Dynamic simulation analysis of molten salt reactor-coupled air-steam combined cycle power generation system

A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the molten salt reactor and power system.This model considers the impact of thermal properties of fluid variation on accuracy and has been validated with Simulink.This study reveals the capability of the control system to compensate for anomalous situations and maintain shaft stability in the event of perturbations occurring in high-temperature molten salt tank outlet parameters.Meanwhile,the control system’s impact on the system’s dynamic characteristics under molten salt disturbance is also analyzed.The results reveal that after the disturbance occurs,the controlled system benefits from the action of the control,and the overshoot and disturbance amplitude are positively correlated,while the system power and frequency eventually return to the initial values.This simulation model provides a basis for utilizing molten salt reactors for power generation and maintaining grid stability.

Salt-Water Transport in Unsaturated Soils Under Crop Planting: Dynamics and Numerical Simulation

A laboratory salt-water dynamics experiment using unsaturated soils in packed silt loam and clay soil columns withdifferent soil texture profiles and groundwater levels under crops were conducted to study the changes of salt-waterdynamics induced by water uptake of crops and to propose the theoretical basis for the regulation and control of salt-water dynamics as well as to predict salinity levels. The HYDRUS 1D model was applied to simulate the one-dimensionalmovement of water and salt transport in the soil columns. The results showed that the salts mainly accumulated in theplow layer in the soil columns under crops. Soil water and salt both moved towards the plow layer due to soil waterabsorption by the crop root system. The salt contents in the column with lower groundwater were mostly greater thanthose with high groundwater. The water contents in the soil columns increased from top to the bottom due to plant rootwater uptake. The changes in groundwater level had little influence on water content of the root zone in the soil columnswith crop planting. Comparison between the simulated and the determined values showed that model simulation resultswere ideal, so it is practicable to do numerical simulation of soil salt and water transport by the HYDRUS 1D model.Furthermore, if the actual movement of salt and water in fields is to be described in detail, much work needs to be done.The most important thing is to refine the parameters and select precise boundary conditions.

Salt-Water Dynamics in Highly Salinized Topsoil of Salt-Affected Soil During Water Infiltration

Continuous monitoring of salt and water movement in the soil profile of highly salinized topsoil under steadystate infiltration was conducted.It gives that salt and water dynamics during convection-diffusion period can be divided into three stages:1.formation of a salt peak,2.the salt peak moving downwards till the appearance of the summit of the salt peak,3.the salt peak moving further downwards with the peak value decreasing.Results show that the maximum salt peak appears at the same depth if soil texture and outflow condition are the same.Factors affecting salt and water movement and ion components in the outflow solution underinfiltration are discussed.

Salt-Water Dynamics in Soils: Ⅰ. Salt-Water Dynamics in Unsaturated Soils Under Stable Evaporation Condition

A long term simulation test on salt-water dynamics in unsaturated soils with different groundwater depths and soil texture profiles under stable evaporation condition was conducted.Salinity sensors and tensiometers were used to monitor salt and water variation in soils.The experiment revealed that in the process of fresh groundwater moving upwards by capillary rise in the column,the salts in subsoil were brought upwards and accumulated in the surface soil,and consequently the salinization of surface soil took place.The rate of salt accumulation is determined mainly by the volume of capillary water flow and the conditions of salts contained in the soil profile.Water flux in soils decreased obviously when groundwater depths fell below 1.5m.When there was an interbedded clay layer 30cm in thickness in the silty loam soil profile or a clay layer 100cm in thickness at the top layer,the water flux was 3-5 times less than in the soil profile of homogeneous silty loam soil.Therefore,the rate of salt accumulation was decreased and the effect of variation of groundwater depth on the water flux in soils was weakened comparatively.If there was precipitation or irrigation supplying water to the soil,the groundwater could rarely take a direct part in the process of salt accumulation in surface soil,especially,in soil profiles with an interbedded stratum or a clayey surface soil layer.

