In this paper,a fault-tolerance wide voltage conversion gain DC/DC converter for More Electric Aircraft(MEA)is proposed.The proposed converter consists of a basic Cuk converter module and n expandable units.By adjusti...In this paper,a fault-tolerance wide voltage conversion gain DC/DC converter for More Electric Aircraft(MEA)is proposed.The proposed converter consists of a basic Cuk converter module and n expandable units.By adjusting the operation state of the expandable units,the voltage conversion gain of the proposed converter could be regulated,which makes it available for wide voltage conversion applications.Especially,since mutual redundancy can be realized between the basic Cuk converter module and the expandable units,the converter can continuously work when an unpredictable fault occurs to the fault-tolerant parts of the proposed converter,which reflects the fault tolerance of the converter and significantly improves the reliability of the system.Moreover,the advantages of small input current ripple,automatic current sharing and low voltage stress are also integrated in this converter.The working principle and features of the proposed converter are mainly introduced,and an experimental prototype with 800 W output power has been manufactured to verify the practicability and availability of the proposed converter.展开更多
A design for a CMOS frontend integrated circuit (chip) for neural signal acquisition working at wide voltage supply range is presented in this paper. The chip consists of a preamplifier, a serial instrumental amplif...A design for a CMOS frontend integrated circuit (chip) for neural signal acquisition working at wide voltage supply range is presented in this paper. The chip consists of a preamplifier, a serial instrumental amplifier (IA) and a cyclic analog-to-digital converter (CADC). The capacitive-coupled and capacitive-feedback topology combined with MOS-bipolar pseudo-resistor element is adopted in the preamplifier to create a -3 dB upper cut-off frequency less than 1 Hz without using a ponderous discrete device. A dual-amplifier instrumental amplifier is used to provide a low output impedance interface for ADC as well as to boost the gain. The preamplifier and the serial instrumental amplifier together provide a midband gain of 45.8 dB and have an input-referred noise of 6.7 μVrms integrated from 1 Hz to 5 kHz. The ADC digitizes the amplified signal at 12-bits precision with a highest sampling rate of 130 kS/s. The measured effective number of bits (ENOB) of the ADC is 8.7 bits. The entire circuit draws 165 to 216 μA current from the supply voltage varied from 1.34 to 3.3 V. The prototype chip is fabricated in the 0.18-μm CMOS process and occupies an area of 1.23 mm2 (including pads). In-vitro recording was successfully carried out by the proposed frontend chip.展开更多
Ultrafast-charging energy storage devices are attractive for powering personal electronics and electric vehicles.Most ultrafast-charging devices are made of carbonaceous materials such as chemically converted graphene...Ultrafast-charging energy storage devices are attractive for powering personal electronics and electric vehicles.Most ultrafast-charging devices are made of carbonaceous materials such as chemically converted graphene and carbon nanotubes.Yet,their relatively low electrical conductivity may restrict their performance at ultrahigh charging rate.Here,we report the fabrication of a porous titanium nitride(TiN)paper as an alternative electrode material for ultrafast-charging devices.The TiN paper shows an excellent conductivity of 3.67×104 S m−1,which is considerably higher than most carbon-based electrodes.The paper-like structure also contains a combination of large pores between interconnected nanobelts and mesopores within the nanobelts.This unique electrode enables fast charging by simultaneously providing efficient ion diffusion and electron transport.The supercapacitors(SCs)made of TiN paper enable charging/discharging at an ultrahigh scan rate of 100 V s−1 in a wide voltage window of 1.5 V in Na2SO4 neutral electrolyte.It has an outstanding response time with a characteristic time constant of 4 ms.Significantly,the TiN paper-based SCs also show zero capacitance loss after 200,000 cycles,which is much better than the stability performance reported for other metal nitride SCs.Furthermore,the device shows great promise in scalability.The filtration method enables good control of the thickness and mass loading of TiN electrodes and devices.展开更多
