Nuclear magnetic resonance experiments on the time-varying law of oil viscosity and wettability in high-multiple waterflooding sandstone cores

A simulated oil viscosity prediction model is established according to the relationship between simulated oil viscosity and geometric mean value of T2spectrum,and the time-varying law of simulated oil viscosity in porous media is quantitatively characterized by nuclear magnetic resonance(NMR)experiments of high multiple waterflooding.A new NMR wettability index formula is derived based on NMR relaxation theory to quantitatively characterize the time-varying law of rock wettability during waterflooding combined with high-multiple waterflooding experiment in sandstone cores.The remaining oil viscosity in the core is positively correlated with the displacing water multiple.The remaining oil viscosity increases rapidly when the displacing water multiple is low,and increases slowly when the displacing water multiple is high.The variation of remaining oil viscosity is related to the reservoir heterogeneity.The stronger the reservoir homogeneity,the higher the content of heavy components in the remaining oil and the higher the viscosity.The reservoir wettability changes after water injection:the oil-wet reservoir changes into water-wet reservoir,while the water-wet reservoir becomes more hydrophilic;the degree of change enhances with the increase of displacing water multiple.There is a high correlation between the time-varying oil viscosity and the time-varying wettability,and the change of oil viscosity cannot be ignored.The NMR wettability index calculated by considering the change of oil viscosity is more consistent with the tested Amott(spontaneous imbibition)wettability index,which agrees more with the time-varying law of reservoir wettability.

Separate-layer balanced waterflooding development technology for thick and complex carbonate reservoirs in the Middle East

Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic limestone reservoirs of Cretaceous in Iran-Iraq as an example,this paper proposes a balanced waterflooding development technology for thick and complex carbonate reservoirs.This technology includes the fine division of development units by concealed baffles and barriers,the combination of multi well type and multi well pattern,and the construction of balanced water injection and recovery system.Thick carbonate reservoirs in Iran-Iraq are characterized by extremely vertical heterogeneity,development of multi-genesis ultra-high permeability zones,and highly concealed baffles and barriers.Based on the technologies of identification,characterization,and sealing evaluation for concealed baffles and barriers,the balanced waterflooding development technology is proposed,and three types of balanced waterflooding development modes/techniques are formed,namely,conventional stratigraphic framework,fine stratigraphic framework,and deepened stratigraphic framework.Numerical simulations show that this technology is able to realize a fine and efficient waterflooding development to recover,in a balanced manner,the reserves of thick and complex carbonate reservoirs in Iran and Iraq.The proposed technology provides a reference for the development optimization of similar reservoirs.

Experimental analysis of matrix moveable oil saturation in tight sandstone reservoirs of the south Ordos Basin,China

Tight oil reservoirs in the south Ordos Basin are characterized by fractured,heterogeneous oil-bearing strata(an oil saturation of less than 55%on average),normal pressure(0.8±)and extra-low permeability(less than 0.3 mD).In the Chang 8 tight sandstone reservoir in Honghe oilfield,micro-and nanopores,especially those with a pore-throat radius of less than 1 mm,account for more than 90%.Fluid flow in the matrix is non-linear and crude oil flow rates are very low under normal pressure gradients.An improved understanding of oil mobility in a tight matrix is key to further development of normalpressure tight-oil resources in the continental basin.In this study,constant-velocity and high-pressure mercury injection experiments were conducted using samples of typical tight sandstone cores obtained from the south of Ordos Basin.A new method for reconstructing the full-scale pore-throat distribution characteristics of tight sandstone reservoirs was established successfully,based on which multistage centrifugal tests,tests of low-pressure differential displacement of oil by water,and nuclear magnetic resonance tests were conducted in order to obtain the distribution characteristics of moveable fluid in different pores.The moveable oil saturation(MOS)and degree of oil recovery(i.e.ratio of accumulative oil production to producing geologic reserves)of the core samples under different differential pressures for displacement were determined.As for the tight oil reservoirs in the south Ordos Basin,the moveable fluids are mainly stored in sub-micron(0.10-0.5 mm)pores.For Type I reservoirs(k>0.1 mD),the volume percentage of moveable fluid in pores with a radius larger than 0.5 mm is relatively high(greater than 40%).The degree of oil recovery of water flooding serves as the basis for forecasting recoverable reserves for tight oil reservoirs.Recoverable reserves under water flooding,mainly occur in pores with a radius greater than 0.5 mm.The contribution of Type I reserves to oil production is observed to be greater than 60%,and the degree of oil recovery reaches up to 17.1%.These results help improve our understanding on the evaluation and classification of Chang 8 tight sandstone reservoirs in Honghe oilfield and serve as theoretical basis for pilot tests to explore effective injection media and development methods to improve the matrix-driven pressure differences and displacement efficiency for oil.

