A new process of welding aluminum water-cooled busbars is proposed, It can not only reduce the weight and cost, but also improve the dynamic and thermal stability. Furthermore~ both finite element method analysis and ...A new process of welding aluminum water-cooled busbars is proposed, It can not only reduce the weight and cost, but also improve the dynamic and thermal stability. Furthermore~ both finite element method analysis and a prototype test testify the advantages of the design which is not limited by load current and provides a new approach for water-cooled reactors.展开更多
A heat transfer model of furnace roller cooling process was established based on analysis of furnace roller's structure. The complicated model was solved with iteration planning algorithm based on Newton search. The ...A heat transfer model of furnace roller cooling process was established based on analysis of furnace roller's structure. The complicated model was solved with iteration planning algorithm based on Newton search. The model is proved logical and credible by comparing calculated results and measured data. Then, the relationship between water flow velocity, inlet water temperature, furnace temperature and roller cross section temperature, outlet water temperature, water temperature rise, cooling water heat absorption was studied. The conclusions and recommendations are mainly as follows: l) Cooling water temperature rise decreases with the increase of water flow velocity, but it has small relationship with inlet water temperature; 2) In order to get little water scale, inlet water temperature should be controlled below 30 ℃. 3) The cooling water flow velocity should be greater than critical velocity. The critical velocity is 0.07 m/s and water flow velocity should be controlled within 0.4-0.8 m/s. Within this velocity range, water cooling efficiency is high and water temperature rise is little. If cooling water velocity increases again, heat loss will increase, leading to energy wasting.展开更多
In order to realize safe and stable operation of a water-cooled W/Cu divertor under high heating condition,the exact knowledge of its subcooled boiling heat transfer characteristics under different design parameters i...In order to realize safe and stable operation of a water-cooled W/Cu divertor under high heating condition,the exact knowledge of its subcooled boiling heat transfer characteristics under different design parameters is crucial.In this paper,subcooled boiling heat transfer in a water-cooled W/Cu divertor was numerically investigated based on computational fluid dynamic(CFD).The boiling heat transfer was simulated based on the Euler homogeneous phase model,and local differences of liquid physical properties were considered under one-sided high heating conditions.The calculated wall temperature was in good agreement with experimental results,with the maximum error of 5%only.On this basis,the void fraction distribution,flow field and heat transfer coefficient(HTC)distribution were obtained.The effects of heat flux,inlet velocity and inlet temperature on temperature distribution and pressure drop of a water-cooled W/Cu divertor were also investigated.These results provide a valuable reference for the thermal-hydraulic design of a water-cooled W/Cu divertor.展开更多
The semisolid slurry of Al-Zn-Mg-Cu alloy was prepared through a self-designed water-cooled copper serpentine pouring channel(WSPC) machine. Influences of pouring temperature, the number of turns and the cooling water...The semisolid slurry of Al-Zn-Mg-Cu alloy was prepared through a self-designed water-cooled copper serpentine pouring channel(WSPC) machine. Influences of pouring temperature, the number of turns and the cooling water flow rate on the microstructure of the semisolid Al-Zn-Mg-Cu alloy slurry were investigated. The results show that the semisolid Al-Zn-Mg-Cu alloy slurry with satisfactory quality can be generated by the WSPC when the pouring temperature is in the range between 680 ℃ and 700 ℃. At a given pouring temperature, the average grain size of primary α-Al decreases and the shape factor increases with the increase of the number of turns. When the cooling water flow rate is 450 L·h^(-1), the obtained semisolid slurry is optimal. During the preparation of the semisolid Al-Zn-Mg-Cu alloy slurry with low superheat pouring, the alloy melt has mixed inhibition and convection flow characteristics by "self-stirring". When the alloy melt flows through the serpentine channel, the chilling effect of the inner wall of the channel, the convection and mixed inhibition of the alloy melt greatly promote the heterogeneous nucleation and grain segregation. This effect destroys the dendrite growth mode under traditional solidification conditions, and the primary nuclei gradually evolve into spherical or nearspherical grains.展开更多
An orthogoual experimental scheme was designed for optimizing a water-cooled structure of the divertor plate. There were three influencing factors: the radius R of the water- cooled pipe, and the pipe spacing L1 and ...An orthogoual experimental scheme was designed for optimizing a water-cooled structure of the divertor plate. There were three influencing factors: the radius R of the water- cooled pipe, and the pipe spacing L1 and L3. The influence rule of different factors on the cooling effect and thermal stress of the plate were studied, for which the influence rank was respectively R 〉 L1 〉 L3 and L3 〉 R 〉 L1. The highest temperature value decreased when R and L1 increased~ and the maximum thermal stress value dropped when R, L1 and L3 increased. The final optimized results can be summarized as: R equals 6 mm or 7 mm, L1 equals 19 mm, and L3 equals 20 mm. Compared with the initial design, the highest temperature value had a small decline~ and the maximum thermal stress value dropped by 19~ to 24~. So it was not ideal to improve the cooling effect by optimizing the geometry sizes of the water-cooled structure, even worse than increasing the flow speed, but it was very effective for dropping the maximum thermal stress value. The orthogoaal experimental method reduces the number of experiments by 80%, and thus it is feasible and effective to optimize the water-cooled structure of the divertor plate with the orthogonal theory.展开更多
