming wood aerogel(WA).The delignification process produced many pores and exposed numerous aligned cellulose nanofibers.Afterwards,the WA absorbed a quantity of moisture and was directly densified to form above high-performance cellulosic material.Such treatment imitates highly ordered"brick-and-mortar" arrangement of nacre,in which water molecules plays the role of mortar and cellulose nanofibrils make the brick part.The lightweight and good mechanical properties make this material promising for new energy car,aerospace,etc.This paper also explains the strengthening mechanism for making biomimetic materials by water molecules-induced hydrogen bonding and will open a new path for designing high-performance bio-based structural materials.展开更多
The contributions of explicit water molecules to color-tuning mechanism of firefly were studied. The explicit water molecules cause two different structures in the geometrical parameters of keto(-1) both in vacuo an...The contributions of explicit water molecules to color-tuning mechanism of firefly were studied. The explicit water molecules cause two different structures in the geometrical parameters of keto(-1) both in vacuo and aqueous solution. There are somewhat larger influences on absorption and emission spectra. When water molecules were added only on the side of benzothiazole ring, the spectra shift to the blue. In contrast, when waters were added only on the side of the thiazoline ring, the spectra shift to red. In a word, the color modulation of the emitted light depends on charge redistribution of molecule keto(-1), mainly the charge change of the benzothiazole and thiazole tings at the two terminal in keto(-1).展开更多
The exploitation of the interaction between nanostructured matter and small molecules,such as H_(2)O at interfaces via dynamic hydrogen bonding,is essentially the key for smart,responsive nanodevices but remains chall...The exploitation of the interaction between nanostructured matter and small molecules,such as H_(2)O at interfaces via dynamic hydrogen bonding,is essentially the key for smart,responsive nanodevices but remains challenging.Herein,the authors report that the carbon nitride nanoribbons(CNNRs)with an anisotropic intraplanar and interplanar molecular arrangement underwent a deformation by H_(2)O triggering.Both experiments of bulk samples and single nanoribbons disclosed that the reversible formation of a hydrogen-bonded H_(2)O adsorption layer was the source of the CNNRs deformation,reminiscent of the hydration-triggered twist of natural bean pods in seeding.Nonetheless,CNNRs had a more balanced H_(2)O affinity,enabling a superior response and recovery time.By coupling with carbon nanotubes,the authors also converted the deformation of CNNRs into more straightforward electrical readouts with record-fast response time.Further applied to capture fluctuations in humidity in real-time respiration,a higher detection sensitivity was obtained in a contactless mode,which compared favorably with the clinical breath-testing station.Given the carbon nitride family with various C/N ratios,surface properties,and topography,this finding that CNNRs are an outstanding H_(2)O transducer would significantly pave the way for the H_(2)O-triggered smart devices in broad prospective applications.展开更多
Reaction of p-t-butylcalix[6]arene with ethylene oxide gives a water soluble host compound with a hydrophobic cavity and it can include organic molecules and ions in aqueous solution.
Understanding the transport resistance of water molecules in polyamide(PA)reverse osmosis(RO)membranes at the molecular level is of great importance in guiding the design,preparation,and applications of these membrane...Understanding the transport resistance of water molecules in polyamide(PA)reverse osmosis(RO)membranes at the molecular level is of great importance in guiding the design,preparation,and applications of these membranes.In this work,we use molecular simulation to calculate the total transport resistance by dividing it into two contributions:the interior part and the interfacial part.The interior resistance is dependent on the thickness of the PA layer,while the interfacial resistance is not.Simulation based on the 5 nm PA layer reveals that interfacial resistance is the dominating contribution(>62%)to the total resistance.However,for real-world RO membranes with a 200 nm PA layer,interfacial resistance plays a minor role,with a contribution below 10%.This implies that there is a risk of inaccuracy when using the typical method to estimate the transport resistance of RO membranes,as this method involves simply multiplying the total transport resistance of the simulated value based on a membrane with a 5 nm PA layer.Furthermore,both the interfacial resistance and the interior resistance are dependent on the chemistry of the PA layer.Our simulation reveals that decreasing the number of residual carboxyl groups in the PA layer leads to decreased interior resistance;therefore,the water permeability can be improved at no cost of ion rejection,which is in excellent agreement with the experimental results.展开更多