Salt-Water Dynamics in Soils: V. Salt Balance in Soil Profiles

Salt balance in simulated soil columns was calculated on the basis of a large amount of long termobservation data. The results showed that under the climate conditions of senii-arid region of the Hnaiig-Huai-Hai Plain, the soils in the columns were under salt accumulation conditions when the groundwater depthwas controlled at less than 2.0 m, and under desalinization conditions when at larger than 2.5 m. In the soilcolnmns with clay soil and silty loam soil intercalated with a clay layer, the aniount of salt accumulated wasfar less than that in the soil column with silty loain soil throughout the whole profile. Under no irrigationconditions crop planting niay increase groundwater evaporation and hence salt accumulation in soil, mforingthe soil colnmns under desalinization be under salt accumulation conditions.

Salt Dynamics in Rhizosphere of Puccinellia ciliata Bor. in a Loamy Soil

A glasshouse experiment using a rhizobox technique was conducted to examine salt dynamics in the rhizosphere of a salt-tolerant grass, Puccinellia ciliata Bor. ’Irwin Hunter’, grown in a loamy soil, and to study the effect of rainfall flush on salt accumulation in the rhizosphere. The rhizobox (10 × 5.5 × 50 cm) had a nylon mesh (1 μm) positioned vertically in the middle to create two compartments filled with soil amended with 1 g NaCl kg-1. The plants were grown in one compartment only. Flushed treatments received 275 mL of deionized water two days before harvest. In the plant-growing compartment, soils were sectioned vertically at 5 cm intervals. Significant differences in soil electrical conductivity (EC) (P < 0.05) and pH (P < 0.05) were observed for depths, but not between flushed and non-flushed treatments. In the no-plant compartment (rhizosphere), soil cores were taken horizontally at depths of 5, 20 and 40 cm and sliced at 1, 2, 3, 4, 5, 7, 10, 15 and 20 mm away from the roots. Soil EC and Cl- concentration at the 5 and 20 cm depths, and Na+ concentration at the 5 cm depth significantly decreased (P < 0.05) with the distance away from the root, but no significant differences were observed in soil pH and concentrations of the K+ and Ca2+. The flush treatment only had significant influence on soil EC, pH, and Cl- concentration at the 20 cm depth. Thus, salt accumulation could occur in the rhizosphere of salt-tolerant species on saline soils, and the periodic low rainfall might not have a strong influence on salt distribution in the rhizosphere and/or root zone.

Molecular Dynamics Simulation of Effect of Salt on the Compromise of Hydrophilic and Hydrophobic Interactions in Sodium Dodecyl Sulfate Micelle Solutions

The presence of salt has a profound effect on the size,shape and structure of sodium dodecyl sulfate(SDS)micelles.There have been a great number of experiments on SDS micelles in the presence and absence of salt to study this complex problem.Unfortunately,it is not clear yet how electrolyte ions influence the structure of micelles.By describing the compromise between dominant mechanisms,a simplified atomic model of SDS in presence of salt has been developed and the molecular dynamics(MD)simulations of two series of systems with different concentrations of salt and charges of ion have been performed.Polydispersity of micelle size is founded at relatively high concentration of SDS and low charge of cation.Although the counter-ion pairs with head groups are formed,the transition of micelle shape is not observed because the charge of cation is not enough to neutralize the polar of micelle surface.

Decondensation behavior of DNA chains induced by multivalent cations at high salt concentrations:Molecular dynamics simulations and experiments

Using molecular dynamics simulations and atomic force microscopy （AFM）, we study the decondensation process of DNA chains induced by multivalent cations at high salt concentrations in the presence of short cationic chains in solutions. The typical simulation conformations of DNA chains with varying salt concentrations for multivalent cations imply that the concentration of salt cations and the valence of multivalent cations have a strong influence on the process of DNA decondensation. The DNA chains are condensed in the absence of salt or at low salt concentrations, and the compacted conformations of DNA chains become loose when a number of cations and anions are added into the solution. It is explicitly demonstrated that cations can overcompensate the bare charge of the DNA chains and weaken the attraction interactions between the DNA chains and short cationic chains at high salt concentrations. The condensation-decondensation transi- tions of DNA are also experimentally observed in mixing spermidine with X-phage DNA at different concentrations of NaCl/MgCl2 solutions.

