Different surface modification methods and coating materials of zinc metal anode

Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Nevertheless,zinc metal anodes suffer from severe dendrite growth and side reactions,resulting in the inferior electrochemical performance of AZIBs.To address these problems,surface modification of zinc metal anodes is a facile and effective method to regulate the interaction between the zinc anode and an electrolyte.In this review,the current challenges and strategies for zinc metal anodes are presented.Furthermore,recent advances in surface modification strategies to improve their electrochemical performance are concluded and discussed.Finally,challenges and prospects for future development of zinc metal anodes are proposed.We hope this review will be useful for designing and fabricating highperformance AZIBs and boosting their practical applications.

Study on Industrial Application of Hydrogen Sulfide Removal by Wet Oxidation Method with High Gravity Technology

The removal of hydrogen sulfide from gas plays an important role in rational utilization of resources and environ- mental protection. In this paper, the process of hydrogen sulfide removal by wet oxidation method in a rotating packed bed was investigated in a scale for treating 10 000 Nm3/h of gas. On the basis of studying the influence of the species and con- centration of alkali source, the liquid/gas volume ratio, the high gravity factor, and the hydrogen sulfide content in feed gas on the desulfurization effect, the suitable technological conditions were obtained. The hydrogen sulfide removal efficiency could reach 98.0% under these conditions. The results of continuous operation of process facilities showed that the high gravity method has many merits including higher desulfurization rate, good stability in operation, lower liquid/gas volume ratio, greater operation elasticity, and apparent energy saving effects.

Effects of Ga,Al,Ag,and Ce multi-additions on the wetting characteristics of Sn-9Zn lead-free solder

An orthogonal method was used to evaluate the effects of Ga, Al, Ag, and Ce multi-additions on the wetting characteristics of Sn-9Zn lead-free solders by wetting balance method. The results show that the optimal loading of Ga, Al, Ag, and Ce was 0.2 wt.%, 0.002 wt.%, 0.25 wt.%, and 0.15 wt.%, respectively. Intermetallic compounds （IMCs） formed at the interface between Sn-9Zn-0.2Ga-0.002Al-0.25Ag- 0.15Ce solder and Cu substrate were investigated by scanning electron microscope （SEM） and energy dispersive spectroscopy （EDS） analysis. The SEM images illustrate that the IMCs can be divided into two portions from the substrate side to the solder side： a planar CusZns layer and an additional continuous scallop-like AgZn3 layer. The EDS analysis also shows that Ga segregates in the solder abutting upon the interface. X-ray photoelectron spectroscopy （XPS） and Auger electron spectroscopy （AES） of the surface components of Sn-9Zn-0.2Ga-0.002Al- 0.25Ag-0.15Ce solder indicate that Al aggregates at the surface in the form of Al203 protective fdm, which prevents the further oxidation of the solder surface. On the other hand, Ce aggregates at the subsurface, which may reduce the surface tension of the solder and improve the wettability in consequence.

A general multi-objective programming model for minimum ecological flow or water level of inland water bodies

Assessment of ecological flow or water level for water bodies is important for the protection of de- graded or degrading ecosystems caused by water shortage in arid regions, and it has become a key issue in water resources planning. In the past several decades, many methods have been proposed to assess ecological flow for rivers and ecological water level for lakes or wetlands. To balance water uses by human and ecosystems, we proposed a general multi-objective programming model to determine minimum ecological flow or water level for inland water bodies, where two objectives are water index for human and habitat index for ecosystems, respectively Using the weighted sum method for multi-objective optimization, minimum ecological flow or water level can be determined from the breakpoint in the water index-habitat index curve, which is similar to the slope method to de- termine minimum ecological flow from wetted perimeter-discharge curve. However, the general multi-objective programming model is superior to the slope method in its physical meaning and calculation method. This model provides a general analysis method for ecological water uses of different inland water bodies, and can be used to define minimum ecological flow or water level by choosing appropriate water and habitat indices. Several com- monly used flow or water level assessment methods were found to be special cases of the general model, including the wetted perimeter method and the multi-objective physical habitat simulation method for ecological river flow, the inundated forest width method for regeneration flow of floodplain forest and the lake surface area method for eco- logical lake level. These methods were applied to determine minimum ecological flow or water level for two repre- sentative rivers and a lake in northern Xinjiang of China, including minimum ecological flow for the Ertix River, minimum regeneration flow for floodplain forest along the midstream of Kaxgar River, and minimum ecological lake level for the Ebinur Lake. The results illustrated the versatility of the general model, and can provide references for water resources planning and ecosystem protection for these rivers and lake.