In the direct fired furnace of a continuous annealing line, seal rolls are susceptible to deformation that leads to surface defects of steel strips. According to failure analysis, the reasons include improper structur...In the direct fired furnace of a continuous annealing line, seal rolls are susceptible to deformation that leads to surface defects of steel strips. According to failure analysis, the reasons include improper structural design and heat imbalance. An improved design has been proposed to reduce stress concentration and thermal radiation. A heat transfer model has been employed to determine the proper water flow rate for roll cooling. Industrial application proves that seal rolls with the new design has less deformation and longer service life.展开更多
A novel scheme of fully immersing water cooling is proposed for a Nd:glass radial slab laser. The slab medium is entirely immersed in the circulating water Ailing the pumping cavity, which enables much lower temperat...A novel scheme of fully immersing water cooling is proposed for a Nd:glass radial slab laser. The slab medium is entirely immersed in the circulating water Ailing the pumping cavity, which enables much lower temperature and reasonably smaller thermal gradient in the slab medium. The radial slab is symmetrically and synchronously pumped by eight flash lamps, and produces multi-output beams with a total energy of 469md. Incoherent beam combination property of the multi-output beams is also investigated. The approach suggested here provides a way of scaling the slab lasers to much higher output levels and also a convenience for beam combinations.展开更多
The miscibility of flue gas and different types of light oils is investigated through slender-tube miscible displacement experiment at high temperature and high pressure.Under the conditions of high temperature and hi...The miscibility of flue gas and different types of light oils is investigated through slender-tube miscible displacement experiment at high temperature and high pressure.Under the conditions of high temperature and high pressure,the miscible displacement of flue gas and light oil is possible.At the same temperature,there is a linear relationship between oil displacement efficiency and pressure.At the same pressure,the oil displacement efficiency increases gently and then rapidly to more than 90% to achieve miscible displacement with the increase of temperature.The rapid increase of oil displacement efficiency is closely related to the process that the light components of oil transit in phase state due to distillation with the rise of temperature.Moreover,at the same pressure,the lighter the oil,the lower the minimum miscibility temperature between flue gas and oil,which allows easier miscibility and ultimately better performance of thermal miscible flooding by air injection.The miscibility between flue gas and light oil at high temperature and high pressure is more typically characterized by phase transition at high temperature in supercritical state,and it is different from the contact extraction miscibility of CO_(2) under conventional high pressure conditions.展开更多
An accurate critical heat flux(CHF) prediction method is the key factor for realizing the steady-state operation of a water-cooled divertor that works under one-sided high heating flux conditions.An improved CHF pre...An accurate critical heat flux(CHF) prediction method is the key factor for realizing the steady-state operation of a water-cooled divertor that works under one-sided high heating flux conditions.An improved CHF prediction method based on Euler's homogeneous model for flow boiling combined with realizable k-ε model for single-phase flow is adopted in this paper in which time relaxation coefficients are corrected by the Hertz-Knudsen formula in order to improve the calculation accuracy of vapor-liquid conversion efficiency under high heating flux conditions.Moreover,local large differences of liquid physical properties due to the extreme nonuniform heating flux on cooling wall along the circumference direction are revised by formula IAPWSIF97.Therefore,this method can improve the calculation accuracy of heat and mass transfer between liquid phase and vapor phase in a CHF prediction simulation of water-cooled divertors under the one-sided high heating condition.An experimental example is simulated based on the improved and the uncorrected methods.The simulation results,such as temperature,void fraction and heat transfer coefficient,are analyzed to achieve the CHF prediction.The results show that the maximum error of CHF based on the improved method is 23.7%,while that of CHF based on uncorrected method is up to 188%,as compared with the experiment results of Ref.[12].Finally,this method is verified by comparison with the experimental data obtained by International Thermonuclear Experimental Reactor(ITER),with a maximum error of 6% only.This method provides an efficient tool for the CHF prediction of water-cooled divertors.展开更多
During wet complexation denitrification of flue gas,Fe^(Ⅱ)EDTA regeneration,also known as reducing Fe^(Ⅱ)EDTA and Fe^(Ⅱ)EDTA-nitric oxide(NO)to Fe^(Ⅱ)EDTA,is crucial.In this paper,ultraviolet(UV)light was used for...During wet complexation denitrification of flue gas,Fe^(Ⅱ)EDTA regeneration,also known as reducing Fe^(Ⅱ)EDTA and Fe^(Ⅱ)EDTA-nitric oxide(NO)to Fe^(Ⅱ)EDTA,is crucial.In this paper,ultraviolet(UV)light was used for the first time to reduce Fe^(Ⅱ)EDTA-NO.The experimental result demonstrated that Fe^(Ⅱ)EDTA-NO reduction rate increased with UV power increasing,elevated temperature,and initial Fe^(Ⅱ)EDTA-NO concentration decreasing.Fe^(Ⅱ)EDTA-NO reduction rate increased first and then decreased as pH value increased(2.0-10.0).Fe^(Ⅱ)EDTA-NO reduction with UV irradiation presented a first order reaction with respect to Fe^(Ⅱ)EDTA-NO.Compared with other Fe^(Ⅱ)EDTA regeneration methods,Fe^(Ⅱ)EDTA regeneration with UV show more superiority through comprehensive consideration of regeneration rate and procedure.Subsequently,NO absorption experiment by Fe^(Ⅱ)EDTA solution with UV irradiation confirmed that UV can significantly promote the NO removal performance of Fe^(Ⅱ)EDTA.Appropriate oxygen concentration(3%(vol))and acidic environment(pH=4)was favorable for NO removal.With UV power increasing as well as temperature decreasing,NO removal efficiency rose.In addition,the mechanism research indicates that NO from flue gas is mostly converted to NO_(2)-,NO_(3)-,NH_(4)^(+),N_(2),and N_(2)O with Fe^(Ⅱ)EDTA absorption liquid with UV irradiation.UV strengthens NO removal in Fe^(Ⅱ)EDTA absorption liquid by forming a synergistic effect of oxidation-reduction-complexation.Finally,compared with NO removal methods with Fe^(Ⅱ)EDTA,Fe^(Ⅱ)EDTA combined UV system shows prominent technology advantage in terms of economy and secondary pollution.展开更多
