Assessment of Super Absorbent Polymer (SAP) on Plant Available Water (PAW) in Dry Lands

One of the ways of overcoming the cost of irrigation is through in-situ water harvesting at the plant roots. Super absorbent polymer (SAP) can facilitate water harvesting at the plant roots. This study attempted to assess the effect of SAP on plant available water (PAW) of different soils. In this study, SAP was sequentially added at the rate of 0.2%, 0.3% and 0.5% of the soil weight and its impact assessed in clay, sandy clay and sandy loam soils. The moisture retention characteristics of the original and SAP treated soils were studied using soil water retention curves (SWRC) and results modelled using Gardner model. PAW was estimated from SWRC as the difference between moisture content at 1.5 and 3 bar in all soils. The difference in PAW between original and treated soils was assessed at 5% level of significance. The WRC of all the samples was adequately found to be described by the Gardner model (Coefficient of determination R2 ≥ 98% and residual standard error (RSE) ≤ 0.04). SWRC changed with increase in SAP percentage in clay, sandy clay and sandy loam soils. Clay had a higher change in water retention then sandy clay and lastly sandy loam. Plant available water content (PAW) in all soils increased. In clay soil it increased with increase in SAP from 0.3291 at zero SAP to 0.6223 at 0.5% SAP. Sandy clay soil increased in PAW from 0.2721 at zero SAP to 0.5335 at 0.5% SAP and Sandy loam soils from 0.1691 at zero SAP to 0.3461 at 0.5% SAP. Hence, from the study SAP can be used to conserve irrigation water in the plant roots and therefore reducing the cost since PAW has been increased.

A thermodynamics-based three-scale constitutive model for partially saturated granular materials

A three-scale constitutive model for unsaturated granular materials based on thermodynamic theory is presented.The three-scale yield locus,derived from the explicit yield criterion for solid matrix,is developed from a series of discrete interparticle contact planes.The three-scale yield locus is sensitive to porosity changes;therefore,it is reinterpreted as a corresponding constitutive model without phenomenological parameters.Furthermore,a water retention curve is proposed based on special pore morphology and experimental observations.The features of the partially saturated granular materials are well captured by the model.Under wetting and isotropic compression,volumetric compaction occurs,and the degree of saturation increases.Moreover,the higher the matric suction,the greater the strength,and the smaller the volumetric compaction.Compared with the phenomenological Barcelona basic model,the proposed three-scale constitutive model has fewer parameters;virtually all parameters have clear physical meanings.

Unraveling the hydraulic properties of loess for landslide prediction:A study on variations in loess landslides in Lanzhou,Dingxi,and Tianshui,China

Loess has distinctive characteristics,leading to frequent landslide disasters and posing serious threats to the lives and properties of local re sidents.The involvement of water repre sents a critical factor in inducing loess landslides.This study focuses on three neighboring cities sequentially situated on the Loess Plateau along the direction of aeolian deposition of loess,namely Lanzhou,Dingxi,and Tianshui,which are densely populated and prone to landslide disasters.The variations in hydraulic properties,including water retention capacity and permeability,are investigated through Soil Water Characteristic Curve(SWCC)test and hydraulic conductivity test.The experimental findings revealed that Tianshui loess exhibited the highest water retention capacity,followed by Dingxi loess,while Lanzhou loess demonstrated the lowest water retention capacity.Contrastingly,the results for the saturated permeability coefficient were found to be the opposite:Tianshui loess showed the lowest permeability,whereas Lanzhou loess displayed the highest permeability.These results are supported and analyzed by scanning electron microscopy(SEM)observation.In addition,the water retention capacity is mathematically expressed using the van Genuchten model and extended to predict unsaturated hydraulic properties of loess.The experimental results exhibit a strong accordance with one another and align with the regional distribution patterns of disasters.

