Surface activity and cleaning performance of rosin-based quaternary ammonium salt type asymmetric Gemini surfactants

Rosin,a renewable and abundant resource,has been extensively processed and chemically modified to endow it with special properties,especially in the surfactant industry.In this study,four rosin-based quaternary ammonium asymmetric gemini surfactants(RGS-2-n)with different alkyl chain lengths(n=12,14,16,18)were synthesized using a simple two-step method based on dehydroabietylamine as the raw material.The feasibility of these surfactants for cleaning purposes was comprehensively evaluated,suggesting that the surfactants own high surface activity and good cleaning performance.Furthermore,by successfully introducing the amine group of dehydroabietylamine into the hydrophilic group of the surfactants,we avoided its potential harm to the environment and water pollution.Density functional theory proves rosin-based gemini surfactants with asymmetric structure can further improve cleaning efficiency.Overall,our findings suggests that RGS-2-n surfactants are promising and sustainable candidates for cleaning electric plates,and provide new opportunities for rosin application in the electric industry.

Cleaning of two mirrors in the first mirror unit using radiofrequency capacitively coupled plasma

First mirror(FM)cleaning,using radio frequency(RF)plasma,has been proposed to recover FM reflectivity in nuclear fusion reactors such as the International Thermonuclear Experimental Reactor(ITER).To investigate the influence of simultaneous cleaning of two mirrors on mirror cleaning efficiency and uniformity,experiments involving single-mirror cleaning and dual-mirror cleaning were conducted using RF capacitively coupled plasma in the laboratory.For the test and simultaneous cleaning of two mirrors,the FM and second mirror(SM),both measuring 110 mm×80 mm,were placed inside the first mirror unit(FMU).They were composed of 16 mirror samples,each with a dimension of 27.5 mm×20 mm.These mirror samples consist of a titanium-zirconium-molybdenum alloy substrate,a 500 nm Mo intermediate layer and a 30 nm Al_(2)O_(3) surface coating as a proxy for Be impurities.The cleaning of a single first mirror(SFM)and the simultaneous cleaning of the FM and SM(DFM and DSM)lasted for 9 h using Ar plasma at a pressure of 1 Pa.The total reflectivity of mirror samples on the DSM did not fully recover and varied with location,with a self-bias of−140 V.With a self-bias of−300 V,the total reflectivity of mirror samples on the SFM and DFM was fully recovered.The energy dispersive spectrometer results demonstrated that the Al_(2)O_(3) coating had been completely removed from these mirror samples.However,the mass loss of each mirror sample on the SFM and DFM before and after cleaning varied depending on its location,with higher mass loss observed for mirror samples located in the corners and lower loss for those in the center.Compared with SM cleaning,the simultaneous cleaning of two mirrors reduced the difference between the highest and lowest mass loss.Furthermore,this mass loss for the mirror samples of the DFM facing the DSM was increased.This indicated that mirror samples cleaned face to face in the FMU simultaneously could influence each other,highlighting the need for special attention in future studies.

Hole cleaning evaluation and installation spacing optimization of cuttings bed remover in extended-reach drilling

In extended-reach or long-horizontal drilling,cuttings usually deposit at the bottom of the annulus.Once cuttings accumulate to a certain thickness,complex problems such as excessive torque and drag,tubing buckling,and pipe stuck probably occur,which results in a lot of non-productive time and remedial operations.Cuttings bed remover can efficiently destroy deposited cuttings in time through hydraulic and mechanical stirring effects.This paper aims to build a method for hole cleaning evaluation and installation spacing optimization of cuttings bed remover to improve the wellbore cleaning effect.Firstly,a Computational Fluid Dynamics approach with Eulerian—Eulerian multiphase model was utilized to investigate the mechanism of cuttings transportation,and a new type of cuttings bed remover was designed.Next,an evaluation method of hole cleaning effect of remover was established.After that,the effects of several drilling parameters on hole cleaning including flow rate of drilling fluid,rotational speed of drillpipe,rate of penetration,wellbore size,rheological property of drilling fluid,and remover eccentricity on the performance of cuttings bed remover were investigated.The results demonstrate that the new type of remover with streamline blade performs better than conventional removers.The efficiency of hole cleaning is greatly improved by increasing the rotational speed of drillpipe,flow rate of drilling fluid,remover eccentricity,and 6 rpm Fann dial reading for drilling fluid.While higher rate of penetration and large wellbore size result in worse hole cleaning.These findings can serve as an important guide for the structure optimization design of cuttings bed remover and installation spacing of removers.

