Composite Portland cement (PC) played an important role in various kinds of construction engineering owing to low hydration heat,low-cost,and application of solid industrial waste,but its brittleness and low strengt...Composite Portland cement (PC) played an important role in various kinds of construction engineering owing to low hydration heat,low-cost,and application of solid industrial waste,but its brittleness and low strength limited its use in stress-bearing locations.The aim of this study is to improve the toughness and fracture resistance by incorporating CaCO3 whisker in cement matrix.Effect of different content of calcium carbonate whiskers on the mechanical properties of PC was investigated.The results showed that the flexural strength,impact strength and split tensile strength were increased by 39.7%,39.25% and 36.34% at maximum,respectively.Microstructure and elements of the whiskers in hardened cement were observed and analyzed by SEM/EDS.The mechanisms of the reinforcement of CaCO3 whisker on cement were also discussed,and the conclusion was that the improvement could be correlated to energy-dissipating processes owing to crack bridging,crack deflection,and whisker pull-out at the crack tips.展开更多
The present paper continues the discussion in Part I. Model and Formulation. Based on the theory proposed in Part I, the formulae predicting stiffness moduli of the composites in some typical cases of whisker orientat...The present paper continues the discussion in Part I. Model and Formulation. Based on the theory proposed in Part I, the formulae predicting stiffness moduli of the composites in some typical cases of whisker orientations and loading conditions are derived and compared with theoretical representatives in literatures, experimental measurement and commonly used empirical formulae. It seems that (1) with whisker reinforcing and matrix hardening considered, the present prediction is in well agreement with the experimental measurement; (2) the present theory can predict accurate moduli with the proper pre calculated parameters; (3) the upper bound and lower bound of the present theory are just the predictions of equal strain theory and equal stress theory; (4) the present theory provides a physical explanation and theoretical base for the present commonly used empirical formulae. Compared with the microscopic mechanical theories, the present theory is competent for modulus prediction of practical engineering composite in accuracy and simplicity. [WT5”HZ]展开更多
Based on study of strain distribution in whisker reinforced metal matrix composites, an explicit precise stiffness tensor is derived. In the present theory, the effect of whisker orientation on the macro property of c...Based on study of strain distribution in whisker reinforced metal matrix composites, an explicit precise stiffness tensor is derived. In the present theory, the effect of whisker orientation on the macro property of composites is considered, but the effect of random whisker position and the complicated strain field at whisker ends are averaged. The derived formula is able to predict the stiffness modulus of composites with arbitrary whisker orientation under any loading condition. Compared with the models of micro mechanics, the present theory is competent for modulus prediction of actual engineering composites. The verification and application of the present theory are given in a subsequent paper published in the same展开更多
The fracture toughness (KIC) values determined by indentation microfracture method (IM ) for SiC whisker reinforced Al2O3 and ZrO2 based composites were calculated with different IM equations and compared with those o...The fracture toughness (KIC) values determined by indentation microfracture method (IM ) for SiC whisker reinforced Al2O3 and ZrO2 based composites were calculated with different IM equations and compared with those obtained by singte edge notched beam (SENB) technique. Experimental results show that the KIC (IM) values calculated with different equations are quite different one from another. For composites without phase transformable components the KIC (IM) and KIC (SENB) values are practically on the same level, but for composites with phase transformable components (partially stabilized zirconia) the KIC (SENB) values are always higher than KIC (IM). This is because that the IM method can not reveal sensitively the toughening effect due to dynamic t-m transformation of ZrO2 as the SENB method does. The accuracy of the IM method depends on the Suitability of the IM equations and was evaluated for the materials used in this investigation. Two new IM equations are suggested with which the KIC (IM ) values can be obtained very close to KIC (SENB) values for composites having phase transformable components.展开更多
The creep behaviour of β-Si3N4 whisker reinforced Al-8.5Fe-1.3V-1.7Si composite has been investigated at the temperature 773 and 823 K. The results are characterized by high stress exponent and high apparent creep ac...The creep behaviour of β-Si3N4 whisker reinforced Al-8.5Fe-1.3V-1.7Si composite has been investigated at the temperature 773 and 823 K. The results are characterized by high stress exponent and high apparent creep activation energy The creep data can be interpreted based on the incorporation of a threshold Stress and a load transfer coefficient into the power-law creep equation. A good correlation between the normalized creep rate and normalized effective stress is available which demonstrates that the creep behaviour of both the alloy and the composite is controlled by the matrix lattice self-diffusion in AI. EXamination on microstructure shows that edge dislocations exist at the interfaces between two adjacent whiskers and the intedeces emit edge dislocations in parallel paired-columns.展开更多
By using self-made metal-alkoxide yttrium isopropoxide as a sintering additive and disperser of whisker, the SiC whisker reinforced AIN ceramics was prepared. Its apparent density is 99.5 percent of the theoretical de...By using self-made metal-alkoxide yttrium isopropoxide as a sintering additive and disperser of whisker, the SiC whisker reinforced AIN ceramics was prepared. Its apparent density is 99.5 percent of the theoretical density; its flexural strength and fracture toughness are 681 MPa and 5.21 MPa·m1/2 respectively. Comparing the result with that by applying Y2O3 powder as a sintering additive, the flexural strength is increased by 25% and the fracture toughness is increased by 33% . The dispersity of whisker by increased yttrium isopropoxide is significantly better than that by Triton X-100.展开更多
Alumina whisker reinforced zirconia ceramic composite was prepared by both hot oscillatory pressing(HOP)and conventional hot pressing(HP).The results show that compared with HP,HOP can significantly increase the final...Alumina whisker reinforced zirconia ceramic composite was prepared by both hot oscillatory pressing(HOP)and conventional hot pressing(HP).The results show that compared with HP,HOP can significantly increase the final density and densification rate of the material.Analysis of densification kinetics reveals that the predominant densification mechanism transits from grain boundary sliding in the beginning to the diffusion in the later stage.The main effect of the oscillating pressure is to increase the densification rate in the process of grain boundary sliding.The current study suggests that HOP is a promising technique for densifying whisker reinforced ceramics.展开更多
文摘Composite Portland cement (PC) played an important role in various kinds of construction engineering owing to low hydration heat,low-cost,and application of solid industrial waste,but its brittleness and low strength limited its use in stress-bearing locations.The aim of this study is to improve the toughness and fracture resistance by incorporating CaCO3 whisker in cement matrix.Effect of different content of calcium carbonate whiskers on the mechanical properties of PC was investigated.The results showed that the flexural strength,impact strength and split tensile strength were increased by 39.7%,39.25% and 36.34% at maximum,respectively.Microstructure and elements of the whiskers in hardened cement were observed and analyzed by SEM/EDS.The mechanisms of the reinforcement of CaCO3 whisker on cement were also discussed,and the conclusion was that the improvement could be correlated to energy-dissipating processes owing to crack bridging,crack deflection,and whisker pull-out at the crack tips.