Effect of vegetation on soil water retention and storage in a semi-arid alpine forest catchment

The runoff generated from mountainous regions is recognized as the main water source for inland river basins in arid environments. Thus, the mechanisms by which catchments retain water in soils are to be understood. The water storage capacity of soil depends on its depth and capacity to retain water under gravita- tional drainage and evapotranspiration. The latter can be studied through soil water retention curve （SWRC）, which is closely related to soil properties such as texture, bulk density, porosity, soil organic carbon conteMt, and so on. The present study represented SWRCs using HYDRUS-1D. In the present study, we measured pl^ysical and hydraulic properties of soil samples collected from Sabina przewalskii forest （south-facing slope with highest solar radiation）, shrubs （west-facing slope with medium radiation）, and Picea crassifolia forest （north-facing slope with lowest radiation）, and analyzed the differences in soil water storage capacity of these soil samples. Soil water content of those three vegetation covers were also measured to validate the soil water storage capacity and to analyze the relationship between soil organic matter content and soil water content. Statistical analysis showed that different vegetation covers could lead to different soil bulk densities and differences in soil water retention on the three slope aspects. Sand content, porosity, and organic carbon content of the P. crassifolia forest were rela- tively greater compared with those of the S. przewalskii forest and shrubs. However, silt content and soil bulk density were relatively smaller than those in the S. przewalskii forest and shrubs. In addition, there was a sig- nificant linear positive relationship between averaged soil water content and soil organic matter content （P〈0.0001）. However, this relationship is not significant in the P. crassifolia forest. As depicted in the SWRCs, the water storage capacity of the soil was 39.14% and 37.38% higher in the P. crassifolia forest than in the S. przewalskii forest and shrubs, respectively, at a similar soil depth.

Scenario simulation of water retention services under land use/cover and climate changes: a case study of the Loess Plateau, China

Comprehensive assessments of ecosystem services in environments under the influences of human activities and climate change are critical for sustainable regional ecosystem management. Therefore,integrated interdisciplinary modelling has become a major focus of ecosystem service assessment. In this study, we established a model that integrates land use/cover change(LUCC), climate change, and water retention services to evaluate the spatial and temporal variations of water retention services in the Loess Plateau of China in the historical period(2000–2015) and in the future(2020–2050). An improved Markov-Cellular Automata(Markov-CA) model was used to simulate land use/land cover patterns, and ArcGIS 10.2 software was used to simulate and assess water retention services from 2000 to 2050 under six combined scenarios, including three land use/land cover scenarios(historical scenario(HS), ecological protection scenario(EPS), and urban expansion scenario(UES)) and two climate change scenarios(RCP4.5 and RCP8.5, where RCP is the representative concentration pathway). LUCCs in the historical period(2000–2015) and in the future(2020–2050) are dominated by transformations among agricultural land, urban land and grassland. Urban land under UES increased significantly by 0.63×10^(3) km^(2)/a, which was higher than the increase of urban land under HS and EPS. In the Loess Plateau, water yield decreased by 17.20×10^(6) mm and water retention increased by 0.09×10^(6) mm in the historical period(2000–2015),especially in the Interior drainage zone and its surrounding areas. In the future(2020–2050), the pixel means of water yield is higher under RCP4.5 scenario(96.63 mm) than under RCP8.5 scenario(95.46mm), and the pixel means of water retention is higher under RCP4.5 scenario(1.95 mm) than under RCP8.5 scenario(1.38 mm). RCP4.5-EPS shows the highest total water retention capacity on the plateau scale among the six combined scenarios, with the value of 1.27×10^(6) mm. Ecological restoration projects in the Loess Plateau have enhanced soil and water retention. However, more attention needs to be paid not only to the simultaneous increase in water retention services and evapotranspiration but also to the type and layout of restored vegetation. Furthermore, urbanization needs to be controlled to prevent uncontrollable LUCCs and climate change. Our findings provide reference data for the regional water and land resources management and the sustainable development of socio-ecological systems in the Loess Plateau under LUCC and climate change scenarios.

