Bimetallic Single‑Atom Catalysts for Water Splitting

Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society.The field of catalysis has been revolutionized by single-atom catalysts(SACs),which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports.Recently,bimetallic SACs(bimSACs)have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports.BimSACs offer an avenue for rich metal–metal and metal–support cooperativity,potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges,substrate activation with reversible redox cycles,simultaneous multi-electron transfer,regulation of spin states,tuning of electronic properties,and cyclic transition states with low activation energies.This review aims to encapsulate the growing advancements in bimSACs,with an emphasis on their pivotal role in hydrogen generation via water splitting.We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs,elucidate their electronic properties,and discuss their local coordination environment.Overall,we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction,the two half-reactions of the water electrolysis process.

Sugarcane Requirement of Water and Effect of Fertigation on Sugarcane

The sugarcane is a main sugar crop in China. The seasonal drying is one of the problems that influence the improvement of output and quality of sugarcane in China. The experimental results for the water requirement and fertigation of the sugarcane showed, that the distribution of the rainfall in spring, autumn and winter, all could not suit the requirements for sugarcane growth. Detailedly, it can suit that sugarcane requirement of 74.4%, 68.6% and 35.7% respectively at seedling emerging stage, tillering stage and mature stage according to sugarcane growth. The drought has already limited the yield of sugarcane. Application of fertigation can enhance the fertilizer use efficiency, and it is also a water saving technique in sugarcane production.

Study on the Characteristics of Ecological Water Requirement in Maijishan Scenic Spot

[Objective] This study aimed to explore the characteristics of ecological water requirement in Maijishan Scenic Spot. [Methed] The characteristics of ecologi- cal water requirement in Maijishan Scenic Spot were analyzed based on,the data of soil humidity and meteorology of the spot. [Result] The result showed that the actual annual ecological water requirement in the spot was 678×10^6 m^3, and the proportion of soil water and evapotranspiration were 21% and 79%, respectively; the minimum annual ecological water requirement quota in the spot was 480.27×10^6 m^3, and the proportion of soil water and evapotranspiration were 16% and 84%, respectively; the minimum annual suitable ecological water requirement quota in the spot was 624.22×10^6 m^3, and the proportion of soil water and evapotranspiration were 18% and 82%, respectively. The precipitation was 614×10^6 m^3, and consumptive water surplus reached up to 78×10^6 m^3. The years when the precipitation was higher than the evapotranspiration accounted for 76%. Since 1980s, the evapotranspiration showed a linearly increasing trend. The precipitation was higher than the evapotranspiration from Jun. to Oct. and less than the evapotranspiration from Nov. to Dec. and Jan. to May. Evapotranspiration water requirement was regulated by soil water. The dis- parity between precipitation and evapotranspiration was huge in spring, thus having certain influence on waterfalls and streams in the spot. [Conclusion] The results of this study provided a basis for the rational use and long-term planning of the water sources in Maijishan Scenic Spot.

Estimation of Ecological Water Requirements Based on Habitat Response to Water Level in Huanghe River Delta,China

In recent years,wetland ecological water requirements (EWRs) have been estimated by using hydrological and functional approaches,but those approaches have not yet been integrated for a whole ecosystem.This paper presents a new method for calculating wetland EWRs,which is based on the response of habitats to water level,and determines water level threshold through the functional integrity of habitats.Results show that in the Huanghe (Yellow) River Delta water levels between 5.0 m and 5.5 m are required to maintain the functional integrity of the wetland at a value higher than 0.7.One of the dominant plants in the delta,Phragmites australis,tolerates water level fluctuation of about ± 0.25 m without the change in wetland functional integrity.The minimum,optimum and maximum EWRs for the Huanghe River Delta are 9.42×106 m3,15.56×106 m3 and 24.12×106 m3 with water levels of 5.0 m,5.2 m and 5.5 m,corresponding to functional integrity indices of 0.70,0.84 and 0.72,respectively.A wetland restoration program has been performed,which aims to meet these EWRs in attempt to recover from losses of up to 98% in the delta's former wetland area.

