Aim To study the exchange reaction characteristics of anion exchange resin for diclofenac sodium. Methods The drug-resin complexes were prepared by a batch method with diclofenac sodium as the model drug and the stron...Aim To study the exchange reaction characteristics of anion exchange resin for diclofenac sodium. Methods The drug-resin complexes were prepared by a batch method with diclofenac sodium as the model drug and the strong anion exchange resin (201 × 7) as the carrier. The effects of different forms (OH~ - and Cl~ - ) of the strong anion exchange resin, the particle size of the resin, and the reaction temperature on the exchange behavior were described. The exchange kinetic profiles were fitted. The related exc...展开更多
Ca(OH)2 nanoparticles in hydro-alcoholic dispersion (nanolime) were successfully employed in Cultural Heritage conservation, thanks to the ability to overcome the limiting aspects of traditional lime treatments. Nanol...Ca(OH)2 nanoparticles in hydro-alcoholic dispersion (nanolime) were successfully employed in Cultural Heritage conservation, thanks to the ability to overcome the limiting aspects of traditional lime treatments. Nanolime were currently produced by chemical precipitation process, at high temperature, with long times of synthesis, and after several purification steps to remove undesired secondary phases. In this paper, an innovative, simple and original method for nanolime production was described. The method was based on an ion exchange process between an anionic resin and a calcium chloride aqueous solution, operating at room temperature. A pure Ca(OH)2 nanoparticles suspension can be rapidly obtained after separating the resin from suspension, and any purification step was necessary. The exhausted resins can be regenerated and reused for a cyclic nanolime production. Structural and morphological features of the produced nanolime were preliminarily characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Moreover, XRD measurements allowed estimating nanoparticles reactivity by following their carbonatation process in air, in relation to different water/alcohol ratios and medium or high relative humidity conditions. The produced Ca(OH)2 nanoparticles appeared hexagonally plated, with dimension less than 100 nm and, compared with those obtained by typical wet precipitation method, they proved to be more reactive.展开更多
This paper presents a new method for preparing anion exchange resins based on crosslinked polystyrene which consists in the acylation of crosslinked polystyrene by FriedelCrafts reaction followed by reductive aminatio...This paper presents a new method for preparing anion exchange resins based on crosslinked polystyrene which consists in the acylation of crosslinked polystyrene by FriedelCrafts reaction followed by reductive amination. Aminated resins are quaternized to formcorresponding strong base anion exchange resins. The method avoids the use of carcinogenic chloromethyl methyl ether which is widely used in the preparation of commercial anion exchange resins.展开更多
Sulfate mass transfer coefficient(MTC) is a sensitive parameter to evaluate the kinetic leakage of anion exchange resin used in condensate polishing system of thermal and nuclear power plant.However,a sufficiently pre...Sulfate mass transfer coefficient(MTC) is a sensitive parameter to evaluate the kinetic leakage of anion exchange resin used in condensate polishing system of thermal and nuclear power plant.However,a sufficiently precise determination method has not been well established.In this paper,the final expression of sulfate MTC derived based on plug flow reactor model is the same as Harries' model,which is widely acknowledged in this field.In the determining system we constructed,in-situ calibration of the concentration of sulfate and its cation conductivity was conducted and sulfate MTCs of four typical strongly basic anion exchange resin samples were determined.The systematic error is 8.26% and the calibrated curve used for quantifying sulfate is obtained.The repeatability and reproducibility standard deviation are 0.05×10^(-4) m·s^(-1) and 0.07×10^(-4) m·s^(-1) respectively,which are lower than previous works.By controlling test condition accurately,this study has developed a more precise sulfate MTC determining method.This method provides a basis for further research.展开更多
