The objectives of the study were to select suitable wavebands for rice leaf area index (LAI) estimation using the data acquired over a whole growing season, and to test the efficiency of the selected wavebands by co...The objectives of the study were to select suitable wavebands for rice leaf area index (LAI) estimation using the data acquired over a whole growing season, and to test the efficiency of the selected wavebands by comparing them with feature positions of rice canopy spectra. In this study, the field experiment in 2002 growing season was conducted at the experimental farm of Zhejiang University, Hangzhou, China. Measurements of hyperspectral reflectance (350-2500 nm) and corresponding LAI were made for a paddy rice canopy throughout the growing season. And three methods were employed to identify the optimal wavebands for paddy rice LAI estimation: correlation coefficient-based method, vegetation index-based method, and stepwise regression method. This research selected 15 wavebands in the region of 350-2500 nm, which appeared to be the optimal wavebands for the paddy rice LAI estimation. Of the selected wavebands, the most frequently occurring wavebands were centered around 554, 675, 723, and 1633 rim. They were followed by 444, 524, 576, 594, 804, 849, 974, 1074, 1219, 1510, and 2194 rim. Most of them made physical sense and had their counterparts in spectral known feature positions, which indicates the promising potential of the 15 selected wavebands for the retrieval of paddy rice LAI.展开更多
Partial least squares discriminant analysis (PLS-DA) with integrated moving-window (MW) waveband screening was applied to the discriminant analysis of liquor brands with near-infrared (NIR) spectroscopy. Luzhou Laojia...Partial least squares discriminant analysis (PLS-DA) with integrated moving-window (MW) waveband screening was applied to the discriminant analysis of liquor brands with near-infrared (NIR) spectroscopy. Luzhou Laojiao, a popular liquor with strong fragrant flavor, was used as the identified liquor brand (160 samples, negative, 52 vol alcoholicity). Liquors of 10 other brands with strong fragrant flavor were used as the interferential brands (200 samples, positive, 52 vol alcoholicity). The Kennard-Stone algorithm was used for the division of modeling samples to achieve uniformity and representativeness. Based on the MW-PLS-DA, a simplified optimal model set with 157 wavebands was further proposed. This set contained five types of wavebands corresponding to the NIR absorption bands of water, ethanol, and other micronutrients (i.e., acids, aldehydes, phenols, and aromatic compounds) in liquor for practical choice. Using five selected simple models with 4775 - 4239, 7804 - 6569, 6264 - 5844, 9435 - 7896, and 12066 - 10373 cm-1, the validation recognition rates were obtained as 99.3% or higher. Results show good prediction performance and low model complexity, and also provided a valuable reference for designing small dedicated instruments. The proposed method is a promising tool for large-scale inspection of liquor food safety.展开更多
The level of chemical oxygen demand(COD)is an important index to evaluate whether sewage meets the discharge requirements,so corresponding tests should be carried out before discharge.Fourier transform infrared spectr...The level of chemical oxygen demand(COD)is an important index to evaluate whether sewage meets the discharge requirements,so corresponding tests should be carried out before discharge.Fourier transform infrared spectroscopy(FTIR)and attenuated total reflectance(ATR)can detect COD in sewage effectively,which has advantages over conventional chemical analysis methods.And the selection of characteristic bands was one of the key links in the application of FTIR/ATR spectroscopy.In this work,based on the moving window partial least-squares(MWPLS)regression to select a characteristic wavelength,a method of equivalent wavelength selection was proposed combining with paired t-test equivalent concept.The results showed that the prediction effect of the selected wavelength was very close to that of the MWPLS method,while the number of wavelength points was much smaller.SEPAve,RP,Ave,SEPStd,and RP,Std which characterized the modeling effect were 26.3 mg L^-1,0.969,3.49 mg L^-1,and 0.006,respectively.The validation effect V-SEP and V-RP were 28.64 mg L^-1 and 0.960,respectively.The selected waveband was between 1809 cm^-1 and 1568 cm^-1.The method was of more reference value for the design of FTIR/ATR spectral instrument for COD detection.展开更多
