Carbon materials were prepared using mesoporous silica HMS with different pore sizes as the hard templates and water-soluble phenolic resin as the carbon source. The obtained materials were characterized by powder X-r...Carbon materials were prepared using mesoporous silica HMS with different pore sizes as the hard templates and water-soluble phenolic resin as the carbon source. The obtained materials were characterized by powder X-ray diffraction, transmission electron microscopy and N2 physical adsorption, and were used in adsorptive desulfurization. It has been shown that the carbon material prepared using HMS with larger pore size (〉3 nm) presented uniform wormlike mesopore of 2.3 nm and large BET surface area (1903 m2/g). The mesoporous carbon was an excellent adsorbent to remove the refractory sulfur compound in diesel, especially dibenzothiophene and 4, 6-dimethyldibenzothiophene.展开更多
基金sponsored by the Foundation for the Author of National Excellent Doctoral Dissertation of PR China (NO.200346)Program for New Century Excellent Talents in University (NCET-04-0270)National Natural Science Foundation of China (NO.20406005)
文摘Carbon materials were prepared using mesoporous silica HMS with different pore sizes as the hard templates and water-soluble phenolic resin as the carbon source. The obtained materials were characterized by powder X-ray diffraction, transmission electron microscopy and N2 physical adsorption, and were used in adsorptive desulfurization. It has been shown that the carbon material prepared using HMS with larger pore size (〉3 nm) presented uniform wormlike mesopore of 2.3 nm and large BET surface area (1903 m2/g). The mesoporous carbon was an excellent adsorbent to remove the refractory sulfur compound in diesel, especially dibenzothiophene and 4, 6-dimethyldibenzothiophene.