To isolate and separate thorium from nitric acid solutions, three silica-based anion exchange resins were synthesized. Batch experiments were carried out to investigate adsorption behavior of thorium in nitric acid so...To isolate and separate thorium from nitric acid solutions, three silica-based anion exchange resins were synthesized. Batch experiments were carried out to investigate adsorption behavior of thorium in nitric acid solutions. Adsorption at different concentrations of nitric acid and thorium, influence of contact time and coexisting metal ions, and effect of NO3– were investigated in detail. It was found that at high HNO3 concentrations,the resins exhibited higher adsorption capacity and better affinity towards thorium. The adsorption kinetics could be described by the pseudo-second order model equation, while the adsorption isotherms were well correlated by the Langmuir model. The maximum capacity towards thorium species on SiPyR-N4 was evaluated at 27–28 mg/g-resin. The thermodynamic parameters indicated the adsorption was an exothermic reaction. The presence of NO3– was found to promote the retention of the thorium species.展开更多
A separation methodology to isolate natural uranium from its radioactive daughters: Th, Ra, Bi, Pb, Pa and Po, was developed using an only one anion exchange resin and varying concentrations of HC1 solutions. Three t...A separation methodology to isolate natural uranium from its radioactive daughters: Th, Ra, Bi, Pb, Pa and Po, was developed using an only one anion exchange resin and varying concentrations of HC1 solutions. Three types of anion exchange resins were tested and the separation process was followed by gamma and alpha spectrometry. Uranium can be quantitatively isolated from its descendants using Dowex IX8 (20-50 mesh) or Amerlite IRA (100 mesh) resins in three steps: using 4 and 8 mol/L-1 HCI and water to recover uranium. The method is easy, quick, and inexpensive.展开更多
Studied the effect of ionic strength on the uptake of taurine on a strong-basic anion exchange resin The batch phase equilibrium experiments of taurine on the anion exchange resin D290 were conducted at different ioni...Studied the effect of ionic strength on the uptake of taurine on a strong-basic anion exchange resin The batch phase equilibrium experiments of taurine on the anion exchange resin D290 were conducted at different ionic strength, and then the amounts of uptake of taurine on the resin at different pH were determined. The ion exchange mechanisms of taurine on the anion exchange resin at different pH were discussed. Experimental results showed that with increase of the ionic strength of solution, the adsorbed amount of taurine on the resin D290 decreased; Adding small amounts of NaOH or HCl into the system of taurine aqueous solution/D290 anion resin would nfake the amount of taurine taken up on the resin to decrease due to the competition uptakes of hydroxyl ion with taurine or the decrease in the amount of absorbable zwitterions of taurine in the solution and excluding the cations of taurine from the anion resin.展开更多
The exchange behaviors of WO_4 ̄(2-) MoO_4 ̄(2-), H_2 W_(12) O_(40) ̄(6-) and Mo8 O_(26) ̄(4-) anions within macrOPorous exchange resin (D290) phases have been studied.The values of diffusion constant (B), inner diffu...The exchange behaviors of WO_4 ̄(2-) MoO_4 ̄(2-), H_2 W_(12) O_(40) ̄(6-) and Mo8 O_(26) ̄(4-) anions within macrOPorous exchange resin (D290) phases have been studied.The values of diffusion constant (B), inner diffusion coefficient (D), retarted time (td) half - exchange-period (t1/2), and activation energy (△E) were found from the kinetic analyses. A new method to separate W(Ⅵ) and Mo (Ⅵ) from each other was also suggested.展开更多
