Mixed salts for lithium iron phosphate-based batteries operated at wide temperature range

To achieve good performance for LiFePO4-based batteries operated at a wide temperature range,mixed salts of LiBF4 LiBOB（lithium bis（oxalato）borate） and LiTFSI（lithium bis（trifluoromethanesulfonyl）imide）-LiBOB were investigated as alternative lithium salts to LiPF6 in non-aqueous electrolytes.LiFePO4/Li half cells using LiPF6,LiBF4-LiBOB and LiTFSI-LiBOB slats as lithium salts were investigated by galvanostatic cycling,cyclic voltammetry,thermogravimetric analysis.The results show that LiBF4-LiBOB and LiTFSI-LiBOB mixed salts are much more thermally stable than LiPF6.Corrosion of Al foil in the LiTFSI-based electrolytes can be suppressed successfully by the addition of LiBOB as a co-salt.The electrochemical performance of LiBF4-LiBOB and LiTFSI-LiBOB mixed salts based cells are both better than that of LiPF6-based cell.LiTFSI-LiBOB mixed salt based electrolyte is considered to be a very promising electrolyte candidate for Li-ion batteries that will be used in wide-temperature applications.

An Adaptive-Bandwidth CMOS PLL with Low Jitter and a Wide Tuning Range

This paper presents a novel adaptive-bandwidth charge pump PLL with low jitter and a wide tuning range. With an adaptive bandwidth,the proposed PLL can scale its loop dynamics proportional to the output frequency and maintain optimal performance over its entire output range. In order to improve the jitter performance of the PLL,a matching tech- nique is employed in the charge pump,and a voltage-to-voltage converter is used to achieve a low gain VCO. The experimental chip was fabricated in a 0. 35μm CMOS process. The measured results show that the PLL has perfect jitter performance within its operating range from 200MHz to 1.1GHz.

Design of a high sensitivity and wide range angular rate sensor based on exceptional surface

It is found that when the parity–time symmetry phenomenon is introduced into the resonant optical gyro system and it works near the exceptional point,the sensitivity can in theory be significantly amplified at low angular rate.However,in fact,the exceptional point is easily disturbed by external environmental variables,which means that it depends on harsh experimental environment and strong control ability,so it is difficult to move towards practical application.Here,we propose a new angular rate sensor structure based on exceptional surface,which has the advantages of high sensitivity and high robustness.The system consists of two fiber-optic ring resonators and two optical loop mirrors,and one of the resonators contains a variable ratio coupler and a variable optical attenuator.We theoretically analyze the system response,and the effects of phase and coupling ratio on the system response.Finally,compared with the conventional resonant gyro,the sensitivity of this exceptional surface angular rate sensor can be improved by about 300 times at low speed.In addition,by changing the loss coefficient in the ring resonator,we can achieve a wide range of 600 rad/s.This scheme provides a new approach for the development of ultra-high sensitivity and wide range angular rate sensors in the future.

Design of wide-range energy material beamline at the Shanghai Synchrotron Radiation Facility

We report the design of a wide-range energy material beamline(E-line) with multiple experimental techniques at the Shanghai Synchrotron Radiation Facility.The undulators consisted of an elliptically polarizing undulator and in-vacuum undulator that generate the soft and hard X-rays, respectively. The beamline covered a wide energy range from 130 to 18 ke V with both a high photon flux([ 10^(12) phs/s with exit silt 30 lm in soft X-ray and [ 5 9 10^(12) phs/s in hard X-ray within 0.1%BW bandwidth) and promising resolving power(maximum E/DE [ 15,000 in soft X-ray with exit silt 30 lm and [6000 in hard X-ray). Moreover, the beam spots from the soft and hard X-rays were focused to the same sample position with a high overlap ratio, so that the surfaces, interfaces, and bulk properties were characterized in situ by changing the probing depth.