Supercapacitors(SCs)are emerging as efficient energy storage devices but still suffering from limited energy density compared with batteries.Electrolytes have been regarded as the key to determine the energy storage p...Supercapacitors(SCs)are emerging as efficient energy storage devices but still suffering from limited energy density compared with batteries.Electrolytes have been regarded as the key to determine the energy storage performance of SCs.However,none of the conventional electrolytes can fully meet the increasing requirements of SCs in terms of high ion conductivity,excellent stability,wide voltage window and operating temperature range,as well as environmentally friend concerns.To this end,hybrid electrolytes have sprung up in recent years,which are believed to be the candidate to solve these shortcomings.Herein,the state-of-the-art types of hybrid electrolytes for SCs,including the combination of aqueous and organic,aqueous and gel polymer,ionic liquids(ILs)and organic,and ILs and gel polymer hybrid electrolytes,are reviewed.The effects of different hybrid systems on the performance of SCs and the underlying mechanisms are among the focal points of the review,and prospects and possible directions are discussed as well to provide further insight into the future development of this field.展开更多
Ternary and quadruple lithium silicon nitride anode materials for lithium ion batteries with different precursors were prepared by the simple process of high-energy ball milling. High capacity and excellent cyclabilit...Ternary and quadruple lithium silicon nitride anode materials for lithium ion batteries with different precursors were prepared by the simple process of high-energy ball milling. High capacity and excellent cyclability were obtained. The influence of precursor introduction on the electrochemical performance of products was investigated. This research reveals that the electrochemical performance of lithium silicon hitilde can be enhanced significantly by doping O. The cyclability of quadruple lithium silicon nitfide can be optimized remarkably by controlling the introduction quantity of the precursors. It is possible for the composite to be used as a capacity compensator within a wide voltage cut-off window.展开更多
This paper proposes a new variable-mode control strategy that is applicable for LLC resonant converters operating in a wide input voltage range. This control strategy incorporates advantages from full-bridge LLC reson...This paper proposes a new variable-mode control strategy that is applicable for LLC resonant converters operating in a wide input voltage range. This control strategy incorporates advantages from full-bridge LLC resonant converters, half-bridge LLC resonant converters, variable-frequency control mode, and phase-shift control mode. Under this control strategy, different input voltages determine the different operating modes of the circuit. When the input voltage is very low, it works in a full-bridge circuit and variable frequency mode(FB_VF mode). When the input voltage rises to a certain level, it shifts to a full-bridge circuit and phase-shifting control mode(FB_PS mode). When the input voltage further increases, it shifts into a half-bridge circuit and variable frequency mode(HB_VF mode). Such shifts are enabled by the digital signal processor(DSP), which means that no auxiliary circuit is needed, just a modification of the software. From light load to heavy load, the primary MOSFET for the LLC resonant converter can realize zero-voltage switching(ZVS), and the secondary rectifier diode can realize zero-current switching(ZCS). With an LLC resonant converter prototype with a 300 W rated power and a 450 V output voltage, as well as a resonant converter with 20–120 V input voltage, the experiments verified the proposed control strategy. Experimental results showed that under this control strategy, the maximum converter efficiency reaches 95.7% and the range of the input voltage expands threefold.展开更多
