Tandem white organic light-emitting diodes adopting a C_(60) :rubrene charge generation layer

Organic bulk heterojunction fullerence(C60) doped 5, 6, 11, 12-tetraphenylnaphthacene(rubrene) as the high quality charge generation layer(CGL) with high transparency and superior charge generating capability for tandem organic light emitting diodes(OLEDs) is developed. This CGL shows excellent optical transparency about 90%, which can reduce the optical interference effect formed in tandem OLEDs. There is a stable white light emission including 468 nm and 500 nm peaks from the blue emitting layer and 620 nm peak from the red emitting layer in tandem white OLEDs. A high efficiency of about 17.4 cd/A and CIE coordinates of(0.40, 0.35) at 100 cd/m2 and(0.36, 0.34) at 1000 cd/m2 have been demonstrated by employing the developed CGL, respectively.

White organic light-emitting diodes based on electroplex from polyvinyl carbazole and carbazole oligomers blends

White organic light-emitting diodes with a blue emitting material fluorene-centred ethylene-liked carbazole oligomer （Cz6F） doped into polyvinyl carbazole （PVK） as the single light-emitting layer are reported. The optical properties of Cz6F, PVK, and PVK：Cz6F blends are studied. Single and double layer devices are fabri- cated by using PVK： Cz6F blends, and the device with the configuration of indium tin oxide （ITO）/PVK：Cz6F/ tris（8-hydroxyquinolinate）aluminium （Alq3）/LiF/A1 exhibits white light emission with Commission Internationale de l＇Eclairage chromaticity coordinates of （0.30, 0.33） and a brightness of 402 cd/m^2. The investigation reveals that the white light is composed of a blue-green emission originating from the excimer of Cz6F molecules and a red emission from an electroplex from the PVK：Cz6F blend films.

High-Performance Hybrid White Organic Light-Emitting Diodes Utilizing a Mixed Interlayer as the Universal Carrier Switch

A new interlayer is successfully used to be a universal carrier switch, developing high-performance hybrid white organic light-emitting diodes （WOLEDs）. By dint of this interlayer, the two-color hybrid WOLED shows a maximum total current efficiency （CE） and power efficiency （PE） of 48.1 cd/A and 37.6 Im/W, respectively, while the three-color hybrid WOLED shows a maximum total CE and PE of 33.8 cd/A and 25.7Im/W, respectively. The color rendering index of the three-color hybrid WOLEDs are ≥ 75, which is already a sufficient level for many commercial lighting applications. In addition, both the two-color and three-color hybrid WOLEDs show low efficiency roll-off and stable color. Furthermore, devices with the new interlayer show much higher performance than devices with the most commonly used 4,4-N,N-dicarbazolebiphenyl and N,N＇-di（naphthalene-l-yl）-N,N＇- diphenyl-benzidine interlayers.

White organic light-emitting diodes based on a combined electromer and monomer emission in doubly-doped polymers

We report on white organic light-emitting diodes （WOLEDs） based on polyvinylcarbazole （PVK） doped with 1,1-bis（（di-4-tolylamino）phenyl）cyclohexane （TAPC） and perylene, and investigate the luminescence mechanism of the devices. The chromaticity of light emission can be tuned by adjusting the concentration of the dopants. White light with the Commission Internationale de L＇Eclairage （CIE） coordinates of （0.33, 0.34） is achieved by mixing the yellow electromer emission of TAPC and the blue monomer emission of perylene from the device ITO/PVK： TAPC： perylene （100：9：1 in wt.） （100 nm）/tris-（8-hydroxyquinoline aluminum （Alq3） （10 nm）/A1. The device exhibits a maximal luminance of 3727 cd/m2 and a current efficiency of 2 cd/A.

Top-Emitting White Organic Light-Emitting Diodes Based on Cu as Both Anode and Cathode

It is still challenging to obtain broadband emission covering visible light spectrum as much as possible with negligible angular dependence. In this work, we demonstrate a low driving voltage top-emitting white organic light-emitting diode （TEWOLED） based on complementary blue and yellow phosphor emitters with negligible angular dependence. The bottom copper anode with medium reflectance, which is compatible with the standard complementary metal oxide semiconductor （CMOS） technology below 0.13 μm, and the semitransparent multi- layer Cs2CO3/AI/Cu cathode as a top electrode, are introduced to realize high-performance TEWOLED. Our TEWOLED achieves high efficiencies of 15.4callA and 12.1 1m/W at a practical brightness of lO00cd/m2 at low voltage of 4 V.