A hierarchically structured tin-cobalt composite with an enhanced electronic effect for high-performance CO_(2) electroreduction in a wide potential range

Earth-abundant and nontoxic Sn-based materials have been regarded as promising catalysts for the electrochemical conversion of CO_(2)to C1 products,e.g.,CO and formate.However,it is still difficult for Snbased materials to obtain satisfactory performance at low-to-moderate overpotentials.Herein,a simple and facile electrospinning technique is utilized to prepare a composite of a bimetallic Sn-Co oxide/carbon matrix with a hollow nanotube structure(Sn Co-HNT).Sn Co-HNT can maintain>90%faradaic efficiencies for C1 products within a wide potential range from-0.6 VRHE to-1.2 VRHE,and a highest 94.1%selectivity towards CO in an H-type cell.Moreover,a 91.2%faradaic efficiency with a 241.3 m A cm^(-2)partial current density for C1 products could be achieved using a flow cell.According to theoretical calculations,the fusing of Sn/Co oxides on the carbon matrix accelerates electron transfer at the atomic level,causing electron deficiency of Sn centers and reversible variation between Co^(2+)and Co^(3+)centers.The synergistic effect of the Sn/Co composition improves the electron affinity of the catalyst surface,which is conducive to the adsorption and stabilization of key intermediates and eventually increases the catalytic activity in CO_(2)electroreduction.This study could provide a new strategy for the construction of oxide-derived catalysts for CO_(2)electroreduction.

Development of a wide-range and fast-response digitizing pulse signal acquisition and processing system for neutron flux monitoring on EAST

The neutron count rate fluctuation reaches six orders of magnitude between the ohmic plasma scenario and high power of auxiliary heating on an experimental advanced superconducting tokamak(EAST).The measurement result of neutron flux monitoring(NFM)is a significant feedback parameter related to the acquisition of radiation protection-related information and rapid fluctuations in neutron emission induced by plasma magnetohydrodynamic activity.Therefore,a wide range and high time resolution are required for the NFM system on EAST.To satisfy these requirements,a digital pulse signal acquisition and processing system with a wide dynamic range and fast response time was developed.The present study was conducted using a field-programmable gate array(FPGA)and peripheral component interconnect extension for instrument express(PXIe)platform.The digital dual measurement modes,which are composed of the pulse-counting mode and AC coupled square integral's Campbelling mode,were designed to expand the measurement range of the signal acquisition and processing system.The time resolution of the signal acquisition and processing system was improved from 10 to 1 ms owing to utilizing highspeed analog-to-digital converters(ADCs),a high-speed PXIe communication with a direct memory access(DMA)mode,and online data preprocessing technology of FPGA.The signal acquisition and processing system was tested experimentally in the EAST radiation field.The test results showed that the time resolution of NFM was improved to 1 ms,and the dynamic range of the neutron counts rate was expanded to more than 10^(6) counts per second.The Campbelling mode was calibrated using a multipoint average linear fitting method;subsequently,the fitting coefficient reached 0.9911.Therefore,the newly developed pulse signal acquisition and processing system ensures that the NFM system meets the requirements of high-parameter experiments conducted on EAST more effectively.

Gel-state polybenzimidazole proton exchange membranes with flexible alkyl sulfonic acid side chains for a wider operating temperature range(25–240 ℃)

High-temperature proton exchange membrane fuel cells(HT-PEMFC) possess distinct technical advantages of high output power, simplified water/heat management, increased tolerance to fuel impurities and diverse fuel sources, within the temperature range of 120–200 ℃. However, for practical automobile applications, it was crucial to broaden their low-temperature operating window and enable cold start-up capability. Herein, gel-state phosphoric acid(PA) doped sulfonated polybenzimidazole(PBI) proton exchange membranes(PEMs) were designed and synthesized via PPA sol-gel process and in-situ sultone ring-opening reactions with various proton transport pathways based on absorbed PA, flexible alkyl chain connected sulfonic acid groups and imidazole sites. The effects of flexible alkyl sulfonic acid side chain length and content on PA doping level, proton conductivity, and membrane stability under different temperature and relative humidity(RH) were thoroughly investigated. The prepared gel-state membranes contained a self-assembled lamellar and porous structure that facilitated the absorption of a large amount of PA with rapid proton transporting mechanisms. At room temperature, the optimized membrane exhibited a proton conductivity of 0.069 S cm^(-1), which was further increased to 0.162 and 0.358 S cm^(-1)at 80 and 200 ℃, respectively, without additional humidification. The most significant contribution of this work was demonstrating the feasibility of gel-state sulfonated PBI membranes in expanding HT-PEMFC application opportunities over a wider operating range of 25 to 240 ℃.