Sensing the content of macronutrients in the agricultural soil is an essential task in precision agriculture.It helps the farmers in the optimal use of fertilizers.It reduces the cost of food production and also the n...Sensing the content of macronutrients in the agricultural soil is an essential task in precision agriculture.It helps the farmers in the optimal use of fertilizers.It reduces the cost of food production and also the negative environmentalimpacts on atmosphere and water bodies due to indiscriminate dosageof fertilizers.The traditional chemical-based laboratory soil analysis methodsdo not serve the purpose as they are hardly suitable for site specific soil management.Moreover,the spectral range used in the chemical-based laboratory soil analysismay be of 350-2500 nm,which leads to redundancy and confusion.Developing sensors based on the discovery of spectral wavebands that respondto soil macronutrient concentrations,on the other hand,is an innovative and successfultechnology since the results are dependable and timely.The goal of thisarticle is to use a supervised neuro-fuzzy based dimensionality reduction approachin the sensor development process to determine sensitive wavebands of soilmacronutrients.Accordingly,the spectral signatures of the soil are collected inan outdoor environment and mapped with its macronutrient concentrations.In thisspectral analysis,the spectral reflectance of 424 wavelengths has been obtainedand these wavelengths are evaluated through combined and individual modesas well.Appropriate wavelengths are selected in each case by minimizing the fuzzy reflectance assessment index.The effectiveness of these selected wavelengthsin each mode is validated by modeling the relation between the reduced reflectancespace and each macronutrient concentration using Partial Least Squares Multi Variable Regression(PLS-MVR)method.Set of optimal wavebands areidentified and the results are compared with the existing systems.展开更多
Development of a high power fiber laser at special waveband,which is difficult to achieve by conventional rare-earth-doped fibers,is a significant challenge.One of the most common methods for achieving lasing at speci...Development of a high power fiber laser at special waveband,which is difficult to achieve by conventional rare-earth-doped fibers,is a significant challenge.One of the most common methods for achieving lasing at special wavelength is Raman conversion.Phosphorus-doped fiber(PDF),due to the phosphorus-related large frequency shift Raman peak at 40 THz,is a great choice for large frequency shift Raman conversion.Here,by adopting 150 m large mode area triple-clad PDF as Raman gain medium,and a novel wavelength-selective feedback mechanism to suppress the silica-related Raman emission,we build a high power cladding-pumped Raman fiber laser at 1.2μm waveband.A Raman signal with power up to 735.8 W at 1252.7 nm is obtained.To the best of our knowledge,this is the highest output power ever reported for fiber lasers at 1.2μm waveband.Moreover,by tuning the wavelength of the pump source,a tunable Raman output of more than 450 W over a wavelength range of 1240.6–1252.7 nm is demonstrated.This work proves PDF’s advantage in high power large frequency shift Raman conversion with a cladding pump scheme,thus providing a good solution for a high power laser source at special waveband.展开更多
Based on a silicon platform, we design and fabricate a four-mode division(de)multiplexer for chip-scale optical data transmission in the 2 μm waveband for the first time, to the best of our knowledge. The(de)multiple...Based on a silicon platform, we design and fabricate a four-mode division(de)multiplexer for chip-scale optical data transmission in the 2 μm waveband for the first time, to the best of our knowledge. The(de)multiplexer is composed of three tapered directional couplers for both mode multiplexing and demultiplexing processes. In the experiment, the average crosstalk for four channels is measured to be less than-18 dB over a wide wavelength range(70 nm) from 1950 to 2020 nm, and the insertion losses are also assessed. Moreover, we further demonstrate stable 5 Gbit/s direct modulation data transmission through the fabricated silicon photonic devices with nonreturn-to-zero on–off keying signals. The experimental results show clear eye diagrams, and the penalties at a bit error rate of 3.8 × 10-3 are all less than 2.5 dB after on-chip data transmission. The obtained results indicate that the presented silicon four-mode division multiplexer in the mid-infrared wavelength band might be a promising candidate facilitating chip-scale high-speed optical interconnects.展开更多
We propose a cascade system of filters for realizing a non-uniform waveband separation for optical networks. The use of such separation is required at the DEMUX stage in a optical OXC switching wavebands. The design o...We propose a cascade system of filters for realizing a non-uniform waveband separation for optical networks. The use of such separation is required at the DEMUX stage in a optical OXC switching wavebands. The design of the system is based on optimized balanced tree, which minimizes the overall optical loss.展开更多