The microstructure and mechanical properties of as-cast Al−Cu−Li−Mg−Zn alloys fabricated by conventional gravity casting and centrifugal casting techniques combined with rapid solidification were investigated.Experime...The microstructure and mechanical properties of as-cast Al−Cu−Li−Mg−Zn alloys fabricated by conventional gravity casting and centrifugal casting techniques combined with rapid solidification were investigated.Experimental results demonstrated that compared with the gravity casting technique,the water-cooling centrifugal casting technique significantly reduces porosity,refinesα(Al)grains and secondary phases,modifies the morphology of secondary phases,and mitigates both macro-and micro-segregation.These improvements arise from the synergistic effects of the vigorous backflow,centrifugal field,vibration and rapid solidification.Porosity and coarse plate-like Al13Fe4/Al7Cu2Fe phase result in the fracture before the gravity-cast alloy reaches the yield point.The centrifugal-cast alloy,however,exhibits an ultra-high yield strength of 292.0 MPa and a moderate elongation of 6.1%.This high yield strength is attributed to solid solution strengthening(SSS)of 225.3 MPa,and grain boundary strengthening(GBS)of 35.7 MPa.Li contributes the most to SSS with a scaling factor of 7.9 MPa·wt.%^(-1).The elongation of the centrifugal-cast alloy can be effectively enhanced by reducing the porosity and segregation behavior,refining the microstructure and changing the morphology of secondary phases.展开更多
The synthesis of α-calcium sulfate hemihydrate (α-CSH) from flue gas desulfurization (FGD)gypsum is a good way to realize the comprehensive utilization of FGD gypsum. To obtainα-CSH with the satisfactory performanc...The synthesis of α-calcium sulfate hemihydrate (α-CSH) from flue gas desulfurization (FGD)gypsum is a good way to realize the comprehensive utilization of FGD gypsum. To obtainα-CSH with the satisfactory performances, a facile hydrothermal-aging pretreatment process for FGD gypsum raw materials was proposed, where FGD gypsum was firstly hydrothermally converted to α-CSH whiskers, and α-CSH whiskers were further hydrated to synthesize CaSO4·2H2O (CSD) by aging under the regulation of N,N'-methylenebisacrylamide (MBA). The effects of aging time, MBA addition, aging temperature, and pH on the morphology of the synthesized CSD were investigated. The synthesized CSD crystals exhibit highly uniform prismatic morphology with the length of ca 100μm and the whiteness of 91.56%. The regulation mechanism of MBA was also illustrated. The synthesized CSD crystals with prismatic morphology were further used as raw materials to synthesize the short columnar α-CSH. The absolute dry compressive strength of paste prepared from the short columnar α-CSH is 40.85 MPa, which reaches α40 strength grade.展开更多
The synergistic impact of mechanical ball milling and flue gas desulfurization(FGD)gypsum on the dealkalization of bauxite residue was investigated through integrated analyses of solution chemistry,mineralogy,and micr...The synergistic impact of mechanical ball milling and flue gas desulfurization(FGD)gypsum on the dealkalization of bauxite residue was investigated through integrated analyses of solution chemistry,mineralogy,and microtopography.The results showed a significant decrease in Na_(2)O content(>30 wt.%)of FGD gypsum-treated bauxite residue after 30 min of mechanical ball milling.Mechanical ball milling resulted in differentiation of the elemental distribution,modification of the minerals in crystalline structure,and promotion in the dissolution of alkaline minerals,thus enhancing the acid neutralization capacity of bauxite residue.5 wt.%FGD gypsum combined with 30 min mechanical ball milling was optimal for the dealkalization of bauxite residue.展开更多
1. An Overview of Manufacture and Operation A turbine generator utilizing a new technology of electrical machinery industry, i.e. the windings of its stator and rotor all being inner water-cooled, was first successful...1. An Overview of Manufacture and Operation A turbine generator utilizing a new technology of electrical machinery industry, i.e. the windings of its stator and rotor all being inner water-cooled, was first successfully created in China and was known afterwards as a turbine generator with watercooled stator and rotor windings (Abbrev, TGWSR). The teachers from Zhejiang University came to Shanghai between展开更多
In this study,the impact of different reaction times on the preparation of powdered activated carbon(PAC)using a one-step rapid activation method under flue gas atmosphere is investigated,and the underlying reaction m...In this study,the impact of different reaction times on the preparation of powdered activated carbon(PAC)using a one-step rapid activation method under flue gas atmosphere is investigated,and the underlying reaction mechanism is summarized.Results indicate that the reaction process of this method can be divided into three stages:stage I is the rapid release of volatiles and the rapid consumption of O_(2),primarily occurring within a reaction time range of 0-0.5 s;stage II is mainly the continuous release and diffusion of volatiles,which is the carbonization and activation coupling reaction stage,and the carbonization process is the main in this stage.This stage mainly occurs at the reaction time range of 0.5 -2.0 s when SL-coal is used as material,and that is 0.5-3.0 s when JJ-coal is used as material;stage III is mainly the activation stage,during which activated components diffuse to both the surface and interior of particles.This stage mainly involves the reaction stage of CO_(2)and H2O(g)activation,and it mainly occurs at the reaction time range of 2.0-4.0 s when SL-coal is used as material,and that is 3.0-4.0 s when JJ-coal is used as material.Besides,the main function of the first two stages is to provide more diffusion channels and contact surfaces/activation sites for the diffusion and activation of the activated components in the third stage.Mastering the reaction mechanism would serve as a crucial reference and foundation for designing the structure,size of the reactor,and optimal positioning of the activator nozzle in PAC preparation.展开更多