Moderately concentrated electrolyte enabling high-performance lithium metal batteries with a wide working temperature range

The electrolyte integrated with lithium metal anodes is subjected to the issues of interfacial compatibility and stability,which strongly influence the performances of high-energy lithium metal batteries.Here,we report a new electrolyte recipe viz.a moderately concentrated electrolyte comprising of 2.4 M lithium bis(fluorosulfonyl)imide(LiFSI)in a cosolvent mixture of fluorinated ethylene carbonate(FEC)and dimethyl carbonate(DMC)with relatively high ion conductivity.Owing to the preferential decomposition of LiFSI and FEC,an inorganic-rich interphase with abundant Li_(2)O and LiF nanocrystals is formed on lithium metal with improved robustness and ion transfer kinetics,enabling lithium plating/stripping with an extremely low overpotential of~8 mV and the average CE of 97%.When tested in Li||LiFePO_(4) cell,this electrolyte provides long-term cycling with a capacity retention of 98.3%after 1000 cycles at 1 C and an excellent rate performance of 20 C,as well as an areal capacity of 1.35 mA h cm^(-2)at the cathode areal loading of 9 mg cm^(-2).Moreover,the Li||LiFePO_(4) cell exhibits excellent wide-temperature performances(-40~60℃),including long-term cycling stability over 2600 cycles without visible capacity fading at 0℃,as well as extremely high average CEs of 99.6%and 99.8% over 400 cycles under-20℃ and 45℃.

Characteristics of fluidization and dry-beneficiation of a wide-size-range medium-solids fluidized bed

Wide-size-range medium-solids are used in a modularized coal beneficiation demonstration system with a gas-solid fluidized bed. The characteristics of fluidization and dry-beneficiation of the medium solids were studied. The numerical simulation results show that 0.15–0.06 mm fine magnetite powder can decrease the disturbances caused by the bubbles. This is beneficial to the uniformity of the gas-solid interactions and thus to the uniformity and stability of the bed density and height. The experimental results show that, with an increase in the fine coal content in medium solids, both the fluidization quality and the beneficiation performance of the bed decreased gradually. When the fine coal content was no more than 13%, a relatively high superficial gas velocity increased the beneficiation efficiency. When the content was more than 13%, part of the fine coal was separated, leading to product layers. The separation efficiency was therefore gradually decreased. The models for predicting the bed density standard deviation and the probable error, E, value were both proposed. The E value can reach to 0.04–0.07 g/cm^3 under the optimized experimental parameters. This work provides a foundation for the adjustment of the bed density and the separation performance of the modularized 40–60 ton per hour dry coalbeneficiation industrial system.

Supercapacitor electrode based on few-layer h-BNNSs/rGO composite for wide-temperature-range operation with robust stable cycling performance

Currently,developing supercapacitors with robust cycle stability and suitability for wide-temperature-range operations is still a huge challenge.In the present work,few-layer hexagonal boron nitride nanosheets(h-BNNSs)with a thickness of 2−4 atomic layers were fabricated via vacuum freeze-drying and nitridation.Then,the h-BNNSs/reduced graphene oxide(rGO)composite were further prepared using a hydrothermal method.Due to the combination of two two-dimensional(2D)van der Waals-bonded materials,the as-prepared h-BNNSs/rGO electrode exhibited robustness to wide-temperature-range operations from−10 to 50℃.When the electrodes worked in a neutral aqueous electrolyte(1 M Na2SO4),they showed a great stable cycling performance with almost 107%reservation of the initial capacitance at 0℃ and 111% at 50℃ for 5000 charge−discharge cycles.

Investigation of an Intensifying-flux Variable Flux-leakage Interior Permanent Magnet Machine for Wide Speed Range

In this paper,a novel intensifying-flux variable flux-leakage interior permanent magnet(IFVF-IPM)machine is proposed,in which flux barriers were designed deliberately between the adjacent poles to obtain intensifying-flux effect and variable flux-leakage property.The rotor topology and design principles of the proposed machine are also introduced.Then,a multi-objective optimization method is adopted based on the sensitivity analysis,and some design variables of IFVF-IPM machine with strong sensitivity are selected to optimization progress by using the non-dominated sorting genetic algorithm-Ⅱ(NSGA-Ⅱ).Moreover,the electromagnetic characteristics of conventional IPM machine,conventional IFVF-IPM machine(CIFVF-IPM)and the novel IFVF-IPM machine are compared based on the finite element analysis(FEA)method which includes flux linkage,inductances characteristic,torque-speed envelops and power characteristic,as well as evaluation of the risk of irreversible demagnetization.Finally,the experiment results show that the IFVF-IPM machine has a better performance in flux weakening capability for wide speed range and a lower risk of irreversible demagnetization,which indicates the validity and feasibility of the proposed machine.

