With the rapid increase of water contamination,membrane separation technology and their corresponding molecular weight cut-off(MWCO) evaluation method become more necessary.In this study,Panax notoginseng saponins was...With the rapid increase of water contamination,membrane separation technology and their corresponding molecular weight cut-off(MWCO) evaluation method become more necessary.In this study,Panax notoginseng saponins was used as a new standard marker to determinate ultrafiltration(UF) membrane MWCOs,series of Millipore membranes were selected as control group to analyze and calculate the relationship between retention rate and MWCOs with exponential or logarithmic equation.A new and convenient method was provided for determining the membrane MWCO by modeling analysis retention rate with MWCOs,and the regression coefficients >0.990.The feasibility and practicability of established method was verified by different manufactures' membrane and dextrans.In the detection progress,as the main ingredient of Panax notoginseng saponins,Notoginsenoside R_1,Ginsenoside Rg_1,Ginsenoside Rb_1 and Ginsenoside Rd with different surface activity,the MWCO range of UF membranes can be divided into two zones mainly due to the retention rate difference among Notoginsenoside R_1,Ginsenoside Rg_1,Ginsenoside Rb_1 and Ginsenoside Rd.Zone 1,1000-10000;and Zone II,10000-100000.Thus,the new method would be helpful to improve the applicability of UF membrane in separation technology.展开更多
泥水平衡盾构机气垫仓内岩屑的快速排出对于保证施工安全和提高掘进效率至关重要,已有研究主要集中在岩屑在排浆管中运输的运动特性,而从气垫仓进入排浆管直至排出的完整过程却往往被忽略,因此现有研究对于指导实际工程还存在局限性。基...泥水平衡盾构机气垫仓内岩屑的快速排出对于保证施工安全和提高掘进效率至关重要,已有研究主要集中在岩屑在排浆管中运输的运动特性,而从气垫仓进入排浆管直至排出的完整过程却往往被忽略,因此现有研究对于指导实际工程还存在局限性。基于CFD-DEM(computational fluid dynamics-discrete element method)计算流体力学-离散单元耦合计算方法并结合实际工程建立了可以完整反映气垫仓内岩屑排出的数值计算模型,对比了不同冲刷管布设情况下(垂直距离h1、水平距离h_(2)和转角β)岩屑的排出情况,总结了不同因素对岩屑排出率的敏感度。研究结果表明排出率随着h1的增加而减小,随着h_(2)和β的增加而增加,三个因素的平均敏感度排序从大到小依次为h1(1.6)>h_(2)(0.79)>β(0.61),因此在实际工程中降低冲刷管高度是提高岩屑率最有效的措施。研究结果可为优化冲刷管的布设和制定相关施工措施提供实用参考。展开更多
基金Supported by the National Natural Science Foundation of China(No.81503258,No.81373980)Youth Natural Science Foundation of Jiangsu Province(No.BK20151005)Science and Technology Project of Jiangsu Traditional Chinese Medicine Administration(No.YB2015009)
文摘With the rapid increase of water contamination,membrane separation technology and their corresponding molecular weight cut-off(MWCO) evaluation method become more necessary.In this study,Panax notoginseng saponins was used as a new standard marker to determinate ultrafiltration(UF) membrane MWCOs,series of Millipore membranes were selected as control group to analyze and calculate the relationship between retention rate and MWCOs with exponential or logarithmic equation.A new and convenient method was provided for determining the membrane MWCO by modeling analysis retention rate with MWCOs,and the regression coefficients >0.990.The feasibility and practicability of established method was verified by different manufactures' membrane and dextrans.In the detection progress,as the main ingredient of Panax notoginseng saponins,Notoginsenoside R_1,Ginsenoside Rg_1,Ginsenoside Rb_1 and Ginsenoside Rd with different surface activity,the MWCO range of UF membranes can be divided into two zones mainly due to the retention rate difference among Notoginsenoside R_1,Ginsenoside Rg_1,Ginsenoside Rb_1 and Ginsenoside Rd.Zone 1,1000-10000;and Zone II,10000-100000.Thus,the new method would be helpful to improve the applicability of UF membrane in separation technology.
文摘泥水平衡盾构机气垫仓内岩屑的快速排出对于保证施工安全和提高掘进效率至关重要,已有研究主要集中在岩屑在排浆管中运输的运动特性,而从气垫仓进入排浆管直至排出的完整过程却往往被忽略,因此现有研究对于指导实际工程还存在局限性。基于CFD-DEM(computational fluid dynamics-discrete element method)计算流体力学-离散单元耦合计算方法并结合实际工程建立了可以完整反映气垫仓内岩屑排出的数值计算模型,对比了不同冲刷管布设情况下(垂直距离h1、水平距离h_(2)和转角β)岩屑的排出情况,总结了不同因素对岩屑排出率的敏感度。研究结果表明排出率随着h1的增加而减小,随着h_(2)和β的增加而增加,三个因素的平均敏感度排序从大到小依次为h1(1.6)>h_(2)(0.79)>β(0.61),因此在实际工程中降低冲刷管高度是提高岩屑率最有效的措施。研究结果可为优化冲刷管的布设和制定相关施工措施提供实用参考。