Circulating fluidized bed flue gas desulfurization(CFB-FGD) process has been widely applied in recent years. However, high cost caused by the use of high-quality slaked lime and difficult operation due to the complex ...Circulating fluidized bed flue gas desulfurization(CFB-FGD) process has been widely applied in recent years. However, high cost caused by the use of high-quality slaked lime and difficult operation due to the complex flow field are two issues which have received great attention. Accordingly, a laboratory-scale fluidized bed reactor was constructed to investigate the effects of physical properties and external conditions on desulfurization performance of slaked lime, and the conclusions were tried out in an industrial-scale CFB-FGD tower. After that, a numerical model of the tower was established based on computational particle fluid dynamics(CPFD) and two-film theory. After comparison and validation with actual operation data, the effects of operating parameters on gas-solid distribution and desulfurization characteristics were investigated. The results of experiments and industrial trials showed that the use of slaked lime with a calcium hydroxide content of approximately 80% and particle size greater than 40 μm could significantly reduce the cost of desulfurizer. Simulation results showed that the flow field in the desulfurization tower was skewed under the influence of circulating ash. We obtained optimal operating conditions of 7.5 kg·s^(-1)for the atomized water flow, 70 kg·s^(-1)for circulating ash flow, and 0.56 kg·s^(-1)for slaked lime flow, with desulfurization efficiency reaching 98.19% and the exit flue gas meeting the ultraclean emission and safety requirements. All parameters selected in the simulation were based on engineering examples and had certain application reference significance.展开更多
Based on the basic principle and mechanism of flue gas denitrification,the commonly used catalysts for flue gas denitrification were introduced firstly,and then the catalytic performance,stability and reaction mechani...Based on the basic principle and mechanism of flue gas denitrification,the commonly used catalysts for flue gas denitrification were introduced firstly,and then the catalytic performance,stability and reaction mechanism of catalysts in the market were analyzed.Different types of catalysts were studied to look for green catalysts with high activity,sulfur resistance,water vapor resistance and other advantages.The mechanism of denitration reaction of green catalysts was discussed,and the laws of formation,propagation and consumption of active species in the reaction process were revealed to provide theoretical basis for optimizing catalyst design and improving reaction conditions.Then the research status and problems of new catalysts for flue gas denitrification were described.Finally,the future development direction of green catalysts for flue gas denitration was discussed to improve the performance and stability of catalysts and meet the performance requirements of denitration catalysts in different industries.展开更多
This research has focused on the treatment of zinc flue dust by an acid leach process, combining an environmentally suitable impurity removal process to recover cadmium. Optimum conditions were found as follows: H2SO...This research has focused on the treatment of zinc flue dust by an acid leach process, combining an environmentally suitable impurity removal process to recover cadmium. Optimum conditions were found as follows: H2SO4 concentration 90 g/L, liquid/solid ratio 6:1, leaching temperature 60 ℃ and leaching time 1.0 h. Under these conditions, 95.8% cadmium was recovered. FeAsO4 and Fe(OH)3 precipitates with FeCI3 are found to be highly effective to obtain a high degree of separation of heavy metals and the oxyanions of arsenic from the leachate. The overall separation of arsenic and other heavy metals and precipitate settling rates are optimum at n(Fe)/n(As) ratio of 3:l and pH 6. The removal rates ofFe, Pb and Cu from the solution were greater than 98.9%, and As removal rate was 99.6%. A solvent extraction with P204 was used for the separation of zinc and cadmium. Optimum conditions are obtained as follows: 20% P204 (volume fraction) diluted with kerosene at room temperature, pH 3.0, and varying organic/aqueous (O/A) phase ratio 1:1. The extraction rate of zinc is 99.2% under these conditions. Spherical cadmium particles showing nearly uniform size were produced by hydrogen reduction at 310 ℃ and the crystal structure was cubic. In addition, the purity of the recovered cadmium powder is more than 99.99%.展开更多
The in-situ instrumentation technique for measuring mercury and itsspeciation downstream a utility 100 MW pulverized coal (PC) fired boiler system was developed andconducted by the use of the Ontario hydro method (OHM...The in-situ instrumentation technique for measuring mercury and itsspeciation downstream a utility 100 MW pulverized coal (PC) fired boiler system was developed andconducted by the use of the Ontario hydro method (OHM) consistent with American standard test methodtogether with the semi-continuous emissions monitoring (SCEM) system as well as a mobile laboratoryfor mercury monitoring. The mercury and its speciation concentrations including participate mercuryat three locations of before air preheater, before electrostatic precipitator (ESP) and after ESPwere measured using the OHM and SCEM methods under normal operation conditions of the boiler systemas a result of firing a bituminous coal. The vapor-phase total mercury Hg(VT) concentration declinedwith the decrease of flue gas temperature because of mercury species transformation from oxidizedmercury to particulate mercury as the flue gas moved downstream from the air preheater to the ESPand after the ESP. A good agreement for Hg°, Hg^(2+) and Hg( VT) was obtained between the twomethods in the ash-free area. But in the dense particle-laden flue gas area, there appeared to be abig bias for mercury speciation owing to dust cake formed in the filter of OHM sampling probe. Theparticulateaffinity to the flue gas mercury and the impacts of sampling condition to accuracy ofmeasure were discussed.展开更多
文摘A new process of welding aluminum water-cooled busbars is proposed, It can not only reduce the weight and cost, but also improve the dynamic and thermal stability. Furthermore~ both finite element method analysis and a prototype test testify the advantages of the design which is not limited by load current and provides a new approach for water-cooled reactors.