Alkaline hydrogen evolution reaction(HER)offers a near-zero-emission approach to advance hydrogen energy.However,the activity limited by the multiple reaction steps involving H_(2)O molecules transfer,absorption,and a...Alkaline hydrogen evolution reaction(HER)offers a near-zero-emission approach to advance hydrogen energy.However,the activity limited by the multiple reaction steps involving H_(2)O molecules transfer,absorption,and activation still unqualified the thresholds of economic viability.Herein,we proposed a multisite complementary strategy that incorporates hydrophilic Mo and electrophilic V into Ni-based catalysts to divide the distinct steps on atomically dispersive sites and thus realize sequential regulation of the HER process.The Isotopic labeled in situ Raman spectroscopy describes 4-coordinated hydrogen bonded H_(2)O to be free H_(2)O passing the inner Helmholtz plane in the vicinity of the catalysts under the action of hydrophilic Mo sites.Furthermore,potential-dependent electrochemical impedance spectroscopy(EIS)reveals that electrophilic V sites with abundant 3d empty orbitals could activate the lone-pair electrons in the free H_(2)O molecules to produce more protic hydrogen,and dimerize into H_(2) at the Ni sites.By the sequential management of reactive H_(2)O molecules,NiMoV oxides multisite catalysts surpass Pt/C hydrogen evolution activity(49 mV@10 mA∙cm^(-2) over 140 h).Profoundly,this study provides a tangible model to deepen the comprehension of the catalyst–electrolyte interface and create efficient catalysts for diverse reactions.展开更多
Accurate spectroscopic data for H_(2)^(16)O in the 1.1μm region are particularly important for the study of Earth's atmosphere.The pure water vapor molecular spectra were measured based on direct laser absorption...Accurate spectroscopic data for H_(2)^(16)O in the 1.1μm region are particularly important for the study of Earth's atmosphere.The pure water vapor molecular spectra were measured based on direct laser absorption spectroscopy using a narrow line-width external cavity diode laser combined with a high-precision Fabry-Pérot etalon.A total of 31 H_(2)^(16)O transitions were studied for the first time by using the speed-dependent Nelkin-Ghatak profile and the Hartmann-Tran profile.From an accurate line-shape analysis,we obtained the line intensities and the self-broadening coefficients,and they are compared with the available data reported in the HITRAN 2016 database and the HITRAN 2020 database.Finally,we obtained information on the influence of Dicke narrowing,as well as the correlations between Dicke narrowing and speed dependence,and of speed-dependent effects.展开更多
Surface charges and hydration are predominant properties of colloidal particles that govern colloidal stability in aqueous suspensions.These properties usually coexist and interact with each other.The correlation betw...Surface charges and hydration are predominant properties of colloidal particles that govern colloidal stability in aqueous suspensions.These properties usually coexist and interact with each other.The correlation between the surface charge and hydration of minerals is summarized on the basis of innovative experimental,theoretical,and molecular dynamics simulation studies.The factors affecting the adsorption behavior of ions and water molecules,such as ion concentration,ion hydration radius and valence,and surface properties,are discussed.For example,the hydration and adsorption states completely differ between monovalent and divalent ions.For ions of the same valence,the effect of surface charge on the hydration force follows the Hofmeister adsorption series.Electrolyte concentration exerts a significant effect on the hydration force at high ion concentrations.Meanwhile,the ion correlations in high-concentration electrolyte systems become long range.The interfacial water structure largely depends on surface chemistry.The hydration layer between different surfaces shows large qualitative differences.展开更多
Lanthanide ions-doped upconversion nanoparticles(UCNPs)have shown great potential in various biomedical applications.However,the upconversion luminescence(UCL)intensity of UCNPs in water environment tends to be quench...Lanthanide ions-doped upconversion nanoparticles(UCNPs)have shown great potential in various biomedical applications.However,the upconversion luminescence(UCL)intensity of UCNPs in water environment tends to be quenched.This quenching is typically attributed to non-radiative relaxation of the excited state.In this study,we designed a core-shellshell-shell NaYb_(0.88)Er_(0.12)F_(4)@NaY_(0.9)b_(0.1)F_(4)@NaY_(0.6)Nd_(0.3)Yb_(0.1)F_(4)@NaYF_(4)UCNPs that could be excited by both 980 nm and 808 nm laser,due to the doping of Nd^(3+)and Yb^(3+)ions.Our research not only utilized bulk spectral measurement but also employed single-particle level microscopic imaging to comprehensively investigate the impact of water molecules on UCL under 980 nm and 808 nm irradiation.Interestingly,our findings indicate that the absorption of water molecules has a significant effect on the UCL decay of UCNPs in aqueous solutions when excited by a 980 nm laser.This work offers a new perspective on the luminescence behavior of UCNPs in aquatic environments and provides valuable insights for their application and development in biomedicine.展开更多