Design of scale model of plate-shaped absorber in a wide frequency range

In order to design the scale model in a wide frequency range,a method based on the reflective loss is proposed according to the high-frequency approximation algorithm,and an example of designing the scale model of a plate-shaped absorber is given in this paper.In the example,the frequency of the full-size measurement ranges from 2.0 GHz to 2.4 GHz,the thickness of the full-size absorber is 1 mm and the scale ratio is 1/5.A two-layer scale absorber is obtained by the proposed method.The thickness values of the bottom and top layer are 0.4 mm and 0.5 mm,respectively.Furthermore,the scattering properties of a plate model and an SLICY model are studied by FEKO to verify the effectiveness of the designed scale absorber.Compared with the corresponding values from the theoretical scale model,the average values of the absolute deviations in 10 GHz～12 GHz are 0.53 d Bm^2,0.65 d Bm^2,0.76 d Bm^2 for the plate model and 0.20 d Bm^2,0.95 d Bm^2,0.77 d Bm^2 for the SLICY model while the incident angles are 0°,30°,and 60°,respectively.These deviations fall within the Radar cross section（RCS） measurement tolerance.Thus,the work in this paper has important theoretical and practical significance.

A novel wide-range precision instrument for measuring three-dimensional surface topography

We developed a measuring instrument that had wide range, high precision, small measuring touch force. The instrument for three-dimensional (3D) surface topography measurement was composed of a high precision displacement sensor based on the Michelson interference principle, a 3D platform based on vertical scanning, a measuring and control circuit, and an industrial control computer. It was a closed loop control system, which changed the traditional moving stylus scanning style into a moving platform scanning style. When the workpiece was measured, the lever of the displacement sensor returned to the balanced position in every sample interval according to the zero offset of the displacement sensor. The non-linear error caused by the rotation of the lever was, therefore, very small even if the measuring range was wide. The instrument can measure the roughness and the profile size of a curved surface.

A Novel Method of Auxiliary Power Supply Used in Wide-Range High Voltage Input DC-DC Converter

In high voltage input DC-DC converter, auxiliary winding of isolation transformer is usually used to supply power for control circuit. Due to the wide-range of input voltage, the variable output voltage of auxiliary winding will cause a series of problems, such as variable drive pulse amplitude, increased driver switching devices loss and drive transformer core saturation. This paper analyzes the influence of variable output voltage of auxiliary winding in detail. A novel method is proposed to solve the problem of large variation range of auxiliary winding output voltage, which is adding a buck converter between the auxiliary winding and the control circuit. A dual switch forward convert has been designed with 300 V - 800 V input and 24 V/5 A output. The results show that this method is effective by comparing the different results of using buck converter or not.

Design of a Bandgap Reference with a Wide Supply Voltage Range

An on-chip voltage reference with a wide supply voltage range is required by some applications,especially that of power management （PM） controller chips applied to telecommunication, automotive, lighting equipment, etc., when high power supply voltage is needed. Accordingly,a new bandgap reference with a wide supply voltage range is proposed. Due to the improved structure,it features a high power supply rejection ratio （PSRR） and high temperature stability. In addition, an auxiliary micro-power reference is introduced to support the sleep mode of the PM chip and reduce its standby power consumption. The auxiliary reference provides bias currents in normal mode and a 1.28V reference voltage in sleep mode to replace the main reference and save power. Simulation results show that the reference provides a reference volt- age of 1.27V,which has a 3.5mV drift over the temperature range from -20 to 120~C and 56t^V deviation over a supply voltage range from 3 to 40V. The PSRR is higher than 100dB for frequency below 10kHz. The circuit was completed in 1.5tzm BCD （Bipolar-CMOS-DMOS） technology. The experimental results show that all main expectations are achieved.

