Disinfection Byproducts and Their Precursors in Drinking Water Sources:Origins,Influencing Factors,and Environmental Insights

Tracing the contamination origins in water sources and identifying the impacts of natural and human processes are essential for ecological safety and public health.However,current analysis approaches are not ideal,as they tend to be laborious,time-consuming,or technically difficult.Disinfection byproducts(DBPs)are a family of well-known secondary pollutants formed by the reactions of chemical disinfectants with DBP precursors during water disinfection treatment.Since DBP precursors have various origins(e.g.,natural,domestic,industrial,and agricultural sources),and since the formation of DBPs from different precursors in the presence of specific disinfectants is distinctive,we argue that DBPs and DBP precursors can serve as alternative indicators to assess the contamination in water sources and identify pollution origins.After providing a retrospective of the origins of DBPs and DBP precursors,as well as the specific formation patterns of DBPs from different precursors,this article presents an overview of the impacts of various natural and anthropogenic factors on DBPs and DBP precursors in drinking water sources.In practice,the DBPs(i.e.,their concentration and speciation)originally present in source water and the DBP precursors determined using DBP formation potential tests—in which water samples are dosed with a stoichiometric excess of specific disinfectants in order to maximize DBP formation under certain reaction conditions—can be considered as alternative metrics.When jointly used with other water quality parameters(e.g.,dissolved organic carbon,dissolved organic nitrogen,fluorescence,and molecular weight distribution)and specific contaminants of emerging concern(e.g.,certain pharmaceuticals and personal care products),DBPs and DBP precursors in drinking water sources can provide a more comprehensive picture of water pollution for better managing water resources and ensuring human health.

Mechanism, modification and stability of tungsten oxide-based electrocatalysts for water splitting: A review

Electrocatalysis plays a crucial role in the field of clean energy conversion and provides essential support for the development of eco-friendly technology. There is a pressing need for electrocatalysts in renewable energy systems that exhibit exceptional activity, selectivity, stability, and economic viability. The utilization of metal oxides as electrocatalysts for the process of water splitting has made substantial progress in both theoretical and practical aspects and has emerged as a widely explored field of research. Tungsten oxides(WO_(x)) have attracted much attention and are regarded as a highly promising electrocatalytic material due to their exceptional electrocatalytic activity, cost-effectiveness, and ability to withstand extreme conditions. This review introduces the fundamental mechanism of WOx-based electrocatalysts for the hydrogen evolution reaction and the oxygen evolution reaction, providing a comprehensive overview of recent research advancements in their modification. Factors contributing to the catalytic activity and stability of WOxare explored, highlighting their potential for industrial applications. The aim herein is to provide guidelines for the design and fabrication of WOx-based electrocatalysts, thereby facilitating further research on their mechanistic properties and stability improvements in water splitting.

Development and Experimental Study of Air Source Heat Pump Water Heater

The principle and development prospect of air source heat pump water heat were introduced,as well as the designation of condenser (storage water tank),experimental study on installations was also carried out.The results showed that air source heat pump water heater was superior to conventional system.Under the operation of cooling and heating,heat pump comprehensive utilization equipment could improve heating performance,reduce energy consumption,and recycle condensing heat to provide hot water.

Advances in Microbial Remediation on the Application of Heavy Metal Pollution in Agricultural Water Resources

Heavy metal pollution in agricultural water resources is very serious in re- cent years, resulting in large losses of the agricultural economy and endangering human life and health. Due to the advantages of low cost, high efficiency and less secondary pollution, microbial ramediation technology is widely used in the treatment of heavy metal pollution in agricultural water resources. At present, with the progress of modern biotechnology, microbial remediation of heavy metals in agricul- tural water resources has grown rapidly. The sources and status quo of heavy met- al pollution in agricultural water resources at home and aboard, and the principles of microbial remediation of heavy metals pollution in agricultural water resources were reviewed in this paper, as well as the several common microbial remediation technology of heavy metals in agricultural water resources. Additionally, the further research work of heavy metal contaminated agricultural water resources by microbial ramediation were prospected.

