Redox evolution of western Tianshan subduction zone and its effect on deep carbon cycle

Knowing the phase relations of carbon-bearing phases at high-pressure(HP) and high-temperature(HT) condition is essential for understanding the deep carbon cycle in the subduction zones.In particular,the phase relation of carbon-bearing phases is also strongly influenced by redox condition of subduction zones,which is poorly explored.Here we summarized the phase relations of carbon-bearing phases(calcite,aragonite,dolomite,magnesite,graphite,hydrocarbon) in HP metamorphic rocks(marble,metapelite,eclogite) from the Western Tianshan subduction zone and high-pressure experiments.During prograde progress of subduction,carbonates in altered oceanic crust change from Ca-carbonate(calcite) to Ca,Mg-carbonate(dolomite),then finally to Mgcarbonate(magnesite) via Mg-Ca cation exchange reaction between silicate and carbonate,while calcite in sedimentary calcareous ooze on oceanic crust directly transfers to high-pressure aragonite in marble or amorphous CaCO3 in subduction zones.Redox evolution also plays a significant effect on the carbon speciation in the Western Tianshan subduction zone.The prograde oxygen fugacity of the Western Tianshan subduction zone was constrained by mineral assemblage of garnet-omphacite from FMQ-1.9 to FMQ-2.5 at its metamorphic peak(maximum P-T) conditions.In comparison with redox conditions of other subduction zones,Western Tianshan has the lowest oxygen fugacity.Graphite and light hydrocarbon inclusions were ubiqutously identified in Western Tianshan HP metamorphic rocks and speculated to be formed from reduction of Fe-carbonate at low redox condition,which is also confirmed by high-pressure experimental simulation.Based on petrological observation and high-pressure simulation,a polarized redox model of reducing slab but oxidizing mantle wedge in subduction zone is proposed,and its effect on deep carbon cycle in subduction zones is further discussed.

Zircon Dating and Geological Implications of Granitic Gneiss in the Metamorphic Zone of Gaoligong Mountains in Western Yunnan, China

The general classification of intermediate-acid intrusive rocks in the metamorphic zone of Gaoligong Mountains as one of the metamorphic terranes of Proterozoic Gaoligong Mountains is problematic regarding the intrusion stage and age, as well as the subsequent metamorphism and deformation. In this study, we investigated granitic gneiss in the metamorphic zone of Gaoligong Mountains based on the 1：50,000 regional geological survey of Qushi Street （2011-2013） and SHRIMP U-Pb zircon geochronology. Results showed that the SHRIMP U-Pb zircon dating of granitic gneiss ranged from 163.5±5.7 Ma to 74.0±2.0 Ma. Thus, the granitic gneiss was grouped into orthometamorphic rocks （metamorphic intrusions）. The dating data of granite rocks associated with intense metamorphism and deformation were divided into three groups, 163.5±5.7 to 162.3±3.1 Ma, 132.2-101.0 Ma and 99.4±3.5-74.0±2.0 Ma, which respectively represented three independent geologic events including an important magma intrusion with superimposed metamorphic effects in the late Middle Jurassic, regional dynamic metamorphism and superimposed reformation of fluid action in the early Cretaceous, and dynamic metamorphism dominated by ductile shear and metamorphism starting from the late Cretaceous.

Discovery of the Dagele Eclogite in East Kunlun,Western China and Its Zircon SHRIMP U-Pb Ages:New Constrains on the Central Kunlun Suture Zone

Objective Eclogites are important indicators of ancient plate boundaries or paleosuture zones. Despite their great geological significance, very few investigations have been carried out in the Kunlun region. The Central East Kunlun fault zone was believed to be an Early Paleozoic suture zone, but there has been no reliable evidence for this, though studies on ophiolite, granite, and basic granulite indicate that the Early Paleozoic orogeny occurred in the East Kunlun. This work focused on the Dagele eclogites in Central East Kunlun to provide new constraints for the Central East Kunlun suture zone.