Identification of waterflooded zones and the impact of waterflooding on reservoir properties of the Funing Formation in the Subei Basin,China

This paper describes the identification of waterflooded zones and the impact of waterflooding on reservoir properties of sandstones of the Funing Formation at the Gao 6 Fault-block of the Gaoji Oilfield,in the Subei Basin,east China.This work presents a new approach based on a back-propagation neural network using well log data to train the network,and then generating a cross-plot plate to identify waterflooded zones.A neural network was designed and trained,and the results show that the new method is better than traditional methods.For a comparative study,two representative wells at the Gao 6 Fault-block were chosen for analysis:one from a waterflooded zone,and the other from a zone without waterflooding.Results from this analysis were used to develop a better understanding of the impact of waterflooding on reservoir properties.A range of changes are shown to have taken place in the waterflooded zone,including changes in microscopic pore structure,fluids,and minerals.

Analytical model of 2D leakoff in waterflood-induced fractures

Waterflood-induced fractures,also known as self-induced fractures,spontaneously form at injection wells during waterflooding.These fractures propagate long distances through rock,allowing injected fluids to travel far away from a well,both within and outside the flooding layer.Essentially,the me-chanics of waterflood-induced fracture propagation is similar to that of hydraulic fractures,which are intentionally created for reservoir stimulation.Fracturing models developed for hydraulic fractures can also be applied to waterflood-induced fractures.However,waterflood-induced fractures are typically pumped with much larger volumes of water or brine and grow much longer in time.As a result,fluid leakoff from waterflood fractures into the formation is more extensive and two-dimensional(2D),a characteristic that is often ignored in a majority of modern fracturing simulators,making their appli-cation to waterflood fractures unreliable.In this work,we revisit the problem of leakoff for long-growing waterflood-induced fractures and develop a new analytical model for fluid leakoff that provides improved predictions of fracture geometry and can be easily implemented in fracturing simulators.We incorporate the developed solution into the classical Perkins-Kern-Nordgren(PKN)model of fracture growth,which shows that the choice of the Carter or a 2D leakoff model greatly impacts fracture ge-ometry at large time.The conducted parametric study shows while a toughness-dominated regime af-fects fracture evolution,most of fracture lifetime occurs in a viscosity-and-leakoff-dominated regime.We also develop an asymptotic solution for a leakoff profile in the limiting case of 2D leakoff domination(~~M and~~K).Finally,we study 3D fracture growth and out-of-zone injection with three layers and a complex structure of zones.The study shows that ignoring the 2D leakoff during simulation results in a significant overestimation of fracture geometry predictions.The present work,thus,plays an important role in improving waterflood fracture modelling,as it highlights the significance of 2D leakoff in waterflood-induced fractures and provides a reliable analytical model for fluid leakoff that can be incorporated into modern fracture simulators.

An Integrated Oil Production Enhancement Technology Based on Waterflooding Energy Recovery

A new integrated oil production enhancement technology based on water-flooding energy recovery is proposed.After providing an extensive review of the existing scientific and technical literature on this subject,the proposed integrated technology is described together with the related process flow diagram,the criteria used to select a tar-get facility for its implementation and the outcomes of the laboratory studies conducted to analyze emulsion formation and separation kinetics.Moreover,the outcomes of numerical simulations performed using Ansys CFX software are also presented.According to these results,using the proposed approach the incremental oil production may reach 1.2 t/day(with a 13%increase)and more,even at low flow rates(less than 10 t/day),thereby providing evidence for the benefits associated with this integrated technology.