The combination of high-voltage windows and bending stability remains a challenge for supercapacitors.Here,we present an“advantage-complementary strategy”using sodium lignosulfonate as a pseudocapacitive molecule to...The combination of high-voltage windows and bending stability remains a challenge for supercapacitors.Here,we present an“advantage-complementary strategy”using sodium lignosulfonate as a pseudocapacitive molecule to regulate the spatial stacking pattern of graphene oxide and the interfacial architectures of graphene oxide and polyaniline.Flexible and sustainable sodium lignosulfonate-based electrodes are successfully developed,showing perfect bending stability and high electronic conductivity and specific capacitance(521 F·g^(−1)at 0.5 A·g^(−1)).Due to the resulting rational interfacial structure and stable ion-electron transport,the asymmetric supercapacitors provide a wide voltage window reaching 1.7 V,outstanding bending stability and high energy-power density of 83.87 Wh·kg^(−1)at 3.4 kW·kg^(−1).These properties are superior to other reported cases of asymmetric energy enrichment.The synergistic strategy of sodium lignosulfonate on graphene oxide and polyaniline is undoubtedly beneficial to advance the process for the construction of green flexible supercapacitors with remarkably wide voltage windows and excellent bending stability.展开更多
从储能器件应用前景来看,正负两极使用同一前驱体来制备可以简化工艺过程,显著降低储能器件的成本.在本论文中,我们由单一前驱体——石油焦来制备活性材料并将其组装成了双碳基锂离子电容器.对于负极,通过简单的球磨和碳化工艺制备了石...从储能器件应用前景来看,正负两极使用同一前驱体来制备可以简化工艺过程,显著降低储能器件的成本.在本论文中,我们由单一前驱体——石油焦来制备活性材料并将其组装成了双碳基锂离子电容器.对于负极,通过简单的球磨和碳化工艺制备了石油焦衍生碳(PCC样品),该碳材料具有较大的压实密度(1.80 g cm^(-3))和高电导率(11.5 S cm^(-1)).对于正极,前驱体经氢氧化钾活化(PC-AC样品),获得了良好的孔隙结构,以满足快速电容行为.结果表明,在宽电压窗口下,组装的双碳基锂离子电容器具有良好的结构稳定性,高能量密度(231 W h kg^(-1)/206 W h L^(-1))和超长循环寿命(高达10,000次循环).石油焦衍生的碳材料具有良好的电化学响应性和简单的生产工艺,因而实际应用潜力巨大.展开更多
基金supported by the National Natural Science Foundation of China(No.51707103)the Hubei Provincial Key Laboratory on Operation and Control of Cascaded Hydropower Station,China(No.2022KJX08).
文摘In this paper,a fault-tolerance wide voltage conversion gain DC/DC converter for More Electric Aircraft(MEA)is proposed.The proposed converter consists of a basic Cuk converter module and n expandable units.By adjusting the operation state of the expandable units,the voltage conversion gain of the proposed converter could be regulated,which makes it available for wide voltage conversion applications.Especially,since mutual redundancy can be realized between the basic Cuk converter module and the expandable units,the converter can continuously work when an unpredictable fault occurs to the fault-tolerant parts of the proposed converter,which reflects the fault tolerance of the converter and significantly improves the reliability of the system.Moreover,the advantages of small input current ripple,automatic current sharing and low voltage stress are also integrated in this converter.The working principle and features of the proposed converter are mainly introduced,and an experimental prototype with 800 W output power has been manufactured to verify the practicability and availability of the proposed converter.
基金Project supported by the National Natural Science Foundation of China(Nos.61474107,61372060,61335010,61275200,61178051)the Key Program of the Chinese Academy of Sciences(No.KJZD-EW-L11-01)
文摘A design for a CMOS frontend integrated circuit (chip) for neural signal acquisition working at wide voltage supply range is presented in this paper. The chip consists of a preamplifier, a serial instrumental amplifier (IA) and a cyclic analog-to-digital converter (CADC). The capacitive-coupled and capacitive-feedback topology combined with MOS-bipolar pseudo-resistor element is adopted in the preamplifier to create a -3 dB upper cut-off frequency less than 1 Hz without using a ponderous discrete device. A dual-amplifier instrumental amplifier is used to provide a low output impedance interface for ADC as well as to boost the gain. The preamplifier and the serial instrumental amplifier together provide a midband gain of 45.8 dB and have an input-referred noise of 6.7 μVrms integrated from 1 Hz to 5 kHz. The ADC digitizes the amplified signal at 12-bits precision with a highest sampling rate of 130 kS/s. The measured effective number of bits (ENOB) of the ADC is 8.7 bits. The entire circuit draws 165 to 216 μA current from the supply voltage varied from 1.34 to 3.3 V. The prototype chip is fabricated in the 0.18-μm CMOS process and occupies an area of 1.23 mm2 (including pads). In-vitro recording was successfully carried out by the proposed frontend chip.