Investigation of an electrode-driven hydrogen plasma method for in situ cleaning of tin-based contamination

To prolong the service life of optics,the feasibility of in situ cleaning of the multilayer mirror(MLM)of tin and its oxidized contamination was investigated using hydrogen plasma at different power levels.Granular tin-based contamination consisting of micro-and macroparticles was deposited on silicon via physical vapor deposition(PVD).The electrodedriven hydrogen plasma at different power levels was systematically diagnosed using a Langmuir probe and a retarding field ion energy analyzer(RFEA).Moreover,the magnitude of the self-biasing voltage was measured at different power levels,and the peak ion energy was corrected for the difference between the RFEA measurements and the self-biasing voltage(E_(RFEA)-eV_(self)).XPS analysis of O 1s and Sn 3d peaks demonstrated the chemical reduction process after 1 W cleaning.Analysis of surface and cross-section morphology revealed that holes emerged on the upper part of the macroparticles while its bottom remained smooth.Hills and folds appeared on the upper part of the microparticles,confirming the top-down cleaning mode with hydrogen plasma.This study provides an in situ electrode-driven hydrogen plasma etching process for tin-based contamination and will provide meaningful guidance for understanding the chemical mechanism of reduction and etching.

Wellbore Cleaning Degree and Hydraulic Extension in Shale Oil Horizontal Wells

The efficient development and exploitation of shale oil depends on long-distance horizontal wells. As the degreeof cleaning of the wellbore plays a key role in these processes, in this study, this problem is investigated experimentallyby focusing on the dimensionless cuttings bed height. A method is proposed to calculate the horizontalwellhydraulic extension taking into account the influence of the wellbore cleaning degree on the wellborepressure distribution and assess the effect of a variety of factors such as the bottom hole pressure, the circulatingpressure drop, the drilling pump performance and the formation properties. The analysis shows that the hydraulicextension of horizontal wells decreases with an increase in the cuttings bed height, and the higher the displacementof drilling fluid, the faster the hydraulic extension declines. The annular pressure drop of the horizontalsection increases with the increase of the cuttings bed height, resulting in a higher bottom-hole pressure. Severalarguments are provided to guide the safe drilling of shale oil horizontal wells and overcome the limits of currenttechnological approaches.

A method for cleaning wind power anomaly data by combining image processing with community detection algorithms

Current methodologies for cleaning wind power anomaly data exhibit limited capabilities in identifying abnormal data within extensive datasets and struggle to accommodate the considerable variability and intricacy of wind farm data.Consequently,a method for cleaning wind power anomaly data by combining image processing with community detection algorithms(CWPAD-IPCDA)is proposed.To precisely identify and initially clean anomalous data,wind power curve(WPC)images are converted into graph structures,which employ the Louvain community recognition algorithm and graph-theoretic methods for community detection and segmentation.Furthermore,the mathematical morphology operation(MMO)determines the main part of the initially cleaned wind power curve images and maps them back to the normal wind power points to complete the final cleaning.The CWPAD-IPCDA method was applied to clean datasets from 25 wind turbines(WTs)in two wind farms in northwest China to validate its feasibility.A comparison was conducted using density-based spatial clustering of applications with noise(DBSCAN)algorithm,an improved isolation forest algorithm,and an image-based(IB)algorithm.The experimental results demonstrate that the CWPAD-IPCDA method surpasses the other three algorithms,achieving an approximately 7.23%higher average data cleaning rate.The mean value of the sum of the squared errors(SSE)of the dataset after cleaning is approximately 6.887 lower than that of the other algorithms.Moreover,the mean of overall accuracy,as measured by the F1-score,exceeds that of the other methods by approximately 10.49%;this indicates that the CWPAD-IPCDA method is more conducive to improving the accuracy and reliability of wind power curve modeling and wind farm power forecasting.