Production evolution patterns and development stage division of waterflooding oilfields

The continuous growth of recoverable reserves in a waterflooding oilfield has a significant impact on the patterns of production evolution. A new production evolution model is established by improving the Weng Cycle model. With the new model, the statistical correspondence between the production decline stage and the reserve-production imbalance is clarified,and the correlation of water cut with the recovery percent of recoverable reserves is discussed, providing quantitative basis of reservoir engineering for dividing development stages of oilfield and defining mature oilfields. According to the statistics of oilfields in eastern China, the time point corresponding to the reserve-production balance coefficient dropping to less than 1dramatically is well correlated the beginning point of production decline, thus the time when the reserve-production balance coefficient drops dramatically can be taken as the initiation point of production decline stage. The research results show that the water cut and the recovery percent of recoverable reserves have a good statistical match in the high water cut stage, and it is more rational to take both the start point of production decline stage and the water cut of 90%(or the recovery percent of recoverable reserves of 80%) as the critical criteria for defining a mature oilfield. Five production evolution patterns can be summarized as follows: growth–peak plateau–stepped decline, growth–stepped stabilizing–stepped decline, growth–stepped stabilizing–rapid decline, growth–peak plateau–rapid decline, and growth–continuous decline.

Modeling flow in naturally fractured reservoirs： effect of fracture aperture distribution on dominant sub-network for flow

Fracture network connectivity and aperture （or conductivity） distribution are two crucial features controlling flow behavior of naturally fractured reservoirs. The effect of connectivity on flow properties is well documented. In this paper, however, we focus here on the influence of fracture aperture distribution. We model a two dimensional fractured reservoir in which the matrix is impermeable and the fractures are well connected. The fractures obey a power-law length distribution, as observed in natural fracture networks. For the aperture distribution, since the information from subsurface fracture networks is limited, we test a number of cases： log-normal distributions （from narrow to broad）, power-law distributions （from narrow to broad）, and one case where the aperture is pro- portional to the fracture length. We find that even a well- connected fracture network can behave like a much sparser network when the aperture distribution is broad enough （c~ 〈 2 for power-law aperture distributions and σ ≥ 0.4 for log-normal aperture distributions）. Specifically, most fractures can be eliminated leaving the remaining dominant sub-network with 90% of the permeability of the original fracture network. We determine how broad the aperture distribution must be to approach this behavior and the dependence of the dominant sub-network on the parameters of the aperture distribution. We also explore whether one can identify the dominant sub-network without doing flow calculations.

Low-salinity-based enhanced oil recovery literature review and associated screening criteria

A thorough literature review is conducted that pertains to low-salinity-based enhanced oil recovery(EOR).This is meant to be a comprehensive review of all the refereed published papers,conference papers,master’s theses and other reports in this area.The review is specifically focused on establishing various relations/characteristics or"screening criteria"such as:(1)classification/grouping of clays that have shown or are amenable to low-salinity benefits;(2)clay types vs.range of residual oil saturations;(3)API gravity and down hole oil viscosity range that is amenable for low salinity;(4)salinity range for EOR benefits;(5)pore sizes,porosity,absolute permeability and wettability range for low-salinity EOR;(6)continuous low-salinity injection vs.slug-wise injection;(7)grouping of possible low-salinity mechanisms;(8)contradictions or similarities between laboratory experiments and field evidence;and(9)compositional variations in tested low-salinity waters.A proposed screening criterion for low-salinity waterflooding is introduced.It can be concluded that either one or more of these mechanisms,or a combination thereof,may be the case-specific mechanism,i.e.,depending on the particular oil–brine–rock(OBR)system rather than something that is"universal"or universally applicable.Therefore,every OBR system that is unique or specific ought to be individually investigated to determine the benefits(if any)of low-salinity water injection;however,the proposed screening criteria may help in narrowing down some of the dominant responsible mechanisms.Although this review primarily focuses on sandstones,given the prominence of carbonates containing^60%of the world’s oil reserves,a summary of possible mechanisms and screening criteria,pertaining to low-salinity waterflooding,for carbonates is also included.Finally,the enhancement of polymer flooding by using low-salinity water as a makeup water to further decrease the residual oil saturation is also discussed.