针对2.0~25.0μm波段传输的限制损耗问题,文章采用数值模拟方法研究影响碲基硫系光子晶体光纤(photonic crystal fiber,PCF)限制损耗的主要因素。光纤纤芯和包层材料采用Ge 20 As 20 Se 15 Te 45玻璃,通过改变纤芯直径、空气孔直径和空...针对2.0~25.0μm波段传输的限制损耗问题,文章采用数值模拟方法研究影响碲基硫系光子晶体光纤(photonic crystal fiber,PCF)限制损耗的主要因素。光纤纤芯和包层材料采用Ge 20 As 20 Se 15 Te 45玻璃,通过改变纤芯直径、空气孔直径和空气孔层数等参数进行2.0~25.0μm波段限制损耗的计算,结果表明,影响限制损耗的最大因素是纤芯直径,限制损耗随着纤芯直径和空气孔直径的增大而显著降低,随着空气孔层数的增加而降低;优化设计出一种低限制损耗的PCF,结果表明,当纤芯直径和节距为8.0μm、空气孔直径为7.2μm、包层空气孔层数为4时,该PCF在2.0~25.0μm波长范围的限制损耗低于1.4×10^(-6) dB/m,满足低损耗传输要求。文章研究结果对2.0~25.0μm波段光信号的传输具有一定的意义。展开更多
基金supported by the National Natural Science Foundation of China (No. 40571115)the Hi-Tech Research and Development Program (863) of China (No. 2006AA120101)the National Basic Research Program (973) of China (No. 2006BAD10A09)
文摘The objectives of the study were to select suitable wavebands for rice leaf area index (LAI) estimation using the data acquired over a whole growing season, and to test the efficiency of the selected wavebands by comparing them with feature positions of rice canopy spectra. In this study, the field experiment in 2002 growing season was conducted at the experimental farm of Zhejiang University, Hangzhou, China. Measurements of hyperspectral reflectance (350-2500 nm) and corresponding LAI were made for a paddy rice canopy throughout the growing season. And three methods were employed to identify the optimal wavebands for paddy rice LAI estimation: correlation coefficient-based method, vegetation index-based method, and stepwise regression method. This research selected 15 wavebands in the region of 350-2500 nm, which appeared to be the optimal wavebands for the paddy rice LAI estimation. Of the selected wavebands, the most frequently occurring wavebands were centered around 554, 675, 723, and 1633 rim. They were followed by 444, 524, 576, 594, 804, 849, 974, 1074, 1219, 1510, and 2194 rim. Most of them made physical sense and had their counterparts in spectral known feature positions, which indicates the promising potential of the 15 selected wavebands for the retrieval of paddy rice LAI.
文摘Partial least squares discriminant analysis (PLS-DA) with integrated moving-window (MW) waveband screening was applied to the discriminant analysis of liquor brands with near-infrared (NIR) spectroscopy. Luzhou Laojiao, a popular liquor with strong fragrant flavor, was used as the identified liquor brand (160 samples, negative, 52 vol alcoholicity). Liquors of 10 other brands with strong fragrant flavor were used as the interferential brands (200 samples, positive, 52 vol alcoholicity). The Kennard-Stone algorithm was used for the division of modeling samples to achieve uniformity and representativeness. Based on the MW-PLS-DA, a simplified optimal model set with 157 wavebands was further proposed. This set contained five types of wavebands corresponding to the NIR absorption bands of water, ethanol, and other micronutrients (i.e., acids, aldehydes, phenols, and aromatic compounds) in liquor for practical choice. Using five selected simple models with 4775 - 4239, 7804 - 6569, 6264 - 5844, 9435 - 7896, and 12066 - 10373 cm-1, the validation recognition rates were obtained as 99.3% or higher. Results show good prediction performance and low model complexity, and also provided a valuable reference for designing small dedicated instruments. The proposed method is a promising tool for large-scale inspection of liquor food safety.
基金This work was financially supported by the Natural Science Foundation of Hainan Province(417087)the Key Research and Development Program of Hainan Province(ZDYF2018007)Research Fund for Advanced Talents of Hainan University(No.kyqd1577).
文摘The level of chemical oxygen demand(COD)is an important index to evaluate whether sewage meets the discharge requirements,so corresponding tests should be carried out before discharge.Fourier transform infrared spectroscopy(FTIR)and attenuated total reflectance(ATR)can detect COD in sewage effectively,which has advantages over conventional chemical analysis methods.And the selection of characteristic bands was one of the key links in the application of FTIR/ATR spectroscopy.In this work,based on the moving window partial least-squares(MWPLS)regression to select a characteristic wavelength,a method of equivalent wavelength selection was proposed combining with paired t-test equivalent concept.The results showed that the prediction effect of the selected wavelength was very close to that of the MWPLS method,while the number of wavelength points was much smaller.SEPAve,RP,Ave,SEPStd,and RP,Std which characterized the modeling effect were 26.3 mg L^-1,0.969,3.49 mg L^-1,and 0.006,respectively.The validation effect V-SEP and V-RP were 28.64 mg L^-1 and 0.960,respectively.The selected waveband was between 1809 cm^-1 and 1568 cm^-1.The method was of more reference value for the design of FTIR/ATR spectral instrument for COD detection.