Two‐dimensional(2D)ferroelectrics have attracted considerable attention due to their potential in the development of devices of miniaturization and multifunction.Although several van der Waals(vdW)‐layered materials...Two‐dimensional(2D)ferroelectrics have attracted considerable attention due to their potential in the development of devices of miniaturization and multifunction.Although several van der Waals(vdW)‐layered materials show ferroelectricity,the experimental demonstrations of ferroelectric behavior in monolayers are very limited.Here we report the observation of room‐temperature out‐of‐plane switchable electric polarization in supported MoS_(2) monolayers exfoliated from 3R‐stacked bulk crystals under ambient conditions.Using in situ piezoelectric force microscopy and Kelvin probe force microscopy in a glovebox,we reveal that trapped water/ice molecules are responsible for this switchable electric polarization and this conclusion is strongly supported by theoretical simulations.It is worth noting that the water/ice trapping in the monolayers exfoliated from 2H‐stacked MoS_(2) crystals is not as much as that in 3R monolayers and,consequently,the out‐of‐plane electric polarization is missing there.Our findings indicate that monolayers with a trapped single layer of polar molecules might be emerging alternatives to 2D ferroelectrics.Furthermore,the stacking sequences may bring new properties and applications to 2D vdW materials not only when we stack them up but also when we thin them down.展开更多
基金financially supported by the Scientific and Technological Plan Project of Guizhou Province (Grant No. [2021]060)the Industry and Education Combination Innovation Platform of Intelligent Manufacturing and the Graduate Joint Training Base at Guizhou University (Grant No. 2020-520000-83-01-324061)the Guizhou Engineering Research Center for smart services (Grant No. 2203-520102-04-04-298868)。
文摘Aqueous potassium-ion batteries(APIBs),recognized as safe and reliable new energy devices,are considered as one of the alternatives to traditional batteries.Layered MnO_(2),serving as the main cathode,exhibits a lower specific capacity in aqueous electrolytes compared to organic systems and operates through a different reaction mechanism.The application of highly conductive graphene may effectively enhance the capacity of APIBs but could complicate the potassium storage environment.In this study,a MnO_(2) cathode pre-intercalated with K~+ions and grown on graphene(KMO@rGO) was developed using the microwave hydrothermal method for APIBs.KMO@rGO achieved a specific capacity of 90 mA h g^(-1) at a current density of 0.1 A g^(-1),maintaining a capacity retention rate of>90% after 5000 cycles at 5 A g^(-1).In-situ and exsitu characterization techniques revealed the energy-storage mechanism of KMO@rGO:layered MnO_(2)traps a large amount of "dead" water molecules during K~+ions removal.However,the introduction of graphene enables these water molecules to escape during K~+ ions insertion at the cathode.The galvanostatic intermittent titration technique and density functional theory confirmed that KMO@rGO has a higher K~+ions migration rate than MnO_(2).Therefore,the capacity of this cathode depends on the interaction between dead water and K~+ions during the energy-storage reaction.The optimal structural alignment between layered MnO_(2) and graphene allows electrons to easily flow into the external circuit.Rapid charge compensation forces numerous low-solvent K~+ions to displace interlayer dead water,enhancing the capacity.This unique reaction mechanism is unprecedented in other aqueous battery studies.
文摘The behavior of a water molecule entering carbon nanotubes (CNTs) is stud- ied. The Lennaxd-Jones potential function together with the continuum approximation is used to obtain the van der Waals interaction between a single-walled CNT (SWCNT) and a single water molecule. Three orientations are chosen for the water molecule as the center of mass is on the axis of nanotube. Extensive studies on the variations of force, energy, and velocity distributions axe performed by vaxying the nanotube radius and the orientations of the water molecule. The force and energy distributions are validated by those obtained from molecular dynamics (MD) simulations. The acceptance radius of the nanotube for sucking the water molecule inside is derived, in which the limit of the radius is specified so that the nanotube is favorable to absorb the water molecule. The velocities of a single water molecule entering CNTs axe calculated and the maximum entrance and the interior velocity for different orientations axe assigned and compared.