Influence of meandering river sandstone architecture on waterflooding mechanisms: a case study of the M-I layer in the Kumkol Oilfield, Kazakhstan

In order to explore the influence of sandstone architecture on waterflooding mechanisms using the architecture method,and taking as an example the M-I layer of the Kumkol oilfield in the South Turgay Basin,Kazakhstan,we portrayed the architecture features of different types of sandstones and quantitatively characterized heterogeneities in a single sand body in meandering river facies.Based on the waterflooding characteristics of point bar sand and overbank sand according to waterflooded interpretation results in 367 wells and numerical simulation results of well groups,we finally analyzed the remaining oil potential of the meandering river sandstone and pointed out its development directions at the high water cut stage.The result shows that because lateral accretion shale beds are developed inside single sand bodies,the point bar sand is a semi-connected body.The overbank sand is thin sandstone with poor connectivity,small area and fast lateral changes.The heterogeneity of the overbank sand is stronger than the point bar sand.The sandstone architectures control the waterflooding characteristics.In meandering river sandstones,the bottom of the point bar sand is strongly waterflooded,while the top of the point bar sand and most of the overbank sand are only weakly waterflooded or unflooded.The thickness percentage of unflooded zone and weakly waterflooded zone in point bar sand is 40％,and the remaining oil in its top part is the main direction for future development.

A control volume based finite element method for simulating incompressible two-phase flow in heterogeneous porous media and its application to reservoir engineering

Applying the standard Galerkin finite element method for solving flow problems in porous media encounters some difficulties such as numerical oscillation at the shock front and discontinuity of the velocity field on element faces.Discontinuity of velocity field leads this method not to conserve mass locally.Moreover,the accuracy and stability of a solution is highly affected by a non-conservative method.In this paper,a three dimensional control volume finite element method is developed for twophase fluid flow simulation which overcomes the deficiency of the standard finite element method,and attains high-orders of accuracy at a reasonable computational cost.Moreover,this method is capable of handling heterogeneity in a very rational way.A fully implicit scheme is applied to temporal discretization of the governing equations to achieve an unconditionally stable solution.The accuracy and efficiency of the method are verified by simulating some waterflooding experiments.Some representative examples are presented to illustrate the capability of the method to simulate two-phase fluid flow in heterogeneous porous media.

Changing characteristics of ultralow permeability reservoirs during waterflooding operations

The characteristics of ultralow permeability reservoirs changed after waterflooding. Thin- section analysis and scanning electron microscopy （SEM） of core samples from inspection wells indicated that calcite and barite were formed in ultralow permeability reservoirs during waterflooding operations. Some asphaltene precipitates on the surface of formation rock would influence the reservoir porosity, permeability, wettability, and electrical properties. In this paper, the changes of physical, electrical, and fluid properties of ultralow permeability reservoirs during waterflooding operations were analyzed. This provides important information to improve waterflooding performance in ultralow permeability reservoirs.

Determination of microscopic waterflooding characteristics and influence factors in ultra-low permeability sandstone reservoir

Actual sandstone micromodel was used in this work to conduct the microscopic waterflooding experiment of ultra-low sandstone reservoir,since the inside seepage characteristics of microscopic waterflooding process of Chang 8 ultra-low permeability sandstone reservoir of Upper Triassic Yanchang formation in Huaqing region of the Ordos Basin,China is difficult to observe directly.Combined with physical property,casting thin sections,constant-rate mercury injection capillary pressure and nuclear magnetic resonance,the influence of reservoir property on the waterflooding characteristics in pores were analyzed and evaluated.Seepage paths of waterflooding characteristics were divided into four types:homogeneous seepage,reticular-homogeneous seepage,finger-reticular seepage and finger-like seepage,the waterflooding efficiency of which decreases in turn.More than 70%of residual oil occurs as flowing-around seepage and oil film.Physical property,pore structure and movable fluid characteristics are all controlled by digenesis and their impacts on waterflooding efficiency are in accordance.Generally,the pore throat radius size and distribution and movable fluid percentage are closely related to waterflooding law.