MOLECULAR DYNAMICS STUDY OF STRUCTURE IN MOLTEN SALT SOLUTION NaF-CaF_2

The NaF-CaF_2 system has been studied by molecular dynamics simulation.The pair correlation functions between cations and anions and the bond angle distributions of cation and anion triplets have been obtained.The bridging and complexing in the system are discussed based on the pair correlation functions and bond angle distributions.The results simulated show that the F^- ions around a Ca^(2+)ion do not form tetrahedron coordination,so some of small complexing clusters such as CaF_4^(2-)are hardly found.A possible structure of F^- ions around Ca^(2+)ions is that three Ca^(2+)ions constitute an equilateral triangle through three Ca-F-Ca bridges and two F^- ions are located over and under the center of the right triangle,respectively.Meanwhile,on the outside of the triangle,every Ca^(2+)ion has other two F^- ions as its neighbors.

Preface:Value and dynamics of salt lakes in a changing world

The statement that the world’s ecosystems are rapidly deteriorating due to human intervention and global warming is nowadays commonplace.Some of the ecosystems most heavily impacted are inland salt lakes.The salt lakes are among the most valuable and fascinating ecosystems on Earth,and their study has both basic scientifi c interest as well as applied aspects.

Deep Potential Molecular Dynamics Systematic Study of Microstructure and Thermophysical Properties of NaCl-CaCl_(2) Molten Salt System across Phase Transition Temperature

Understanding the microscopic ionic structure and thermal properties of the NaCl-CaCl_(2) mixture is of great importance for improving its photothermal energy conversion efficiency.However,the measured values of thermophysical parameters are affected by the processes near the phase transition temperature,and the measured values often change abruptly.Classical and first-principles molecular dynamics studies have recently been performed to determine the thermal properties of molten salts,but such simulations for binary molten salts including NaCl-CaCl_(2) are still rare and limited to a range above the phase transition temperature(786.0 K),and the deviations from the measurements are still large.In this study,the molecular dynamics method based on the trained deep potential is used to systematically predict the variations of the ionic structure,phonon density of state,density and thermophysical properties including heat capacity,thermal conductivity,and diffusivity,and Prandtl number of the binary chloride system of NaCl-CaCl_(2) in a wide temperature range(600-1000 K)above the phase transition temperature.The variations and correlations of the properties(especially thermal diffusivity and Prandtl number)with temperature are deduced.It is found that an increase in temperature enhances ionic vibration,thus increasing the specific heat capacity.An increase in temperature weakens the interaction and vibrational transfer between ions,and hence the thermal conductivity tends to decrease.As the temperature increases,the heat capacity increases,while the density,thermal conductivity,thermal diffusion coefficient,and Prandtl number of the system all decrease.In general,the properties obtained by applying the deep potential trained in this work reflect the experimental values more accurately than the classical and first-principles molecular dynamics simulations.

Hydrochemical Dynamic Characteristics and Evolution of Underground Brine in the Mahai Salt Lake of the Qaidam Basin Qinghai-Tibet Plateau

The mineral rock salts present in the Mahai Salt Lake of the Qaidam basin exhibit high solubilities in water. In addition, the multicomponent underground brine exhibits a high salinity and is easily precipitated. In the natural state, brine transport in the brine layer is extremely slow, and the brine is in a relatively stable chemical equilibrium state with the rock salt media. However, during mining, both the seepage and the chemical fields fluctuate significantly, thereby disrupting the equilibrium and leading to variations in the chemical composition and dynamic characteristics of the brine. Therefore, we selected underground brine from the Mahai Salt Lake, collecting a total of 183 brine samples over three stages of mining（i.e., the early stage of underground brine extraction, the initial stage of mining, and the later stage of mining）. Using a range of analytical techniques, the chemical dynamics of the underground brine water and its evolution were systematically studied. We found that evaporation and enrichment were the main mechanisms of underground brine evolution in the Mahai Salt Lake, with cation exchange and mineral dissolution/precipitation being key factors in determining the dynamic characteristics and evolution of the brine.

COMPUTERIZED SIMULATION OF MOLTEN SALT SOLUTION OF Li,KF,Cl SYSTEM BY MOLECULAR DYNAMIC METHOD

The structure and properties of molten salt solution o J Li,K|F,Cl system have been investiged by computerized simulation of molecular dynamic method.The partial RDF,the partial molar energy of mixing and the diffusion coeffients of Li^+,K^+,F^- and Cl^- have been calculated. The results are in agreement with the experimental values.The regularities of the distribution of ions and mieroscopic holes are discussed based on the results of computerized simulation.