Western fault zone of South China Sea and its physical simulation evidences

The western fault zone of the South China Sea is a strike-slip fault system and consists of four typical strike-slip faults. It is the western border of the South China Sea. The formation of the system is due to the extrusion of Indo - China Peninsula caused by the collision of India with Tibet and the spreading of the South China Sea in Cenozoic. There are five episodes of tectonic movement along this fault zone, which plays an important role in the Cenozoic evolution of the South China Sea. By the physical modeling experiments, it can be seen the strike-slip fault undergoes the sinistral and dextral movement due to the relative movement velocity change between the South China Sea block and the Indo - China block. The fault zone controls the evolution of the pull basins locating in the west of the South China Sea.

Spatial variations of the 660-km discontinuity in the western Pacific subduction zones observed from CEArray triplication data

We examined the spatial variation of velocity structures around the 660-kin discontinuity at the western Pacific subduction zones by waveform modeling of triplication data. Data from two deep earthquakes beneath Izu-Bonin and Northeast China are used. Both events were well recorded by a dense broadband seismic network in China （CEArray）. The two events are located at approximately the same distance to the CEArray, yet significant differences are observed in their records： （1） the direct arrivals traveling above the 660-km discontinuity （AB branch） are seen in a different distance extent： -29° for the NE China event, -23° for Izu-Bonin event; （2） the direct （AB） and the refracted waves at the 660-km （CD branch） cross over at 19.5° and 17° for the NE China and the Izu-Bonin event, respectively. The best fitting model for the NE China event has a broad 660-km discontinuity and a constant high velocity layer upon it; while the Izu-Bonin model differs from the standard IASP91 model only with a high velocity layer above the 660-km discontinuity. Variations in velocity models can be roughly explained by subduction geometry.

Characteristics and biogeochemical effects of oxygen minimum zones in typical seamount areas,Tropical Western Pacific

As a serious consequence of ocean warming and increased stratification,a rapid decrease in dissolved oxygen(DO)content of the world’s oceans has attracted more and more attention recently.In open oceans,the decline of DO is characterized by the expansion of oxygen minimum zones(OMZs)in the ocean interior.Vast OMZs exist within the mesopelagic zones of the Tropical Western Pacific(TWP),but have gained very little attention.In this study,we focus on characteristics of OMZs in three typical seamounts areas(named Y3,M2,and Kocebu,respectively)of the TWP.Based on distributions of DO,the OMZs of the three seamounts areas are very different in scope,thickness,and the minimum oxygen content.The significantly different characteristics of OMZs at the seamounts are mainly because they are located in regions affected by different ventilation and consumption characteristic.To quantitatively describe the intensity of OMZs,a parameter,IOMZ,is firstly proposed.According to this quantitative parameter,the intensity order of OMZs for the three seamounts areas is Kocebu>M2>Y3.Potential biogeochemical effects of OMZs in the three seamounts areas are discussed using IOMZ.With higher IOMZ,the degradation of particulate organic carbon(POC)tends to be lower.Yet because of the limited data,their relationship still need more research to prove.However,if this relationship holds in global oceans,the presence of seamounts would—under climate warming with expanding OMZs—promote vertical transport of POC resulting in an enhanced biological pump.Our study provides a new way to quantitatively study the impact of OMZs on the efficiency of biological pump.

The bacterial diversity and community composition altered in the oxygen minimum zone of the Tropical Western Pacific Ocean