Stochastic and upscaled analytical modeling of fines migration in porous media induced by low-salinity water injection

Fines migration induced by injection of low-salinity water(LSW) into porous media can lead to severe pore plugging and consequent permeability reduction. The deepbed filtration(DBF) theory is used to model the aforementioned phenomenon, which allows us to predict the effluent concentration history and the distribution profile of entrapped particles. However, the previous models fail to consider the movement of the waterflood front. In this study, we derive a stochastic model for fines migration during LSW flooding, in which the Rankine-Hugoniot condition is used to calculate the concentration of detached particles behind and ahead of the moving water front. A downscaling procedure is developed to determine the evolution of pore-size distribution from the exact solution of a large-scale equation system. To validate the proposed model,the obtained exact solutions are used to treat the laboratory data of LSW flooding in artificial soil-packed columns. The tuning results show that the proposed model yields a considerably higher value of the coefficient of determination, compared with the previous models, indicating that the new model can successfully capture the effect of the moving water front on fines migration and precisely match the effluent history of the detached particles.

Compositional modeling and simulation of dimethyl ether (DME)-enhanced waterflood to investigate oil mobility improvement

Dimethyl ether （DME） is a widely used industrial compound, and Shell developed a chemical EOR technique called DME- enhanced waterflood （DEW）. DME is applied as a miscible solvent for EOR application to enhance the performance of conventional waterflood. When DME is injected into the reservoir and contacts the oil, the first-contact miscibility process occurs, which leads to oil swelling and viscosity reduction. The reduction in oil density and viscosity improves oil mobility and reduces residual oil saturation, enhancing oil production. A numerical study based on compositional simulation has been developed to describe the phase behavior in the DEW model. An accurate compositional model is imperative because DME has a unique advantage of solubility in both oil and water. For DEW, oil recovery increased by 34% and 12% compared to conventional waterflood and CO2 flood, respectively. Compositional modeling and simulation of the DEW process indicated the unique solubility effect of DME on EOR performance.

Development of the theory and technology for low permeability reservoirs in China

The development theories of low-permeability oil and gas reservoirs are refined, the key development technologies are summarized, and the prospect and technical direction of sustainable development are discussed based on the understanding and research on developed low-permeability oil and gas resources in China. The main achievements include:(1) the theories of low-permeability reservoir seepage, dual-medium seepage, relative homogeneity, etc.(2) the well location optimization technology combining favorable area of reservoir with gas-bearing prediction and combining pre-stack with post-stack;(3) oriented perforating multi-fracture, multistage sand adding, multistage temporary plugging, vertical well multilayer, horizontal and other fracturing techniques to improve productivity of single well;(4) the technology of increasing injection and keeping pressure, such as overall decreasing pressure, local pressurization, shaped charge stamping and plugging removal, fine separate injection, mild advanced water injection and so on;(5) enhanced recovery technology of optimization of injection-production well network in horizontal wells. To continue to develop low-permeability reserves economically and effectively, there are three aspects of work to be done well:(1) depending on technical improvement, continue to innovate new technologies and methods, establish a new mode of low quality reservoir development economically, determine the main technical boundaries and form replacement technology reserves of advanced development;(2) adhering to the management system of low cost technology & low cost, set up a complete set of low-cost dual integration innovation system through continuous innovation in technology and management;(3) striving for national preferential policies.

Effects of microscopic pore structure heterogeneity on the distribution and morphology of remaining oil

Waterflooding experiments were performed using Micro-CT on four cores of different pore structures from Donghe sandstone reservoirs in the Tarim Basin. The water, oil and grains were accurately separated by the advanced image processing technology, the pore network model was established, and parameters such as the number of throats and the throat size distribution were calculated to characterize the microscopic heterogeneity of pore structure, the flow of oil phase during displacement, and the morphology and distribution of remaining oil after displacement. The cores with the same macroscopic porosity-permeability have great differences in microscopic heterogeneity of pore structure. Both macro porosity-permeability and micro heterogeneity of pore structure have an influence on the migration of oil phase and the morphology and distribution of remaining oil. When the heterogeneity is strong, the water phase will preferentially flow through the dominant paths and the remaining oil clusters will be formed in the small pores. The more the number of oil clusters(droplets) formed during displacement process, the smaller the average volume of cluster is, and the remaining oil is dominated by the cluster continuous phase with high saturation. The weaker the heterogeneity, the higher the pore sweep efficiency is, and the remaining oil clusters are mainly trapped in the form of non-continuous phase. The distribution and morphology of micro remaining oil are related to the absolute permeability, capillary number and micro-heterogeneity. So, the identification plate of microscopic residual oil continuity distribution established on this basis can describe the relationship between these three factors and distribution of remaining oil and identify the continuity of the remaining oil distribution accurately.