Disinfection byproducts (DBPs) are emerging pollutants in drinking water with high health risks. Precursor reduction before disinfection is an effective strategy to control the formation of DBPs. In this study, three ...Disinfection byproducts (DBPs) are emerging pollutants in drinking water with high health risks. Precursor reduction before disinfection is an effective strategy to control the formation of DBPs. In this study, three types of anion exchange resins (AERs) and two types of nanofiltration (NF) membranes were tested for their control effects on DBP precursors, DBPs, and total organic halogen (TOX). The results showed that, for AER adsorption, the removal efficiencies of DBP precursors, DBPs, and TOX increased with the increase of resin dose, and the strong basic macroporous anion exchange resin (M500MB) had the highest removal efficiencies. For NF, the highest removal efficiencies were achieved at an operating pressure of 4 bar, and the membrane (NF90) with a smaller molecular weight cut-off, had a better control efficiency. However, AER adsorption was inefficient in removing dissolved organic carbon (DOC);NF was inefficient in removing Br− resulting in insufficient control of Br-DBPs. Accordingly, a sequential approach of AER (M500MB) adsorption followed by NF (NF90) was developed to enhance the control efficiency of DBPs. Compared with single AER adsorption and single NF, the sequential approach further increased the removal efficiencies of DOC by 19.4%–101.9%, coupled with the high Br− removal efficiency of 92%, and thus improved the reduction of cyclic DBPs and TOX by 3.5%–4.9%, and 2.4%–8.4%, respectively;the sequential approach also reduced the cytotoxicity of the water sample by 66.4%.展开更多
研究了采用ZGA351大孔强碱性阴离子交换树脂从粗钨酸铵溶液中吸附分离钼的工艺方法,考察了树脂型号、料液硫含量、料液陈化时间、料液陈化温度、料液pH值、吸附流速、吸附温度对树脂吸附分离钼效果的影响。结果表明:使用100 mL ZGA351...研究了采用ZGA351大孔强碱性阴离子交换树脂从粗钨酸铵溶液中吸附分离钼的工艺方法,考察了树脂型号、料液硫含量、料液陈化时间、料液陈化温度、料液pH值、吸附流速、吸附温度对树脂吸附分离钼效果的影响。结果表明:使用100 mL ZGA351树脂进行动态吸附试验,在料液硫含量为理论量1.1倍、料液陈化时间48 h、料液陈化温度40℃、料液pH值10.0、吸附流速15 mL/h、吸附温度40℃的最优条件下,料液钨损失率仅为0.54%,树脂钼穿透容量为107.77 g/L_(湿树脂),相比目前工业生产应用的HBDM-1树脂钼穿透容量提高了3.15倍。另外,重复试验稳定性良好,ZGA351树脂吸附后得到的纯钨酸铵溶液平均钼钨比为0.88×10^(-4),满足工业生产APT产品用纯钨酸铵溶液钼钨比小于2×10^(-4)的需求。综合而言,采用强碱性阴离子交换树脂从粗钨酸铵溶液中分离钼具有钼穿透容量高、钨损失率低、钨钼分离效率高等优势,为工业化应用提供了一种有效技术参考。展开更多
This study investigated the removal of dissolved organic matter(DOM) from real dyeing bio-treatment effluents(DBEs) with the use of a novel magnetic anion exchange resin(NDMP).DOMs in two typical DBEs were fract...This study investigated the removal of dissolved organic matter(DOM) from real dyeing bio-treatment effluents(DBEs) with the use of a novel magnetic anion exchange resin(NDMP).DOMs in two typical DBEs were fractionized using DAX-8/XAD-4 resin and ultrafiltration membranes. The hydrophilic fractions and the low molecular weight(MW)(〈3 kDa) DOM fractions constituted a major portion(〉50%) of DOMs for the two effluents. The hydrophilic and low MW fractions of both effluents were the greatest contributors of specific UV254absorbance(SUVA254),and the SUVA254 of DOM fractions decreased with hydrophobicity and MW. Two DBEs exhibited acute and chronic biotoxicities. Both acute and chronic toxicities of DOM fractions increased linearly with the increase of SUVA254 value. Kinetics of dissolved organic carbon(DOC) removal via NDMP treatment was performed by comparing it with that of particle active carbon(PAC). Results indicated that the removal of DOC from DBEs via NDMP was 60%,whereas DOC removals by PAC were lower than 15%. Acidic organics could be significantly removed with the use of NDMP. DOM with large MW in DBE could be removed significantly by using the same means. Removal efficiency of NDMP for DOM decreased with the decrease of MW. Compared with PAC,NDMP could significantly reduce the acute and chronic bio-toxicities of DBEs. NaCl/NaOH mixture regenerants,with selected concentrations of 10% NaCl(m/m)/1%NaOH(m/m),could improve desorption efficiency.展开更多