基金Project(2010CB630800) supported by the National Basic Research Program of China
文摘A heat transfer model of furnace roller cooling process was established based on analysis of furnace roller's structure. The complicated model was solved with iteration planning algorithm based on Newton search. The model is proved logical and credible by comparing calculated results and measured data. Then, the relationship between water flow velocity, inlet water temperature, furnace temperature and roller cross section temperature, outlet water temperature, water temperature rise, cooling water heat absorption was studied. The conclusions and recommendations are mainly as follows: l) Cooling water temperature rise decreases with the increase of water flow velocity, but it has small relationship with inlet water temperature; 2) In order to get little water scale, inlet water temperature should be controlled below 30 ℃. 3) The cooling water flow velocity should be greater than critical velocity. The critical velocity is 0.07 m/s and water flow velocity should be controlled within 0.4-0.8 m/s. Within this velocity range, water cooling efficiency is high and water temperature rise is little. If cooling water velocity increases again, heat loss will increase, leading to energy wasting.
基金supported by the National Magnetic Confinement Fusion Science Program of China(No.2010GB104005)Funding of Jiangsu Innovation Program for Graduate Education(CXLX12.0170)the Fundamental Research Funds for the Central Universities of China
文摘In order to realize safe and stable operation of a water-cooled W/Cu divertor under high heating condition,the exact knowledge of its subcooled boiling heat transfer characteristics under different design parameters is crucial.In this paper,subcooled boiling heat transfer in a water-cooled W/Cu divertor was numerically investigated based on computational fluid dynamic(CFD).The boiling heat transfer was simulated based on the Euler homogeneous phase model,and local differences of liquid physical properties were considered under one-sided high heating conditions.The calculated wall temperature was in good agreement with experimental results,with the maximum error of 5%only.On this basis,the void fraction distribution,flow field and heat transfer coefficient(HTC)distribution were obtained.The effects of heat flux,inlet velocity and inlet temperature on temperature distribution and pressure drop of a water-cooled W/Cu divertor were also investigated.These results provide a valuable reference for the thermal-hydraulic design of a water-cooled W/Cu divertor.
基金financially supported by the National Natural Science Foundation of China(Grant No.51701078)China Postdoctoral Science Foundation(Grant Nos.2018M632846 and 2018T110756)the Scientific Research Program of Hubei Provincial Education Department(Grant No.B2016053)
文摘The semisolid slurry of Al-Zn-Mg-Cu alloy was prepared through a self-designed water-cooled copper serpentine pouring channel(WSPC) machine. Influences of pouring temperature, the number of turns and the cooling water flow rate on the microstructure of the semisolid Al-Zn-Mg-Cu alloy slurry were investigated. The results show that the semisolid Al-Zn-Mg-Cu alloy slurry with satisfactory quality can be generated by the WSPC when the pouring temperature is in the range between 680 ℃ and 700 ℃. At a given pouring temperature, the average grain size of primary α-Al decreases and the shape factor increases with the increase of the number of turns. When the cooling water flow rate is 450 L·h^(-1), the obtained semisolid slurry is optimal. During the preparation of the semisolid Al-Zn-Mg-Cu alloy slurry with low superheat pouring, the alloy melt has mixed inhibition and convection flow characteristics by "self-stirring". When the alloy melt flows through the serpentine channel, the chilling effect of the inner wall of the channel, the convection and mixed inhibition of the alloy melt greatly promote the heterogeneous nucleation and grain segregation. This effect destroys the dendrite growth mode under traditional solidification conditions, and the primary nuclei gradually evolve into spherical or nearspherical grains.
基金supported by National Basic Research Program of China(973 Program)(No.2013GB102000)
文摘An orthogoual experimental scheme was designed for optimizing a water-cooled structure of the divertor plate. There were three influencing factors: the radius R of the water- cooled pipe, and the pipe spacing L1 and L3. The influence rule of different factors on the cooling effect and thermal stress of the plate were studied, for which the influence rank was respectively R 〉 L1 〉 L3 and L3 〉 R 〉 L1. The highest temperature value decreased when R and L1 increased~ and the maximum thermal stress value dropped when R, L1 and L3 increased. The final optimized results can be summarized as: R equals 6 mm or 7 mm, L1 equals 19 mm, and L3 equals 20 mm. Compared with the initial design, the highest temperature value had a small decline~ and the maximum thermal stress value dropped by 19~ to 24~. So it was not ideal to improve the cooling effect by optimizing the geometry sizes of the water-cooled structure, even worse than increasing the flow speed, but it was very effective for dropping the maximum thermal stress value. The orthogoaal experimental method reduces the number of experiments by 80%, and thus it is feasible and effective to optimize the water-cooled structure of the divertor plate with the orthogonal theory.