Environmental and ecological water requirement of river system: a case study of Haihe-Luanhe river system

In order to reduce the environmental and ecological problems induced by water resources development and utilization, this paper proposes a concept of environmental and ecological water requirement. It is defined as the minimum water amount to be consumed by the natural water bodies to conserve its environmental and ecological functions. Based on the definition, the methods on calculating the amount of environmental and ecological water requirement are determined. In the case study on Haihe-Luanhe river system, the water requirement is divided into three parts, i.e., the basic in-stream flow, water requirement for sediment transfer and water consumption by evaporation of the lakes or everglades. The results of the calculation show that the environmental and ecological water requirement in the river system is about 124×108 m3, including 57×108 m3 for basic in-stream flow, 63×108 m3 for sediment transfer and 4×108 m3 for net evaporation loss of lakes. The total amount of environmental and ecological water requirement accounts for 54% of the amount of runoff (228×108 m3). However, it should be realized that the amount of environmental and ecological water requirement must be more than that we have calculated. According to this result, we consider that the rational utilization rate of the runoff in the river systems must not be more than 40%. Since the current utilization rate of the river system, which is over 80%, has been far beyond the limitation, the problems of environment and ecology are quite serious. It is imperative to control and adjust water development and utilization to eliminate the existing problems and to avoid the potential ecological or environmental crisis.

Method for calculating ecological water storage and ecological water requirement of marsh

As one of the most typical wetlands,marsh plays an important role in hydrological and economic aspects,especially in keeping biological diversity.In this study,the definition and connotation of the ecological water storage of marsh is discussed for the first time,and its distinction and relationship with ecological water requirement are also analyzed.Furthermore,the gist and method of calculating ecological water storage and ecological water requirement have been provided,and Momoge wetland has been given as an example of calculation of the two variables.Ecological water use of marsh can be ascertained according to ecological water storage and ecological water requirement.For reasonably spatial and temporal variation of water storage and rational water resources planning,the suitable quantity of water supply to marsh can be calculated according to the hydrological conditions,ecological demand and actual water resources.

Investigation of crop evapotranspiration and irrigation water requirement in the lower Amu Darya River Basin, Central Asia

High water consumption and inefficient irrigation management in the agriculture sector of the middle and lower reaches of the Amu Darya River Basin(ADRB)have significantly influenced the gradual shrinking of the Aral Sea and its ecosystem.In this study,we investigated the crop water consumption in the growing seasons and the irrigation water requirement for different crop types in the lower ADRB during 2004–2017.We applied the FAO Penman–Monteith method to estimate reference evapotranspiration(ET0)based on daily climatic data collected from four meteorological stations.Crop evapotranspiration(ETc)of specific crop types was calculated by the crop coefficient.Then,we analyzed the net irrigation requirement(NIR)based on the effective precipitation with crop water requirements.The results indicated that the lowest monthly ET0 values in the lower ADRB were found in December(18.2 mm)and January(16.0 mm),and the highest monthly ET0 values were found in June and July,with similar values of 211.6 mm.The annual ETc reached to 887.2,1002.1,and 492.0 mm for cotton,rice,and wheat,respectively.The average regional NIR ranged from 514.9 to 715.0 mm in the 10 Irrigation System Management Organizations(UISs)in the study area,while the total required irrigation volume for the whole region ranged from 4.2×109 to 11.6×109 m3 during 2004–2017.The percentages of NIR in SIW(surface irrigation water)ranged from 46.4%to 65.2%during the study period,with the exceptions of the drought years of 2008 and 2011,in which there was a significantly less runoff in the Amu Darya River.This study provides an overview for local water authorities to achieve optimal regional water allocation in the study area.

Spatiotemporal variations of evapotranspiration and reference crop water requirement over 1957-2016 in Iran based on CRU TS gridded dataset

Agriculture needs to produce more food to feed the growing population in the 21st century.It makes the reference crop water requirement(WREQ)a major challenge especially in regions with limited water and high water demand.Iran,with large climatic variability,is experiencing a serious water crisis due to limited water resources and inefficient agriculture.In order to overcome the issue of uneven distribution of weather stations,gridded Climatic Research Unit(CRU)data was applied to analyze the changes in potential evapotranspiration(PET),effective precipitation(EFFPRE)and WREQ.Validation of data using in situ observation showed an acceptable performance of CRU in Iran.Changes in PET,EFFPRE and WREQ were analyzed in two 30-a periods 1957-1986 and 1987-2016.Comparing two periods showed an increase in PET and WREQ in regions extended from the southwest to northeast and a decrease in the southeast,more significant in summer and spring.However,EFFPRE decreased in the southeast,northeast,and northwest,especially in winter and spring.Analysis of annual trends revealed an upward trend in PET(14.32 mm/decade)and WREQ(25.50 mm/decade),but a downward trend in EFFPRE(-11.8 mm/decade)over the second period.Changes in PET,EFFPRE and WREQ in winter have the impact on the annual trend.Among climate variables,WREQ showed a significant correlation(r=0.59)with minimum temperature.The increase in WREQ and decrease in EFFPRE would exacerbate the agricultural water crisis in Iran.With all changes in PET and WREQ,immediate actions are needed to address the challenges in agriculture and adapt to the changing climate.