Simulated Dynamic Evaporation of Yiliping Salt Lake Brine

1 Introduction There are numerous salt lakes in western China(Zheng Mianping,et al.,2011).Yiliping playa on the western Qaidam Basin is a magnesium sulfate subtype dry salt lake with high concentrations of potassium,boron and lithium.

Dynamic simulation research on injection and withdrawal performance of underground salt cavern natural gas storage

Owing to perfect impermeability,dynamics stability,flexible and efficient operation mode and strong adjustment,underground salt cavern natural gas storage is especially adapted to be used for short-term dispatch.Based on characteristics of gas flow and heat transfer,dynamic mathematic models were built to simulate the injection and withdrawal performance of underground salt cavern gas storage.Temperature and pressure variations of natural gas in gas storage were simulated on the basis of building models during withdrawal operation,and factors affecting on the operation of gas storage were also analyzed.Therefore,these models can provide theore-tic foundation and technology support for the design,building and operation of salt cavern gas storage.

Interaction of cetyltrimethylammonium bromide with drug in aqueous/electrolyte solution:A combined conductometric and molecular dynamics method study

Interaction between beta-lactum antibiotic drug ciprofloxacin hydrochloride(CFH)and cationic surfactant cetyltrimethylammonium bromide(CTAB)was performed conductometrically in aqueous as well as in the occurrence of different salts(NaCl,KCl as well as NH_4Cl)over the temperature range of 298.15–323.15 K at the regular interval of 5 K.CFH drug has been suggested for the treatment of bacterial infections such as urinary tract infections and acute sinusitis.A clear critical micelle concentration(CMC)was obtained for pure CTAB as well as(CFH+CTAB)mixed systems.The decrease in CMC values of CTAB caused by the addition of CFH reveals the existence of the interaction between the components and therefore it is the indication of micelle formation at lower concentration of CTAB and their CMC values further decrease in attendance of salts.A nonlinear behavior in the CMC versus T plot was observed in all the cases.The ΔG_m^0 values are found to be negative in present study systems demonstrated the stability of the solution.The values of ΔH_m^0 and ΔS_m^0 reveal the existence of hydrophobic and electrostatic interactions between CFH and CTAB.The thermodynamic properties of transfer for the micellization were also evaluated and discussed in detail.Molecular dynamic simulation disclosed that environment of water and salts have impact on the hydrophobic interaction between CFH and CTAB.In water and salts,CTAB adopts spherical micelle in which charged hydrophilic groups are interacted with waters whereas hydrophobic tails form the core of the micelle.This hydrophobic core region is highly conserved and protected.In addition,micelle formation is more favorable in aqueous Na Cl solution than other solutions.

Study on the effect of thermal deformation on the liquid seal of high-temperature molten salt pump in molten salt reactor

The high-temperature molten salt pump is the core equipment in a molten salt reactor that drives the flow of the molten salt coolant.Rotor stability is key to the continuous and reliable operation of the molten salt pump,and the liquid seal at the wear ring can affect the dynamic characteristics of the rotor system.When the molten salt pump is operated in the hightemperature molten salt medium,thermal deformation of the submerged parts inevitably occurs,changing clearance between the stator and rotor,affecting the leakage and dynamic characteristics of the seal.In this study,the seal leakage,seal dynamic characteristics,and rotor system dynamic characteristics are simulated and analyzed using finite element simulation software based on two cases of considering the effect of seal thermal deformation effect or not.The results show a significant difference in the leakage characteristics and dynamic characteristics of the seal obtained by considering the effect of seal thermal deformation and neglecting the effect of thermal deformation.The leakage flow rate decreases,and the first-order critical speed of the seal-bearing-rotor system decrease after considering the seal’s thermal deformation.