An anion exchange resin NDP-5 has been prepared successfully and applied on the selective removal of nitrate from SO_4^(2-)/ NO_3^- binary co-existence system.The composition and morphology of NDP-5 were confirmed b...An anion exchange resin NDP-5 has been prepared successfully and applied on the selective removal of nitrate from SO_4^(2-)/ NO_3^- binary co-existence system.The composition and morphology of NDP-5 were confirmed by FT-IR and SEM.The NDP-5 resin exhibits the completely different behavior on the adsorption capacity,adsorption kinetic and the effect of the completing anion in the absence or presence of sulfate,compared to D213.And,the resultants of kinetic are well fitted by the pseudo-first-order and pseudo-second-order models.These results are very important to develop novel resins with great features.展开更多
N-methylimidazolium functionalized anion exchange resin in NO3 form (RNO3) was prepared and used for adsorption of Ce(Ⅳ) in nitric acid medimn. The adsorption amount increased with shaking time increasing and the...N-methylimidazolium functionalized anion exchange resin in NO3 form (RNO3) was prepared and used for adsorption of Ce(Ⅳ) in nitric acid medimn. The adsorption amount increased with shaking time increasing and the adsorption equilibrium was obtained within 180 rain. Ce(Ⅳ) was partially reduced to Ce(Ⅲ) and the reduction percent of Ce(Ⅳ) increased with shaking time increasing. But RNO3 was more stable than other resins due to the high resistance to oxidation. A little increase of adsorption amount was found with concentration of HNO3 increasing. However, the reduction percent of Ce(Ⅳ) decreased with the increase of HNO3 concentration. The addition of NaNO3 decreased the adsorption amount of Ce(Ⅳ) on RNO3 due to the competitive anion exchange reaction. Ce(Ⅳ) was adsorbed on RNO3 in the form of Ce(Ⅳ) anion nitrato-complex. RNO3 and Ce(Ⅳ)-loaded RNO3 were characterized by fourier transform infrared (FT-IR) and thermogravimeric analysis (TGA). Ce(Ⅳ) could be easily separated from RE(Ⅲ) solution by RNO3.展开更多
The effects of dissolved organic matter (DOM) on the removal of nitrate-nitrogen from the model contaminated water have been investigated utilizing the strong base anion exchange resins. With the increase of gallic ...The effects of dissolved organic matter (DOM) on the removal of nitrate-nitrogen from the model contaminated water have been investigated utilizing the strong base anion exchange resins. With the increase of gallic acid concentration from 0 to 400 mg/L, the adsorption amount of nitrate-nitrogen on the commercial resins, including D201, Purolite A 300 (A300) and Purolite A 520E (A520E), would significantly decrease. However, the presence of tannin acid has little impact on nitrate-nitrogen adsorption on them. Compared to D201 and A300 resins, A520E resin exhibited more preferable adsorption ability toward nitrate-nitrogen in the presence of competing organic molecules, such as gallic acid and tannin acid at greater levels in aqueous solution. Attractively, the equilibrium data showed that the adsorption isotherm of nitrate-nitrogen on A520E resin was in good agreement with Langmuir and Fretmdlich equations. The rate parameters for the intra particle diffusion have been estimated for the different initial concentrations. In batch adsorption processes, nitrate-nitrogen diffuse in porous adsorbent and rate process usually depends on t1/2 rather than the contact time. The pseudo first- and the second-order kinetic models fit better for nitrate-nitrogen adsorption onto A520E resin. The observations reported herein illustrated that A520E resin will be an excellent adsorbent for enhanced removal of nitrate-nitrogen from contaminated groundwater.展开更多
文摘Aim To study the exchange reaction characteristics of anion exchange resin for diclofenac sodium. Methods The drug-resin complexes were prepared by a batch method with diclofenac sodium as the model drug and the strong anion exchange resin (201 × 7) as the carrier. The effects of different forms (OH~ - and Cl~ - ) of the strong anion exchange resin, the particle size of the resin, and the reaction temperature on the exchange behavior were described. The exchange kinetic profiles were fitted. The related exc...