Water-retaining properties of NCZ composite dust suppressant and its wetting ability to hydrophobic coal dust

Coal dust is a primary threat to underground coal miners.The most common approach to control coal dust is hydraulic methods,such as water spray and coal seam water injection.To improve the dust suppressant efficiency of hydraulic methods,a novel chemical composite dust suppressant,called NCZ,was prepared in this study using calcium chloride(CaCl_(2)),magnesium chloride(MgCl_(2)),and nonionic surfactants using a thermal synthesis method.The water-retaining properties of NCZ powder and its solutions were characterized using the water absorption rate(WAR)and evaporation rate(ER),respectively,and the wetting abilities of the NCZ solutions on coal dust were tested using the initial contact angle(ICA)and sink rate(SR).The results indicate that the NCZ solutions have anti-evaporation effects,and the ER of the solution with a 20.0 wt%NCZ is reduced by 11.7%compared with that of clean water.Furthermore,NCZ solutions have remarkable enhancement effects on the wettability of coal dust.The ICA and SR of clean water and the NCZ solution at 20.0 wt%are 141.9°and 0 mg/s,and 29.3°and 1.46 mg/s,respectively.Finally,quantitative relationships between the solution surface tension and the ICA and IR were established using the least squares method.This study provides a new product for dust suppression in underground mines,which is significant for the optimum applied con-centration of dust suppressant in mining operations.

Preparation and Water Retention Properties of Clay-based Sand-fixing and Grass-planting Materials

Targeting the problem of available water conservation in sand fixation, the sand-fixing and grass-planting materials were prepared with clay modified by emulsifying vegetable waxes and octylphenol polyoxyethylene ether （OP4）. The water retention property was studied in simulating desertification environmental climate and the materials were characterized by means of UV-Vis, SEM, FTIR, XRD and TGA measurements. The experimental result showed that the materials had excellent water retention properties, due to that vegetable waxes adhered evenly to clay particle surfaces, made the clay pores changing from hydrophilic to hydrophobic and so inhibited the water evaporation. Grass-planting experiment showed that, with reasonable mass ratio of clay, vegetable waxes and surfactant, the materials not only inhibited water evaporation but also maintained sound air permeability so shat the germination rate and survival rate of grass were significantly improved.

Influence of soil density on gas permeability and water retention in soils amended with in-house produced biochar

Biochar has been used as an environment-friendly enhancer to improve the hydraulic properties(e.g.suction and water retention)of soil.However,variations in densities alter the properties of the soil ebiochar mix.Such density variations are observed in agriculture(loosely compacted)and engineering(densely compacted)applications.The influence of biochar amendment on gas permeability of soil has been barely investigated,especially for soil with different densities.The major objective of this study is to investigate the water retention capacity,and gas permeability of biochar-amended soil(BAS)with different biochar contents under varying degree of compaction(DOC)conditions.In-house produced novel biochar was mixed with the soil at different amendment rates(i.e.biochar contents of 0%,5%and 10%).All BAS samples were compacted at three DOCs(65%,80%and 95%)in polyvinyl chloride(PVC)tubes.Each soil column was subjected to dryingewetting cycles,during which soil suction,water content,and gas permeability were measured.A simplified theoretical framework for estimating the void ratio of BAS was proposed.The experimental results reveal that the addition of biochar significantly decreased gas permeability kg as compared with that of bare soil(BS).However,the addition of 5%biochar is found to be optimum in decreasing kg with an increase of DOC(i.e.k_(g,65%)>k_(g,80%)>k_(g,95%))at a relatively low suction range(<200 kPa)because both biochar and compaction treatment reduce the connected pores.

Preparation and Water Retention Properties of Montmorillonite Modified by EL-10 Emulsifying Agent

Aiming at the problem of available water conservation in desertification ecological restoration, we prepared the water retention materials with montmorillonite（MMT） modified by Castor Oil Polyoxyethylene Ether（10）（EL-10） emulsifying vegetable waxes. The water retention property was studied in simulated desertification climate, and the materials were analyzed and characterized by UV-Vis, SEM, FTIR and XRD measurements. Moreover, a UV carbon arc lamp was used to test the resistance to aging. The experimental results show that the emulsion has good dispersity. Both the water retention property and the aging resistance performance of the modified clay were excellent. The lamellar structure and chemical composition of MMT had no obvious changes before and after modification. The surfaces of clay particles were coated uniformly with modified MMT, so the loose clay particles were cemented together by vegetable waxes. Meanwhile, the original big hydrophilic pores between the clay particles turned into capillary hydrophobic pores. So the clay particles formed a bonding layer which could inhibit water evaporation. Grass-planting experiment showed that reasonable mass ratio of vegetable waxes and EL-10 was 1：18. The materials not only had great water retention property but also maintained sound air permeability so that the germination rate of grass seed significantly increased from 8% to 52%.