Water quantity-quality combined evaluation method for rivers＇ water requirements of the instream environment in dualistic water cycle： A case study of Liaohe River Basin

In this article the meaning of the quantity and quality of environmental flows of river in dualistic water cycle is discussed, and compared with the meaning of unitary water cycle. Based on the analysis of the relationship between environmental flows of river requirements, the efficiency of water resource usage, the consumption coefficient, and the concentration of waste water elimination, the water quantity and water quality calculation method of the environmental flows of river requirements in dualistic water cycle is developed, and the criteria for environmental flows of river requirements are established, and therefore the water quantity-quality combined evaluation of natural river flows requirements are realized Taking the Liaohe River as a model, the environmental flows of river requirements for Xiliao River, Dongliao River, mainstream Liaohe River, Huntai River and northeast rivers along the coasts of the Yellow and Bohai seas in unitary water cycle are calculated, each taking up 39.3%, 63.0%, 43.9%, 43.3% and 43.5% of runoff respectively. Evaluated according to Tennant recommended flow, the results show that： except Xiliao River is ＂median＂, the rest are all upon ＂good＂, the Dongliao River is even ＂very good＂. The corresponding results in dualistic water cycle are that, the proportion of natural flows for each river is 57.5%, 74.1%, 60.8%, 60.3% and 60.4%; while the combined evaluation results show that： considering ＂quantity＂, except Xiliao River, the rest rivers can all achieve the ＂quantity＂ criteria of the en- vironmental flows of river requirements, but if considering the aspect of ＂quality＂, only Dongliao River can reach the ＂quality＂ standard. By water quantity-quality combined evaluation method, only Dongliao River can achieve the criteria. So the water quality is the main factor that determines whether the environmental flows can meet the river ecosystem demands.

Considering the Influence of Multi-weather-factors to Forecasting the Water Requirement of Well Irrigation Rice Based on ANN Model

The author considered the influences of several weather factors, such as air temperature, sunlight, saturation deficiency, wind speed and so on to forecasting the water requirement of well irrigation rice based on Artificial Neutron Network. Through dealing with the time series of water requirement and its influence factors, the author applied the multi-dimension data correlation analysis to ensure the net structure. Thus, the ANN model to forecast the water requirement of well irrigation rice has been built. By means of the ANN model, uncertainty relation between water requirement and many influence factors among the interior and exterior can be discovered. The results of ANN model is good, and can provide some references for establishing the water saving irrigation system.

Climate-induced Changes in Spring Maize Water Requirement in Xiliaohe River Watershed

Xiliaohe River watershed plays an important role in regional and national grain security.With the development of society and economy,water consumption that increased dramatically causes water shortages.Crop water requirement can provide quantitative basis for making regional irrigation scheme.In this study,spring maize water requirement is calculated by using PenmanMonteith formula and spring maize coefficient from May to September at 10 meteorological stations in Xiliaohe River watershed from 1951 to 2005.The variation trend of the spring maize water requirement during the whole growing stage,water requirement in every month,and meteorological influencing factors are obtained by using Mann-Kendall method,and the degree of grey incidence between the water requirement and meteorological influencing factors are shown.The results are the spring maize water requirement during the whole growing stages increases at half of the stations in Xiliaohe River watershed,and are remarkably affected by the water requirement in May.The monthly mean,maximum and minimum air temperature form May to September show an increasing trend in Xiliaohe River watershed in recent 55 years.The monthly mean and minimum air temperature increases notably.The relative humidity,precipitation,wind speed and sunshine show a decreasing trend with variety for different months.The monthly maximum air temperature,wind speed,sunshine and monthly mean air temperature have the highest correlation degree with spring maize water requirement from May to September.