Experimental study of the development mode of gas-cap edge-water reservoir:A case study of Khasib reservoir of Halfaya oilfield in Iraq

Based on the oil,gas and water distribution characteristics of Khasib reservoir in Halfaya oilfield,Iraq,a core displacement experiment is designed to evaluate the influence of different displacement methods and displacement parameters on oil displacement efficiency.The research shows that,in the displacement method with water injected from the edge of the reservoir,early depletion production is conducive to the elastic expansion of the gas cap,forming the three-dimensional displacement of"upper pressure and lower pushing",and the oil displacement effect is good.When gas injection at the top and water injection at the edge are used for synergistic displacement,the injection timing has different influences on the oil displacement effects of high and low parts.Considering the overall oil displacement efficiency,the injection pressure should be greater than the bubble point pressure of crude oil.Two displacement methods are recommended with the reasonable injection time at 20–25 MPa.The injection speed has the same influence on different injection media.Appropriately reducing the injection speed is conducive to the stability of the displacement front,delaying the breakthrough of injection media and improving the oil displacement effect.The reasonable injection rate of water flooding is 0.075 mL/min,the reasonable injection rates of water and gas are 0.15 mL/min and 0.10 mL/min,respectively in gas-water synergistic displacement.Gas-water synergistic displacement is conducive to the production of crude oil at high position,and has crude oil recovery 5.0%–14.8%higher than water flooding from the edge,so it is recommended as the development mode of Khasib reservoir at the middle and late stages.

Numerical Simulation of Liquid-Solid Coupling in Multi-Angle Fractures in Pressure-Sensitive Reservoirs

This study clarifies the seepage characteristics of complex fractured pressure-sensitive reservoirs,and addresses a common technological problem,that is the alteration of the permeability degree of the reservoir bed(known to be responsible for changes in the direction and velocity of fluid flows between wells).On the basis of a new pressuresensitive equation that considers the fracture directional pressure-sensitive effect,an oil-gas-water three-phase seepage mathematical model is introduced,which can be applied to pressure-sensitive,full-tensor permeability,ultralow-permeability reservoirs with fracture-induced anisotropy.Accordingly,numerical simulations are conducted to explore the seepage laws for ultralow-permeability reservoirs.The results show that element patterns have the highest recovery percentage under a fracture angle of 45°.Accounting for the pressure-sensitive effect produces a decrease in the recovery percentage.Several patterns are considered:inverted five-seven-and nine-spot patterns and a cross-row well pattern.Finally,two strategies are introduced to counteract the rotation of the direction of the principal permeability due to the fracture directional pressure-sensitive effect.

Experimental study on the oil production characteristics during the waterflooding of different types of reservoirs in Ordos Basin, NW China

Waterflooding experiments were conducted in micro-models(microscopic scale)and on plunger cores from low permeability,extra-low permeability and ultra-low permeability reservoirs in the Ordos Basin under different displacement pressures using the NMR techniques to find out pore-scale oil occurrence state,oil production characteristics and residual oil distribution during the process of waterflooding and analyze the effect of pore structure and displacement pressure on waterflooding efficiency.Under bound water condition,crude oil mainly occurs in medium and large pores in the low-permeability sample,while small pores and medium pores are the main distribution space of crude oil in extra-low permeability and ultra-low permeability samples.During the waterflooding,crude oil in the medium and large pores of the three types of samples are preferentially produced.With the decrease of permeability of the samples,the waterflooding front sequentially shows uniform displacement,network displacement and finger displacement,and correspondingly the oil recovery factors decrease successively.After waterflooding,the residual oil in low-permeability samples is mainly distributed in medium pores,and appears in membranous and angular dispersed phase;but that in the extra-low and ultra-low permeability samples is mainly distributed in small pores,and appears in continuous phase formed by a bypass flow and dispersed phase.The low-permeability samples have higher and stable oil displacement efficiency,while the oil displacement efficiency of the extra-low permeability and ultra-low permeability samples is lower,but increases to a certain extent with the increase of displacement pressure.