Determination of strain-dependent soil water retention characteristics from gradation curve

The importance of soil water retention characteristics in modelling the hydro-mechanical response of unsaturated soils has been well recognised by many investigators in recent years.Determination of strain-dependent soil water retention curve(SWRC)is likely to be extraordinarily difficult.The first two authors have recently shown that SWRC can be computed from the gradation curve and the calculation result is consistent with the experimental results obtained from pressure plate tests.In this paper,based on a hypothesis related to change in the pore size distribution(POSD)due to volumetric strain of soil skeleton,a method to compute strain-dependent SWRC is presented.It is found that at initial degrees of saturation higher than 0.8,the influence of volumetric strain may be marginal whilst at initial degrees of saturation lower than 0.8,its influence is likely to be substantial.In all cases,the gradation curve of the soil affects the SWRC.

The“Urban Water Machine”:A Landscape-Based Approach for Urban Planning

Climate change is confronting cities across the globe,resulting in extreme weather conditions:floods,droughts,forest fires,and hurricanes.These natural hazards have become so severe that it is increasingly difficult to manage them.Urbanization,which has marginalized nature and water over time,has exacerbated these conditions.By replacing natural features with hardscape,cities are less adaptive to environmental fluctuations,and climate-related hazards are intensified,through heat island effect for example.Streets,squares,and parts of the city are inundated by water.The need to give space to water and nature in the city is more urgent than ever.The essential relationship between water and humans gave birth to our cities.This relationship has evolved across time and geography,and our current climate and ecological crises are calling us to take the next step in this evolution.Improving natural systems within the city,including a holistic approach for rivers,waterways,and green corridors,will improve resilience to flash floods and drought,contribute to heat mitigation,and improve urban living conditions.It will create possibilities for new economic,environmental,community,and social developments.A contemporary and healthy relationship between humanity and nature requires creating a basic,sustainable,spatial framework that upgrades and connects larger green and water(blue)structures.These blue-green structures should also be linked within the city and within its neighborhoods.The new mechanism to balance water in the city will be an integrated system,what we call the“urban water machine”.By integrating our natural and man-made water systems with each other,and with green spaces in and around the urban environment,we can regenerate the“urban water machine”and use it as the basis for a truly holistic approach to spatial planning.To shape our contemporary relationship with water,it is important to develop both innovative design tools and spatial typologies.A design approach based on the“urban water machine”provides climate adaptive solutions with nature-based design tools within the green landscape framework combined with blue-green design tools in public spaces.Such a holistic approach will help to care for the city as a whole,making them more beautiful,vibrant,and resilient.

Seasonal Contrast of Some Anthropic Pollution Parameters in Water Retention in Mountainous Area under Sahelian Climate: Elementary Dynamics and Space Distribution (Territory of the Mounts Mandara, Cameroon)

In order to understand the origin, the extent and the space distribution of the seasonal anthropic pollution parameters in the water retention located in mountainous area thickly populated and which water resources is intended for the production of drinking water for serving a population of approximately 800,000 inhabitants, two sampling campaigns were carried out for the two seasons of the year known as the dry and rainy season. The samples were then conveyed and analyzed in laboratory. The parameters retained for this study were primarily the physicochemical parameters (pH, conductivity and temperature), measured in situ and second the major anthropic origins anions of (, , and ). The results of the study show that overall the anthropic pollution parameters undergo an important seasonal variation of their concentration between the dry and rainy periods although they remain high in any season compared to the quality standards of natural water of the European Union. Their space distribution within retention remains overall random and is not function of the seasons. However, surrounding areas of the retention and the discharge system of the seasonal rivers (Mayos) which feed it present in rainy season space distributions of concentrations in anions of anthropic origin enumerated above highest.