基金financially supported by the National Natural Science Foundation of China (51622102, 51571124, 21421001)MOST (2017YFA0206702)+3 种基金the 111 Project (B12015)the Natural Science Foundation of Tianjin (16PTSYJC00030)the Fundamental Research Funds for the Central Universitiesthe Tianjin Colle ge Students Innovation and Entrepreneurship Training Project (201814038024)。
文摘Nickel-iron layered double hydroxides(NiFe LDHs) have been identified as one of the best promising electrocatalysts-candidates for oxygen evolution reaction(OER). However, the catalytic activity effected by interlayer water molecules is ignored and rarely reported. Herein, Ni(OH)_2, NiFe LDHs vertically aligned Ni foam are designed for OER. As a contrast, the corresponding electrocatalysts with the removal of the interlayer water molecules(Ni(OH)_2-AT, NiFe LDHs-AT) are developed to probe into the influence of the interlayer water molecules towards OER. As expected, NiFe LDH nanoplates exhibit excellent catalytic performance and durability for water electrolysis in alkaline conditions with lower overpotential and smaller Tafel slope compared to those of NiFe LDHs-AT, which are influenced mainly by stability of crystal structure due to the existence of interlayer water molecules. The discovery opens up a similar pathway by controlling the amount of water molecules to boost catalytic performance for studying other electrocatalysts with heteroatom dopant.
基金Project supported by the National Natural Science Foundation of China (Grant No. 10676022)
文摘The dissociation limits of isotopic water molecules are derived for the ground state. The equilibrium geometries, the vibrational frequencies, the force constants and the dissociation energies for the ground states of all isotopic water molecules under the dipole electric fields from -0.05 a.u. to 0.05 a.u. are calculated using B3P86/6-311++G(3df,3pf). The results show that when the dipole electric fields change from -0.05 a.u. to 0.05 a.u., the bond length of H-O increases whereas the bond angle of H-O H decreases because of the charge transfer induced by the applied dipole electric field. The vibrational frequencies and the force constants of isotopic water molecules change under the influence of the strong external torque. The dissociation energies increase when the dipole electric fields change from -0.05 a.u. to 0.05 a.u. and the increased dissociation energies are in the order of H2O, HDO, HTO, D2O, DTO, and T2O under the same external electric fields.
基金Project supported by the Fundamental Research Funds for the Central Universities of China(Grant No.2015QNA48)the Natural Science Foundation of Jiangsu Province,China(Grant No.BK20150173)+1 种基金the Science and Technology Commission of Shanghai Municipality,China(Grant No.16ZR1445100)the National Natural Science Foudnation of China(Grant Nos.11725521 and 11605285)
文摘It is important to know the mechanisms of water molecules across carbon-based nanochannels, which is not only beneficial for understanding biological activities but also for designing various smart devices. Here we review the recent progress of research tbr water transfer across carbon-based nanochannels. In this review, we summarize the recent methods which can affect water molecules across these nanochannels. The methods include exterior factors (i.e., dipolar molecules and gradient electric fields) and interior factors (namely, cone-shaped structures, nonstraight nanochannels, and channel defects). These factors can control water permeation across nanochannels efficiently.
文摘Experimental and theoretical studies of the author (period: 1968-present) have shown that true sources of </span><span style="font-family:"">the </span><span style="font-family:"">magnetic field are magnetic fundamental particles (magnetic charges), and not moving electrons. The main reason for <span>ignoring real magnetic charges, as well as true antielectrons in physical</span> science is the hard conditions for confinement of these particles in atoms and substance</span><span style="font-family:"">s</span><span style="font-family:"">, which </span><span style="font-family:"">is </span><span style="font-family:"">radically different from the confinement of electrons. Magnetic charges together with electric charges form the shells atoms which are <span>electromagnetic, and not electronic. Namely</span></span><span style="font-family:"">,</span><span style="font-family:""> electromagnetic shells are</span><span style="font-family:""> sources of gravitational field which is </span><span style="font-family:"">a </span><span style="font-family:"">vortex electromagnetic field and de<span>scribed by the vortex</span></span><span style="font-family:""> rot [<i>E</i> - <i>H</i>]</span><span style="font-family:"">. Depending on the state polarization o</span><span style="font-family:"">f vortex vectors </span><span style="font-family:"">rot [<i>E</i> - <i>H</i>]</span><span style="font-family:""> in compositions of atomic gravitational fields it </span><span style="font-family:"">is </span><span style="font-family:"">subdivided into paragravitational (PGF) and ferrogravitational fields </span><span style="font-family:"">(FGF). The overwhelming number of atoms emits PGF. Between the masses (bodies, atoms, nucleons and others) emitting PGF areas of negative gravitational “Dark