The oxygen minimum zones(OMZs)are globally expanding,yet the variation pattern of microbial communities related to dissolved oxygen levels remain unclear.Spatial variability of bacterial diversity and community composition(repre sented by 16 S rRNA)of six stations was investigated within the water column in the seamount area of Tropical Western Pacific Ocean(TWPO)in May 2019.The seawater has dissolved oxygen(DO)concentration of 3.01-6.68 mg/L and the core of the oxygen minimum zones was located between the depths of 650 m and 1750 m.The bacterial alpha-diversity showed unimodal pattern with the decreasing DO with depths and peaked in the upper oxycline(UO)of OMZs.The bacterial community structure of the mixed layer(ML)and the bottom layer clustered and separated from each other,while those of UO and the OMZ core(OM)clustered and overlapped.Overall,bacterial community composition transitioned from being Alphaproteobacteria and Gammaproteobacteria-dominant in ML to being Gammaproteobacteria and Nitrososphaeria/Deltaproteobacteria-dominant in UO and OM,and then changed to being Clostridia and unidentified Actinobacteria-dominant in the bottom layer.Moreover,both bacterial alpha-diversity and the abundant classes fitted varying sectioned functions with DO.The DO solely explained 40.37%of the variation of bacterial community composition among layers(P<0.001).The predicted function profiling showed that the water column was predominant by chemoheterotrophy,cyanobacteria,and photoautotrophy in ML,by chemoheterotrophy and nitrate/sulfide cycling in UO and OM,and by chemoheterotrophy and ferme ntation in the bottom layer.Our findings revealed the DO-associated variation in bacterial diversity and community composition,and help to clarify the potential responses of microbes and their involved biogeochemical processes to the expansion and intensification of OMZs.

Constraints of REE and trace elements of high-pressure-veins and host rocks in western Tianshan on origin of deep fluids in paleosubduction zones

The western Tianshan high-pressure(HP) metamorphic belt represents the paleosubduction mélange of paleozoic south Tianshan ocean between the Yili-central Tianshan and Tarim plates. High-pressure veins are extensively developed in this HP belt. Compared with normal mid-ocean ridge basalt(N-MORB), the high-pressure veins and host rocks are enriched in light rare earth elements(LREE) and incompatible elements. But high-pressure veins show a larger variation than host rocks in total REE abundance. On the trace element spidergram, all the samples are enriched in incompatible elements and show strong positive Pb anomaly relative to N-MORB. The array tendency lines of plots of the HP rocks have apparent slopes on diagram of m(Sr) vs m(Sr)/m(Zr), m(Li) vs m(Li)/m(Y) and (m(Ce)) vs m(Ce)/m(Pb), which indicates that the enrichment in LREE and incompatible elements relative to N-MORB of the HP-metamorphic rocks from western Tianshan is not attributed to magma evolution process of the protolith. High field strength elements, such as Nb, Ta, Ti, Zr and Hf, do not show negative anomaly relative to N-MORB, which is dissimilar to that of island arc basalts. Therefore, the enrichment in LREE and incompatible elements of the HP rocks is not attributed to the enrichment of the source of the protolith. The mass ratios of Rb to Ba, Ce to Pb, Nb to U and Ta to U of high-pressure veins and host rocks are intermediate of mid-ocean ridge basalt or oceanic island basalt and continental crust. The fluids in western Tianshan paleosubduction zones are mixtures of two sources, dehydration or devolatilization of host rocks and of subducted sediments.

ECOLOGICAL LANDSCAPE EFFECTS OF WINDBREAK SYSTEMS IN DESERT ZONE OF WESTERN CHINA

This paper, by applying the theories of landscape ecology, illustrates the role and mechanism of windbreak system in the establishment and maintenance of oasis ecosystem on the basis of systematic analysis of characteristics and ecological crises of China's desert, and especially of desert zone in western China. Furthermore, direct economic benefits are summarized.

The Forest Pattern and Its Variation Characteristics in Economic Zone on the Western Coast of the Taiwan Straits

Taking Economic Zone on the Western Coast of the Taiwan Straits as the study area,we use GIS,remote sensing,mathematical statistics and other methods,to analyze the forest pattern and its variation characteristics in Economic Zone on the Western Coast of the Taiwan Straits during the period 1992-2008;use canonical correspondence analysis(CCA)to examine the effects of environmental factors on changes in forest pattern.The results show that the forest resources are rich in Economic Zone on the Western Coast of the Taiwan Straits,accounting for 61.40% of the total area,but the geographical distribution is very uneven,with obvious regional and elevation gradient difference;since1992,the forest has been dwindling in Economic Zone on the Western Coast of the Taiwan Straits,from 89 300 km2 in 1992 to 88 300 km2 in 2008;in terms of changes in region and elevation gradient,there is obvious difference in the forest,and the central and western forest of Wuyi Mountain tends to decline obviously;the main environmental factors influencing changes in forest pattern in Economic Zone on the Western Coast of the Taiwan Straits include temperature,sunshine hours,GDP per capita and precipitation;evaporation,evaporation and population density have weak effects on changes in forest pattern.