Preparation and stability of zinc ferrite nano-particle suspension of ammonia-water solution

In order to apply nano-particles to the ammonia-water absorption refrigeration, the zinc ferrite nano-particles suspension of ammonia-water solution with the mixed surfactants of sodium dodecyl benzene sulfonate （SDBS） and cetyl trimethyl ammonium bromide （CTAB） is prepared. A series of experiments is performed to investigate the stability of the prepared nanofluid with different contents and proportions of surfactants, different durations of ultrasonic wave vibration and different durations of illumination. The optimal dispersion conditions are 1.5% SDBS, 0. 015% CTAB（mass fraction）, 30 min of ultrasonic vibration and over 72 h of illumination. Finally, based on double electrode layer theory, the influences of the content of the surfactants on the stability of nanofluid are analyzed. The existence of the optimal surfactant content is proved, which is in accordance with the experimental results.

Stable isotope analysis of water sources for Tamarix laxa in the mega-dunes of the Badain Jaran Desert, China

The complex interactions in desert ecosystems between functional types and environmental conditions could be reflected by plant water use patterns. However, the mechanisms underlying the water use patterns as well as the water sources of Tamarix laxa in the mega-dunes of the Badain Jaran Desert, China, remain unclear. This study investigated the water sources and water use patterns of T. laxa using the stable oxygen isotope method. The δ18O values of xylem water, soil water in different layers(0–200 cm), rainwater, snow water, lake water, atmospheric water vapor, condensate water, and groundwater were measured. The sources of water used by T. laxa were determined using the IsoSource model. The results indicate that T. laxa mainly relies on soil water. At the beginning of the growing season(in May), the species is primarily dependent on water from the middle soil layer(60–120 cm) and deep soil layer(120–200 cm). However, it mainly absorbs water from the shallow soil layer(0–60 cm) as the rainy season commences. In September, water use of T. laxa reverts to the deep soil layer(120–200 cm). The water use patterns of T. laxa are closely linked with heavy precipitation events and soil water content. These findings reveal the drought resistance mechanisms of T. laxa and are of significance for screening species for ecological restoration.

Hydrogeochemical Characteristics and Groundwater Inrush Source Identification for a Multi-aquifer System in a Coal Mine

Correct identification of water inrush sources is particularly important to prevent and control mine water disasters.Hydrochemical analysis,Fisher discriminant analysis,and geothermal verification analysis were used to identify and verify the water sources of the multi-aquifer groundwater system in Gubei coal mine,Anhui Province,North China.Results show that hydrochemical water types of the Cenozoic top aquifer included HCO3-Na+K-Ca,HCO3-Na+K-Mg and HCO3-Na+K,and this aquifer was easily distinguishable from other aquifers because of its low concentration of Na++K+and Cl-.The Cenozoic middle and bottom aquifers,the Permian fissure aquifer,and the Taiyuan and Ordovician limestone aquifers were mainly characterized by the Cl-Na+K and SO4-Cl-Na+K or HCO3-Cl-Na+K water types,and their hydrogeochemistries were similar.Therefore,water sources could not be identified via hydrochemical analysis.Fisher model was established based on the hydrogeochemical characteristics,and its discrimination rate was 89.19%.Fisher discrimination results were improved by combining them with the geothermal analysis results,and this combination increased the identification rate to 97.3%and reasonably explained the reasons behind two water samples misjudgments.The methods described herein are also applicable to other mines with similar geological and hydrogeological conditions in North China.

Formation and Water Stability of Aggregates in Red Soils as Affected by Organic Matter

The water stability of aggregates in various size classes separated from 18 samples of red soils under different managements, and the mechanisms responsible for the formation of water-stable soil aggregates were studied. The results showed that the water stability of soil aggregates declined with increasing size, especially for the low organic matter soils. Organic matter plays a key role in the formation of water-stable soil aggregates. The larger the soil aggregate size, the greater the impact of organic matter on the water stability of soil aggregates. Removal of organic matter markedly disintegrated the large water-stable aggregates (> 2.0 mm) and increased the small ones (< 0.25-0.smm) to some extent, whereas removal of free iron(aluminium) oxides considerably destroyed aggregates of all sizes, especially the < 0.25-0.5 mm classes. The contents of organic matter in water-stable aggregates increased with aggregate sizes. It is concluded from this study that small water-stable aggregates (< 0.25-0.5 mm) were chiefly cemented by Fe and Al oxides whilst the large ones (> 2.0 mm) were mainly glued up by organic matter. Both free oxides and organic matter contribute to the formation and water stability of aggregates in red soils.