文摘Sensing the content of macronutrients in the agricultural soil is an essential task in precision agriculture.It helps the farmers in the optimal use of fertilizers.It reduces the cost of food production and also the negative environmentalimpacts on atmosphere and water bodies due to indiscriminate dosageof fertilizers.The traditional chemical-based laboratory soil analysis methodsdo not serve the purpose as they are hardly suitable for site specific soil management.Moreover,the spectral range used in the chemical-based laboratory soil analysismay be of 350-2500 nm,which leads to redundancy and confusion.Developing sensors based on the discovery of spectral wavebands that respondto soil macronutrient concentrations,on the other hand,is an innovative and successfultechnology since the results are dependable and timely.The goal of thisarticle is to use a supervised neuro-fuzzy based dimensionality reduction approachin the sensor development process to determine sensitive wavebands of soilmacronutrients.Accordingly,the spectral signatures of the soil are collected inan outdoor environment and mapped with its macronutrient concentrations.In thisspectral analysis,the spectral reflectance of 424 wavelengths has been obtainedand these wavelengths are evaluated through combined and individual modesas well.Appropriate wavelengths are selected in each case by minimizing the fuzzy reflectance assessment index.The effectiveness of these selected wavelengthsin each mode is validated by modeling the relation between the reduced reflectancespace and each macronutrient concentration using Partial Least Squares Multi Variable Regression(PLS-MVR)method.Set of optimal wavebands areidentified and the results are compared with the existing systems.
基金supported by the National Natural Science Foundation of China(NSFC)(Grant Nos.61635005,61905284,and 62305391)the National Postdoctoral Program for Innovative Talents(No.BX20190063).
文摘Development of a high power fiber laser at special waveband,which is difficult to achieve by conventional rare-earth-doped fibers,is a significant challenge.One of the most common methods for achieving lasing at special wavelength is Raman conversion.Phosphorus-doped fiber(PDF),due to the phosphorus-related large frequency shift Raman peak at 40 THz,is a great choice for large frequency shift Raman conversion.Here,by adopting 150 m large mode area triple-clad PDF as Raman gain medium,and a novel wavelength-selective feedback mechanism to suppress the silica-related Raman emission,we build a high power cladding-pumped Raman fiber laser at 1.2μm waveband.A Raman signal with power up to 735.8 W at 1252.7 nm is obtained.To the best of our knowledge,this is the highest output power ever reported for fiber lasers at 1.2μm waveband.Moreover,by tuning the wavelength of the pump source,a tunable Raman output of more than 450 W over a wavelength range of 1240.6–1252.7 nm is demonstrated.This work proves PDF’s advantage in high power large frequency shift Raman conversion with a cladding pump scheme,thus providing a good solution for a high power laser source at special waveband.
基金National Natural Science Foundation of China(NSFC)(61761130082,11574001,11774116,61705072)Royal Society-Newton Advanced Fellowship+4 种基金National Program for Support of Top-notch Young ProfessionalsNatural Science Foundation of Hubei Province(2018CFA048,ZRMS2017000413)Beijing University of Posts and Telecommunications(BUPT))(IPOC2018A002)Program for HUST Academic Frontier Youth Team(2016QYTD05)Fundamental Research Funds for the Central Universities(2019kfyRCPY037)
文摘Based on a silicon platform, we design and fabricate a four-mode division(de)multiplexer for chip-scale optical data transmission in the 2 μm waveband for the first time, to the best of our knowledge. The(de)multiplexer is composed of three tapered directional couplers for both mode multiplexing and demultiplexing processes. In the experiment, the average crosstalk for four channels is measured to be less than-18 dB over a wide wavelength range(70 nm) from 1950 to 2020 nm, and the insertion losses are also assessed. Moreover, we further demonstrate stable 5 Gbit/s direct modulation data transmission through the fabricated silicon photonic devices with nonreturn-to-zero on–off keying signals. The experimental results show clear eye diagrams, and the penalties at a bit error rate of 3.8 × 10-3 are all less than 2.5 dB after on-chip data transmission. The obtained results indicate that the presented silicon four-mode division multiplexer in the mid-infrared wavelength band might be a promising candidate facilitating chip-scale high-speed optical interconnects.
文摘We propose a cascade system of filters for realizing a non-uniform waveband separation for optical networks. The use of such separation is required at the DEMUX stage in a optical OXC switching wavebands. The design of the system is based on optimized balanced tree, which minimizes the overall optical loss.
文摘针对2.0~25.0μm波段传输的限制损耗问题,文章采用数值模拟方法研究影响碲基硫系光子晶体光纤(photonic crystal fiber,PCF)限制损耗的主要因素。光纤纤芯和包层材料采用Ge 20 As 20 Se 15 Te 45玻璃,通过改变纤芯直径、空气孔直径和空气孔层数等参数进行2.0~25.0μm波段限制损耗的计算,结果表明,影响限制损耗的最大因素是纤芯直径,限制损耗随着纤芯直径和空气孔直径的增大而显著降低,随着空气孔层数的增加而降低;优化设计出一种低限制损耗的PCF,结果表明,当纤芯直径和节距为8.0μm、空气孔直径为7.2μm、包层空气孔层数为4时,该PCF在2.0~25.0μm波长范围的限制损耗低于1.4×10^(-6) dB/m,满足低损耗传输要求。文章研究结果对2.0~25.0μm波段光信号的传输具有一定的意义。