Water requirement pattern for tobacco and its response to water deficit in Guizhou Province

The water requirement pattern for tobacco（Yun 85） was identified based on analysis of data obtained from pot experiments in a canopy at the Xiuwen Irrigation Test Central Station in Guizhou Province, China. The results showed that the tobacco water requirement and the tobacco water requirement intensity throughout the growth period in pot experiments were significantly lower than those in field production. In pot experiments, the tobacco water requirement throughout the growth period ranged from 159.00 to 278.90 mm, with a reduction in the range of241e441 mm, as compared with that in field production. Also, the average water requirement intensity at the vigorous growing stage was1.97 mm/d, and the water requirement and water requirement module were 33.80e72.60 mm and 16.39%e33.09%, respectively, at the group stage, almost equal to their values at the vigorous growing stage. The patterns of the tobacco water requirement and water requirement module in pot experiments were different from those in field production. In pot experiments, the tobacco water requirement and water requirement module ranked the highest at the mature stage, followed by those at the group/vigorous growing and rejuvenation stages, while the water requirement intensity ranked the highest at the vigorous growing stage, followed by those at the mature, group, and rejuvenation stages. The pattern of the water requirement intensity in pot experiments was consistent with that in field production. In addition, the response of the tobacco water requirement to water deficit was also analyzed. Serious water deficit at the vigorous growing stage and continuous water stress at the group,vigorous growing, and mature stages can greatly influence the tobacco water requirement. Water deficit led to reductions in the water requirement and water requirement intensity at each growth stage. The vigorous growing stage exhibited the highest sensitivity to water deficit.The lower limit of moderate soil water stress at the vigorous growing stage was 65% of the field capacity. Results of this study can help to establish a reasonable irrigation schedule for tobacco production in Guizhou Province, China.

Water Requirements and Irrigation Scheduling of Spring Maize Using GIS and CropWat Model in Beijing-Tianjin-Hebei Region

Due to the over use of available water resources, it has become very important to define appropriate strategies for planning and management of irrigated farmland. In this paper, Beijing-Tianjin-Hebei (Jing-Jin-Ji) region was chosen as the case study area for its special political and economic status and its severe water problem. To achieve effective planning, the information about crop water requirements, irrigation withdrawals, soil types and climatic conditions were obtained in the study area. In the meantime, a GIS method was adopted, which extends the capabilities of the crop models to a regional level. The main objectives of the study are: 1) to estimate the spatial distribution of the evapotranspiration of spring maize; 2) to estimate climatic water deficit; 3) to estimate the yield reduction of spring maize under different rainfed and irrigated conditions. Based on the water deficit analysis, recommended supplemental irrigation schedule was developed using CropWat model. Compared to the rainfed control, the two or three times of supplemental water irrigated to spring maize at the right time reduced the loss of yield, under different scenarios.

Innovation Requirements and Progress of Dialysis Water Treatment System

With the development of medicine,people are becoming more and more aware of the quality of medical water supply,such as dial ysis water,dental water,preparation water,operating room water,supply room water.Therefore,People are constantly improving the water treatment system and its standardized,and the demand for dialysis water is also becoming more and more strict.Hemodialysis is an effective means of maintaining the life of renal failure patients,120~180L water will be used for a conventional dialysis treatment,and high flux dialysis will consume more.

China's Grain Production and Its Requirement for Water Resources Allocation

Agricultural water is directly related with grain production security. This article analyzes how to allocate the water resources in terms of grain production. Firstly,for the whole country,we established the VAR mathematical model with the data of 1983 to 2008 to test the relationships between the total amount of water and the agriculture production and forecast the water consumption in 2020. Then focusing on the major grain producing areas,we examine the main index and the pressure index,from which we find that the amount of agricultural water in major areas fail to satisfy the demand of production,and that unbalanced development exists between different areas with several areas especially serious. At last,we point out that,to ensure the security of agriculture production and the sustainable utilization of water resources,the government should take measures not only to prevent water pollution and reduce water consumption,but also to improve inter-basin water transfer planning.