Overview of Factors Affecting Dust Deposition on Photovoltaic Cells and Cleaning Methods

Dust deposition on the surface of photovoltaic (PV) cells poses a significant challenge to their efficiency, especially in arid regions characterized by desert and semi-desert conditions. Despite the pronounced impact of dust accumulation, these regions offer optimal solar radiation and minimal cloud cover, making them ideal candidates for widespread PV cell deployment. Various surface cleaning methods exist, each employing distinct approaches. Choosing an appropriate cleaning method requires a comprehensive understanding of the mechanisms involved in both dust deposition on module surfaces and dust adhesion to PV cell surfaces. The mechanisms governing dust deposition and adhesion are complex and multifaceted, influenced by factors such as the nature and properties of the dust particles, environmental climatic conditions, characteristics of protective coatings, and the specific location of the PV installation. These factors exhibit regional variations, necessitating the implementation of diverse cleaning approaches tailored to the unique conditions of each location. The first part of this article explores the factors influencing dust deposition on PV cell surfaces, delving into the intricate interplay of environmental variables and particle characteristics. Subsequently, the second part addresses various cleaning methods, offering an analysis of their respective advantages and disadvantages. By comprehensively examining the factors influencing dust accumulation and evaluating the effectiveness of different cleaning strategies, this article aims to contribute valuable insights to the ongoing efforts to optimize the performance and longevity of photovoltaic systems in diverse geographical contexts.

Data cleaning method for the process of acid production with flue gas based on improved random forest

Acid production with flue gas is a complex nonlinear process with multiple variables and strong coupling.The operation data is an important basis for state monitoring,optimal control,and fault diagnosis.However,the operating environment of acid production with flue gas is complex and there is much equipment.The data obtained by the detection equipment is seriously polluted and prone to abnormal phenomena such as data loss and outliers.Therefore,to solve the problem of abnormal data in the process of acid production with flue gas,a data cleaning method based on improved random forest is proposed.Firstly,an outlier data recognition model based on isolation forest is designed to identify and eliminate the outliers in the dataset.Secondly,an improved random forest regression model is established.Genetic algorithm is used to optimize the hyperparameters of the random forest regression model.Then the optimal parameter combination is found in the search space and the trend of data is predicted.Finally,the improved random forest data cleaning method is used to compensate for the missing data after eliminating abnormal data and the data cleaning is realized.Results show that the proposed method can accurately eliminate and compensate for the abnormal data in the process of acid production with flue gas.The method improves the accuracy of compensation for missing data.With the data after cleaning,a more accurate model can be established,which is significant to the subsequent temperature control.The conversion rate of SO_(2) can be further improved,thereby improving the yield of sulfuric acid and economic benefits.

Effect of a disposable endoscope precleaning kit in the cleaning procedure of gastrointestinal endoscope:A multi-center observational study

BACKGROUND Precleaning is a key step in endoscopic reprocessing.AIM To develop an effective and economic endoscope cleaning method by using a disposable endoscope bedside precleaning kit.METHODS Altogether,228 used gastrointestinal endoscopes were selected from five high-volume endoscopy units and precleaned by a traditional precleaning bucket(group T)or a disposable endoscope bedside precleaning kit(group D).Each group was further subdivided based on the replacement frequency of the cleaning solution,which was replaced every time in subgroups T1 and D1 and every several times in subgroups Ts and Ds.The adenosine triphosphate(ATP)level and residual proteins were measured three times:Before and after precleaning and after manual cleaning.RESULTS After precleaning,the precleaning kit significantly reduced the ATP levels(P=0.034)and has a more stable ATP clearance rate than the traditional precleaning bucket.The precleaning kit also saved a quarter of the cost of enzymatic detergent used during the precleaning process.After manual cleaning,the ATP levels were also significantly lower in the precleaning kit group than in the traditional precleaning bucket group(P<0.05).Meanwhile,the number of uses of the cleaning solution(up to four times)has no significant impact on the cleaning effect(P>0.05).CONCLUSION Considering its economic cost and cleaning effect,the use of a disposable endoscope bedside precleaning kit can be an optimal option in the precleaning stage with the cleaning solution being replaced several times in the manual cleaning stage.