Very-High Color Rendering Index Hybrid White Organic Light-Emitting Diodes with Double Emitting Nanolayers

A very-high color rendering index white organic light-emitting diode(WOLED) based on a simple structure was successfully fabricated. The optimized device exhibits a maximum total efficiency of 13.1 and 5.4 lm/W at 1,000 cd/m2. A peak color rendering index of 90 and a relatively stable color during a wide range of luminance were obtained. In addition, it was demonstrated that the 4,40,400-tri(9-carbazoyl) triphenylamine host influenced strongly the performance of this WOLED.These results may be beneficial to the design of both material and device architecture for high-performance WOLED.

Regulating Charge and Exciton Distribution in High-Performance Hybrid White Organic Light-Emitting Diodes with n-Type Interlayer Switch

The interlayer(IL) plays a vital role in hybrid white organic light-emitting diodes(WOLEDs); however,only a negligible amount of attention has been given to n-type ILs. Herein, the n-type IL, for the first time,has been demonstrated to achieve a high efficiency, high color rendering index(CRI), and low voltage trade-off.The device exhibits a maximum total efficiency of 41.5 lm W^(-1), the highest among hybrid WOLEDs with n-type ILs. In addition, high CRIs(80–88) at practical luminances(C1000 cd m^(-2)) have been obtained, satisfying the demand for indoor lighting. Remarkably, a CRI of 88 is the highest among hybrid WOLEDs. Moreover, the device exhibits low voltages, with a turn-on voltage of only 2.5 V([1 cd m^(-2)), which is the lowest among hybrid WOLEDs. The intrinsic working mechanism of the device has also been explored; in particular, the role of n-type ILs in regulating the distribution of charges and excitons has been unveiled. The findings demonstrate that the introduction of n-type ILs is effective in developing high-performance hybrid WOLEDs.

Spectral Characteristics of White Organic Light-emitting Diodes Based on Novel Phosphorescent Sensitizer

White organic light-emitting diodes were fabricated by using a novel phosphorescence bis（1,2-diphenyl-1H-benzoimidazole）iridium（acetylacetonate）[（pbi）2Ir（acac）] as sensitizer and a fluorescent dye of 4- （dicyanomethylene）-2-t-butyl-6-（1,1,7,7-tetramethyljulolidyl-9-enyl）-4H-pyran （DCJTB） codoped into a carbazole polymer of poly（N-vinylcarbazole） （PVK）. Through characterizing the UV-Vis absorption spectra, the photoluminescence spectra of （pbi）2Ir（acac） and DCJTB, and the electroluminescence spectral properties of the WOLEDs, the energy transfer mechanisms of the codoped polymer system were deduced. The results demonstrate that the luminescent spectra with different intensity of （pbi）2Ir（acac） and DCJTB were co-existent in the EL spectra of the blended system, which is ascribed to an incomplete energy transfer process in the EL process. The efficient Forster and Dexter energy transfer between the host and the guests enabled a strong yellow emission from （pbi）2Ir（acac） and DCJTB, where （pbi）2Ir（acac） plays an important role as a phosphorescent sensitizer for DCJTB. With the blue emitting-layer of N,N＇-diphenyl-N,N＇-bis（1- naphthyl）（1,1＇-biphenyl）-4,4＇-diamine, the codoped system device achieved white emission. The codoped system showed that its Commissions Internationale de 1＇Eclairage coordinates were more independent of the variation of bias voltage than those of phosphorescent doped PVK systems.

White Organic Light-emitting Diodes with A Sr_2SiO_4:Eu^(3+) Color Conversion Layer

Abstract:Hybrid inorganic/organic white organic light emitting diodes(hybrid-WOLEDs)are fabricated by combi-ning the blue phosphorescent organic light emitting diodes(PHOLEDs)with red Sr2SiO4:Eu3+phosphor spin coatedas a color conversion layer(CCL)over the other side of glass substrate on the devices.The basic configuration of thePHOLEDs consists a host material,N,N'-dicarbazolyl-3,5-benzene(mCP)which doped with a blue phosphorescentiridium complexes iridium(Ⅲ)bis[(4,6-di-fluorophenyl)-pyridinato-N-C2'](FIrpic)to produce high efficient blueorganic light emitting diodes.The hybrid-WOLED shows maximum luminous efficiency of 22.1 cd/A,maximumpower efficiency of 11.26 lm/W,external quantum efficiency of 10.2%and CIE coordinates of(0.32,0.34).Mo-reover,the output spectra and CIE coordinates of the hybrid-WOLED have a small shift in different driving currentdensity,which demonstrate good color stability.