文摘Ca(OH)2 nanoparticles in hydro-alcoholic dispersion (nanolime) were successfully employed in Cultural Heritage conservation, thanks to the ability to overcome the limiting aspects of traditional lime treatments. Nanolime were currently produced by chemical precipitation process, at high temperature, with long times of synthesis, and after several purification steps to remove undesired secondary phases. In this paper, an innovative, simple and original method for nanolime production was described. The method was based on an ion exchange process between an anionic resin and a calcium chloride aqueous solution, operating at room temperature. A pure Ca(OH)2 nanoparticles suspension can be rapidly obtained after separating the resin from suspension, and any purification step was necessary. The exhausted resins can be regenerated and reused for a cyclic nanolime production. Structural and morphological features of the produced nanolime were preliminarily characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Moreover, XRD measurements allowed estimating nanoparticles reactivity by following their carbonatation process in air, in relation to different water/alcohol ratios and medium or high relative humidity conditions. The produced Ca(OH)2 nanoparticles appeared hexagonally plated, with dimension less than 100 nm and, compared with those obtained by typical wet precipitation method, they proved to be more reactive.
基金Supported by High Technology Research and Development Programme of China
文摘This paper presents a new method for preparing anion exchange resins based on crosslinked polystyrene which consists in the acylation of crosslinked polystyrene by FriedelCrafts reaction followed by reductive amination. Aminated resins are quaternized to formcorresponding strong base anion exchange resins. The method avoids the use of carcinogenic chloromethyl methyl ether which is widely used in the preparation of commercial anion exchange resins.
文摘Sulfate mass transfer coefficient(MTC) is a sensitive parameter to evaluate the kinetic leakage of anion exchange resin used in condensate polishing system of thermal and nuclear power plant.However,a sufficiently precise determination method has not been well established.In this paper,the final expression of sulfate MTC derived based on plug flow reactor model is the same as Harries' model,which is widely acknowledged in this field.In the determining system we constructed,in-situ calibration of the concentration of sulfate and its cation conductivity was conducted and sulfate MTCs of four typical strongly basic anion exchange resin samples were determined.The systematic error is 8.26% and the calibrated curve used for quantifying sulfate is obtained.The repeatability and reproducibility standard deviation are 0.05×10^(-4) m·s^(-1) and 0.07×10^(-4) m·s^(-1) respectively,which are lower than previous works.By controlling test condition accurately,this study has developed a more precise sulfate MTC determining method.This method provides a basis for further research.
基金Supported by the National Natural Science Foundation of China(No.91026019)
文摘To isolate and separate thorium from nitric acid solutions, three silica-based anion exchange resins were synthesized. Batch experiments were carried out to investigate adsorption behavior of thorium in nitric acid solutions. Adsorption at different concentrations of nitric acid and thorium, influence of contact time and coexisting metal ions, and effect of NO3– were investigated in detail. It was found that at high HNO3 concentrations,the resins exhibited higher adsorption capacity and better affinity towards thorium. The adsorption kinetics could be described by the pseudo-second order model equation, while the adsorption isotherms were well correlated by the Langmuir model. The maximum capacity towards thorium species on SiPyR-N4 was evaluated at 27–28 mg/g-resin. The thermodynamic parameters indicated the adsorption was an exothermic reaction. The presence of NO3– was found to promote the retention of the thorium species.
文摘A separation methodology to isolate natural uranium from its radioactive daughters: Th, Ra, Bi, Pb, Pa and Po, was developed using an only one anion exchange resin and varying concentrations of HC1 solutions. Three types of anion exchange resins were tested and the separation process was followed by gamma and alpha spectrometry. Uranium can be quantitatively isolated from its descendants using Dowex IX8 (20-50 mesh) or Amerlite IRA (100 mesh) resins in three steps: using 4 and 8 mol/L-1 HCI and water to recover uranium. The method is easy, quick, and inexpensive.
基金Science & Technology Foundation of Guangdong Province of China (No. 2003A3050501)
文摘Studied the effect of ionic strength on the uptake of taurine on a strong-basic anion exchange resin The batch phase equilibrium experiments of taurine on the anion exchange resin D290 were conducted at different ionic strength, and then the amounts of uptake of taurine on the resin at different pH were determined. The ion exchange mechanisms of taurine on the anion exchange resin at different pH were discussed. Experimental results showed that with increase of the ionic strength of solution, the adsorbed amount of taurine on the resin D290 decreased; Adding small amounts of NaOH or HCl into the system of taurine aqueous solution/D290 anion resin would nfake the amount of taurine taken up on the resin to decrease due to the competition uptakes of hydroxyl ion with taurine or the decrease in the amount of absorbable zwitterions of taurine in the solution and excluding the cations of taurine from the anion resin.