Study on the characteristics of crust－mantle transition zone in Western Yunnan Province

In this paper the fine structure of crust mantle transition zone in Western Yunnan Province is analysed and discussed based on the reflection phases from Moho discontinuity in Project Western Yunnan 86～87. It shows that in two points: in the north 27.64 km from shot point Jinggu and south 58.74 km from shot point Zhiti, there are transition zones of group of thin layers with inverse velocity.These two reflection points are both situated in the lower velocity anomaly zone in the top of upper mantle. The crust of this region is more seismicity. Maybe the unusual structure of this transition zone is related with the characteristics of this region. This paper discusses the possible geological interpretation model for this transition zone, and also makes suggestion about its application in earthquake prediction.

Multistage tectono-stratigraphic evolution of the Canavese Intracontinental Suture Zone:New constraints on the tectonics of the Inner Western Alps

The Canavese Intracontinental Suture Zone(CISZ) within the Inner Western Alps represents the remnant of a long-lived minor subduction zone involving a narrow, thinned continental crust/oceanic lithosphere seaway between two continental domains of the Adria microplate(i.e., the Sesia Zone and the IvreaVerbano Zone). As opposed to many suture zones, the CISZ mostly escaped pervasive tectonic deformation and metamorphism, thus preserving the original stratigraphy and allowing the relationships between tectonics and sedimentation to be defined. Through detailed geological mapping(1:5000 scale),structural analysis, stratigraphic and petrographic observations, we document evidences for the late Paleozoic to late Cenozoic tectonic evolution of the CISZ, showing that it played a significant role in the context of the tectonic evolution of the Inner Western Alps region from the early to late Permian Pangea segmentation, to the Jurassic Tethyan rifting, and up to the subduction and collisional stages,forming the Western Alps. The site of localization/formation of the CISZ was not accidental but associated with the re-use of structures inherited from regional-scale wrench tectonics related to the segmentation of Pangea, and from the subsequent extensional tectonics related to the Mesozoic rifting, as documented by crosscutting relationships between stratigraphic unconformities and tectonic features. Our findings document that evidences derived from stratigraphy, facies indicators, and relationships between tectonics and sedimentation in the shallow crustal portions of suture zones, such in the CISZ, are important to better constrain the tectonic history of those metamorphic orogenic belts around the world in which evolutionary details are commonly complicated by high-strain deformation and metamorphic transformations.

Fluid flow on centimeter-scale in deep paleosubduction zones in western Tianshan,China:Evidence from high-pressure veins

High-pressure(HP)veins were extensively developed in western Tianshan high-pressure(HP)metamorphic belt.The HP vein and host-rocks were analyzed by electronic microprobe to trace the origin of vein-forming fluids.Analytical data show that the immediately adjacent host-rocks of the studied HP vein are eclogites and gradually turned into blueschist as the distance from the veins increases,which indicates that the vein-forming fluid was derived from adjacent host-rocks;the boundaries between the vein and the host-rocks are sharp,which indicates that the fracture of the host-rocks is brittle during the vein-forming process.It is suggested that this type of HP veins is precipitated from the liquid formed by the dehydration of the host-rocks during the prograde metamorphism from blueschist to eclogite facies,which results in hydrofracturing of the rocks and provides the space for the vein to precipitate.The width of the eclogite-facies host-rocks is usually 1-2 cm,which provides the direct evidence that the fluid flow is on centimeter-scale.