High efficient and high color rendering index white organic light-emitting diodes

We have fabricated high-efficient white organic light-emitting diodes （WOLEDs） using two types of electron transport materials with different electron mobility. The effect of the electron mobility on the device performance is discussed. In addition, to generate the desired white emission and high color rendering index, we perform the structure design of OLED, in which the functions of co-host of blue and green dopants on chromatic-stability are investigated. Experimental results find that the maximum color rendering index reaches as high as 91 at the voltage of 8 V.

Color-Tunable Hybrid White Organic Light-Emitting Diodes with Double Interlayers

An efficient color-tunable hybrid white organic light-emitting diode is demonstrated with double interlayers of 2,7-bis(carbazol-9-yl)-9,9-ditoylfluo- rene/2-(diphenylphosphoryl) spiroflu-orene (DMFL-CBP/SPPO1) inserted between blue fluorescent and yellow phosphorescent-emitting layers, and exhibits Commission Internationale de l’Eclairage (CIE1931) ranging from warm white (0.4368, 0.4497) to cool white (0.2781, 0.2896) with driving current density from 0.2 to 40 mA/cm2. The recombination of singlet and the triplet excitons in blue fluores-cent-emitting layer and yellow phosphorescent-emitting layer, respectively, can be modulated by both the thickness of these double interlayers and the applied current densities.

Finely regulated luminescent Ag-In-Ga-S quantum dots with green-red dual emission toward white light-emitting diodes

Ag-In-Ga-S(AIGS)quantum dots(QDs)have recently attracted great interests due to the outstanding optical properties and eco-friendly components,which are considered as an alternative replacement for toxic Pb-and Cd-based QDs.However,enormous attention has been paid to how to narrow their broadband spectra,ignoring the application advantages of the broadband emission.In this work,the AIGS QDs with controllable broad green-red dual-emission are first reported,which is achieved through adjusting the size distribution of QDs by controlling the nucleation and growth of AIGS crystals.Resultantly,the AIGS QDs exhibit broad dual-emission at green-and red-band evidenced by photoluminescence(PL)spectra,and the PL relative intensity and peak position can be finely adjusted.Furthermore,the dual-emission is the intrinsic characteristics from the difference in confinement effect of large particles and tiny particles confirmed by temperature-dependent PL spectra.Accordingly,the AIGS QDs(the size consists of 17 nm and 3.7 nm)with 530 nm and 630 nm emission could successfully be synthesized at 220°C.By combining the blue light-emitting diode(LED)chips and dual-emission AIGS QDs,the constructed white light-emitting devices(WLEDs)exhibit a continuous and broad spectrum like natural sunlight with the Commission Internationale de l’Eclairage(CIE)chromaticity coordinates of(0.33,0.31),a correlated color temperature(CCT)of 5425 K,color rendering index(CRI)of 90,and luminous efficacy of radiation(LER)of 129 lm/W,which indicates that the AIGS QDs have huge potential for lighting applications.

Extremely high-efficiency and ultrasimplified hybrid white organic light-emitting diodes exploiting double multifunctional blue emitting layers

Numerous hybrid white organic light-emitting diodes(WOLEDs)have recently been developed.However,their efficiency is not comparable to that of their best all-phosphorescent WOLED counterparts,and the structures are usually complicated,restricting their further development.Herein,a novel concept is used to achieve a hybrid WOLED,whose crucial feature is the exploitation of double multifunctional blue emitting layers.The three-organic-layer WOLED exhibits a total efficiency of 89.3 and 65.1 lm W^(-1) at 100 and 1000 cd m^(-2),respectively,making it the most efficient hybrid WOLED reported in the literature so far.Significantly,the efficiencies of hybrid WOLEDs have,for the first time,been demonstrated to be comparable to those of the best all-phosphorescent WOLEDs.In addition,the device exhibits the lowest voltages among hybrid WOLEDs(i.e.,2.4,2.7 and 3.1 V for 1,100 and 1000 cd m^(-2),respectively).Such remarkable performance achieved from such an ultrasimplified structure opens a new path toward low-cost commercialization.