Investigation of a facile plasma-driven method for in situ cleaning of metal-based contamination

Self-cleaning of tin contaminants was realized utilizing a self-driven hydrogen plasma.Cleaning rates of 0.7-6 nm min-1were achieved for removal of discontinuous tin particles at different powers.The analysis of topography and cross-sectional morphology revealed that the removal of tin particles was achieved through top-down cleaning with hydrogen plasma,where the upper part of spherical tin particles was always more intensely cleaned under the synergistic effect of hydrogen atoms and ions due to the vertical incidence of ions to the substrate during the whole cleaning process.Redeposition of tin atoms caused by physical sputtering and its promotion of the chemical cleaning effect was observed for the first time.Reflectance recovery measurements during cleaning and surface analysis of the substrate after cleaning indicated that nondestructive cleaning with a reflectance loss of less than 1%can be achieved at a relatively low power of120 W.Plasma-induced substrate damage,such as holes and valleys,reduced the reflectance of the substrate when cleaning was performed at a high power greater than 120 W,so this method should only be considered for application under conditions without substrate exposure.This study provides a comprehensive understanding of the removal of discontinuous tin particles using the in situ self-driven plasma cleaning method,and also provides meaningful guidance for the extension of this method in other potential fields of application.

Experimental investigation on coal pore-fracture variation and fractal characteristics synergistically affected by solvents for improving clean gas extraction

Chemical solvents instead of pure water being as hydraulic fracturing fluid could effectively increase permeability and improve clean methane extraction efficiency.However,pore-fracture variation features of lean coal synergistically affected by solvents have not been fully understood.Ultrasonic testing,nuclear magnetic resonance analysis,liquid phase mass spectrometry was adopted to comprehensively analyze pore-fracture change characteristics of lean coal treated by combined solvent(NMP and CS_(2)).Meanwhile,quantitative characterization of above changing properties was conducted using geometric fractal theory.Relationship model between permeability,fractal dimension and porosity were established.Results indicate that the end face fractures of coal are well developed after CS2and combined solvent treatments,of which,end face box-counting fractal dimensions range from 1.1227 to 1.4767.Maximum decreases in ultrasonic longitudinal wave velocity of coal affected by NMP,CS_(2)and combined solvent are 2.700%,20.521%,22.454%,respectively.Solvent treatments could lead to increasing amount of both mesopores and macropores.Decrease ratio of fractal dimension Dsis 0.259%–2.159%,while permeability increases ratio of NMR ranges from 0.1904 to 6.4486.Meanwhile,combined solvent could dissolve coal polar and non-polar small molecules and expand flow space.Results could provide reference for solvent selection and parameter optimization of permeability-enhancement technology.

Scheduling a Single-Arm Multi-Cluster Tool With a Condition-Based Cleaning Operation

As wafer circuit widths shrink less than 10 nm,stringent quality control is imposed on the wafer fabrication processes. Therefore, wafer residency time constraints and chamber cleaning operations are widely required in chemical vapor deposition, coating processes, etc. They increase scheduling complexity in cluster tools. In this paper, we focus on scheduling single-arm multi-cluster tools with chamber cleaning operations subject to wafer residency time constraints. When a chamber is being cleaned, it can be viewed as processing a virtual wafer. In this way, chamber cleaning operations can be performed while wafer residency time constraints for real wafers are not violated. Based on such a method, we present the necessary and sufficient conditions to analytically check whether a single-arm multi-cluster tool can be scheduled with a chamber cleaning operation and wafer residency time constraints. An algorithm is proposed to adjust the cycle time for a cleaning operation that lasts a long cleaning time.Meanwhile, algorithms for a feasible schedule are also derived.And an algorithm is presented for operating a multi-cluster tool back to a steady state after the cleaning. Illustrative examples are given to show the application and effectiveness of the proposed method.