Tectonic Evolution of the Dongbo Ophiolite in Western Yarlung Zangbo Suture Zone, Xizang(Tibet)

The Dongbo ophiolite in the western part of the Yarlung-Zangbo suture zone in southern Tibet rests tectonically on the middle-late Triassic and Cretaceous flysch units,and consist mainly of peridotites,mafic dikes,

Ocean-continent Transition to Suprasubduction Zone Origin of the Western Yarlung Zangbo Ophiolites in SW Tibet, China: Multi-stage, Transient Evolution of the Neotethyan Oceanic Lithosphere

The ophiolites that crop out discontinuously along the;000 km Yarlung Zangbo Suture zone（YZSZ）between the Nanga Parbat and Namche Barwa syntaxes in southern Tibet represent the remnants of Neotethyan oceanic lithosphere（Fig.1a）.We have investigated the internal structure and the geochemical makeup of mafic-ultramafic rock assemblages that are exposed in the westernmost segment of the YZSZ where the suture zone architecture displays two distinct sub-belts of ophiolitic and mélange units separated by a continental Zhongba terrane（Fig.1b）.These two sub-belts include the Daba–Xiugugabu in the south（Southern sub-belt,SSB）and the Dajiweng–Saga in the north（Northern sub-belt,NSB）.We present new structural,geochemical,geochronological data from upper mantle peridotites and mafic dike intrusions occurring in these two sub-belts and discuss their tectonomagmatic origin.In-situ analysis of zircon grains obtained from mafic dikes within the Baer,Cuobuzha and Jianabeng massifs in the NSB,and within the Dongbo,Purang,Xiugugabu,Zhaga and Zhongba in the SSB have yielded crystallization ages ranging between130 and 122 Ma.Dike rocks in both sub-belts show N-MORB REE patterns and negative Nb,Ta and Ti anomalies,reminiscent of those documented from SSZ ophiolites.*Harzburgitic host rocks of the mafic dike intrusionsmainly display geochemical compositions of abyssal peridotites（Fig.2）,with the exception of the Dajiweng harzburgites,which show the geochemical signatures of forearc peridotites（Lian et al.,2016）.Extrusive rocks that are spatially associated with these peridotite massifs in both sub-belts also have varying compositional and geochemical features.Tithonian to Valanginian（150–135 Ma）basaltic rocks in the Dongbo massif have OIB-like geochemistry and 138 Ma basaltic lavas in the Purang massif have EMORB-like geochemistry（Liu et al.,2015）.Tuffaceous rocks in the Dajiweng massif are140 Ma in age and show OIB-like geochemistry.We interpret these age and geochemical data to reflect a rifted continental margin origin of the extrusive rock units in both sub-belts.These data and structural observations show that the western Yarluang Zangbo ophiolites represent fragments of an Ocean-Continent Transition（OCT）peridotites altered by fluids in an initial supersubduction setting.We infer that mafic-ultramafic rock assemblages exposed in the SSB and NSB initially formed in an ocean–continent transition zone（OCTZ）during the late Jurassic,and that they were subsequently emplaced in the forearc setting of an intraoceanic subduction zone within a Neotethyan seaway during 130 to 122 Ma.The NSB and SSB are hence part of a single,S-directed nappe sheet derived from a Neotethyan seaway located north of the Zhongba terrane.

Petrological Study on the Ductile Shear Zones in the Core of the Eastern Qinling Orogenic Belt in Western Henan

A series of ductile shear zones of the overthrust and strike-slip-types and related ductile shear metamorphicrocks, including tectonic melange and mylonites. were formed in the core of the Qinling orogenic belt in thecourse of the Caledonian-Indosinian ductilc and brittle-ductile reworking. The study on their petrography. va-riations in composition and conditions of formation is conducive to revealing the metamorphism-deformationhistory of the core of the Qinling orogenic belt and further to understanding the dynamic mechanism of its evo-lution.