文摘In the direct fired furnace of a continuous annealing line, seal rolls are susceptible to deformation that leads to surface defects of steel strips. According to failure analysis, the reasons include improper structural design and heat imbalance. An improved design has been proposed to reduce stress concentration and thermal radiation. A heat transfer model has been employed to determine the proper water flow rate for roll cooling. Industrial application proves that seal rolls with the new design has less deformation and longer service life.
基金Supported by the Major Innovation Program of Shandong Province under Grant No 2013CXA10006the National Natural Science Foundation of China under Grant No 61108008
文摘A novel scheme of fully immersing water cooling is proposed for a Nd:glass radial slab laser. The slab medium is entirely immersed in the circulating water Ailing the pumping cavity, which enables much lower temperature and reasonably smaller thermal gradient in the slab medium. The radial slab is symmetrically and synchronously pumped by eight flash lamps, and produces multi-output beams with a total energy of 469md. Incoherent beam combination property of the multi-output beams is also investigated. The approach suggested here provides a way of scaling the slab lasers to much higher output levels and also a convenience for beam combinations.
基金Supported by the PetroChina Science and Technology Project(2023ZG18).
文摘The miscibility of flue gas and different types of light oils is investigated through slender-tube miscible displacement experiment at high temperature and high pressure.Under the conditions of high temperature and high pressure,the miscible displacement of flue gas and light oil is possible.At the same temperature,there is a linear relationship between oil displacement efficiency and pressure.At the same pressure,the oil displacement efficiency increases gently and then rapidly to more than 90% to achieve miscible displacement with the increase of temperature.The rapid increase of oil displacement efficiency is closely related to the process that the light components of oil transit in phase state due to distillation with the rise of temperature.Moreover,at the same pressure,the lighter the oil,the lower the minimum miscibility temperature between flue gas and oil,which allows easier miscibility and ultimately better performance of thermal miscible flooding by air injection.The miscibility between flue gas and light oil at high temperature and high pressure is more typically characterized by phase transition at high temperature in supercritical state,and it is different from the contact extraction miscibility of CO_(2) under conventional high pressure conditions.
基金supported by the National Magnetic Confinement Fusion Science Program of China(No.2010GB104005)National Natural Science Foundation of China(No.51406085)
文摘An accurate critical heat flux(CHF) prediction method is the key factor for realizing the steady-state operation of a water-cooled divertor that works under one-sided high heating flux conditions.An improved CHF prediction method based on Euler's homogeneous model for flow boiling combined with realizable k-ε model for single-phase flow is adopted in this paper in which time relaxation coefficients are corrected by the Hertz-Knudsen formula in order to improve the calculation accuracy of vapor-liquid conversion efficiency under high heating flux conditions.Moreover,local large differences of liquid physical properties due to the extreme nonuniform heating flux on cooling wall along the circumference direction are revised by formula IAPWSIF97.Therefore,this method can improve the calculation accuracy of heat and mass transfer between liquid phase and vapor phase in a CHF prediction simulation of water-cooled divertors under the one-sided high heating condition.An experimental example is simulated based on the improved and the uncorrected methods.The simulation results,such as temperature,void fraction and heat transfer coefficient,are analyzed to achieve the CHF prediction.The results show that the maximum error of CHF based on the improved method is 23.7%,while that of CHF based on uncorrected method is up to 188%,as compared with the experiment results of Ref.[12].Finally,this method is verified by comparison with the experimental data obtained by International Thermonuclear Experimental Reactor(ITER),with a maximum error of 6% only.This method provides an efficient tool for the CHF prediction of water-cooled divertors.
基金supported by National Natural Science Foundation of China(52260012)Natural Science Foundation of Jiangxi Province(20232BAB203053,20212ACB213001,20232BAB203033)+1 种基金General Project of Jiangxi Province Key Research and Development Program(20192BBG70008)Training Plan for Academic and Technical Leaders of Major Disciplines in Jiangxi Province-youth Talent Project(20232BCJ23047).
文摘During wet complexation denitrification of flue gas,Fe^(Ⅱ)EDTA regeneration,also known as reducing Fe^(Ⅱ)EDTA and Fe^(Ⅱ)EDTA-nitric oxide(NO)to Fe^(Ⅱ)EDTA,is crucial.In this paper,ultraviolet(UV)light was used for the first time to reduce Fe^(Ⅱ)EDTA-NO.The experimental result demonstrated that Fe^(Ⅱ)EDTA-NO reduction rate increased with UV power increasing,elevated temperature,and initial Fe^(Ⅱ)EDTA-NO concentration decreasing.Fe^(Ⅱ)EDTA-NO reduction rate increased first and then decreased as pH value increased(2.0-10.0).Fe^(Ⅱ)EDTA-NO reduction with UV irradiation presented a first order reaction with respect to Fe^(Ⅱ)EDTA-NO.Compared with other Fe^(Ⅱ)EDTA regeneration methods,Fe^(Ⅱ)EDTA regeneration with UV show more superiority through comprehensive consideration of regeneration rate and procedure.Subsequently,NO absorption experiment by Fe^(Ⅱ)EDTA solution with UV irradiation confirmed that UV can significantly promote the NO removal performance of Fe^(Ⅱ)EDTA.Appropriate oxygen concentration(3%(vol))and acidic environment(pH=4)was favorable for NO removal.With UV power increasing as well as temperature decreasing,NO removal efficiency rose.In addition,the mechanism research indicates that NO from flue gas is mostly converted to NO_(2)-,NO_(3)-,NH_(4)^(+),N_(2),and N_(2)O with Fe^(Ⅱ)EDTA absorption liquid with UV irradiation.UV strengthens NO removal in Fe^(Ⅱ)EDTA absorption liquid by forming a synergistic effect of oxidation-reduction-complexation.Finally,compared with NO removal methods with Fe^(Ⅱ)EDTA,Fe^(Ⅱ)EDTA combined UV system shows prominent technology advantage in terms of economy and secondary pollution.