Dynamic Water and Salt Changes in Saline Wasteland on the Lower Edge of Plain Reservoirs in the Desert Oasis Region

In order to reveal the distribution characteristics of water and salt in the non-irrigated saline wasteland and the growth zone of the windbreaks surrounding the plain reservoir,the groundwater and soil monitoring points were set up around the south area of Duolang Reservoir in the desert oasis.Monthly groundwater depth monitoring and soil water content and salt content fixed-point sampling for a period of 2 years were conducted.The results showed that the groundwater depth of salt wasteland in the area around the reservoir area changed slightly during the monitoring period of 2 years,and the average is 1.28 m.The soil moisture content increased with the increase of soil depth,and soil water content of 60-100 cm was larger than that of other soil layers.The salt content of the soil in the salt wasteland varied between 0.48 g/kg and8.86 g/kg in the two years,and the total salt content of different soil decreased with the increase of soil depth.The soil salt content changed greatly in 0-40 cm soil layers,with significant salt accumulation phenomenon.The soil salt content of windbreaks was significantly lower than that of the natural ecological forest.

Effects of Groundwater with Various Salinities on Evaporation and Redistribution of Water and Salt in Saline-sodic Soils in Songnen Plain,Northeast China

Groundwater mineralization is one of the main factors affecting the transport of soil water and salt in saline-sodic areas.To investigate the effects of groundwater with different levels of salinity on evaporation and distributions of soil water and salt in Songnen Plain,Northeast China,five levels of groundwater sodium adsorption ration of water(SARw)and total salt content(TSC mmol/L)were conducted in an oil column lysimeters.The five treated groundwater labeled as ST0:0,ST0:10,ST5:40,ST10:70 and ST20:100,were prepared with NaCl and CaCl2 in proportion,respectively.The results showed the groundwater evaporation(GWE)and soil evaporation(SE)increased firstly and then decreased with the increase of groundwater salinity.The values of GWE and SE in ST10:70 treatment were the highest,which were 2.09 and 1.84 times the values in the ST0:0 treatment with the lowest GWE and SE.There was a positive linear correlation between GWE and the Ca^(2+)content in groundwater,with R^(2)=0.998.The soil water content(SWC)of ST0:0 treatment was significantly(P<0.05)less than those of other treatments during the test.The SWC of the ST0:0 and ST0:10 treatments increased with the increase of soil depth,while the other treatments showed the opposite trend.Statistical analysis indicated the SWC in the 0–60 cm soil layer was positively correlated with the groundwater TSC and its ion contents during the test.Salt accumulation occurred in the topsoil and the salt accumulation in the 0–20 cm soil layer was significantly(P<0.05)greater than that in the subsoil.This study revealed the effects of the salinity level of groundwater,especially the Ca^(2+)content and TSC of groundwater,on the GWE and distributions of soil water and salt,which provided important support for the prevention and reclamation of soil salinization and sodificaton in shallow groundwater regions.

Thrust characteristics of nano-carbon/Al/oxygenated salt nanothermites for micro-energetic applications

Combustion within small motors is key in the application-specific development of nanothermite-based micro-energetic systems. This study evaluates the performance of nanothermite mixtures in a converging-diverging nozzle and an open tube. Mixtures were prepared using nano-aluminum(n-Al),potassium perchlorate(KClO_(4)), and different carbon nanomaterials(CNMs) including graphene-oxide(GO), reduced GO, carbon nanotubes(CNTs) and nanofibers(CNFs). The mixtures were packed at different densities and ignited by laser beam. Performance was measured using thrust measurement,high-speed imaging, and computational fluid dynamics modeling, respectively. Thrust, specific impulse(ISP), volumetric impulse(ISV), as well as normalized energy were found to increase notably with CNM content. Two distinctive reaction regimes(fast and slow) were observed in combustion of low and high packing densities(20% and 55%TMD), respectively. Total impulse(IFT) and ISPwere maximized in the 5%GO/Al/KClO_4 mixture, producing 7.95 m N·s and 135.20 s respectively at 20%TMD, an improvement of 57%compared to a GO-free sample(5.05 m N·s and 85.88 s). CFD analysis of the motors over predicts the thrust generated but trends in nozzle layout and packing density agree with those observed experimentally;peak force was maximized by reducing packing density and using an open tube. The numerical force profiles fit better for the nozzle cases than the open tube scenarios due to the rapid nature of combustion. This study reveals the potential of GO in improving oxygenated salt-based nanothermites,and further demonstrates their applicability for micro-propulsion and micro-energetic applications.