基金National Natural Science Foundation of China !( 19870 2 65 ,1973 2 0 60 ) Chinese Academ y of Sciences Foundation
文摘The present paper continues the discussion in Part I. Model and Formulation. Based on the theory proposed in Part I, the formulae predicting stiffness moduli of the composites in some typical cases of whisker orientations and loading conditions are derived and compared with theoretical representatives in literatures, experimental measurement and commonly used empirical formulae. It seems that (1) with whisker reinforcing and matrix hardening considered, the present prediction is in well agreement with the experimental measurement; (2) the present theory can predict accurate moduli with the proper pre calculated parameters; (3) the upper bound and lower bound of the present theory are just the predictions of equal strain theory and equal stress theory; (4) the present theory provides a physical explanation and theoretical base for the present commonly used empirical formulae. Compared with the microscopic mechanical theories, the present theory is competent for modulus prediction of practical engineering composite in accuracy and simplicity. [WT5”HZ]
基金National Natural Science Foundation of China !( 19870 2 65 ,1973 2 0 60 ) Chinese Academ y of Sciences Foundation
文摘Based on study of strain distribution in whisker reinforced metal matrix composites, an explicit precise stiffness tensor is derived. In the present theory, the effect of whisker orientation on the macro property of composites is considered, but the effect of random whisker position and the complicated strain field at whisker ends are averaged. The derived formula is able to predict the stiffness modulus of composites with arbitrary whisker orientation under any loading condition. Compared with the models of micro mechanics, the present theory is competent for modulus prediction of actual engineering composites. The verification and application of the present theory are given in a subsequent paper published in the same
文摘The fracture toughness (KIC) values determined by indentation microfracture method (IM ) for SiC whisker reinforced Al2O3 and ZrO2 based composites were calculated with different IM equations and compared with those obtained by singte edge notched beam (SENB) technique. Experimental results show that the KIC (IM) values calculated with different equations are quite different one from another. For composites without phase transformable components the KIC (IM) and KIC (SENB) values are practically on the same level, but for composites with phase transformable components (partially stabilized zirconia) the KIC (SENB) values are always higher than KIC (IM). This is because that the IM method can not reveal sensitively the toughening effect due to dynamic t-m transformation of ZrO2 as the SENB method does. The accuracy of the IM method depends on the Suitability of the IM equations and was evaluated for the materials used in this investigation. Two new IM equations are suggested with which the KIC (IM ) values can be obtained very close to KIC (SENB) values for composites having phase transformable components.
文摘The creep behaviour of β-Si3N4 whisker reinforced Al-8.5Fe-1.3V-1.7Si composite has been investigated at the temperature 773 and 823 K. The results are characterized by high stress exponent and high apparent creep activation energy The creep data can be interpreted based on the incorporation of a threshold Stress and a load transfer coefficient into the power-law creep equation. A good correlation between the normalized creep rate and normalized effective stress is available which demonstrates that the creep behaviour of both the alloy and the composite is controlled by the matrix lattice self-diffusion in AI. EXamination on microstructure shows that edge dislocations exist at the interfaces between two adjacent whiskers and the intedeces emit edge dislocations in parallel paired-columns.
文摘By using self-made metal-alkoxide yttrium isopropoxide as a sintering additive and disperser of whisker, the SiC whisker reinforced AIN ceramics was prepared. Its apparent density is 99.5 percent of the theoretical density; its flexural strength and fracture toughness are 681 MPa and 5.21 MPa·m1/2 respectively. Comparing the result with that by applying Y2O3 powder as a sintering additive, the flexural strength is increased by 25% and the fracture toughness is increased by 33% . The dispersity of whisker by increased yttrium isopropoxide is significantly better than that by Triton X-100.
基金We thank the financial support from the National Natural Science Foundation of China(Grant Nos.52072344 and U1904180)Excellent Young Scientists Fund of Henan Province(Grant No.202300410369)Henan Province University Innovation Talents Support Program(Grant No.21HASTIT001).
文摘Alumina whisker reinforced zirconia ceramic composite was prepared by both hot oscillatory pressing(HOP)and conventional hot pressing(HP).The results show that compared with HP,HOP can significantly increase the final density and densification rate of the material.Analysis of densification kinetics reveals that the predominant densification mechanism transits from grain boundary sliding in the beginning to the diffusion in the later stage.The main effect of the oscillating pressure is to increase the densification rate in the process of grain boundary sliding.The current study suggests that HOP is a promising technique for densifying whisker reinforced ceramics.