A Review on Luohuang Power Plant 4×360 MW FGD Project

This paper elaborates the wet limestone gypsum technology adopted in the flue gasdesulfurization projects of 4×360 MW generating units in Luohuang Power Plant, theimplementation process of Phase II desulfurization project, the technical features and differencesof Phase I and II desulfurization plants, and puts forward some suggestions for FGD projectconstruction.[

Preparation of Cationic Starch by Electromagnetic Dry Process (EMDP)

Introduction Cationic starches are a series of products of which various sorts with different properties and usages can all be produced via cationic reactions by using different types of etherification agents under different conditions. As an additive and strengthening agent,

Preparation of W-TiC alloys from core-shell structure powders synthesized by an improved wet chemical method

In order to improve the homogeneous distribution of the TiC particles and facilitate the TiC particles to distribute in the tungsten grain interiors,two kinds of TiCdoped tungsten precursors with a core-shell structure were prepared by an improved wet chemical method at different reaction temperature conditions.Consequently,fine platelike precursor(200-400 nm)and flower-like precursor(approximately 1.25μm)are obtained.After reduction and sintering,the microstructures of the samples were characterized by scanning electron microscopy and transmission electron microscopy.In the sample sintered from the platelike precursor,TiC particles with sizes in the range of40-300 nm and an average size of approximately 80 nm were uniformly distributed in the tungsten matrix with a high share in the grain interiors.However,in the sample sintered from the flower-like precursor,the TiC particles with sizes in the range of 50-700 nm are significantly aggregated and non-uniformly distributed in the tungsten matrix.As a result,the sample sintered from the plate-like precursor achieves higher mechanical properties and a much narrower range of bending strength values than that sintered from the flower-like precursor.The average bending strength of the sample sintered from the plate-like precursor is 655 MPa,which is higher than that of the sample sintered from the flower-like precursor(524 MPa).Different reaction mechanisms and dispersing stabilities of the TiC particles at different temperature conditions should be accounted for the differences between the two samples.

Tuning the face orientation of ZnO nano/microcrystals by a wet chemical method

We successfully synthesize four kinds of ZnO nano/microcrystals including dumbbell microrods, nanoflakes, nanoplates, and microrods by a simple wet chemical method. Growth duration is found to play a crucial role in the morphologies of these ZnO nano/microcrystallites. In addition, growth conditions are systematically studied as a function of precursor concentration and temperature. The structural and optical characteristics of the ZnO samples are further investigated by X-ray diffraction, scanning electron microscopy, and photoluminescence spectroscopy.

Structural,morphological,optical and antibacterial performances of rare earth(Sm)-doped ZnO nanorods

The significant rise of ultra-violet(UV) radiation and pathogenic infectious bacteria poses a serious threat to global health.Numerous researchers' interests are attracted by novel materials with strong UVblocking ability,antibacterial activity and low toxicity to other species.In this case,a simple wet chemical method with different annealing temperatures(400,500,and 600℃) was employed to create highly effective rare earth(Sm)-doped ZnO nanorods.The(101) plane of wurtzite ZnO shifts towards a lower angle with increasing annealing temperature,according to the X-ray diffraction(XRD) study findings,which additionally establishes the consequence of lattice expansion.Occurrence of doublet peaks of Sm 3d(Sm 3d_(5/2) and Sm 3d_(3/2)) in the X-ray photoelectron spectroscopy(XPS) spectrum clearly validates the substitution of Sm^(3+) ions in the 500℃-annealed samples.The 500℃-annealed nanorods exhibit combined performances of the wide band gap,improved UV absorbance,and vivid green luminescent emission(563 nm).Additio nally,the nanorods have favorable UV-blocking execution of 96% for UVA at 360 nm,92% for UVB at 320 nm,and 57% for UVC at 225 nm,which is greater than the majority of ZnO-related materials that have been reported up to this date.Sm doping is also appropriate for improving bacterial inhibition against the two studied strains(Escherichia coli and Staphylococcus aureus),in addition to the intriguing features discussed above.Furthermore,with maximum inhibition zone diameters of 20±0.72 and 18±0.57 mm,respectively,these nanorods exhibit high inhibitory action against E.coli and S.aureus bacterial strains.The rare earth-doped material developed during the current experiment,which was annealed at 500℃,could potentially serve as an effective replacement for UV-blocking and antibacterial material,especially for biomedical applications.