Energy distribution in white organic light-emitting diodes with three primary color emitting layers

Two types of organic light-emitting diodes with structures of ITO/N,N'-bis(1-naphthyl)-N,N'-diphenyl,1,1'-biphenyl-4,4'-diamine (NPB)/tris(8-hydroquinolinato)aluminum(Alq 3)/2,9-dimethyl-4,7-diphenyl-l,10-phenanthroline(BCP)/Alq 3:4-dicyanomethylene-2-(tert-butyl)-6-methyl-4H-pyran(DCJTB)/Alq 3 /Al and ITO/NPB/BCP/Alq 3 /Alq 3:DCJTB/Alq 3 /Al were studied.NPB was chosen as a hole-transporting/blue-emitting layer.Alq 3 adjacent to BCP acted as a green emitting layer while that adjacent to the Al cathode acted as an electron-transporting layer.Alq 3 doped with 2 wt.% DCJTB was used as a red emitting layer.The operating principles of the devices were explained by the mechanism of F rster energy transfer and the hole and exciton blocking effect of BCP.It was found that the spectral characteristics of the devices strongly depended on the relative location between the green emitting Alq 3 layer and the BCP layer,as well as their thickness.Pure white emission with the CIE coordinates of (0.33,0.33) was achieved by mixing the three primary colors in the device with the structure of ITO/NPB(30 nm)/BCP(6 nm)/Alq 3 (30 nm)/Alq 3:DCJTB(30 nm)/Alq 3 (30 nm)/Al.The BCP layer played an important role in distributing the exciton energy among the three emitting layers to achieve a balanced white light.The white emission of this device was largely insensitive to the driving voltage (15-27 V) with the insertion of the green emitting Alq 3 layer.

Doping-free tandem white organic light-emitting diodes

Tandem white organic light-emitting diodes(WOLEDs) are of great research interest since they can greatly boost the performance compared with the single-unit counterparts. However, their structures are more complicated than those of single-unit OLEDs. Besides, to achieve high performance, the doping technology is required to tandem OLEDs, particularly for tandem WOLEDs, further complicating the structures. Herein, doping-free tandem WOLEDs, for the first time, have been demonstrated. By managing an effective doping-free charge generation layer to interconnect doping-free emitting layers/charge transport layers, high-performance doping-free tandem WOLEDs have been developed. The blueyellow device accomplishes the simplified structure/short fabrication time/reduced cost/high efficiency/low efficiency roll-off/low voltage/high luminance trade-off, which cannot be achieved by previous tandem WOLEDs. Remarkably, the efficiency(81.2 cd A^(-1)) is ~2-fold higher than the highest efficiency of previous doping-free WOLEDs and even higher than those of some best doping tandem WOLEDs. The maximum luminance is 44,886 cd m^(-2), which is the highest for doping-free WOLEDs.Besides, the blue-red device can exhibit a color rendering index(CRI) of 67, which is even higher than that of some representative three-color tandem WOLEDs. Such findings may not only represent a significant step for doping-free WOLEDs, but unlock a novel avenue that doping-free tandem WOLEDs are promising to achieve the simplicity and high performance trade-off.

Numerical Study of Optimization of Layer Thickness in Bilayer Organic Light-Emitting Diodes

A numerical model for bilayer organic light-emitting diodes (OLEDs) is developed under the basis of trapped charge limited conduction.The dependences of the current density on the layer thickness,trap properties and carrier mobility of the hole transport layer (HTL) and emission layer (EML) in bilayer OLEDs of the structure anode/HTL/EML/cathode are numerically investigated.It is found that,for given values of the total thickness of organic layers,reduced depth of trap,total density of trap,and carrier mobility of HTL as well as EML,there exists an optimal thickness ratio of HTL to EML,by which a maximal quantum efficiency can be achieved.Through optimization of the thickness ratio,an enhancement of current density and quantum efficiency of as much as two orders of magnitude can be obtained.The dependences of the optimal thickness ratio to the characteristic trap energy,total density of trap and carrier mobility are numerically analyzed.

Pure blue and white light electroluminescence in a multilayer organic light-emitting diode using a new blue emitter

We characterized the 6,12-bis{[N-（3,4-dimethylphenyl）-N-（2,4,5-trimethylphenyl）]amino} chrysene （BmPAC）, which has been proven to be a blue fluorescent emission with high EL efficiency. The blue fluorescent device exhibits good performance with an external quantum efficiency of 5.8% and current efficiency of 8.9 cd/A, respectively. Using BmPAC, we also demonstrate a hybrid phosphorescence/fluorescence white organic light-emitting device （WOLED） with high efficiency of 36.3 cd/A. In order to improve the relative intensity of blue light, we plus a blue light-emitting layer （BEML） in front of the orange light emitting layer （YEML） to take advantage of the excess singlet excitons. With the new emitting layer of BEML/YEML/BEML, we demonstrate the fluorescence/phosphorescence/fluorescence WOLED exhibits good performance with a current efficiency of 47 cd/A and an enhanced relative intensity of blue light.