基金financially supported by the Natural Science Foundation of Ningbo,China (No.2023J053)。
文摘The microstructure and mechanical properties of as-cast Al−Cu−Li−Mg−Zn alloys fabricated by conventional gravity casting and centrifugal casting techniques combined with rapid solidification were investigated.Experimental results demonstrated that compared with the gravity casting technique,the water-cooling centrifugal casting technique significantly reduces porosity,refinesα(Al)grains and secondary phases,modifies the morphology of secondary phases,and mitigates both macro-and micro-segregation.These improvements arise from the synergistic effects of the vigorous backflow,centrifugal field,vibration and rapid solidification.Porosity and coarse plate-like Al13Fe4/Al7Cu2Fe phase result in the fracture before the gravity-cast alloy reaches the yield point.The centrifugal-cast alloy,however,exhibits an ultra-high yield strength of 292.0 MPa and a moderate elongation of 6.1%.This high yield strength is attributed to solid solution strengthening(SSS)of 225.3 MPa,and grain boundary strengthening(GBS)of 35.7 MPa.Li contributes the most to SSS with a scaling factor of 7.9 MPa·wt.%^(-1).The elongation of the centrifugal-cast alloy can be effectively enhanced by reducing the porosity and segregation behavior,refining the microstructure and changing the morphology of secondary phases.
基金Funded by National Natural Science Foundation of China(No.22008049)Natural Science Foundation of Hebei Province,China (Nos.B2020202081 and B2018202330)+1 种基金Key Laboratory of Gas Hydrate,Guangzhou Institute of Energy Conversion,Chinese Academy of Sciences,China (No.E029kf1601)Research Fund Program of Science and Technology of Colleges and Universities of Hebei Province,China (No.QN2019012)。
文摘The synthesis of α-calcium sulfate hemihydrate (α-CSH) from flue gas desulfurization (FGD)gypsum is a good way to realize the comprehensive utilization of FGD gypsum. To obtainα-CSH with the satisfactory performances, a facile hydrothermal-aging pretreatment process for FGD gypsum raw materials was proposed, where FGD gypsum was firstly hydrothermally converted to α-CSH whiskers, and α-CSH whiskers were further hydrated to synthesize CaSO4·2H2O (CSD) by aging under the regulation of N,N'-methylenebisacrylamide (MBA). The effects of aging time, MBA addition, aging temperature, and pH on the morphology of the synthesized CSD were investigated. The synthesized CSD crystals exhibit highly uniform prismatic morphology with the length of ca 100μm and the whiteness of 91.56%. The regulation mechanism of MBA was also illustrated. The synthesized CSD crystals with prismatic morphology were further used as raw materials to synthesize the short columnar α-CSH. The absolute dry compressive strength of paste prepared from the short columnar α-CSH is 40.85 MPa, which reaches α40 strength grade.
基金the National Natural Science Foundation of China(Nos.42177391,42077379)the Natural Science Foundation of Hunan Province,China(No.2022JJ20060)+1 种基金the Central South University Innovation-driven Research Program,China(No.2023CXQD065)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2023ZZTS0800).
文摘The synergistic impact of mechanical ball milling and flue gas desulfurization(FGD)gypsum on the dealkalization of bauxite residue was investigated through integrated analyses of solution chemistry,mineralogy,and microtopography.The results showed a significant decrease in Na_(2)O content(>30 wt.%)of FGD gypsum-treated bauxite residue after 30 min of mechanical ball milling.Mechanical ball milling resulted in differentiation of the elemental distribution,modification of the minerals in crystalline structure,and promotion in the dissolution of alkaline minerals,thus enhancing the acid neutralization capacity of bauxite residue.5 wt.%FGD gypsum combined with 30 min mechanical ball milling was optimal for the dealkalization of bauxite residue.
文摘1. An Overview of Manufacture and Operation A turbine generator utilizing a new technology of electrical machinery industry, i.e. the windings of its stator and rotor all being inner water-cooled, was first successfully created in China and was known afterwards as a turbine generator with watercooled stator and rotor windings (Abbrev, TGWSR). The teachers from Zhejiang University came to Shanghai between
基金supported by the Qingdao Postdoctoral Program Funding(QDBSH20220202045)Shandong provincial Natural Science Foundation(ZR2021ME049,ZR2022ME176)+1 种基金National Natural Science Foundation of China(22078176)Taishan Industrial Experts Program(TSCX202306135).
文摘In this study,the impact of different reaction times on the preparation of powdered activated carbon(PAC)using a one-step rapid activation method under flue gas atmosphere is investigated,and the underlying reaction mechanism is summarized.Results indicate that the reaction process of this method can be divided into three stages:stage I is the rapid release of volatiles and the rapid consumption of O_(2),primarily occurring within a reaction time range of 0-0.5 s;stage II is mainly the continuous release and diffusion of volatiles,which is the carbonization and activation coupling reaction stage,and the carbonization process is the main in this stage.This stage mainly occurs at the reaction time range of 0.5 -2.0 s when SL-coal is used as material,and that is 0.5-3.0 s when JJ-coal is used as material;stage III is mainly the activation stage,during which activated components diffuse to both the surface and interior of particles.This stage mainly involves the reaction stage of CO_(2)and H2O(g)activation,and it mainly occurs at the reaction time range of 2.0-4.0 s when SL-coal is used as material,and that is 3.0-4.0 s when JJ-coal is used as material.Besides,the main function of the first two stages is to provide more diffusion channels and contact surfaces/activation sites for the diffusion and activation of the activated components in the third stage.Mastering the reaction mechanism would serve as a crucial reference and foundation for designing the structure,size of the reactor,and optimal positioning of the activator nozzle in PAC preparation.
