Sensitivity of the Grid-point Atmospheric Model of IAP LASG(GAMILI.I.0)Climate Simulations to Cloud Droplet Effective Radius and Liquid Water Path

This paper documents a study to examine the sensitivity to cloud droplet effective radius and liquid water path and the alleviation the energy imbalance at the top of the atmosphere and at the surface in the latest version of the Grid-point Atmospheric Model of the State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics （LASG）, Institute of Atmospheric Physics （IAP） （GAMIL1.1.0）. Considerable negative biases in all flux components, and thus an energy imbalance, are found in GAMIL1.1.0. In order to alleviate the energy imbalance, two modifications, namely an increase in cloud droplet effective radius and a decrease in cloud liquid water path, have been made to the cloud properties used in GAMIL. With the increased cloud droplet effective radius, the single scattering albedo of clouds is reduced, and thus the reflection of solar radiation into space by clouds is reduced and the net solar radiation flux at the top of the atmosphere is increased. With the reduced cloud optical depth, the net surface shortwave radiation flux is increased, causing a net warming over the land surface. This results in an increase in both sensible and latent heat fluxes over the land regions, which is largely balanced by the increased terrestrial radiation fluxes. Consequently, the energy balance at the top of atmosphere and at the surface is achieved with energy flux components consistent with available satellite observations.

VAPOR-LIQUID EQUILIBRIA OF N METHYLPYRROLIDONE(1)-WATER(2) BINARY SYSTEM BY AN EBULLIOMETER

1 INTRODUCTIONVapor-liquid equilibrium（VLE）data are useful for the study of solution properties ofnon-ideal mixtures as well as for the design of the separation equipment.Then-methylpyrrolidone（NMP）is a new-type and excellent solvent which can be used in somechemical engineering separation processes.The NMP sucks up moisture so easily that it isnecessary to study the VLE relations of the NMP-H2O binary system,

A Comparative Study of Cloud Liquid Water Content from Radiosonde Data at a Tropical Location

In this paper, some features of cloud liquid water content with respect to rain and water vapor are presented. Cloud liquid water density profile is obtained from radiosonde observation with Salonen's model and Karsten's model at Kolkata, a tropical location in the Indian region. Cloud liquid water contents (LWC) are obtained from these profiles which show a prominent seasonal variation. The monsoon months exhibit much higher values of LWC than in other months. However Salonen's model yields higher LWC values than that obtained with Karsten's model. The variation of daily total rainfall with LWC shows a positive relationship indicating the role of LWC in controlling the rainfall. Also the variation pattern of LWC with integrated water vapor (IWV) content of the atmosphere indicates that a threshold value of water vapor is required for cloud to form and once cloud is formed LWC increases with IWV.

Isobaric Vapor–Liquid Equilibrium for tert-Butyl Alcohol + Water + Propane-1,3-Diol + 1-Ethyl-3-Methylimidazolium Chloride at 101.3 kPa

In this study, we used a mixture of organic liquid propane-1,3-diol and ionic liquid 1-ethyl-3-methylimidazolium chloride([emim]Cl) as the entrainer to separate tert-butyl alcohol(TBA) + water. We measured the isobaric vapor–liquid equilibrium(VLE) for the quaternary system TBA + water + propane-1,3-diol + [emim]Cl at 101.3 kPa, and found the VLE data to be well correlated with the nonrandom two-liquid model. These results show that the mixed solvent of propane-1,3-diol + [emim]Cl can increase the relative volatility of TBA to water and break the azeotropic point. We found no notable synergetic effect between them, and observed that the liquid mixed solvent of propane-1,3-diol and [emim]Cl had lower viscosity than [emim]Cl, which makes it a promising entrainer for separating the TBA + water azeotrope in industrial applications.