Stability analysis of different cotton genotypes under normal and water-deficit conditions

Cotton plant observes significant reduction in seed cotton yield when subjected to water stress.To find out genotypes having better drought tolerance,seven genotypes of Gossypium hirsutum L.were tested under two moisture levels,i.e.,normal and water deficit stress conditions at five locations of Punjab,Pakistan(Faisalabad,Sahiwal,Vehari,Rahim Yar Khan,and Bahawalpur)in 2013 and 2014.Genotype×environment interaction(GEI)was studied using the genotype main effects and genotype by environment interaction(GGE)biplot and additive main effect and multiplicative interaction analysis.The genotypes G3(7001/11)and G6(FH-942)were stable under normal condition,while under drought condition,the stable genotype was G5(FH-326)when analysed using additive main effects and multiplicative interaction(AMMI)biplot scheme.While GGE biplot analysis on the basis of best performance revealed that under normal condition the genotypes,G1(L-13/10)and G2(FH-2056/10),carrying the common position in biplot.Whereas,under water deficit stress condition,G5 was the best adaptive genotype at all five locations.In the same way,ranking of genotypes showed that the G5 was the ideal genotype under both conditions.So,it is concluded that the genotype G5(FH-326)was found best for water deficit stress condition and can be cultivated under water scarce areas of Punjab.

Estimation of water balance in the source region of the Yellow River based on GRACE satellite data

Water storage has important significance for understanding water cycles of global and local domains and for monitoring climate and environmental changes. As a key variable in hydrology, water storage change represents the sum of precipitation, evaporation, surface runoff, soil water and groundwater exchanges. Water storage change data during the period of 2003-2008 for the source region of the Yellow River were collected from Gravity Recovery and Climate Experiment （GRACE） satellite data. The monthly actual evaporation was estimated according to the water balance equation. The simulated actual evaporation was significantly consistent and correlative with not only the observed pan （20 cm） data, but also the simulated results of the version 2 of Simple Biosphere model. The average annual evaporation of the Tangnaihai Basin was 506.4 mm, where evaporation in spring, summer, autumn and winter was 130.9 mm, 275.2 mm, 74.3 mm and 26.1 mm, and accounted for 25.8%, 54.3%, 14.7% and 5.2% of the average annual evaporation, respectively, The precipitation increased slightly and the actual evaporation showed an obvious decrease. The water storage change of the source region of the Yellow River displayed an increase of 0.51 mm per month from 2003 to 2008, which indicated that the storage capacity has significantly increased, probably caused by the degradation of permafrost and the increase of the thickness of active layers. The decline of actual evaporation and the increase of water storage capacity resulted in the increase of river runoff.

Bearing splitting and near-surface source ranging in the direct zone of deep water

Sound multipath propagation is very important for target localization and identification in different acoustical zones of deep water. In order to distinguish the multipath characteristics in deep water, the Northwest Pacific Acoustic Experiment was conducted in 2015. A low-frequency horizontal line array towed at the depth of around 150 m on a receiving ship was used to receive the noise radiated by the source ship. During this experiment, a beating-splitting phenomenon in the direct zone was observed through conventional beamforming of the horizontal line array within the frequency band 160 Hz- 360 Hz. In this paper, this phenomenon is explained based on ray theory. In principle, the received signal in the direct zone of deep water arrives from two general paths including a direct one and bottom bounced one, which vary considerably in arrival angles. The split bearings correspond to the contributions of these two paths. The beating-splitting phenomenon is demonstrated by numerical simulations of the bearing-time records and experimental results, and they are well consistent with each other. Then a near-surface source ranging approach based on the arrival angles of direct path and bottom bounced path in the direct zone is presented as an application of bearing splitting and is verified by experimental results. Finally, the applicability of the proposed ranging approach for an underwater source within several hundred meters in depth in the direct zone is also analyzed and demonstrated by simulations.

Genotoxicity evaluation and a primary risk assessment of organic pollutants in the drinking water sources of Nanjing, China

An increasing number of industrial, agricultural, and commercial chemicals in the aquatic environment leads to various deleterious effects on organisms, which is becoming an increasingly serious problem in China. In this study, the comet assay was conducted to investigate the genotoxicity to human body caused by organic concentrates in the drinking water sources of Nanjing City from Yangtze River of China, and health and ecology risk due to expose to these organic pollutants were evaluated with the multimedia environmental assessment system （MEAS）. For all the water samples, they were collected from four different locations in the drinking water sourcr samples, es of Nanjing City. The results of the comet assay showed that all the organic concentrates from the water samples could induce different levels DNA damages on human peripheral blood lymphocytes, and a statistically significant difference （p〈0.01） was observed compared with the solvent control, which demonstrated the genotoxicity was in existence. According to the ambient severity （AS） of individual compound, we had sorted out the main organic pollutants in the drinking water source of the four waterworks, and the results showed that there was some potential hazard to human body for all the source water, namely the total ambient severity （TAS） of health for each water source was more than 1. However, the TAS of ecology for each water source was less than 1, which indicated that it was safe to ecology. The results of this investigation demonstrate the application of the comet assay and the MEAS in aquatic environmental monitoring studies, and the comet assay found to be fast, sensitive, and suitable for genotoxicity monitoring programs of drinking water source.