Experimental investigation into temperature effect on hydro-mechanical behaviours of bentonite

The bentonite barrier of underground repositories for high-level radioactive waste will be hydrated by the groundwater while it is subjected to high temperatures due to the radioactive decay of the wastes. These changes of temperature affect the hydraulic and mechanical responses of bentonite, which has important effects on design and performance of repositories. The temperature influence on the hydro-mechanical behaviour of bentonite was studied in this paper by experiments, which were carried out with the Spanish FEBEX bentonite compacted at dry densities expected in the＇ repository （from 1.5 to 1.8 Mg/m^3）. The dependence of the swelling strains of bentonite on the temperature has been measured from 30℃ to 90 ℃. At high temperatures the swelling capacity of clay slightly decreases. Also, a clear decrease of swelling pressure as a function of temperature was observed for the same dry densities. Nevertheless, the deformation of bentonite is more dependent on the stress than the temperature. An increase in the permeability of water saturated bentonite with temperature has also been detected. The water retention curves of bentonite compacted at different dry densities were determined under isochoric conditions and in the range of temperatures from 20 ℃ to 120℃. For a given density and water content, the suction decreases as the temperature increases at a rate, which is larger than the one predicted on the basis of water surface tension changing with temperature. Mechanisms related to the physico-chemical interactions that take place at microscopic level, in particular the transfer of interlayer water to the macropores triggered by temperature, seem to explain qualitatively the experimental observations.

Topographic differentiations of biological soil crusts and hydraulic properties in fixed sand dunes, Tengger Desert

Biological soil crusts （BSCs） play an important role in surface soil hydrology. Soils dominated with moss BSCs may have higher infiltration rates than those dominated with cyanobacteria or algal BSCs. However, it is unnown whether improved infiltration in moss BSCs is accompanied by an increase in soil hydraulic conductivity or water retention capacity. We investigated this question in the Tengger Desert, where a 43-year-old revegetation program has promoted the formation of two distinct types of BSCs along topographic positions, i.e. the moss-dominated BSCs on the interdune land and windward slopes of the fixed sand dunes, and the al- gal-dominated BSCs on the crest and leeward slopes. Soil water retention capacity and hydraulic conductivity were measured using an indoor evaporation method and a field infiltration method. And the results were fitted to the van Genuchten-Mualem model. Unsaturated hydraulic conductivities under greater water pressure （〈-0.01 MPa） and water retention capacities in the entire pressure head range were higher for both crust types than for bare sand. However, saturated and unsaturated hydraulic conductivities in the near-saturation range （〉-0.01 MPa） showed decreasing trends from bare sand to moss crusts and to algal crusts. Our data suggested that topographic differentiation of BSCs significantly affected not only soil water retention and hydraulic conductivities, but also the overall hydrology of the fixed sand dunes at a landscape scale, as seen in the reduction and spatial variability in deep soil water storage.

On the hydro-mechanical behaviour of MX80 bentonite-based materials

Bentonite-based materials have been considered in many countries as engineered barrier/backfilling materials in deep geological disposal of high-level radioactive waste.During the long period of waste storage,these materials will play an essential role in ensuring the integrity of the storage system that consists of the waste canisters,the engineered barrier/backfill,the retaining structures as well as the geological barrier.Thus,it is essential to well understand the hydro-mechanical behaviours of these bentonite-based materials.This review paper presents the recent advances of knowledge on MX80 bentonite-based materials,in terms of water retention properties,hydraulic behaviour and mechanical behaviour.Emphasis is put on the effect of technological voids and the role of the dry density of bentonite.The swelling anisotropy is also discussed based on the results from swelling tests with measurements of both axial and radial swelling pressures on a sand-bentonite mixture compacted at different densities.Microstructure observation was used to help the interpretation of macroscopic hydromechanical behaviour.Also,the evolution of soil microstructure thus the soil density over time is discussed based on the results from mock-up tests.This evolution is essential for understanding the longterm hydro-mechanical behaviour of the engineered barrier/backfill.

Effects of mineralogy on thermo-hydro-mechanical parameters of MX80 bentonite

Thermal conductivity, water retention curve and swelling behavior of two MX80 bentonite samples were studied in the present work. The difference obtained from these two MX80 bentonite samples was then analyzed in terms of mineralogical effects （effects of the proportion of quartz and montmorillonite）. It was concluded that the mineralogical effect was significant on the thermal conductivity and the swelling capacity; on the contrary, it was negligible on the water retention property.