Energy” are realized the forces of which press the masses towards each other. Namely</span><span style="font-family:"">,</span><span style="font-family:""> the compression of atoms by the forces of paragravitational “Dark Energy” underlies the chemical bond. The exception here is the ionic bond in ionic crystals. However, all ions have electromagnetic shells that generate the gravitational field. Consequently, ionic bonding is a relatively rare addition to gravito-chemical bond processes. The direct gravito-chemical bond of carbon atom</span><span style="font-family:"">s</span><span style="font-family:""> with hydrogen (<sup>1</sup>H) is physically forbidden due to </span><span style="font-family:"">the </span><span style="font-family:"">manifestation of the effect of ferrogravitational levitation between them and the repulsion of atoms from each other. Paradoxically, but all existing ideas about the structural device of hydrocarbons are based on such physically forbidden bonds which, moreover, must be realized through ionic <span>bonds which in reality do not exist. Chemical bonding of carbon and hydrogen </span>atoms to form hydrocarbons molecules is possible only if the hydrogen atoms are in the molecular form (<sup>1</sup>H<sub>2</sub>). In the composition of water, within the framework of the chemical formula H<sub>2</sub>O, two stable isomorphic molecular structures are formed. The chemical bond in the first structure is similar to the hydrocarbon scenario described above, </span><span style="font-family:""><i></span><i><span style="font-family:"">i.e.</span></i><i><span style="font-family:""></i></span></i><span style="font-family:""> in the process of combining paragravitational oxygen with a hydrogen molecule <sup>1</sup>H<sub>2</sub>. The second molecular structure in water is <span>formed under conditions of ferropolarization of the gravitational field of</span> oxygen atom</span><span style="font-family:"">s</span><span style="font-family:""> under the influence of FGF of neighboring <sup>1</sup>H atoms. In this case, the chemical bond is realized under the conditions of ferropolarization</span><span style="font-family:""> </span><span style="font-family:"">of the vortex vectors </span><span style="font-family:"">rot [<i>E</i> - <i>H</i>]</span><span style="font-family:""> of the gravitational fields of all atoms in</span><span style="font-family:""> the molecule and the co-directionality of them vectors </span><span style="font-family:""><i></span><b><i><span style="font-family:"">P</span></i></b><i><sub><span style="font-family:"">fp</span></sub></i><i><sub><span style="font-family:""></i></span></sub></i><span style="font-family:""> ferropolarization. The gravito-physical properties of the presented molecular structures in the composition of water make it possible to name them, respectively, as heavy and light clusters.
基金This work was supported by a Doctoral program of Zhejiang University of science and technology(F701104L08)。
文摘The problems of traditional concrete such as brittleness,poor toughness and short service life of concrete engineering under acid rain or marine environment need to be solved urgently.Hydrated calcium silicate(C-S-H)is a key component to improve the mechanical properties and durability of concrete.However,the traditional method of concrete material design based on empirical models or comparative tests has become a bottleneck restricting the sustainable development of concrete.The synthesis method,molecular structure and properties of C-S-H were systematically described in this paper;The interface structure and interaction of graphene oxide/calcium silicate hydrate(C-S-H/GO)were discussed.On this basis,the saturated and unsaturated transport characteristics of ions and water molecules in C-S-H/GO nanochannels under the environment of ocean and acid rain were introduced.The contents of this review provide the basis for improving the multi-scale transmission theory and microstructure design of concrete.It has important guiding significance for analyzing and improving the service life of concrete in complex environment.
基金The authors are grateful for the financial support provided by the National Natural Science Foundation of China(NSFC)(Nos.51974094,51964004,and U20A20269).
文摘Chalcopyrite is a common copper-bearing mineral with antiferromagnetic properties.However,this property has rarely been considered in previous studies for detailed adsorption behaviors of molecules on chalcopyrite.Based on density functional theory(DFT),new adsorption pathways by H_(2)O and O_(2)on the chalcopyrite metal terminated(112)surface((112)-M)is found in this work.First,through simulating the adsorption of an isolated water molecule and monolayer water molecules,it is confirmed that H_(2)O molecules tend to adsorb on the surface Fe atoms more than on the surface Cu atoms.Then,we studied various adsorption behaviors of the O_(2)molecule.It is found that the adsorption on the hollow FeAFe site is the most stable case;however,O_(2)is undissociated.Two adsorption cases will happen when H_(2)OAO_(2)adsorb simultaneously on the surface.For the S site,the H_(2)O molecule thoroughly dissociated and formed SAO species,and the other case is H_(2)O undissociated adsorbing at the Cu site.For the former case,it is interesting that H_(2)O is dissociated before O_(2).