Legislation on protection of drinking water sources and local management practices in the Pearl River Delta region of China

The protection of drinking water sources is vital to urban development and public health.In this study,the current situation of the mandatory protection area for drinking water source in the Pearl River Delta region was investigated using a method combining Google Earth with the field survey.The gaps between management practices and legislation requirements were analyzed.Finally,several countermeasures for water resource protection were proposed as follows:to promote delineation in a more scientific way,to safeguard the sanctity of the law,to make better plan on water saving,and to encourage public participation in supervision and management.

RESEARCH ON THE WATER-RESISTANCE OF MAGNESIUM OXYCHLORIDE CEMENT——I:THE STABILITY OF THE REACTION PRODUCTS OF MAGNESIUM OXYCHLORIDE CEMENT IN WATER

In this paper .the change of the crystalline phases in hardened magnesium oxychloride cement (MOC) paste in mater was analyzed by XRD. It was developed that the reaction products 5 phase or 3 phase of MOC are instable in water and can be changed into Mg(OH)2 by the action of water, which causes the content of 5 phase or 3 phase to be less and less,the content of Mg(OH)2 to be more and more and the strength to be the lower the lower,after hardended MOC paste was immersed in water. The change of 5 pliase and 3 phase into Mg(OH)2 is not a dissolve process, but a hydrolysis process. The hydrolysis products of 5 phase and 3 phase are Mg(OH)2 precipitation and soluble Cl-,AIg+ ions and H2O. The hydrolysis is sponta-neous thermodynamically and its chemical kinatic equation is C = C,,e-k Thus .it is suggested that only by enhancing the stability of 5 phase or 3 phase in water and preventing 5 phase or 3 phase from the hydrolyzing can the water resistance of MOC be improved well.

Influencing factors of water resources in the source region of the Yellow River

Taking the source region of the Yellow River as a study area and based on the data from Madoi Meteorological Station and Huangheyan Hydrological Station covering the period 1955-2005, this paper analyses the changing trends of surface water resources, climate and frozen ground and reveals their causes. Results show that there exist frequent fluctuations from high to low water flow in the 51-year period. In general, the discharge has shown a de- clining trend in the 51 years especially since the 1990s. The annual distribution shows one peak which, year on year is getting smaller. （1） Precipitation has a significant and sustained influence on discharge. （2） A sharp rise of temperature resulted in the increase of evaporation and the decrease of discharge, which has a greater effect than on ice-snow melting. （3） Frozen ground tends to be degraded markedly. There is a significant positive correlation be- tween the permafrost thickness and the discharge. （4） Evaporation rates are significantly increasing, leading to the decrease of discharge. 70% of the discharge reduction resulted from climate change, and the remaining 30% may have been caused by human activities.

Assessment of Point and Nonpoint Sources Pollution in Songhua River Basin,Northeast China by Using Revised Water Quality Model

Individual participation of pollutants in the pollution load should be estimated even if roughly for the appropriate environmental management of a river basin.It is difficult to identify the sources and to quantify the load, especially in modeling nonpoint source.In this study a revised model was established by integrating point and nonpoint sources into one-dimensional Streeter-Phelps(S-P) model on the basis of real-time hydrologic data and surface water quality monitoring data in the Jilin Reach of the Songhua River Basin.Chemical oxygen demand(COD) and ammonia nitrogen(NH 3-N) loads were estimated.Results showed that COD loads of point source and nonpoint source were 134 958 t/yr and 86 209 t/yr, accounting for 61.02% and 38.98% of total loads, respectively.NH 3-N loads of point source and nonpoint source were 16 739 t/yr and 14 272 t/yr, accounting for 53.98% and 46.02%, respectively.Point source pollution was stronger than nonpoint source pollution in the study area at present.The water quality of upstream was better than that of downstream of the rivers and cities.It is indispensable to treat industrial wastewater and municipal sewage out of point sources, to adopt the best management practices to control diffuse pollutants from agricultural land and urban surface runoff in improving water quality of the Songhua River Basin.The revised S-P model can be successfully used to identify pollution source and quantify point source and nonpoint source loads by calibrating and validating.