Integrated ecosystem assessment for western development of China

The objectives of Integrated Ecosystem Assessment for Western Development of China includes: (1) providing scientific basis for ecosystem protection, ecosystem management and ecological construction in the western development; (2) developing complete database and analytical tools and strengthening decision-making support capacity; and (3) improving ecosystem management in China, spreading ecological knowledge to the public, serving decision-making of local and central governments, and promoting socio-economic sustainable development. The design and implementation of the project are of significance under the macro background of western development of China. By the integrated assessment of western China, we can get the first-hand data covering all the environmental factors as well as disclose the situations and their changing trends of ecosystem in the western part of China, which will benefit the decision-making for the central and local governments in the implementation of the western development strategy. In other words, the implementation of the project, to a certain extent, can guarantee the regional sustainable development of western China.

A review on investigation of water-preserved coal mining in western China

Yushenfu mining area is located in an ecological fragile area in western China, the coal seam of which is the Jurassic Ysn'an Foirnalion. The Jurassic Yan'an Formation con tains five minable coal seams, the top layer of which is thick, covered by shallow overburden and located under aquifers. Therefore, the mining induced water flowing fractured zone can easily extend to the aquifers of both the Quaternary Sarahu and Jurassic Zhiluo Formation. This would result in a series of negative hydrological and ecological effects, including groundwater leakage, groundwater lowering, furtherly causing surface vegetation withering and dying, surface water body reduction, spring drying out, and water flow of river being decreased substantially. To solve these environmental problems, several technologies have been carried out by Chinese scientists, one of which is water-preserved coal mining. This paper presents a review of the origin, definition and development of water-preserved coal mining, and its applications in Yushenfu mining area. The applicable conditions, research contents, research methodology, and technical foundation of water-preserved coal mining are addressed in this paper. The future research focuses regarding water-preserved coal mining in China are also discussed in this paper. Its results serve as a guide for selecting the methods to be preferred for mining in case the geological conditions, roof overburden structure and coal mining process are similar to Yushenfu mining area.

Natural Gas Types,Distribution Controlling Factors,and Future Exploration in the Western Qaidam Basin

The Paleogene and Neogene oil and gas in the western Qaidam basin have a regular distribution in three concentric zones from the edge to the center of the basin. Natural gas mainly occurs in the inner zone, and the gas-oil ratio of the northern area of the basin is significantly higher than that of the southern area. Large amounts of carbon isotope data of natural gas, plotted in X- shaped and comprehensive identification diagrams for the southern area and northern area, respectively, were used to identify the types of natural gas. The large-scale distribution of natural gas is highly consistent with the Ro values of major source rocks, but is poorly correlated with the type of organic matter. This indicates that the main controlling factor of natural gas distribution is organic matter maturity, and the kerogen types act as the basis for the formation of different types of natural gas. Paleouplifts and squeezed anticlines near hydrocarbon generation depression centers, which are major natural gas-rich regions, control the migration directions of natural gas, while hydrocarbon migration pathways and fault systems connecting gas sources are the most important factors for natural gas reservoir formation in the inner basin. Therefore, favorable zones for natural gas distribution can be predicted on the basis of the distribution of thermal evolution and the gas generation intensity of major source rocks as well as the structural map. The Shizigou-Youshashan- Yingdong-Dawusi, Youquanzi -Kaitemilike - Youdunzi, and Xiaoliangshan - Nanyishan - Dafengshan structural belts are favorable zones for natural gas accumulation. This study has important theoretical and practical significance for future natural gas exploration.

Soil Fertility Survey in Western Usambara Mountains, Northern Tanzania

Soil samples from thirty sites representing four agro-ecological zones in the Western Usambara Mountains (WUM) of the Lushoto District in northern Tanzania were collected and analyzed for different nutrients. The results suggested that the major soil fertility constraint was P deficiency. On the basis of critical levels established in other areas, 90% of the soils were ranked as P deficient. This was followed by N, which was ranked as inadequate in 73% of the sites. Magnesium, K, and Ca also appeared limiting with 67%, 53% and 50% of the soils falling below the established critical values, respectively. A few soils (10%) were also found to contain exchangeable Al. The metallic micronutrients (Cu, Fe, and Zn) were adequate in all soils. Two sites had excessive Mn that could lead to toxicity in crops, and one was Mn deficient.