The Instream Ecological Water Flow Research at the Lower Reach of Guanting Reservoir on Yongdinghe River,Beijing

作为北京市母亲河的永定河自上个世纪80年代以来三家店以下一直处于断流,河床裸露、河道两岸土地沙化严重,是北京春季沙尘天气的主要沙源之一,由于地下水超采严重,加之无水补给地下水,使得北京西部地区第四纪地下水已经基本枯竭,永定河的生态系统已经受到严重破坏。要想恢复或治理受损的河道生态环境,作为生态系统中最活跃最重要的水分多少要先算清楚。本文采用湿周法计算了永定河官厅水库下游三个控制断面（官厅水库（坝下）、雁翅、卢沟桥）的河道内生态需水流量,计算结果为:官厅水库（坝下）站的河道内流量为3.7m3 s-1。（平水年P=50%,1978年）,占年平均流量的20.7%,雁翅站的河道内流量为4.1m3 s-1（平水年P=50%,1981年）,占年平均流量的20.1%,卢沟桥站的河道内流量为1.3m3 s-1（平水年P=50%,1978年）,占年平均流量的22.1%。若能按照计算的流量来补充河道水量,即可使永定河恢复其基本的生态功能,按照Tennant法的标准,基本能使当地的河道生态系统处于较为良好的状态。

A new criterion for defining the breakpoint of the wetted perimeter-discharge curve and its application to estimating minimum instream flow requirements

The wetted perimeter method(WPM) is used in hydrology and hydraulics to calculate instream flows.The WPM requires few data.It requires only the values of the wetted perimeter,flow and water level,which can be obtained from the hydrologic stations of the river in question.In addition,the WPM is not limited by the impacts of human activities on the river runoff.Therefore,this method is generally suitable for the current conditions in China.However,the process of applying the WPM involves two key aspects:how to plot the curve describing the relationship between the wetted perimeter and the discharge and how to confirm the breakpoint of the wetted perimeter-discharge curve.The traditional method is to calculate the curvature or the slope of the wetted perimeter-discharge curve to obtain the minimum flow.According to this method,the minimum flow corresponds to the point of maximum curvature or to the point at which the slope of the curve is equal to 1.The wetted perimeter-discharge curve of a natural river is only part of the complete curve.Thus,the instream flow calculated by the traditional method is the minimum or maximum discharge.The new criterion for defining the breakpoint of the wetted perimeter-discharge curve is that the slope at the breakpoint is a relative maximum,the second-largest slope.The discharges at the breakpoints corresponded to the minimum flow levels required to maintain the ecological function of the river.The minimum instream flow requirements(MIFRs) of four typical reaches,Zhuba,Daofu,Ganzi and Zumuzu hydrological stations on the West Course of the First Stage Project of the South-North Water Transfer Project(WCFSPSNWTP),are calculated using an improved wetted perimeter method(IWPM).The results show that the MIFRs of Zhuba,Daofu,Ganzi and Zumuzu are approximately 9.06-14.5 m 3 s-1,20.7-43.5 m3 s-1,38.8-77.2 m 3 s-1 and 40.4-59.5 m 3 s-1,corresponding to 11.7%-33.9%,14.2%-37.6%,12.4%-28.4% and 17.5%-30.2%,respectively of the annual average flow(AAF).These MIFRs can maintain good ecological function in a river according to the criterion furnished by the Tennant method.

Squeeze flow of interstitial Herschel-Bulkley fluid between two rigid spheres

Interaction between two spheres with an interstitial fluid is crucial in discrete element modeling for simulating the behaviors of ＇wet＇ particulate materials. The normal viscous force of squeeze flow between two arbitrary rigid spheres with an interstitial HerscheI-Bulkley fluid was studied on the basis of Reynolds＇ lubrication theory, resulting in analytical integral expressions of pressure distribution and the viscous force between the two spheres. According to the variation of shear stress, the fluid was divided into yielding and unyielding regions, followed by a discussion on the thickness of the two regions. The result of this paper could be reduced to either the power-law fluid or the Bingham fluid case.

Preparation and photocatalytic activities of 3D flower-like CuO nanostructures

Hierarchical 3D flower-like CuO nanostructures on the Cu substrates were synthesized by a wet chem- ical method and subsequent heat treatment. The synthesis, structure and morphologies of obtained samples under different concentrations of NazS203 were investigated in detail and the possible growth mechanisms of the 3D flower-like CuO nanostructures were discussed. Na2S203 plays a key role in the generation of the 3D flower-like CuO nanostructures. When the concentration of Na2S203 is more than 0.4 mol/L, the 3D flower-like CuO nano- structures can be prepared on the Cu foils. The photocatalytic performances were studied by analyzing the degra- dation of methyl orange （MO） in aqueous solution in the presence of hydroxide water （H202）. The 3D flower-like CuO nanostructures exhibit higher photocatalytic activity （96.2% degradation rate） than commercial CuO particles （36.3% degradation rate）. The origin of the higher photocatalytic activity of the 3D flower-like CuO nanostructures was also discussed.