基金Project supported by the Fok Ying Tung Education Foundation, China (Grant No. 131008), the National Basic Research Program of China (Grant No. 2011CB922004)the National Natural Science Foundation of China (Grant No. 11075035)
文摘The detection of macromolecular conformation is particularly important in many physical and biological applications. Here we theoretically explore a method for achieving this detection by probing the electricity of sequential charged segments of macromolecules. Our analysis is based on molecular dynamics simulations, and we investigate a single file of water molecules confined in a half-capped single-walled carbon nanotube (SWCNT) with an external electric charge of +e or -e (e is the elementary charge). The charge is located in the vicinity of the cap of the SWCNT and along the centerline of the SWCNT. We reveal the picosecond timescale for the re-orientation (namely, from one unidirectional direction to the other) of the water molecules in response to a switch in the charge signal, -e -+ +e or +e -+ --e. Our results are well understood by taking into account the electrical interactions between the water molecules and between the water molecules and the external charge. Because such signals of re-orientation can be magnified and transported according to Tu et al. [2009 Proc. Natl. Aead. Sci. USA 106 18120], it becomes possible to record fingerprints of electric signals arising from sequential charged segments of a macromolecule, which are expected to be useful for recognizing the conformations of some particular macromolecules.
基金We acknowledge the financial support by the National Natural Science Foundation of China under Grant No. 11222544, the Fok Ying Tung Education Foundation under Grant No. 131008, and the Program for New Century Excellent Talents in University (NCET-12-0121). The computational resources uti- lized in this research were provided by Shanghai Supercomputer Center.
文摘The realization of rapid and unidirectional single-file wate^molecule flow in nanochannels has posed a challenge to date. Here, we report unprecedentedly rapid unidirectional single-file water-molecule flow under a translational terahertz electric field, which is obtained by developing a Debye double- relaxation theory. In addition, we demonstrate that all the single-file molecules undergo both stable translation and rotation, behaving like high-speed train wheels moving along a railway track. Inde- pendent molecular dynamics simulations help to confirm these theoretical results. The mechanism involves the resonant relaxation dynamics of H and O atoms. Purther, an experimental demon- stration is suggested and discussed. This work has implications for the design of high-efficiency nanochannels or smaller nanomachines in the field of nanotechnology, and the findings also aid in the understanding and control of water flow across biological nanochannels in biology-related research.
基金supported by the National Natural Science Foundation of China (No.51803093)National Science Foundation of Jiangsu Province (No.BK20180770)。
文摘Lightweight,highly strong and bio-based structural materials remain a long-lasting challenge.Here,inspired by nacre,a lightweight and high mechanical performance cellulosic material was fabricated via a facile and effective top-down approach and the resulting material has a high tensile strength of149.21 MPa and toughness of 1.91 MJ/m^(3).More specifically,the natural balsawood(NW) was subjected to a simple chemical treatment,removing most lignin and partial hemicellulose,follow by freeze-drying,forming wood aerogel(WA).The delignification process produced many pores and exposed numerous aligned cellulose nanofibers.Afterwards,the WA absorbed a quantity of moisture and was directly densified to form above high-performance cellulosic material.Such treatment imitates highly ordered"brick-and-mortar" arrangement of nacre,in which water molecules plays the role of mortar and cellulose nanofibrils make the brick part.The lightweight and good mechanical properties make this material promising for new energy car,aerospace,etc.This paper also explains the strengthening mechanism for making biomimetic materials by water molecules-induced hydrogen bonding and will open a new path for designing high-performance bio-based structural materials.
基金Project supported by the National Natural Science Foundation of china (Nos. 201173099, 20973078, 20673045), Graduate Innovation Fund of Jilin University (No. 20111031) and the Natural Sciences and Engineering Research Council of Canada.
文摘The contributions of explicit water molecules to color-tuning mechanism of firefly were studied. The explicit water molecules cause two different structures in the geometrical parameters of keto(-1) both in vacuo and aqueous solution. There are somewhat larger influences on absorption and emission spectra. When water molecules were added only on the side of benzothiazole ring, the spectra shift to the blue. In contrast, when waters were added only on the side of the thiazoline ring, the spectra shift to red. In a word, the color modulation of the emitted light depends on charge redistribution of molecule keto(-1), mainly the charge change of the benzothiazole and thiazole tings at the two terminal in keto(-1).
基金This study was financially supported in part by the National Natural Science Foundation of China(nos.21775018,21675022,and 21573097)the Natural Science Foundation of Jiangsu Province(no.BK20170084)+2 种基金the Postgraduate Research and Innovation Program of Jiangsu Province(no.KYCX17_0137)the Open Funds of the State Key Laboratory of Electroanalytical Chemistry(no.SKLEAC201909)the Fundamental Research Funds for the Central Universities.