Study of Oil-Bearing Drill Cuttings Cleaning and De-Oiling Treatment Method for Shale Gas Reservoirs

Due to its extensive use in shale gas exploration and development,oil-based drilling fluids generate large amounts of oil-bearing drill cuttings during the drilling process.The large amount of oil-bearing drill cuttings generated during the drilling process can lead to serious secondary contamination.In this study,a wetting agent FSC-6 with good hydrophobic and oleophobic properties was synthesized to construct an efficient oil removal system.For the first time,the mechanism of this system was analyzed by using the theory of adhesion function,interfacial tension and wettability.At the same time,a combined acoustic-chemical treatment process was applied to the wastewater and slag generated after the cleaning of the oil-bearing drill cuttings.The experimental results show that the application of this pollution-free technology can effectively solve the environmental pollution and resource recovery problems of oil-bearing drill cuttings.It meets the standard of drilling chips with oil content less than 2%in SY/T7422-2018“Oil-based drilling fluid drilling chips treatment system for oil and gas drilling equipment”.

关于*r-clean环

称对合环为*r-clean环是指环中任一元素都可表示为投射子和*-正则元的和.研究了该环的一些扩张性质,并给出了*-阿贝尔的*r-clean环中元素的刻画.

Cleaning of Multi-Source Uncertain Time Series Data Based on PageRank

There are errors in multi-source uncertain time series data.Truth discovery methods for time series data are effective in finding more accurate values,but some have limitations in their usability.To tackle this challenge,we propose a new and convenient truth discovery method to handle time series data.A more accurate sample is closer to the truth and,consequently,to other accurate samples.Because the mutual-confirm relationship between sensors is very similar to the mutual-quote relationship between web pages,we evaluate sensor reliability based on PageRank and then estimate the truth by sensor reliability.Therefore,this method does not rely on smoothness assumptions or prior knowledge of the data.Finally,we validate the effectiveness and efficiency of the proposed method on real-world and synthetic data sets,respectively.

Hydraulic modeling and optimization of jet mill bit considering the characteristics of depressurization and cuttings cleaning

A jet mill bit(JMB)is proposed to increase the drilling efficiency and safety of horizontal wells,which has the hydraulic characteristics of depressurization and cuttings cleaning.This paper fills the gap in the hydraulic study of the JMB by focusing on the hydraulic modeling and optimization of the JMB and considering these two hydraulic characteristics.First,the hydraulic depressurization model and the hydraulic cuttings cleaning model of the JMB are developed respectively.In the models,the pressure ratio and efficiency are chosen as the evaluation parameters of the depressurization capacity of the JMB,and the jet hydraulic power and jet impact force are chosen as the evaluation parameters of cuttings cleaning capacity of the JMB.Second,based on the hydraulic models,the effects of model parameters[friction loss coefficient,target inclination angle,rate of penetration(ROP),flow ratio,and well depth]on the hydraulic performance of the JMB are investigated.The results show that an increase in the friction loss coefficient and target inclination angle cause a significant reduction in the hydraulic depressurization capacity,and the effect of ROP is negligible.The flow ratio is positively related to the hydraulic cuttings cleaning capacity,and the well depth determines the maximum hydraulic cuttings cleaning capacity.Finally,by combining the hydraulic depressurization model and hydraulic cuttings cleaning model,an optimization method of JMB hydraulics is proposed to simultaneously maximize the jet depressurization capacity and the cuttings cleaning capacity.According to the drilling parameters given,the optimal values of the drilling fluid flow rate,backward nozzle diameter,forward nozzle diameter,and throat diameter can be determined.Moreover,a case study is conducted to verify the effectiveness of the optimization method.