High color rendering index white organic light-emitting diode using levofloxacin as blue emitter

Levofloxacin （LOFX）, which is well-known as an antibiotic medicament, was shown to be useful as a 452-nm blue emitter for white organic light-emitting diodes （OLEDs）. In this paper, the fabricated white OLED contains a 452-nm blue emitting layer （thickness of 30 nm） with 1 wt% LOFX doped in CBP （4,4＇-bis（carbazol-9-yl）biphenyl） host and a 584-nm orange emitting layer （thickness of 10 nm） with 0.8 wt% DCJTB （4-（dicyanomethylene）-2-tert-butyl-6-（1,1,7,7- tetramethyljulolidin-4-yl-vinyl）-4H-pyran） doped in CBE which are separated by a 20-nm-thick buffer layer of TPBi （2,2＇,2＂-（benzene-1,3,5-triyl）-tri（1-phenyl-lH-benzimidazole）. A high color rendering index （CRI） of 84.5 and CIE chromaticity coordinates of （0.33, 0.32）, which is close to ideal white emission CIE （0.333, 0.333）, are obtained at a bias voltage of 14 V. Taking into account that LOFX is less expensive and the synthesis and purification technologies of LOFX are mature, these results indicate that blue fluorescence emitting LOFX is useful for applications to white OLEDs although the maximum current efficiency and luminance are not high. The present paper is expected to become a milestone to using medical drug materials for OLEDs.

Enhancing The Efficiency of White Organic Light-emitting Diode Using Energy Recyclable Photovoltaic Cells

We demonstrate that power recycling is feasible by using a semi-transparent stripped Al electrode as interconnecting layer to merge a white organic light-emitting devices(WOLED) and an organic photovoltaic(OPV) cell.The device is called a PVOLED.It has a glass / ITO / CuPc / m-MTDATA ∶ V 2 O 5 / NPB / CBP ∶ FIrpic ∶ DCJTB / BPhen / LiF / Al / P3HT∶ PCBM / V 2 O 5 / Al structure.The power recycling efficiency of 10.133% is achieved under the WOLED of PVOLED operated at 9 V and at a brightness of 2 110 cd / m 2,when the conversion efficiency of OPV is 2.3%.We have found that the power recycling efficiency is decreased under high brightness and high applied voltage due to an increase input power of WOLED.High efficiency(18.3 cd / A) and high contrast ratio(9.3) were obtained at the device operated at 2 500 cd / m 2 under an ambient illumination of 24 000 lx.Reasonable white light emission with Commission Internationale De L'Eclairage(CIE) color coordinates of(0.32,0.44) at 20 mA / cm 2 and slight color shift occurred in spite of a high current density of 50 mA / cm 2.The proposed PVOLED is highly promising for use in outdoors display applications.

Influence of Transparent Anode on Luminescent Performance of Near-infrared Organic Light-emitting Diodes

The optical transmission（200--2000 nm）, sheet resistance and work functions of indium-tin oxide（ITO）（100 Ω/）, ITO（12 Ω/）, zinc-oxide（ZnO）, aluminum-doped ZnO（AZO） and polyaniline（PANI） films were investigated. Near-infrared organic light-emitting diodes（NIR-OLEDs） emitting around 1.54 μm based on Er（DBM）3Phen with ITO（100 Ω/）, ITO（12 Ω/） and PANI as anodes, respectively, were fabricated. The device structure was anode/4＂-tris（N-3-methylphenyl-N-phenyl-amino）-triphenylamine（m-MTDATA）/ N,N＇-di-l-naphthyl- N,N＇-diphenylbenzidine（NPB）/Er（DBM）3Phen/tris-（8-hydroxyquinoline） aluminum（Alq3）/A1. The results suggest that the performance of NIR-OLEDs with ITO（100 Ω/）, which has a lower Sn content, as anodes appear to be better than that of NIR-OLEDs with ITO（12 Ω/） and PANI as anodes, respectively. The high N1R transmittance of ITO（100 Ω/） is a major reason for the relatively high NIR EL efficiency. The more balanced holes and electrons in the device based on ITO（100 Ω/） are another reasons.