文摘The exploitation of the interaction between nanostructured matter and small molecules,such as H_(2)O at interfaces via dynamic hydrogen bonding,is essentially the key for smart,responsive nanodevices but remains challenging.Herein,the authors report that the carbon nitride nanoribbons(CNNRs)with an anisotropic intraplanar and interplanar molecular arrangement underwent a deformation by H_(2)O triggering.Both experiments of bulk samples and single nanoribbons disclosed that the reversible formation of a hydrogen-bonded H_(2)O adsorption layer was the source of the CNNRs deformation,reminiscent of the hydration-triggered twist of natural bean pods in seeding.Nonetheless,CNNRs had a more balanced H_(2)O affinity,enabling a superior response and recovery time.By coupling with carbon nanotubes,the authors also converted the deformation of CNNRs into more straightforward electrical readouts with record-fast response time.Further applied to capture fluctuations in humidity in real-time respiration,a higher detection sensitivity was obtained in a contactless mode,which compared favorably with the clinical breath-testing station.Given the carbon nitride family with various C/N ratios,surface properties,and topography,this finding that CNNRs are an outstanding H_(2)O transducer would significantly pave the way for the H_(2)O-triggered smart devices in broad prospective applications.
文摘Reaction of p-t-butylcalix[6]arene with ethylene oxide gives a water soluble host compound with a hydrophobic cavity and it can include organic molecules and ions in aqueous solution.
基金Financial support from the National Key Research and Development Program of China(2017YFC0403902)the National Basic Research Program of China(2015CB655301)+5 种基金the National Natural Science Foundation of China(21825803)the Jiangsu Natural Science Foundations(BK20190085 and BK20150063)the Program of Excellent Innovation Teams of Jiangsu Higher Education Institutionsthe Project of Priority Academic Program Development of Jiangsu Higher Education Institutions is gratefully acknowledgedWe are also grateful to the High Performance Computing Center of Nanjing Tech Universitythe National Supercomputing Center in Wuxi for supporting us with computational resources.
文摘Understanding the transport resistance of water molecules in polyamide(PA)reverse osmosis(RO)membranes at the molecular level is of great importance in guiding the design,preparation,and applications of these membranes.In this work,we use molecular simulation to calculate the total transport resistance by dividing it into two contributions:the interior part and the interfacial part.The interior resistance is dependent on the thickness of the PA layer,while the interfacial resistance is not.Simulation based on the 5 nm PA layer reveals that interfacial resistance is the dominating contribution(>62%)to the total resistance.However,for real-world RO membranes with a 200 nm PA layer,interfacial resistance plays a minor role,with a contribution below 10%.This implies that there is a risk of inaccuracy when using the typical method to estimate the transport resistance of RO membranes,as this method involves simply multiplying the total transport resistance of the simulated value based on a membrane with a 5 nm PA layer.Furthermore,both the interfacial resistance and the interior resistance are dependent on the chemistry of the PA layer.Our simulation reveals that decreasing the number of residual carboxyl groups in the PA layer leads to decreased interior resistance;therefore,the water permeability can be improved at no cost of ion rejection,which is in excellent agreement with the experimental results.
文摘Alkaline hydrogen evolution reaction(HER)offers a near-zero-emission approach to advance hydrogen energy.However,the activity limited by the multiple reaction steps involving H_(2)O molecules transfer,absorption,and activation still unqualified the thresholds of economic viability.Herein,we proposed a multisite complementary strategy that incorporates hydrophilic Mo and electrophilic V into Ni-based catalysts to divide the distinct steps on atomically dispersive sites and thus realize sequential regulation of the HER process.The Isotopic labeled in situ Raman spectroscopy describes 4-coordinated hydrogen bonded H_(2)O to be free H_(2)O passing the inner Helmholtz plane in the vicinity of the catalysts under the action of hydrophilic Mo sites.Furthermore,potential-dependent electrochemical impedance spectroscopy(EIS)reveals that electrophilic V sites with abundant 3d empty orbitals could activate the lone-pair electrons in the free H_(2)O molecules to produce more protic hydrogen,and dimerize into H_(2) at the Ni sites.By the sequential management of reactive H_(2)O molecules,NiMoV oxides multisite catalysts surpass Pt/C hydrogen evolution activity(49 mV@10 mA∙cm^(-2) over 140 h).Profoundly,this study provides a tangible model to deepen the comprehension of the catalyst–electrolyte interface and create efficient catalysts for diverse reactions.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.41805014 and 62205005)the Key Program of the Natural Science Research Fund of the Education Department of Anhui Province (Grant Nos.KJ2021A0637 and KJ2021A0638)the Key Program in the Youth Talent Support Plan in Universities of Anhui Province (Grant No.gxyqZD2020032)。
文摘Accurate spectroscopic data for H_(2)^(16)O in the 1.1μm region are particularly important for the study of Earth's atmosphere.The pure water vapor molecular spectra were measured based on direct laser absorption spectroscopy using a narrow line-width external cavity diode laser combined with a high-precision Fabry-Pérot etalon.A total of 31 H_(2)^(16)O transitions were studied for the first time by using the speed-dependent Nelkin-Ghatak profile and the Hartmann-Tran profile.From an accurate line-shape analysis,we obtained the line intensities and the self-broadening coefficients,and they are compared with the available data reported in the HITRAN 2016 database and the HITRAN 2020 database.Finally,we obtained information on the influence of Dicke narrowing,as well as the correlations between Dicke narrowing and speed dependence,and of speed-dependent effects.