Existence forms of water in solid liquid systems

Two approaches, named pressure filtration (PF) and vaporization dewatering (VD), for qualitative and quantitative analysis of the water forms were presented. The principle of VD is that with the process of heating, the free water, surface water and capillary water are in turn vaporized at different rates, then the turning points of the rates are determined and the quantitative analysis can be made. Some experiments with suspension of water and CaCO 3 powder were given and discussed by applying the vaporization dewatering approach. [

Magnitude and Trends of High-elevation Cloud Water Pollutant Concentrations and Modeled Deposition Fluxes

Cloud water samples, LWC （Liquid Water Content） and meteorological data were collected at the Clingmans Dome, Tennessee, high-elevation site in Great Smoky Mountains National Park during the warm season from 1994 through 2011. This paper presents results from 2000 through the conclusion of the study in 2011. Samples were analyzed for SO42＂, NO3, NH4＋ and H＋. These measurements were supplemented by measurements of ambient air and precipitation concentrations to estimate dry and wet deposition. Cloud water concentrations, LWC, cloud frequency, various meteorological measurements and information on nearby forest canopy were used to model cloud water deposition to gauge trends in deposition. Total deposition was calculated as the sum of cloud, dry and wet deposition estimates. Concentrations and deposition fluxes declined over the study period. The decreases in cloud water SO42＂ and NO3 concentrations were 40 percent and 26 percent, respectively. Three-year mean 5042 and NO3 deposition rates decreased by 71 percent and 70 percent, respectively. Trends in concentrations and depositions were comparable with trends in SO2 and NOx emissions from Tennessee Valley Authority power plants and aggregated emission reductions from electric generating units in adjacent states. Back trajectories were simulated with the HYSPLIT model and aggregated over cloud sampling periods from 2000 through 2007 and 2009 through 2011. Trajectories during periods with high H＋ concentrations traveled over local EGU （Electric Generating Unit） emission sources in Tennessee and Kentucky to the Ohio River Valley, Alabama and Georgia with the conclusion that these source regions contributed to acidic cloud water deposition at Clingmans Dome. This work was supported by U.S. Environmental Protection Agency and the Tennessee Valley Authority with infrastructure support provided by the National Park Service.

Aircraft Observations of Liquid and Ice in Midlatitude Mixed-Phase Clouds

ABSTRACT This paper reports airborne measurements of midlatitude altostratus clouds observed over Zhengzhou, Henan Province, China on 3 March 2007. The case demonstrates mixed-phase conditions at altitudes from 3200 to 4600 m （0°C to -7.6°C）, with liquid water content ranging from 0.01 to 0.09 g m-3. In the observed mixed-phase cloud, liquid water content exhibited a bimodal distribution, whereas the maximum ice particle concentration was located in the middle part of the cloud. The liquid and ice particle data showed significant horizontal variability on the scale of a few hundred meters. The cloud droplet concentration varied greatly over the horizontal sampling area. There was an inverse relationship between the cloud droplet concentration and ice particle concentration. A gamma distribution provided the best description of the cloud droplet spectra. The liquid droplet distributions were found to increase in both size and concentration with altitude. It was inferred from the profile of the spectra parameters that the cloud droplet sizes tend to form a quasi-monodisperse distribution. Ice particle spectra in the cloud were fitted well by an exponential distribution. Finally, a remarkable power law relationship was found between the slope （λ） and intercept （No） parameters of the exponential size distribution.

Determination of Vapor Pressures for Binary and Ternary Mixtures Containing Ionic Liquid 1-propyl-3-methylimidazolium Bromide

Vapor pressure values of binary systems water ＋ ethanol, water ＋ ionic liquid 1-propyl-3- methylimidazolium bromide （[PMIM] [Br]）, ethanol ＋ [PMIM] [Br] and ternary system water ＋ ethanol ＋ [PMIM] [Br] at different temperatures were measured by using a modified boiling point method in various concentrations of （16.66%, 33.7%）, （17.4%, 33.9%） and （16.5%, 32%） mass percent of ionic liquid, respectively. The experimental vapor pressures of solvent were well correlated by the Antoine-type equation, and the overall average absolute deviation （AAD） was found to be 0.39%. The experimental results for mixtures containing ionic liquid indicate that the vapor pressure of the solvents can be decreased noticeably to different extent due to the affinity difference between ionic liquid and solvent, which is similar to the salt effect of common inorganic salts. As a result, ionic liquid may find industrial applications in extractive distillations for the system with a low separation factor or even for an azeotropic mixture.

An Investigation on Water Transmission Through Two-layer Knitted Fabrics

The aim of this paper is to investigate water transmissionproperties of two-layer weft knitted fabrics and somerelated factors.The author prepared some experimentalfabrics with specific yarns and stitch densities,and mea-sured water vapor permeating rate through the fabricsand liquid water transferability from inner to outerlayer.Results show that the permeating rate is closelyrelated to porosity within fabric while the transferabilitydepends mainly upon the water absorbabilities of fiberson two layers and the degree or their difference.