STUDY ON ACRYLAMIDE-SODIUM ACRYLATE COPOLYMER GELS

Acrylamide-sodium acrylate copolymer hydrogels have been obtained by radiation techniques. Two different methods have been used to introduce—COONa groups into polymer chains of the gels: (1) by partial hydrolysis of acrylamide homopolymer gel; (2) by direct copolymerization and crosslinking of acrylamide and sodium acrylate in aqueous solutions. It was found that the gels obtained in different ways had different properties, the swelling character of the gels obtained by partial hydrolysis were more sensitive to pH of swelling aqueous media, in order to explain these differences, ^(13)C-NMR techniques were used to investigate the sequence distribution of monomer units of both gels.

Variation of soil organic carbon and bulk density during afforestation regulates soil hydraulic properties

Grain to Green program on arable land has been conducted for decades in semi-arid regions of North China.However,it remains uncertain how afforestation practices affect soil hydraulic properties(SHP).Two afforestation types,i.e.shrubland(SL)and woodland(WL),and the adjacent cropland(CL)were investigated to determine afforestation effects on SHP in this area.Disturbed and undisturbed soil cores were collected in three experimental sites.Soil field capacity(FC),wilting point(WP),and available water capacity(AWC)increased in SL compared to the CL.Soil saturated water content,however,decreased significantly in both SL and WL.Correlation and redundancy analysis identified that bulk density(BD)and soil organic carbon(SOC)were the main factors regulating SHP across different land uses.Lower saturated water contents in afforestation sites were likely driven by the higher BD,compared to the adjacent cropland.FC,WP,and AWC were positively correlated to SOC content.While afforestation may not increase the saturated water content of a landscape,our results indicate that it can improve soil water retention and could be an effective practice for soil and water conservation.

On the thermo-mechanical properties of unsaturated soils

The establishment of energy balance equation is necessary to study the thermo-mechanical properties of unsaturated soils.To solve this equation,the determination of two fundamental parameters as volumetric specific parameter and thermal conductivity coefficient is essential.In this paper,the effective thermal conductivity coefficient of dry soil grain is analyzed for soils with different compositions,and the thermo-mechanical properties of porous media with water and gas are studied by considering the soil water retention curve（SWRC）.Different methods,i.e.volumetric average method,self-consistent method,Hashin-Strikman method,are employed to calculate thermal conductivity coefficients,and a new method is proposed to determine the thermo-mechanical parameters.Comparison of the results obtained by different methods shows that the proposed method is in a good agreement with the experimental results and is suitable for describing the main properties of the thermo-mechanical behaviors of soils.The relationship between the SWRC and the seepage curve is further studied by the natural proportional rule.The characteristics of the SWRC,its differential coefficient and the seepage curve,are investigated by considering the physico-mechanical mechanism;the limit scopes of the indices of the SWRC and the seepage curve are also given.

Synthesis and Characterization of Hydrogels Based on Potato Starch/Poly(vinyl Alcohol)/N,N′-Methylenebisacrylamide

Several hydrogels were synthesized by free-radical polymerization in an aqueous medium based on potato starch(PS),poly(vinyl alcohol)(PVA),and N,N′-Methylenebisacrylamide(MBAm),being possible to study these hydrogels as a function of the proportion of components incorporated.In this way,the products generated from the synthesis were characterized by swelling and deswelling kinetics,the first swelling being verified with Schott and statistical models,allowing to contrast the proximity between the experimental and theoretical behavior.Additionally,water retention in soil(R%),spectroscopy(FTIR),morphological(SEM),and thermal(TGA and DSC)analysis allowing to know the intrinsic characteristics of the material,increasing in general terms the knowledge of this type of material.In this context,it was possible to verify the characteristics and effectiveness of the synthesis and crosslinking of the main components.The experimental results obtained show that the synthesized hydrogels present representative swellings consistent with kinetic and statistical models,optimal thermal stability depending on the amount of crosslinker,and excellent water retention in environments such as soil,presenting it as an excellent alternative to be used in agro-industrial applications in an eco-friendly way.