英语强化词Clean的语法化研究

本文以英语强化词“clean”为研究对象,进行语法化的历时演变个案研究。研究基于《牛津英语词典》以及美国历史英语语料库中的语料,分析了强化词“clean”的语法化演变路径、演变机制和动因。研究最后得出结论,“clean”经历了实义形容词到低强化副词再到高强化副词的语法化演变路径,主要分为两个阶段;其演变过程中主要体现了隐喻转喻与主观化两大演变机制,动因主要是语义泛化和效率性动因,并且机制和动因充分体现了人类作为语言使用者的主体性特征。该研究在一定程度上丰富了英语强化词语法化的个案研究,具有一定的参考价值和意义。This paper focuses on the English intensifier “clean”, presenting a case study for its grammaticalization. Based on the Old English Dictionary and the Corpus of Historical American English, the study analyzes the evolutionary path, mechanism and motivation of the grammaticalization of “clean”. The study concludes that with two stages, the evolutionary path is from notional adjective to low-intensive functional adverb, and then to high-intensive functional adverb. Metaphor and metonymy as well as subjectivity are the main mechanisms, while semantic generalization and efficiency factor serve as motivations. Both the mechanism and the motivation demonstrate the predominant role of human beings. This study, to some degree, enriches the case study of the grammaticalization of English intensifiers, with some reference value and significance.

Effects of Househould Cleaning Methods on Carbendazim Residue in Apples

Carbendazim,belonging to fungicides,was commonly used for controlling crop diseases,resulting in frequent residues in fruits and vegetables.Washing was the initial step of household fruit processing for cleaning and reducing pollutant contents.However,the effect of washing on the removal of carbendazim in apples was not systemically studied.Thus,in this study,an analytical method was firstly established for the determination of carbendazim with great accuracy and precision through quick,simple,cheap,effective and safe(QuEChERS)method and ultra-performance liquid chromatography-fluorescence detection(UPLC-FLD).Then,the influencing factors were systematically researched to unveil their effects on the carbendazim residue in apples.The results indicated that water temperature,washing products and washing method could obviously affect the carbendazim content in apples.In addition,the best cleaning scheme for removal of carbendazim was soaking apples for 5 min in a cleaning solution,which was prepared by dissolving 8 g of commercial fruit washing soup with 500 ml of water at 45℃.Under this condition,the removal rate of carbendazim in the washing step reached 73.91%.This study will be helpful for providing guidance for household cleaning methods for controlling pesticide residues.

New steelmaking process based on clean deoxidation technology

After the converter steelmaking process,a considerable number of ferroalloys are needed to remove dissolved oxygen from the molten steel,but it also forms a lot of oxide inclusions that cannot be completely removed.At the same time,it increases the carbon emis-sions in the steel production process.After years of research,our team have developed a series of clean deoxidation technologies,includ-ing carbon deoxidation,hydrogen deoxidation,and waste plastic deoxidation of molten steel to address the aforementioned issues.In this study,thermodynamic calculations and laboratory experiments were employed to verify that carbon and hydrogen can reduce the total oxygen content in the molten steel melt to below 5×10^(-6) and 10×10^(-6),respectively.An analysis of the deoxidation mechanisms and ef-fects of polyethylene and polypropylene was also conducted.In addition,the applications of carbon deoxidation technology in different steels with the hot-state experiment and industrial production were discussed carefully.The carbon deoxidation experimental results of different steels were as follows:(1)the oxygen content of bearing steel was effectively controlled at 6.3×10^(-6) and the inclusion number density was lowered by 74.73%compared to aluminum deoxidized bearing steel;(2)the oxygen content in gear steel was reduced to 7.7×10^(-6) and a 54.49%reduction of inclusion number density was achieved with almost no inclusions larger than 5μm from the average level of industry gear steels;(3)a total oxygen content of M2 high-speed steel was as low as 3.7×10^(-6).In industrial production practice,car-bon deoxidation technique was applied in the final deoxidation stage for non-aluminum deoxidized bearing steel,and it yielded excellent results that the oxygen content was reduced to below 8×10^(-6) and the oxide inclusions in the steel mainly consist of silicates,along with small amounts of spinel and calcium aluminate.

满足DNV船级符号Clean(Design)要求的轮机设备订货及系统设计

为有效避免在船舶产品设计过程中出现疏漏,研究挪威船级社船级符号Clean(Design)对轮机设备订货、系统设计和舱柜布置的最新要求,并对各设备和系统的特殊要求及设计原则进行梳理和归纳。用于处理污染物的设备主要包括油水分离器、污水处理装置和焚烧炉,涉及的船舶系统主要包括舱底水系统、生活污水处理系统、泡沫灭火系统和艉管滑油系统等。该研究可供满足该规范要求的环保型船舶产品的设计参考。