基金financially supported by the National Natural Science Foundation of China(Nos.51804213,51820105006,51474167,51674183,and 51674174)the China Scholarships Council(No.201906935041)。
文摘Surface charges and hydration are predominant properties of colloidal particles that govern colloidal stability in aqueous suspensions.These properties usually coexist and interact with each other.The correlation between the surface charge and hydration of minerals is summarized on the basis of innovative experimental,theoretical,and molecular dynamics simulation studies.The factors affecting the adsorption behavior of ions and water molecules,such as ion concentration,ion hydration radius and valence,and surface properties,are discussed.For example,the hydration and adsorption states completely differ between monovalent and divalent ions.For ions of the same valence,the effect of surface charge on the hydration force follows the Hofmeister adsorption series.Electrolyte concentration exerts a significant effect on the hydration force at high ion concentrations.Meanwhile,the ion correlations in high-concentration electrolyte systems become long range.The interfacial water structure largely depends on surface chemistry.The hydration layer between different surfaces shows large qualitative differences.
基金financially suppor ted by the National Key Research and Development Program of China(2022YFB3503700)the National Natural Science Foundation of China(22074021)
文摘Lanthanide ions-doped upconversion nanoparticles(UCNPs)have shown great potential in various biomedical applications.However,the upconversion luminescence(UCL)intensity of UCNPs in water environment tends to be quenched.This quenching is typically attributed to non-radiative relaxation of the excited state.In this study,we designed a core-shellshell-shell NaYb_(0.88)Er_(0.12)F_(4)@NaY_(0.9)b_(0.1)F_(4)@NaY_(0.6)Nd_(0.3)Yb_(0.1)F_(4)@NaYF_(4)UCNPs that could be excited by both 980 nm and 808 nm laser,due to the doping of Nd^(3+)and Yb^(3+)ions.Our research not only utilized bulk spectral measurement but also employed single-particle level microscopic imaging to comprehensively investigate the impact of water molecules on UCL under 980 nm and 808 nm irradiation.Interestingly,our findings indicate that the absorption of water molecules has a significant effect on the UCL decay of UCNPs in aqueous solutions when excited by a 980 nm laser.This work offers a new perspective on the luminescence behavior of UCNPs in aquatic environments and provides valuable insights for their application and development in biomedicine.
基金supported by the National Key Research and Development Program of China(No.2021YFA 1200800)the Start‐up Funds of Wuhan Universitysupported by the National Research Foundation,Singapore,under its Competitive Research Programmer(No.NRF‐CRP22‐2019‐0007).
文摘Two‐dimensional(2D)ferroelectrics have attracted considerable attention due to their potential in the development of devices of miniaturization and multifunction.Although several van der Waals(vdW)‐layered materials show ferroelectricity,the experimental demonstrations of ferroelectric behavior in monolayers are very limited.Here we report the observation of room‐temperature out‐of‐plane switchable electric polarization in supported MoS_(2) monolayers exfoliated from 3R‐stacked bulk crystals under ambient conditions.Using in situ piezoelectric force microscopy and Kelvin probe force microscopy in a glovebox,we reveal that trapped water/ice molecules are responsible for this switchable electric polarization and this conclusion is strongly supported by theoretical simulations.It is worth noting that the water/ice trapping in the monolayers exfoliated from 2H‐stacked MoS_(2) crystals is not as much as that in 3R monolayers and,consequently,the out‐of‐plane electric polarization is missing there.Our findings indicate that monolayers with a trapped single layer of polar molecules might be emerging alternatives to 2D ferroelectrics.Furthermore,the stacking sequences may bring new properties and applications to 2D vdW materials not only when we stack them up but also when we thin them down.