Application of a Stereo Constructed Wetland Mode to the Treatment of Slightly Polluted Source Water

[Objective] The study aimed to discuss the application of a stereo constructed wetland to the treatment of slightly polluted source water. [Method] In this study, a new stereo constructed wetland mode was put forward, and a pilot project of water ecological purification in Xinsheng River, the diversion channel of Shijiuyang Waterwork in Jiaxing City, were analyzed. Afterwards, the impact factors of water purification by the technology were discussed from water quality and quantity, season and climate, species configuration, management and maintenance. [Result] Under three different hydraulic loading conditions, the pilot project effectively improved water SD and DO level, and reduced SS, CODCr, NH3-N, TN and TP significantly in summer and autumn, so that effluent water quality reached surface water standard at Grade III. [Conclusion] The stereo constructed wetland mode composed of constructed wetland and underwater forest used to treat slightly polluted source water is feasible and has a good promotion prospect.

Characteristics and Effects of Inorganic Nitrogen in East Water-source and Inflow Rivers of Chaohu Lake

[Objective] To study the characteristics and effects of inorganic nitrogen in east water-source and inflow rivers of Chaohu Lake. [Method] The speciation and distribution characteristics of dissolvable inorganic nitrogen （DIN） in east water-source and inflow rivers of Chaohu Lake were investigated, and their effects on water qual- ity were examined. [Result] The concentrations of NH3-N and NO2--N were the high in flood season, and low in non-flood season, while the concentration of NO3--N pre- sented the opposite trend; the concentration of NO3--N was the highest in Shuangqiao estuary, where the pollution was the worst. DIN in Zhegao estuary and Xiaozhegao estuary was mainly caused by domestic sewage and industrial wastewaters; surface runoff and pollution from ships contribute the most to the DIN content in Shuangqiao estuary. [Conclusion] This study provided basic data and theoretical basis for the control and management of eutrophication in Chaohu Lake.

Connotation and principles of ecological compensation in water source reserve areas based on the theory of externality

Understanding the connotation and principles of ecological compensation in water source reserve areas is the basis and guarantee for establishing and improving the ecological compensation mechanism of water source reserve areas.First,this paper reviews the three stages of ecological compensation research progress.Based on the review,using the theory of externality,the ecological environment system of water source reserve areas is then analyzed.This paper argues that the connotation of ecological compensation in water source reserve areas is a kind of institutional arrangement,which is designed to internalize externalities.Finally,based on the understanding of the connotation of ecological compensation in water source reserve areas,five principles for establishing and improving the ecological compensation mechanism are proposed,including the principle of fairness and justice,the principle of equivalence of equality and responsibility,the principle of flexibility and effectiveness,the principle of "earmark funds,and implementation by law," and the principle of government compensation supplemented with market compensation.

Source apportionment of river water pollution in a typical agricultural city of Anhui Province, eastern China using multivariate statistical techniques with APCS– MLR

The deterioration of the surface water environment has become a serious challenge for water resources management due to increasing anthropogenic disturbance. Water resources protection requires control of potential pollution sources. In this study, 99 water samples were collected from a river in a typical agricultural city of Anhui Province in eastern China, and these samples were analyzed in terms of pH, electrical conductivity, and the concentrations of F-, Cl-, SO42-, Na+, K+, Mg2+, Ca2+, As, Cr, Cu, Zn, and Pb. Cluster analysis, co-occurrence network analysis, and principal component analysis/factor analysis were conducted to qualitatively identify the potential sources of river water pollution in the study area. An absolute principal component score-multiple linear regression receptor model was used to quantitatively evaluate the contribution of each source to water quality parameters. The results showed that all observed water quality indices met the quality criteria specified in the Chinese drinking water standards, except for pH, ρ(F-), ρ(SO42-), and ρ(As). The heat map showed that the frequent recharge of pollutants from the tributaries during the wet season was the main reason for the deterioration of water quality. Five sources of river water pollution were identified, and their contribution ratios in a descending order were as follows: the geogenic process (24%) > agricultural activities (21%) > poultry farming sources (17%) > domestic pollution (9%) > transportation pollution (5%). Therefore, controlling pollution from agricultural activities, strengthening the regulation of livestock farming, and improving the sewage network are the recommended strategies for improving the quality of surface water resources in this area.