Retrieval of Oceanic Total Precipitable Water Vapor and Cloud Liquid Water from Fengyun-3D Microwave Sounding Instruments

Fengyun-3 D(FY-3 D) satellite is the latest polar-orbiting meteorological satellite launched by China and carries 10 instruments onboard. Its microwave temperature sounder(MWTS) and microwave humidity sounder(MWHS) can acquire a total of 28 channels of brightness temperatures, providing rich information for profiling atmospheric temperature and moisture. However, due to a lack of two important frequencies at 23.8 and 31.4 GHz, it is difficult to retrieve the total precipitable water vapor(TPW) and cloud liquid water path(CLW) from FY-3 D microwave sounder data as commonly done for other microwave sounding instruments. Using the channel similarity between Suomi National Polar-orbiting Partnership(NPP) advanced technology microwave sounder(ATMS) and FY-3 D microwave sounding instruments, a machine learning(ML) technique is used to generate the two missing low-frequency channels of MWTS and MWHS. Then, a new dataset named as combined microwave sounder(CMWS) is obtained,which has the same channel setting as ATMS but the spatial resolution is consistent with MWTS. A statistical inversion method is adopted to retrieve TPW and CLW over oceans from the FY-3 D CMWS. The intercomparison between different satellites shows that the inversion products of FY-3 D CMWS and Suomi NPP ATMS have good consistency in magnitude and distribution. The correlation coefficients of retrieved TPW and CLW between CMWS and ATMS can reach 0.95 and 0.85, respectively.

利用CloudSat和MODIS数据研究气溶胶对层积云的影响

利用CloudSat的云雷达数据研究了太平洋东部副热带地区的层积云微物理特性。结果显示,CloudSat反演的云滴数浓度在垂直方向变化很小。结合CloudSat的云雷达数据和MODIS的气溶胶数据,研究了气溶胶对层积云的微物理特性和液态水路径的影响。结果表明:对于相同的液态水路径,气溶胶增加可以使得云滴的尺度减小,但总体上对云滴尺度的影响并不显著;由于云中液态水路径本身变化极大,导致气溶胶对液态水路径的影响很难和云中液态水路径本身的变化分离开。此外还发现:CloudSat反演的层积云液态水路径比MODIS反演的液态水路径偏高;层积云内液态水路径的不均一性比环境气溶胶光学厚度的不均一性大。

Properties of Cloud and Precipitation over the Tibetan Plateau

The characteristics of seasonal precipitation over the Tibetan Plateau （TP） were investigated using TRMM （Tropical Rain- fall Measuring Mission） precipitation data （3B43）. Sensitive regions of summer precipitation interannual variation anomalies were investigated using EOF （empirical orthogonal function） analysis. Furthermore, the profiles of cloud water content （CWC） and precipitable water in different regions and seasons were analyzed using TRMM-3A12 data observed by the TRMM Microwave Imager. Good agreement was found between hydrometeors and precipitation over the eastern and southeastern TP, where water vapor is adequate, while the water vapor amount is not significant over the western and northern TE Further analysis showed meridional and zonal anomalies of CWC centers in the ascending branch of the Hadley and Walker Circulation, especially over the south and east of the TE The interannual variation of hydrometeors over the past decade showed a decrease over the southeastern and northwestern TP, along with a corresponding increase over other regions.

Retrieval of Liquid Water Path Inside Nonprecipitating Clouds Using TMI Measurements