基金supported by National Natural Science Foundation of China(52336005 and 52106133).
文摘Circulating fluidized bed flue gas desulfurization(CFB-FGD) process has been widely applied in recent years. However, high cost caused by the use of high-quality slaked lime and difficult operation due to the complex flow field are two issues which have received great attention. Accordingly, a laboratory-scale fluidized bed reactor was constructed to investigate the effects of physical properties and external conditions on desulfurization performance of slaked lime, and the conclusions were tried out in an industrial-scale CFB-FGD tower. After that, a numerical model of the tower was established based on computational particle fluid dynamics(CPFD) and two-film theory. After comparison and validation with actual operation data, the effects of operating parameters on gas-solid distribution and desulfurization characteristics were investigated. The results of experiments and industrial trials showed that the use of slaked lime with a calcium hydroxide content of approximately 80% and particle size greater than 40 μm could significantly reduce the cost of desulfurizer. Simulation results showed that the flow field in the desulfurization tower was skewed under the influence of circulating ash. We obtained optimal operating conditions of 7.5 kg·s^(-1)for the atomized water flow, 70 kg·s^(-1)for circulating ash flow, and 0.56 kg·s^(-1)for slaked lime flow, with desulfurization efficiency reaching 98.19% and the exit flue gas meeting the ultraclean emission and safety requirements. All parameters selected in the simulation were based on engineering examples and had certain application reference significance.
基金Supported by the Interdisciplinary Team Project of Shenyang University of Technology in 2021:Green and Low-carbon(Technology and Evaluation)of Typical Industries of Carbon Peak(2021-70-06)"Double First-class"Construction Project of Liaoning Province in 2020(Scientific Research)(FWDFGD2020041).
文摘Based on the basic principle and mechanism of flue gas denitrification,the commonly used catalysts for flue gas denitrification were introduced firstly,and then the catalytic performance,stability and reaction mechanism of catalysts in the market were analyzed.Different types of catalysts were studied to look for green catalysts with high activity,sulfur resistance,water vapor resistance and other advantages.The mechanism of denitration reaction of green catalysts was discussed,and the laws of formation,propagation and consumption of active species in the reaction process were revealed to provide theoretical basis for optimizing catalyst design and improving reaction conditions.Then the research status and problems of new catalysts for flue gas denitrification were described.Finally,the future development direction of green catalysts for flue gas denitration was discussed to improve the performance and stability of catalysts and meet the performance requirements of denitration catalysts in different industries.
文摘This research has focused on the treatment of zinc flue dust by an acid leach process, combining an environmentally suitable impurity removal process to recover cadmium. Optimum conditions were found as follows: H2SO4 concentration 90 g/L, liquid/solid ratio 6:1, leaching temperature 60 ℃ and leaching time 1.0 h. Under these conditions, 95.8% cadmium was recovered. FeAsO4 and Fe(OH)3 precipitates with FeCI3 are found to be highly effective to obtain a high degree of separation of heavy metals and the oxyanions of arsenic from the leachate. The overall separation of arsenic and other heavy metals and precipitate settling rates are optimum at n(Fe)/n(As) ratio of 3:l and pH 6. The removal rates ofFe, Pb and Cu from the solution were greater than 98.9%, and As removal rate was 99.6%. A solvent extraction with P204 was used for the separation of zinc and cadmium. Optimum conditions are obtained as follows: 20% P204 (volume fraction) diluted with kerosene at room temperature, pH 3.0, and varying organic/aqueous (O/A) phase ratio 1:1. The extraction rate of zinc is 99.2% under these conditions. Spherical cadmium particles showing nearly uniform size were produced by hydrogen reduction at 310 ℃ and the crystal structure was cubic. In addition, the purity of the recovered cadmium powder is more than 99.99%.
文摘The in-situ instrumentation technique for measuring mercury and itsspeciation downstream a utility 100 MW pulverized coal (PC) fired boiler system was developed andconducted by the use of the Ontario hydro method (OHM) consistent with American standard test methodtogether with the semi-continuous emissions monitoring (SCEM) system as well as a mobile laboratoryfor mercury monitoring. The mercury and its speciation concentrations including participate mercuryat three locations of before air preheater, before electrostatic precipitator (ESP) and after ESPwere measured using the OHM and SCEM methods under normal operation conditions of the boiler systemas a result of firing a bituminous coal. The vapor-phase total mercury Hg(VT) concentration declinedwith the decrease of flue gas temperature because of mercury species transformation from oxidizedmercury to particulate mercury as the flue gas moved downstream from the air preheater to the ESPand after the ESP. A good agreement for Hg°, Hg^(2+) and Hg( VT) was obtained between the twomethods in the ash-free area. But in the dense particle-laden flue gas area, there appeared to be abig bias for mercury speciation owing to dust cake formed in the filter of OHM sampling probe. Theparticulateaffinity to the flue gas mercury and the impacts of sampling condition to accuracy ofmeasure were discussed.