基金supported by Merced nAnomaterials Center for Energy and Sensing (MACES), a NASA funded MIRO center, under award NNX15AQ01supported by the US NSF MRI grant, MRI-1126845)
文摘Ultrafast-charging energy storage devices are attractive for powering personal electronics and electric vehicles.Most ultrafast-charging devices are made of carbonaceous materials such as chemically converted graphene and carbon nanotubes.Yet,their relatively low electrical conductivity may restrict their performance at ultrahigh charging rate.Here,we report the fabrication of a porous titanium nitride(TiN)paper as an alternative electrode material for ultrafast-charging devices.The TiN paper shows an excellent conductivity of 3.67×104 S m−1,which is considerably higher than most carbon-based electrodes.The paper-like structure also contains a combination of large pores between interconnected nanobelts and mesopores within the nanobelts.This unique electrode enables fast charging by simultaneously providing efficient ion diffusion and electron transport.The supercapacitors(SCs)made of TiN paper enable charging/discharging at an ultrahigh scan rate of 100 V s−1 in a wide voltage window of 1.5 V in Na2SO4 neutral electrolyte.It has an outstanding response time with a characteristic time constant of 4 ms.Significantly,the TiN paper-based SCs also show zero capacitance loss after 200,000 cycles,which is much better than the stability performance reported for other metal nitride SCs.Furthermore,the device shows great promise in scalability.The filtration method enables good control of the thickness and mass loading of TiN electrodes and devices.
基金financial support from the National Natural Science Foundation of China(21671173)Zhejiang Provincial Ten Thousand Talent Program(2017R52043)。
文摘Supercapacitors(SCs)are emerging as efficient energy storage devices but still suffering from limited energy density compared with batteries.Electrolytes have been regarded as the key to determine the energy storage performance of SCs.However,none of the conventional electrolytes can fully meet the increasing requirements of SCs in terms of high ion conductivity,excellent stability,wide voltage window and operating temperature range,as well as environmentally friend concerns.To this end,hybrid electrolytes have sprung up in recent years,which are believed to be the candidate to solve these shortcomings.Herein,the state-of-the-art types of hybrid electrolytes for SCs,including the combination of aqueous and organic,aqueous and gel polymer,ionic liquids(ILs)and organic,and ILs and gel polymer hybrid electrolytes,are reviewed.The effects of different hybrid systems on the performance of SCs and the underlying mechanisms are among the focal points of the review,and prospects and possible directions are discussed as well to provide further insight into the future development of this field.
基金This study is f'mancially supported by the National Natural Science Foundation of China (No.50502009)the Natural Science Foundation of Liaoning Province of China (No.20072146).
文摘Ternary and quadruple lithium silicon nitride anode materials for lithium ion batteries with different precursors were prepared by the simple process of high-energy ball milling. High capacity and excellent cyclability were obtained. The influence of precursor introduction on the electrochemical performance of products was investigated. This research reveals that the electrochemical performance of lithium silicon hitilde can be enhanced significantly by doping O. The cyclability of quadruple lithium silicon nitfide can be optimized remarkably by controlling the introduction quantity of the precursors. It is possible for the composite to be used as a capacity compensator within a wide voltage cut-off window.