文摘The exchange behaviors of WO_4 ̄(2-) MoO_4 ̄(2-), H_2 W_(12) O_(40) ̄(6-) and Mo8 O_(26) ̄(4-) anions within macrOPorous exchange resin (D290) phases have been studied.The values of diffusion constant (B), inner diffusion coefficient (D), retarted time (td) half - exchange-period (t1/2), and activation energy (△E) were found from the kinetic analyses. A new method to separate W(Ⅵ) and Mo (Ⅵ) from each other was also suggested.
基金supported by the National Natural Science Foundation of China(Nos.22176089 and 52270072)funding from the State Key Laboratory of Pollution Control and Resource Reuse(China)(No.PCRR-ZZ-202103).
文摘Disinfection byproducts (DBPs) are emerging pollutants in drinking water with high health risks. Precursor reduction before disinfection is an effective strategy to control the formation of DBPs. In this study, three types of anion exchange resins (AERs) and two types of nanofiltration (NF) membranes were tested for their control effects on DBP precursors, DBPs, and total organic halogen (TOX). The results showed that, for AER adsorption, the removal efficiencies of DBP precursors, DBPs, and TOX increased with the increase of resin dose, and the strong basic macroporous anion exchange resin (M500MB) had the highest removal efficiencies. For NF, the highest removal efficiencies were achieved at an operating pressure of 4 bar, and the membrane (NF90) with a smaller molecular weight cut-off, had a better control efficiency. However, AER adsorption was inefficient in removing dissolved organic carbon (DOC);NF was inefficient in removing Br− resulting in insufficient control of Br-DBPs. Accordingly, a sequential approach of AER (M500MB) adsorption followed by NF (NF90) was developed to enhance the control efficiency of DBPs. Compared with single AER adsorption and single NF, the sequential approach further increased the removal efficiencies of DOC by 19.4%–101.9%, coupled with the high Br− removal efficiency of 92%, and thus improved the reduction of cyclic DBPs and TOX by 3.5%–4.9%, and 2.4%–8.4%, respectively;the sequential approach also reduced the cytotoxicity of the water sample by 66.4%.
基金supported by the Program for Changjiang Scholars and Innovative Research Team in University (Nos.51208249,51290282)Natural Science Foundation of China (Nos.51178215,51308283)+1 种基金the Jiangsu Nature Science Fund,China (Nos.BK2010006,BK2011032)the Joint Innovation Project for Production-Study-Research in Jiangsu Province,China (No.BY2013061)
文摘This study investigated the removal of dissolved organic matter(DOM) from real dyeing bio-treatment effluents(DBEs) with the use of a novel magnetic anion exchange resin(NDMP).DOMs in two typical DBEs were fractionized using DAX-8/XAD-4 resin and ultrafiltration membranes. The hydrophilic fractions and the low molecular weight(MW)(〈3 kDa) DOM fractions constituted a major portion(〉50%) of DOMs for the two effluents. The hydrophilic and low MW fractions of both effluents were the greatest contributors of specific UV254absorbance(SUVA254),and the SUVA254 of DOM fractions decreased with hydrophobicity and MW. Two DBEs exhibited acute and chronic biotoxicities. Both acute and chronic toxicities of DOM fractions increased linearly with the increase of SUVA254 value. Kinetics of dissolved organic carbon(DOC) removal via NDMP treatment was performed by comparing it with that of particle active carbon(PAC). Results indicated that the removal of DOC from DBEs via NDMP was 60%,whereas DOC removals by PAC were lower than 15%. Acidic organics could be significantly removed with the use of NDMP. DOM with large MW in DBE could be removed significantly by using the same means. Removal efficiency of NDMP for DOM decreased with the decrease of MW. Compared with PAC,NDMP could significantly reduce the acute and chronic bio-toxicities of DBEs. NaCl/NaOH mixture regenerants,with selected concentrations of 10% NaCl(m/m)/1%NaOH(m/m),could improve desorption efficiency.