Quantitative estimates of liquid water path （LWP） in clouds using satellite measurements are critical to understanding of cloud properties and the assessment of global climate change. In this paper, the relationship between microwave brightness temperature （TB） and LWP in the nonprecipitating clouds is studied by using satellite microwave measurements from the TRMM Microwave Imager （TMI） onboard the Tropical Rainfall Measuring Mission （TRMM）, together with a radiative transfer model for microwave radiance calculations. Radiative transfer modeling shows that the sensitivity is higher at both 37.0- and 85.5-GHz horizontal polarization channels for the LWP retrievals. Also, the differences between the retrieved values responding to TBs of various channels and the theoretical values are displayed by the model. Based upon above simulations, with taking into account the factor of resolution and retrieval bias for a single,channel, a nonprecipitating cloud LWP in the summer subtropical marine environment retrieval algorithm is formulated by the combination of the two TMI horizontal polarization channels, 37.0 and 85.5 GHz. Moreover,by using TMI measurements （1Bll）, this algorithm is applied to retrieving respectively LWPs for clear sky, nonprecipitating clouds, and typhoon precipitating clouds. In the clear sky case, the LWP cl^anges from -1 to 1 g m-2, and its mean value is about 10^-5 g m^-2. It indicates that, using this combination retrieval algorithm, there are no obvious systemic deviations when the LWP is low enough. The LWP values varying from 0 to 1000 g m^-2 in nonprecipitating clouds are reasonable, and its distribution pattern is very similar to the detected results in the visible channel of Visible and Infrared Scanner （VIRS） on the TRMM. In typhoon precipitating clouds, there is much more proportion of high LWP in the mature phase than the early stage. When surface rainfall rate is lower than 5 mm h^-1, the LWP increases with increasing rainfall rate.

Relationship between Cloud Characteristics and Radar Reflectivity Based on Aircraft and Cloud Radar Co-observations

Cloud properties were investigated based on aircraft and cloud radar co-observation conducted at Yitong, Jilin, Northeast China. The aircraft provided in situ measurements of cloud droplet size distribution, while the millimeter-wavelength cloud radar vertically scanned the same cloud that the aircraft penetrated. The reflectivity factor calculated from aircraft measurements was compared in detail with sinmltaneous radar observations. The results showed that the two reflectivities were comparable in warm clouds, but in ice cloud there were more differences, which were probably associated with the occurrence of liquid water. The acceptable agreement between reflectivities obtained in water cloud confirmed that it is feasible to derive cloud properties by using aircraft data, and hence for cloud radar to remotely sense cloud properties. Based on the dataset collected in warm clouds, the threshold of reflectivity to diagnose drizzle and cloud particles was studied by analyses of the probability distribution function of reflectivity from cloud particles and drizzle drops. The relationship between refiectivity factor （Z） and cloud liquid water content （LWC） was also derived from data on both cloud particles and drizzle. In comparison with cloud droplets, the relationship for drizzle was blurred by many scatter points and thus was less evident. However, these scatters could be partly removed by filtering out the drop size distribution with a large ratio of reflectivity and large extinction coefficient but small effective radius. Empirical relationships of Z-LWC for both cloud particles and drizzle could then be derived.

Comparison of Cloud Properties between Cloud Sat Retrievals and Airplane Measurements in Mixed-Phase Cloud Layers of Weak Convective and Stratus Clouds

Cloud microphysical properties including liquid and ice particle number concentration （NC）, liquid water content （LWC）, ice water content （IWC） and effective radius （RE） were retrieved from CloudSat data for a weakly convective and a widespread stratus cloud. Within the mixed-phase cloud layers, liquid-phase fractions needed to be assumed in the data retrieval process, and one existing linear （Pl） and two exponential （P2 and P3） functions, which estimate the liquid-phase fraction as a function of subfreezing temperature （from -20℃ to 0℃）, were tested. The retrieved NC, LWC, IWC and RE using Pl were on average larger than airplane measurements in the same cloud layer, Function P2 performed better than p1 or P3 in retrieving the NCs of cloud droplets in the convective cloud, while function Pl performed better in the stratus cloud. Function P3 performed better in LWC estimation in both convective and stratus clouds. The REs of cloud droplets calculated using the retrieved cloud droplet NC and LWC were closer to the values of in situ observations than those retrieved directly using the Pl function. The retrieved NCs of ice particles in both convective and stratus clouds, on the assumption of liquid-phase fraction during the retrieval of liquid droplet NCs, were closer to those of airplane observations than on the assumption of function P1.