A Fast Acquisition PLL with Wide Tuning Range

We present a design for an adaptive gain phase-locked loop （PLL） that features fast acquisition,low jitter,and wide tuning range. A dual-edge-triggered phase frequency detector （PFD） and a self-regulated voltage controlled oscillator （VCO） are employed in this design to realize the aforementioned properties. Measured results show that the experimental chip, implemented in a standard 0.5μm 5V CMOS logic process, has an acquisition time of about 150ns at 37% frequency variation and an output RMS jitter of 39ps at 640MHz.（dual-edge-triggered phase frequency detector）

Bioinspired flexible piezoresistive sensor for high-sensitivity detection of broad pressure range

The human skin has the ability to sense tactile touch and a great range of pressures.Therefore,in prosthetic or robotic systems,it is necessary to prepare pressure sensors with high sensitivity in a wide measurement range to provide human-like tactile sensation.Herein,we developed a flexible piezoresistive pressure sensor that is highly sensitive in a broad pressure range by using lotus leaf micropatterned polydimethylsiloxane and multilayer superposition.By superposing four layers of micropatterned constructive substrates,the multilayer piezoresistive pressure sensor achieves a broad pressure range of 312 kPa,a high sensitivity of 2.525 kPa^(−1),a low limit of detection(LOD)of<12 Pa,and a fast response time of 45 ms.Compared with the traditional flexible pressure sensor,the pressure range of this sensor can be increased by at least an order of magnitude.The flexible piezoresistive pressure sensor also shows high robustness:after testing for at least 1000 cycles,it shows no sign of fatigue.More importantly,these sensors can be potentially applied in various human motion detection scenarios,including tiny pulse monitoring,throat vibration detection,and large under-feet pressure sensing.The proposed fabrication strategy may guide the design of other kinds of multifunctional sensors to improve the detection performance.

Wide speed range for traction motor in braking force of electric braking control system

A vehicle stopping method using an electric brake until a traction motor is stopped is studied. At the moment of vehicle stop, electric brake is changed to control mode where torque is reduced at a low speed. Gradient is controlled by estimating the load torque of motor, thereby traction motor is not rotated after stop. In addition, coasting operation and brake test are performed from normal-opposite operation and start using a small-scale model comprising the inertial load equipment and the power converter. Further, traction motor is made to be equipped with a suspension torque. Pure electric braking that makes traction motor stop by an air brake at the time of stop is also implemented. Constant torque range and constant power range are expanded during braking so that braking force is secured with the electric brakes even in high speed region. Therefore, vehicle reduction effect can be expected by reducing parts related with an air brake which is not used frequently by using a pure electric brake in the M car in wide speed region. Further, maintenance of brake system can be reduced. Besides, ride comfort of passenger in the electric rail car, energy efficiency improvement, and noise reduction effect can be additionally expected. Further, an improved brake method that uses only an electric brake till motor stop is proposed by comparing those in the blending brake that uses an air brake while reducing brake torque at vehicle stop.

A Uniform Reference Line Based Differential Phase Shifter with Wide Phase Range and Wide Bandwidth

To implement the multi-way phase shifting maintaining the compact size and simplicity in structure,the uniform reference line concept was proposed for the differential phase shifter.However,the performance in bandwidth and phase range deteriorates with the additional requirements considered.To solve this problem,a quarter wavelength coupled line section loaded with open/short stubs is proposed as the basic element to implement the main line and also reference line.According to the theoretical analysis on this basic element,the loading stubs can be used to control the phase shift and also the phase slope of the basic element without affecting the amplitude property.With the predetermined parameters of the uniform reference line,only two parameters are required for the implementation of different differential phase shifts.This demonstrates the high simplicity of the proposed structure.For demonstration,an eight-way differential phase shifter operating at 3.5 GHz was implemented using the vertically installed planar structure.The prototype was further fabricated and measured.Good agreement between simulation and measurement can be observed.The implemented phase shifter can provide a wide range of phase shifting values from 45°to 315°with reference to the uniform reference line over a relative bandwidth of 62.3%.

A NEW SOLVENT POLYMERIC MEMBRANE pH SENSOR WITH WIDE LINEAR pH RANGE

A new solvent polymeric membrane (SPM)pH2sensor based on 4,4'-bis (N, N-didecylamino)methyl)azobenzene as neutral carricr has been reported. It has excellent pH response characteristics with the linear response range (1.7—13.2)much wider than that of similar SPM pH sensors reported so far. The sensor has a theoretical Nernstian response of 57.4+0.2V/pH(at 20℃)without super—Nernstian response phenomenon.