Implications of future climate change on crop and irrigation water requirements in a semi-arid river basin using CMIP6 GCMs

Agriculture faces risks due to increasing stress from climate change,particularly in semi-arid regions.Lack of understanding of crop water requirement(CWR)and irrigation water requirement(IWR)in a changing climate may result in crop failure and socioeconomic problems that can become detrimental to agriculture-based economies in emerging nations worldwide.Previous research in CWR and IWR has largely focused on large river basins and scenarios from the Coupled Model Intercomparison Project Phase 3(CMIP3)and Coupled Model Intercomparison Project Phase 5(CMIP5)to account for the impacts of climate change on crops.Smaller basins,however,are more susceptible to regional climate change,with more significant impacts on crops.This study estimates CWRs and IWRs for five crops(sugarcane,wheat,cotton,sorghum,and soybean)in the Pravara River Basin(area of 6537 km^(2))of India using outputs from the most recent Coupled Model Intercomparison Project Phase 6(CMIP6)General Circulation Models(GCMs)under Shared Socio-economic Pathway(SSP)245 and SSP585 scenarios.An increase in mean annual rainfall is projected under both scenarios in the 2050s and 2080s using ten selected CMIP6 GCMs.CWRs for all crops may decline in almost all of the CMIP6 GCMs in the 2050s and 2080s(with the exceptions of ACCESS-CM-2 and ACCESS-ESM-1.5)under SSP245 and SSP585 scenarios.The availability of increasing soil moisture in the root zone due to increasing rainfall and a decrease in the projected maximum temperature may be responsible for this decline in CWR.Similarly,except for soybean and cotton,the projected IWRs for all other three crops under SSP245 and SSP585 scenarios show a decrease or a small increase in the 2050s and 2080s in most CMIP6 GCMs.These findings are important for agricultural researchers and water resource managers to implement long-term crop planning techniques and to reduce the negative impacts of climate change and associated rainfall variability to avert crop failure and agricultural losses.

Crop water requirements of major crops indryland of northern China

The concept of crop water requirements is discussed, based on which the calculation modelof crop water requirements is established. In light with crop, soil and meteorological data. the cropwater requirements of major crops in sub-humid and send-arid dryland farming areas of northernChina. including wheat maize , cotton. millet, soybean, sweet potato and potato, are calculated, andthe patterns of crop water requirements of these crops are revealed and discussed in this paper.

Study of Panjin Wetlands Along Bohai Coast(Ⅱ):Ecological Water Requirement of Shuangtaizi Estuarine Wetland

Shuangtaizi estuarine wetland along the Bohai Sea coast,the biggest bulrush wetland in the world,has been listed in 'The Record of Important International Wetland Conservation District'. Taking the year of 2 000 as an example,the minimum,the most suitable and the maximum ecological water requirement of Shuangtaizi estuarine wetland are calculated in this paper based on both ecological theory and Geological Information System technology. In addition,the remote sensing technique is adopted in the data acquisition process. Moreover,the total water requirement and the unit area water requirement for different wetland types are obtained. The result is very important for water resources planning,ecological conservation and regional agriculture structure adjustment in Shuangtaizi. Meanwhile,this study can serve as a useful example for calculating the ecological water requirement in other similar estuarine wetlands.

Research on Forecasting Water Requirement of Well Irrigation Rice by Time Series Analysis Method

The paper builds up the forecasting model of air temperature according to the data (1994～1998) of Fu Jin area.At the same time,the writer inquires into the relation of water requirement of well irrigation rice (ET) and average air temperature (T).Furthermore,the rice irrigation water requirement (ET) of Fu Jin area has been forecast in 1999.Thus,we can apply the model in irrigation management.

Water-requirement Characteristics and Water-saving Irrigation Indices of Dry-raised Rice Seedlings in Paddy Field

The dry-raised seedlings (D-RS)of rice had obvious superiority in tillering and growth after transplanting. Especially under the condition of water-saving irrigation or low soil moisture, D-RS had more productive tillers, higher dry matter accumulation, larger grain-filling rate, slower senescence of leaves and stronger root activity during ripening, and higher grain yield, compared with the moist-raised seedlings (MRS). D-RS had smaller yield reduction than M-RS when subject to heavy water stress. The results suggested that D-RS had the ability to adapt to lower soil moisture in paddy field. Basedon the response of D-RS to soil moisture at each growth stage, the water-saving and high-yielding irrigation indices through controlling lowlimit soil water potential were proposed, i.e. soil water potential was - 15 - - 20 kPa from the recovery to the criticalleaf-age of productive tillering, - 20 - - 40 kPa from the critical leaf-age of productive tillering to secondary branch-differentiating stage, - 15 - - 25 kPa from secondary branch-differentiating stage to 20 days after heading and - 25 - - 35 kPa from 21 to 45 days after heading.