基金acknowledge generous suppoa provided by Program for Changjiang Scholars Innovative Research Team in UniversityNSFC(Nos50938004,50825802 and 51178215)+1 种基金Jiangsu Natural Science Fund(Nos BK2010006 and BK201 1032)P.R. Chinathe Scientific Research Starting Fund for Postdoctors,Nanjing University(No0211003046)
文摘An anion exchange resin NDP-5 has been prepared successfully and applied on the selective removal of nitrate from SO_4^(2-)/ NO_3^- binary co-existence system.The composition and morphology of NDP-5 were confirmed by FT-IR and SEM.The NDP-5 resin exhibits the completely different behavior on the adsorption capacity,adsorption kinetic and the effect of the completing anion in the absence or presence of sulfate,compared to D213.And,the resultants of kinetic are well fitted by the pseudo-first-order and pseudo-second-order models.These results are very important to develop novel resins with great features.
基金supported by the National Natural Science Foundation of China(51174184)National High-Tech R&D Program(2007AA06Z202)+1 种基金Scientific Research Foundation for the Returned Overseas Chinese ScholarsMinistry of Education of China
文摘N-methylimidazolium functionalized anion exchange resin in NO3 form (RNO3) was prepared and used for adsorption of Ce(Ⅳ) in nitric acid medimn. The adsorption amount increased with shaking time increasing and the adsorption equilibrium was obtained within 180 rain. Ce(Ⅳ) was partially reduced to Ce(Ⅲ) and the reduction percent of Ce(Ⅳ) increased with shaking time increasing. But RNO3 was more stable than other resins due to the high resistance to oxidation. A little increase of adsorption amount was found with concentration of HNO3 increasing. However, the reduction percent of Ce(Ⅳ) decreased with the increase of HNO3 concentration. The addition of NaNO3 decreased the adsorption amount of Ce(Ⅳ) on RNO3 due to the competitive anion exchange reaction. Ce(Ⅳ) was adsorbed on RNO3 in the form of Ce(Ⅳ) anion nitrato-complex. RNO3 and Ce(Ⅳ)-loaded RNO3 were characterized by fourier transform infrared (FT-IR) and thermogravimeric analysis (TGA). Ce(Ⅳ) could be easily separated from RE(Ⅲ) solution by RNO3.
基金supported by the Program for Changjiang Scholars Innovative Research Team in University and NS-FC (No.50938004,51178215,51008152)the Jiangsu Nature Science Foundation for Distinguished Scientists(No.BK2010006, BK2011032)the Scientific Research Starting Found for Postdoctors,Nanjing University(No.0211003046, 021114340069)
文摘The effects of dissolved organic matter (DOM) on the removal of nitrate-nitrogen from the model contaminated water have been investigated utilizing the strong base anion exchange resins. With the increase of gallic acid concentration from 0 to 400 mg/L, the adsorption amount of nitrate-nitrogen on the commercial resins, including D201, Purolite A 300 (A300) and Purolite A 520E (A520E), would significantly decrease. However, the presence of tannin acid has little impact on nitrate-nitrogen adsorption on them. Compared to D201 and A300 resins, A520E resin exhibited more preferable adsorption ability toward nitrate-nitrogen in the presence of competing organic molecules, such as gallic acid and tannin acid at greater levels in aqueous solution. Attractively, the equilibrium data showed that the adsorption isotherm of nitrate-nitrogen on A520E resin was in good agreement with Langmuir and Fretmdlich equations. The rate parameters for the intra particle diffusion have been estimated for the different initial concentrations. In batch adsorption processes, nitrate-nitrogen diffuse in porous adsorbent and rate process usually depends on t1/2 rather than the contact time. The pseudo first- and the second-order kinetic models fit better for nitrate-nitrogen adsorption onto A520E resin. The observations reported herein illustrated that A520E resin will be an excellent adsorbent for enhanced removal of nitrate-nitrogen from contaminated groundwater.