GENERATION AND DEVELOPMENT OF MESOSCALE CLOUD ON HEAVY RAIN BELT ON THE PERIPHERY OF TYPHOON 9608 (Herb)

Typhoon-induced heavy rains are mostly studied from the viewpoint of upper-level westerly troughs. It is worthwhile to probe into a case where the rain is caused by tropical cyclone system, which is much heavier. During August 3 ~ 5, 1996, an unusually heavy rainstorm happened in the southwest of Hebei province. It was caused by 3 mesoscale convective cloud clusters on the periphery of a tropical cyclone other than the direct effects of a westerly trough. Generating in a weak baroclinic environment that is unstable with high energy, the cloud clusters were triggered off for development by unstable ageostrophic gravity waves in the low-level southeast jet stream on the periphery of the typhoon. There was a vertical circulation cell with horizontal scale close to 1000 km between the rainstorm area and westerly trough in northeast China. As shown in a computation of the Q vector of frontogenesis function, the circulation cell forms a mechanism of transforming energy between the area of interest and the westerly trough system farther away in northeast China. Study of water vapor chart indicates that high-latitude troughs in the northeast portion of the rain migrate to the southeast to enhance anti-cyclonic divergence in upper-level convection over the area of heavy rain and cause rain clusters, short-lived otherwise, to develop vigorously. It is acting as an amplifier in this case of unusually strong process of rain.

NUMERICAL STUDY OF REMOTE SENSING OF CLOUD LIQUID WATER CONTENT BY SPACE-BORNE COMBINED RADAR-RADIOMETER

A retrieval method of microwave(MW)space-borne remote sensing of cloud liquid water content by the combined radar-radiometer is suggested.A three-layer cloud model is chosen to represent the typical stratified precipitating cloud.The retrieval method mainly follows our previously suggested scheme with some modifications.Numerical comparative study shows that in space-borne remote sensing of cloud liquid water content by the combined method is much better than by radar only;Also the retrieval accuracy of cloud liquid water content may be improved when using the three-layer cloud model in the combined method.

An Evidence of Aerosol Indirect Effect on Stratus Clouds from the Integrated Ground-Based Measurements at the ARM Shouxian Site

The aerosol effect on clouds was explored using remote sensing of aerosol and cloud data at Shouxian, China. Non-precipitation, ice-free, and overcast clouds were firstly chosen by a combination of sky im- ages from the Total Sky Imager （TSI）, cloud base heights from the Ceilometer, and vertical temperature profiles from the Balloon-Borne Sounding System （BBSS）. Six cases were chosen in summer, and seven in autumn. The averaged cloud effective radii （re）, cloud optical depth （COD）, aerosol total light scattering coefficient （a）, and liquid water path （LWP） are, respectivey, 6.47 μm, 35.4, 595.9 mm-1, 0.19 mm in summer, and 6.07 μm, 96.0, 471.7 mm-1, 0.37 mm in autumn. The correlation coefficient between re and tc was found to change from negative to positive value as LWP increases.

Identifying Supercooled Liquid Water in Cloud Based on Airborne Observations: Correlation of Cloud Particle Number Concentration with Icing Probability and Proportion of Spherical Particles

Identifying supercooled liquid water(SLW)in clouds is critical for weather modification,aviation safety,and atmospheric radiation calculations.Currently,aircraft identification in the SLW area mostly depends on emprical estimation of cloud particle number concentration(N_(c))in China,and scientific verification and quantitative identification criteria are urgently needed.In this study,the observations are from the Fast Cloud Droplets Probe,Rosemount ice detector(RICE),and Cloud Particle Imager(CP_(i))onboard a King Air aircraft during seven flights in 2018 and 2019 over central and eastern China.Based on this,the correlation among N_(c),the proportion of spherical particles(P_(s)),and the probability of icing(P_(i))in supercooled stratiform and cumulus-stratus clouds is statistically analyzed.Subsequently,this study proposes a method to identify SLW areas using N_(c) in combination with ambient temperature.The reliability of this method is evaluated through the true skill statistics(TSS)and threat score(TS)methods.Numerous airborne observations during the seven flights reveal a strong correlation among Nc,P_(s),and P_(i)at the temperature from 0 to−18°C.When Nc is greater than a certain threshold of 5 cm^(−3),there is always the SLW,i.e.,P_(i)and P_(s)are high.Evaluation results demonstrate that the TSS and TS values for Nc=5 cm^(−3)are higher than those for Nc<5 cm^(−3),and a larger Nc threshold(>5 cm^(−3))corresponds to a higher SLW identification hit rate and a higher SLW content.Therefore,Nc=5 cm^(−3)can be used as the minimum criterion for identifying the SLW in clouds at temperature lower than 0°C.The SLW identification method proposed in this study is especially helpful in common situations where aircraft are equipped with only Nc probes and without the CP_(i)and RICE.