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A Pilot-scale Demonstration of Reverse Osmosis Unit for Treatment of Coal-bed Methane Co-produced Water and Its Modeling 被引量:1
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作者 钱智 刘新春 +2 位作者 余志晟 张洪勋 琚宜文 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第2期302-311,共10页
This study presents the first demonstration project in China for treatment of coal-bed methane(CBM) co-produced water and recycling.The work aims to provide a research and innovation base for solving the pollution pro... This study presents the first demonstration project in China for treatment of coal-bed methane(CBM) co-produced water and recycling.The work aims to provide a research and innovation base for solving the pollution problem of CBM extraction water.The reverse osmosis(RO) unit is applied to the treatment of CBM co-produced water.The results indicate that system operation is stable,the removal efficiency of the total dissolved solids(TDS) is as high as 97.98%,and Fe,Mn,and F-are almost completely removed.There is no suspended solids(SS) detected in the treated water.Furthermore,a model for the RO membrane separation process is developed to describe the quantitative relationship between key physical quantities-membrane length,flow velocity,salt concentration,driving pressure and water recovery rate,and the water recovery restriction equation based on mass balance is developed.This model provides a theoretical support for the RO system design and optimization.The TDS in the CBM co-produced water are removed to meet the "drinking water standards" and "groundwater quality standards" of China and can be used as drinking water,irrigation water,and livestock watering.In addition,the cost for treatment of CBM co-produced water is assessed,and the RO technology is an efficient and cost-effective treatment method to remove pollutants. 展开更多
关键词 coal-bed methane co-produced water high salt pretreatment process mass balance reverse osmosis
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氢氧化铝沉淀法从煤层气田产出水中吸附锂的方法探索 被引量:1
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作者 刘新春 王斌 +6 位作者 刘研萍 李娟 余志晟 钱智 陶莹 琚宜文 张洪勋 《化工矿物与加工》 CAS 北大核心 2012年第9期20-22,37,共4页
煤层气在开采的过程中会产生大量伴生水,经过反渗透处理后的浓水中含有Li+等多种离子,本文以山西某煤层气田产出水经反渗透处理后的浓水为样本,按照一定的比例配水进行Li+吸附试验,结果显示:在50℃,不断搅拌,m(Al)/m(Li)为3.3,m(Na)/m(... 煤层气在开采的过程中会产生大量伴生水,经过反渗透处理后的浓水中含有Li+等多种离子,本文以山西某煤层气田产出水经反渗透处理后的浓水为样本,按照一定的比例配水进行Li+吸附试验,结果显示:在50℃,不断搅拌,m(Al)/m(Li)为3.3,m(Na)/m(Al)为2.6,2mol/L的NaOH溶液的滴加速率为10mL/min的条件下,反应1.5h后,有明显吸附效果的最低Li+质量浓度为0.5g/L,Li+沉淀率为86.57%。将煤层气田产出水经反渗透处理的浓水浓缩600倍,使其中Li+质量浓度达0.5g/L,按照配水试验条件进行Li+吸附试验,Li+沉淀率为86.17%。 展开更多
关键词 氢氧化铝沉淀法 煤层气田产出水
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煤层气田产出水中锂的回收方法研究
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作者 王斌 郭佳林 《化工矿物与加工》 CAS 北大核心 2013年第6期15-17,共3页
煤层气田产出水经过反渗透处理后的浓水中含有较高质量浓度的Li+,本文以山西某煤层气田产出水经反渗透处理后的浓水为样本进行配水提Li+试验,结果表明:控制Al/Li(物质的量比)为3.3,Na/Al(物质的量比)为2.6,同时滴加铝盐溶液和NaOH溶液... 煤层气田产出水经过反渗透处理后的浓水中含有较高质量浓度的Li+,本文以山西某煤层气田产出水经反渗透处理后的浓水为样本进行配水提Li+试验,结果表明:控制Al/Li(物质的量比)为3.3,Na/Al(物质的量比)为2.6,同时滴加铝盐溶液和NaOH溶液并不断搅拌,在恒温55℃下反应120min后,Li+沉淀率最高,为88.71%。 展开更多
关键词 氢氧化铝沉淀法 煤层气田产出水
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