基金Project supported by the National Natural Science Foundation of China(Nos.51177148 and 51407151)
文摘This paper proposes a new variable-mode control strategy that is applicable for LLC resonant converters operating in a wide input voltage range. This control strategy incorporates advantages from full-bridge LLC resonant converters, half-bridge LLC resonant converters, variable-frequency control mode, and phase-shift control mode. Under this control strategy, different input voltages determine the different operating modes of the circuit. When the input voltage is very low, it works in a full-bridge circuit and variable frequency mode(FB_VF mode). When the input voltage rises to a certain level, it shifts to a full-bridge circuit and phase-shifting control mode(FB_PS mode). When the input voltage further increases, it shifts into a half-bridge circuit and variable frequency mode(HB_VF mode). Such shifts are enabled by the digital signal processor(DSP), which means that no auxiliary circuit is needed, just a modification of the software. From light load to heavy load, the primary MOSFET for the LLC resonant converter can realize zero-voltage switching(ZVS), and the secondary rectifier diode can realize zero-current switching(ZCS). With an LLC resonant converter prototype with a 300 W rated power and a 450 V output voltage, as well as a resonant converter with 20–120 V input voltage, the experiments verified the proposed control strategy. Experimental results showed that under this control strategy, the maximum converter efficiency reaches 95.7% and the range of the input voltage expands threefold.
基金This work was supported by the Natural Science Foundation of Guangxi(Grant No.2018GXNSFBA138025)the National Natural Science Foundation of China(Grant No.32171720).
文摘The combination of high-voltage windows and bending stability remains a challenge for supercapacitors.Here,we present an“advantage-complementary strategy”using sodium lignosulfonate as a pseudocapacitive molecule to regulate the spatial stacking pattern of graphene oxide and the interfacial architectures of graphene oxide and polyaniline.Flexible and sustainable sodium lignosulfonate-based electrodes are successfully developed,showing perfect bending stability and high electronic conductivity and specific capacitance(521 F·g^(−1)at 0.5 A·g^(−1)).Due to the resulting rational interfacial structure and stable ion-electron transport,the asymmetric supercapacitors provide a wide voltage window reaching 1.7 V,outstanding bending stability and high energy-power density of 83.87 Wh·kg^(−1)at 3.4 kW·kg^(−1).These properties are superior to other reported cases of asymmetric energy enrichment.The synergistic strategy of sodium lignosulfonate on graphene oxide and polyaniline is undoubtedly beneficial to advance the process for the construction of green flexible supercapacitors with remarkably wide voltage windows and excellent bending stability.
基金financially supported by the Natural Science Foundation of Shandong Province(ZR2020MB078 and ZR2021QB085)the National Natural Science Foundation of China(51877216 and 22109178)+6 种基金Taishan Scholar Foundation(tsqn20161017)China Postdoctoral Science Foundation(2021M693498)the Postdoctoral Innovative Talent Support Program of Shandong Province(SDBX2021005)the Postdoctoral Innovation Project of Shandong Province(202101009)the Postdoctoral Applied Research Program of Qingdao(qdyy20200071)the Fundamental Research Funds for the Central Universities(19CX05001A,19CX05002A,and 20CX06101A)the Research Project of State Key Laboratory for Heavy Oil Processing(SLK-ZZKT-2021)。
文摘从储能器件应用前景来看,正负两极使用同一前驱体来制备可以简化工艺过程,显著降低储能器件的成本.在本论文中,我们由单一前驱体——石油焦来制备活性材料并将其组装成了双碳基锂离子电容器.对于负极,通过简单的球磨和碳化工艺制备了石油焦衍生碳(PCC样品),该碳材料具有较大的压实密度(1.80 g cm^(-3))和高电导率(11.5 S cm^(-1)).对于正极,前驱体经氢氧化钾活化(PC-AC样品),获得了良好的孔隙结构,以满足快速电容行为.结果表明,在宽电压窗口下,组装的双碳基锂离子电容器具有良好的结构稳定性,高能量密度(231 W h kg^(-1)/206 W h L^(-1))和超长循环寿命(高达10,000次循环).石油焦衍生的碳材料具有良好的电化学响应性和简单的生产工艺,因而实际应用潜力巨大.